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  • Article
  • Open Access
40 Citations
4,036 Views
20 Pages

Stages in the Dynamics of Hydrate Formation and Consequences for Design of Experiments for Hydrate Formation in Sediments

  • Bjørn Kvamme,
  • Richard B. Coffin,
  • Jinzhou Zhao,
  • Na Wei,
  • Shouwei Zhou,
  • Qingping Li,
  • Navid Saeidi,
  • Yu-Chien Chien,
  • Derek Dunn-Rankin and
  • Mojdeh Zarifi
  • + 1 author

3 September 2019

Natural gas hydrates in sediments can never reach thermodynamic equilibrium. Every section of any hydrate-filled reservoir is unique and resides in a stationary balance that depends on many factors. Fluxes of hydrocarbons from below support formation...

  • Article
  • Open Access
35 Citations
3,497 Views
19 Pages

18 March 2019

The international interest in the energy potential related to the huge amounts of methane trapped in the form of hydrates is rapidly increasing. Unlike conventional hydrocarbon sources these natural gas hydrate deposits are widely spread around the w...

  • Review
  • Open Access
53 Citations
9,066 Views
44 Pages

Towards Gas Hydrate-Free Pipelines: A Comprehensive Review of Gas Hydrate Inhibition Techniques

  • Salma Elhenawy,
  • Majeda Khraisheh,
  • Fares Almomani,
  • Mohammad A. Al-Ghouti,
  • Mohammad K. Hassan and
  • Ala’a Al-Muhtaseb

15 November 2022

Gas hydrate blockage is a major issue that the production and transportation processes in the oil/gas industry faces. The formation of gas hydrates in pipelines results in significant financial losses and serious safety risks. To tackle the flow assu...

  • Article
  • Open Access
39 Citations
3,839 Views
12 Pages

Tri-Axial Shear Tests on Hydrate-Bearing Sediments during Hydrate Dissociation with Depressurization

  • Dongliang Li,
  • Qi Wu,
  • Zhe Wang,
  • Jingsheng Lu,
  • Deqing Liang and
  • Xiaosen Li

11 July 2018

A series of tri-axial shear tests were carried out to determine the stress and strain characteristics, as well as the volume deformation of methane hydrate-bearing sediments during gas hydrate dissociation. An innovative type of depressurization was...

  • Article
  • Open Access
14 Citations
2,584 Views
21 Pages

3 February 2021

Natural gas hydrate is a new clean energy source in the 21st century, which has become a research point of the exploration and development technology. Acoustic well logs are one of the most important assets in gas hydrate studies. In this paper, an i...

  • Article
  • Open Access
43 Citations
7,153 Views
11 Pages

Combustion Characteristics of Methane Hydrate Flames

  • Yu-Chien Chien and
  • Derek Dunn-Rankin

21 May 2019

This research studies the structure of flames that use laboratory-produced methane hydrates as fuel, specifically for the purpose of identifying their key combustion characteristics. Combustion of a methane hydrate involves multiple phase changes, as...

  • Article
  • Open Access
14 Citations
3,327 Views
12 Pages

25 November 2019

The effect of kinetic hydrate inhibitors (KHIs) on the growth of methane hydrate in the gas–liquid phase separation state is studied at the molecular level. The simulation results show that the kinetic inhibitors, named PVP and PVP-A, show good...

  • Article
  • Open Access
6 Citations
1,926 Views
27 Pages

The effectiveness of horizontal well drilling in improving the gas recovery efficiency of hydrate production makes it a promising technology for commercial exploitation. However, during horizontal well drilling in hydrate reservoirs, it is crucial to...

  • Article
  • Open Access
5 Citations
2,317 Views
29 Pages

29 April 2022

The process of drilling in natural gas hydrate reservoirs in sea areas involves problems such as hydrate decomposition and wellbore instability. To study the response behaviors of a reservoir during the drilling process, a two-dimensional numerical m...

  • Article
  • Open Access
1 Citations
1,438 Views
20 Pages

The inversion of gas hydrate saturation is a critical procedure in the evaluation of hydrate reservoirs. In this paper, a theoretical model for a borehole acoustic wavefield excited by multipole sources is established for the first time. On this basi...

  • Feature Paper
  • Article
  • Open Access
37 Citations
7,562 Views
26 Pages

Enthalpies of Hydrate Formation and Dissociation from Residual Thermodynamics

  • Solomon Aforkoghene Aromada,
  • Bjørn Kvamme,
  • Na Wei and
  • Navid Saeidi

11 December 2019

We have proposed a consistent thermodynamic scheme for evaluation of enthalpy changes of hydrate phase transitions based on residual thermodynamics. This entails obtaining every hydrate property such as gas hydrate pressure-temperature equilibrium cu...

