Search Results (91)

Transition metal borides have garnered significant research interest due to their versatile properties, including superconductivity and exceptional hardness. This study examines the stable crystal structures of Rhodium-Boron (Rh-B) compounds under high pressure using first-principles structural searching. Beyond the previously known Rh₂B, RhB₂, and RhB₄ phases, three new boron-rich phases—C2/m-RhB₆, Amm2-RhB₆, and Cmca-RhB₈—are identified, each characterized by three-dimensional covalent bonding networks. Their mechanical and thermodynamic stability is validated through elastic property assessments and phonon dispersion calculations. Surprisingly, these phases exhibit low bulk and shear moduli, ruling them out as candidates for hard materials. The metallic character of these borides is evident from their electronic density of states, which exhibits a sharp peak at the E_F-a signature often associated with superconducting systems. Indeed, our calculations predict T_c values of 8.93 K and 9.36 K for Amm2-RhB₆ and Cmca-RhB₈, respectively, at 100 GPa. Full article

The process of normal (N) zone propagation in three superconducting YBaCuO thin films with different Pearl length values was theoretically studied. The point appearance of the N zone was found to result from powerful energy release caused by micro-sized magnetic cumulation. Solutions of the heat equation for hot electrons, diffusing to ~15 nm depth into the edge of the Pearl length, were obtained for the two length cases. The hot electron thermalization induced a transition to N state at the aforementioned depth due to fast exceeding of T_c, followed by flash high temperature growth. In the third case, we considered a process of crack branching when the superconducting current concentrated at the tips, followed by the transition to N state caused by exceeding j_c. The superfast reaction of the superconductor allowed it to restore the energy loss at the Pearl length in all cases. This explains the step propagation process of the N zone with velocities up to 2.7 × 10³ and 1.1 × 10³ m/s in the first and second cases. In the third, the propagation can reach the detonation wave velocity of about 1 × 10⁴ m/s. It is concluded that the process of the N zone propagation has the character of a combustion wave. Full article

Recently, the quest for high-Tc superconductors has evolved from the trial-and-error methodology to the