  • Article
  • Open Access
11 Citations
2,133 Views
12 Pages

Experimental Investigation into Three-Dimensional Spatial Distribution of the Fracture-Filling Hydrate by Electrical Property of Hydrate-Bearing Sediments

  • Jinhuan Zhao,
  • Changling Liu,
  • Qiang Chen,
  • Changchun Zou,
  • Yang Liu,
  • Qingtao Bu,
  • Jiale Kang and
  • Qingguo Meng

12 May 2022

As a future clean energy resource, the exploration and exploitation of natural gas hydrate are favorable for solving the energy crisis and improving environmental pollution. Detecting the spatial distribution of natural gas hydrate in the reservoir i...

  • Article
  • Open Access
2 Citations
3,077 Views
19 Pages

Coupled Simulation of Hydrate-Bearing and Overburden Sedimentary Layers to Study Hydrate Dissociation and Methane Leakage

  • Yan Xie,
  • Jingchun Feng,
  • Liwei Sun,
  • Junwen Wang,
  • Weiqiang Hu,
  • Bo Peng,
  • Yujun Wang and
  • Yi Wang

Methane leakage during natural gas hydrate (NGH) exploitation is one of the important challenges restricting its safe development, which necessitates further investigation. However, only a few experimental studies have been conducted to characterize...

  • Article
  • Open Access
5 Citations
2,410 Views
21 Pages

Hydrate distribution heterogeneity is often observed in natural and artificial hydrate-bearing sediments (HBSs). To capture hydrate distribution heterogeneity, a pore-scale method is proposed to model cemented HBSs using the discrete element method (...

  • Article
  • Open Access
3 Citations
2,710 Views
11 Pages

Thermal Conductivity Variations in Frozen Hydrate-Bearing Sand upon Heating and Dissociation of Pore Gas Hydrate

  • Evgeny Chuvilin,
  • Dinara Davletshina,
  • Boris Bukhanov,
  • Sergey Grebenkin and
  • Elena Pankratova

19 October 2023

High-latitude permafrost, including hydrate-bearing frozen ground, changes its properties in response to natural climate change and to impacts from petroleum production. Of special interest is the behavior of thermal conductivity, one of the key para...

  • Article
  • Open Access
6 Citations
3,879 Views
16 Pages

Formation Kinetics Evaluation for Designing Sustainable Carbon Dioxide-Based Hydrate Desalination via Tryptophan as a Biodegradable Hydrate Promotor

  • Muhammad Saad Khan,
  • Bhajan Lal,
  • Hani Abulkhair,
  • Iqbal Ahmed,
  • Azmi Mohd Shariff,
  • Eydhah Almatrafi,
  • Abdulmohsen Alsaiari and
  • Omar Bamaga

1 January 2023

Desalination using hydrates is a developing field, and initial research promises a commercially feasible approach. The current study proposes the natural amino acid, namely tryptophan, as a biodegradable gas hydrate promotor for desalination applicat...

  • Article
  • Open Access
9 Citations
2,613 Views
29 Pages

23 January 2023

There is an international consensus that reductions of CO2 emissions are needed in order to reduce global warming. So far, underground aquifer storage of CO2 is the only commercially active option, and it has been so since 1996, when STAOIL started i...

  • Article
  • Open Access
15 Citations
2,100 Views
17 Pages

Production Behavior of Hydrate-Bearing Sediments with Mixed Fracture- and Pore-Filling Hydrates

  • Yaobin Li,
  • Xin Xin,
  • Tianfu Xu,
  • Yingqi Zang,
  • Zimeng Yu,
  • Huixing Zhu and
  • Yilong Yuan

Most hydrate-bearing sediments worldwide exhibit mixed pore- and fracture-filling hydrates. Due to the high exploitation value, pore-filling hydrate production is the focus of current hydrate production research, and there is a lack of systematic res...

  • Review
  • Open Access
12 Citations
3,579 Views
15 Pages

Review of Biosurfactants Gas Hydrate Promoters

  • Cornelius B. Bavoh,
  • Eric Broni-Bediako and
  • Solomon Adjei Marfo

8 August 2023

Biosurfactants are promising additives for gas hydrate technology applications. They are believed to have better eco properties than conventional kinetic hydrate promoters such as sodium dodecyl sulfate (SDS). In this article, the research advances o...

  • Article
  • Open Access
29 Citations
3,709 Views
14 Pages

12 July 2019

The effects of sediments with different clay contents on the mechanical properties of hydrate deposits were studied using a high-pressure, low-temperature triaxial apparatus with in-situ synthesis, as well as the mechanical properties of self-develop...

  • Article
  • Open Access
5 Citations
2,870 Views
16 Pages

29 May 2022

Depressurization combined with brine injection is a potential method for field production of natural gas hydrate, which can significantly improve production efficiency and avoid secondary formation of hydrate. In this work, the experiments of hydrate...

  • Article
  • Open Access
23 Citations
3,794 Views
15 Pages

Influence of Water Saturation, Grain Size of Quartz Sand and Hydrate-Former on the Gas Hydrate Formation

  • Yulia Zaripova,
  • Vladimir Yarkovoi,
  • Mikhail Varfolomeev,
  • Rail Kadyrov and
  • Andrey Stoporev

25 February 2021

The development of technologies for the accelerated formation or decomposition of gas hydrates is an urgent topic. This will make it possible to utilize a gas, including associated petroleum one, into a hydrate state for its further use or to produce...

  • Article
  • Open Access
5 Citations
2,748 Views
23 Pages

19 December 2022

Determining the geomechanical properties of hydrate-bearing sands (HBS), such as strength and stiffness, are critical for evaluating the potential for the economic and safe recovery of methane gas from HBS reservoirs. To date, results from numerous i...

  • Article
  • Open Access
2 Citations
2,209 Views
17 Pages

The permeability of natural gas hydrate (NGH) turbidite reservoirs typically exhibits significant anisotropy, with anisotropy being a crucial basis for evaluating reservoir production. The presence of hydrates, as a crucial constituent of the solid f...

  • Review
  • Open Access
24 Citations
6,566 Views
17 Pages

Hydrogen Hydrate Promoters for Gas Storage—A Review

  • Tinku Saikia,
  • Shirish Patil and
  • Abdullah Sultan

13 March 2023

Clathrate and semi-clathrate hydrates have recently been gaining major interest as hydrogen storage material. The benefits of hydrates, such as reversible formation and dissociation, their environmentally friendly nature, economical costs, and lower...

  • Article
  • Open Access
4 Citations
4,526 Views
17 Pages

A 3-In-1 Approach to Evaluate Gas Hydrate Inhibitors

  • Narendra Kumar,
  • Niaz Bahar Chowdhury and
  • Juan G. Beltran

29 July 2019

With a single apparatus and very short experimentation times, we have assessed phase equilibria, apparent kinetics and morphology of methane gas hydrates in the presence of thermodynamic inhibitors ethane-1,2-diol (MEG) and sodium chloride (NaCl); an...

  • Article
  • Open Access
3 Citations
1,807 Views
17 Pages

10 August 2023

The accurate prediction of wellbore temperature and pressure is important for safe drilling. However, annulus temperature and pressure changes are more complicated due to phase transition. To study this problem, a prediction model of temperature and...

  • Article
  • Open Access
20 Citations
4,032 Views
11 Pages

Experimental Investigation of Methane Hydrate Induction Time in the Presence of Cassava Peel as a Hydrate Inhibitor

  • Mazlin Idress,
  • Muhammad Afiq Shahril,
  • Ahmad Syahir Zuraidin and
  • Mazuin Jasamai

17 June 2019

The oil and gas industry faces numerous problems, from the exploration to the production phase. One of the most common problems faced by the industry is the formation of gas hydrates in the pipeline during the deep-water operation. The advancement of...

  • Article
  • Open Access
43 Citations
14,911 Views
22 Pages

Rapid Gas Hydrate Formation Processes: Will They Work?

  • Thomas D. Brown,
  • Charles E. Taylor and
  • Mark P. Bernardo

7 June 2010

Researchers at DOE’s National Energy Technology Laboratory (NETL) have been investigating the formation of synthetic gas hydrates, with an emphasis on rapid and continuous hydrate formation techniques. The investigations focused on unconventional met...

  • Feature Paper
  • Review
  • Open Access
21 Citations
5,192 Views
19 Pages

26 April 2023

Applications of clathrate hydrate require fast formation kinetics of it, which is the long-standing technological bottleneck due to mass transfer and heat transfer limitations. Although several methods, such as surfactants and mechanical stirring, ha...

  • Article
  • Open Access
169 Views
12 Pages

14 January 2026

As a future abundant and environmentally friendly clean energy source, the decomposition process of natural gas hydrates is significantly regulated by reservoir structural characteristics. Improper extraction can easily trigger geological hazards, ye...

  • Article
  • Open Access
21 Citations
3,447 Views
26 Pages

Hydrate—A Mysterious Phase or Just Misunderstood?

  • Bjørn Kvamme,
  • Jinzhou Zhao,
  • Na Wei and
  • Navid Saeidi

17 February 2020

Hydrates that form during transport of hydrocarbons containing free water, or water dissolved in hydrocarbons, are generally not in thermodynamic equilibrium and depend on the concentration of all components in all phases. Temperature and pressure ar...

  • Article
  • Open Access
16 Citations
5,052 Views
12 Pages

Anti-Agglomerator of Tetra-n-Butyl Ammonium Bromide Hydrate and Its Effect on Hydrate-Based CO2 Capture

  • Rong Li,
  • Xiao-Sen Li,
  • Zhao-Yang Chen,
  • Yu Zhang,
  • Chun-Gang Xu and
  • Zhi-Ming Xia

8 February 2018

Tetra-n-butyl ammonium bromide (TBAB) was widely used in the research fields of cold storage and CO2 hydrate separation due to its high phase change latent heat and thermodynamic promotion for hydrate formation. Agglomeration always occurred in the p...

  • Article
  • Open Access
28 Citations
2,743 Views
14 Pages

Effect of Hydrate Microscopic Distribution on Acoustic Characteristics during Hydrate Dissociation: An Insight from Combined Acoustic-CT Detection Study

  • Qingtao Bu,
  • Tongju Xing,
  • Chengfeng Li,
  • Jinhuan Zhao,
  • Changling Liu,
  • Zihao Wang,
  • Wengao Zhao,
  • Jiale Kang,
  • Qingguo Meng and
  • Gaowei Hu

Geophysical detection techniques are important methods in marine gas hydrate exploration and monitoring, because the small-scale distribution of hydrates has a large impact on the wave velocity. The acoustic response characteristics of hydrate micro-...

  • Article
  • Open Access
2 Citations
1,758 Views
21 Pages

Studying the mechanical characteristics of hydrate-bearing sediments (HBS) contributes to the comprehensive understanding of the mechanical behavior in environments with natural gas hydrate (NGH) occurrences. Simultaneously, the distribution patterns...

  • Article
  • Open Access
5 Citations
3,467 Views
13 Pages

Gas Hydrate System Offshore Chile

  • Ivan Vargas-Cordero,
  • Michela Giustiniani,
  • Umberta Tinivella,
  • Lucia Villar-Muñoz and
  • Giulia Alessandrini

30 January 2021

In recent decades, the Chilean margin has been extensively investigated to better characterize the complex geological setting through the geophysical data. The analysis of seismic lines allowed us to identify the occurrence of gas hydrates and free g...

  • Review
  • Open Access
38 Citations
10,505 Views
24 Pages

Towards Commercial Gas Production from Hydrate Deposits

  • Jill Marcelle-De Silva and
  • Richard Dawe

25 January 2011

Over the last decade global natural gas consumption has steadily increased since many industrialized countries are substituting natural gas for coal to generate electricity. There is also significant industrialization and economic growth of the heavi...

  • Article
  • Open Access
1 Citations
944 Views
19 Pages

Sedimentary Processes of Gas Hydrate-Bearing Layers in the Dongsha Area, South China Sea: Implications for Hydrate Accumulation

  • Yuhan Wang,
  • Chenyang Bai,
  • Zhe Wang,
  • Wenlin Chen,
  • Xiaolei Xu,
  • Hongyuan Xu and
  • Hongbin Wang

The methane flux in the Dongsha area in the northern South China Sea is relatively high. The results indicate the presence of both shallow and deep gas hydrate reservoirs at the Site DS-W08. The gas hydrate reservoir in this area is mainly composed o...

  • Article
  • Open Access
6 Citations
1,442 Views
19 Pages

31 October 2023

The mechanical characteristics of gas hydrate-bearing sediments (HBS) are important for evaluating reservoir stability. The interbedded formation of HBS is common in target mining reservoirs. Existing studies on the triaxial mechanical properties of...

  • Article
  • Open Access
13 Citations
2,904 Views
10 Pages

Impacts of Space Restriction on the Microstructure of Calcium Silicate Hydrate

  • Yue Zhou,
  • Zhongping Wang,
  • Zheyu Zhu,
  • Yuting Chen,
  • Linglin Xu and
  • Kai Wu

30 June 2021

The effect of hydration space on cement hydration is essential. After a few days, space restriction affects the hydration kinetics which dominate the expansion, shrinkage and creep of cement materials. The influence of space restriction on the hydrat...

  • Article
  • Open Access
2 Citations
793 Views
28 Pages

13 May 2025

The mining of CH4 hydrate through the CO2-CH4 replacement method mostly occurs within CH4 hydrate-bearing sediments. Therefore, it is crucial to investigate the replacement process on the pore scale. This study aims to explore the impacts of pore mic...

  • Article
  • Open Access
77 Citations
6,152 Views
20 Pages

17 June 2019

CH4–CO2 replacement is a carbon-negative, safer gas production technique to produce methane gas from natural gas hydrate reservoirs by injecting pure CO2 or other gas mixtures containing CO2. Laboratory-scale experiments show that this technique prod...

  • Article
  • Open Access
17 Citations
2,321 Views
20 Pages

Screening of Low-Dosage Methanol as a Hydrate Promoter

  • Jyoti Shanker Pandey,
  • Saad Khan and
  • Nicolas von Solms

18 September 2022

We report a quantitative study of the effect of low-concentration methanol (MeOH) on the formation and dissociation of hydrates based on CH4 and CO2/N2 guest molecules. The kinetic promotion and dissociation ability of MeOH is also compared with the...

  • Review
  • Open Access
9 Citations
5,036 Views
16 Pages

Surface Coatings and Treatments for Controlled Hydrate Formation: A Mini Review

  • Tausif Altamash,
  • José M. S. S. Esperança and
  • Mohammad Tariq

4 December 2021

Gas hydrates (GHs) are known to pose serious flow assurance challenges for the oil and gas industry. Neverthless, over the last few decades, gas hydrates-based technology has been explored for various energy- and environmentally related applications....

  • Article
  • Open Access
2 Citations
1,404 Views
18 Pages

A Comparative Study on Acoustic Characteristics of Methane and Tetrahydrofuran Hydrate-Bearing Sediments

  • Wengao Zhao,
  • Qingtao Bu,
  • Zihao Wang,
  • Tong Liu,
  • Qingguo Meng,
  • Yapeng Zhao and
  • Gaowei Hu

5 December 2024

Laboratory acoustic measurements of hydrate-bearing sediments serve as an important reference for the geological interpretation of seismic exploration data. Tetrahydrofuran (THF) hydrates are relatively easy to form with precise control of hydrate sa...

  • Review
  • Open Access
21 Citations
5,065 Views
23 Pages

Polysaccharides Are Effective Inhibitors of Natural Gas Hydrate Formation

  • Alsu Venerovna Fakhreeva,
  • Vasily Viktorovich Nosov,
  • Alexander Iosifovich Voloshin and
  • Vladimir Anatolyevich Dokichev

4 April 2023

This review covers the types and applications of chemical inhibitors of gas hydrate formation in the oil and gas industry. The main directions of the development of new types of highly effective and environmentally safe “green” kinetic hy...

  • Article
  • Open Access
34 Citations
3,169 Views
34 Pages

Hydrate Production Philosophy and Thermodynamic Calculations

  • Bjørn Kvamme,
  • Jinzhou Zhao,
  • Na Wei,
  • Wantong Sun,
  • Navid Saeidi,
  • Jun Pei and
  • Tatiana Kuznetsova

4 February 2020

The amount of energy in the form of natural gas hydrates is huge and likely substantially more than twice the amount of worldwide conventional fossil fuel. Various ways to produce these hydrates have been proposed over the latest five decades. Most o...

  • Article
  • Open Access
19 Citations
2,618 Views
16 Pages

21 January 2021

Natural gas hydrate (NGH) has been widely focused on having great potential for alternative energy. Numerous studies on gas production from hydrate-bearing sediments have been conducted in both laboratory and field. Since the strength of hydrate-bear...

  • Article
  • Open Access
4 Citations
2,731 Views
10 Pages

Study on the Influence of Pressure Reduction and Chemical Injection on Hydrate Decomposition

  • Lei Wang,
  • Zhikang Song,
  • Xin Huang,
  • Wenjun Xu and
  • Zhengbang Chen

29 November 2022

This study simulated seabed high pressure and low temperature conditions to synthesize natural gas hydrates, multi-stage depressurization mode mining hydrates as the blank group, and then carried out experimental research on the decomposition and min...

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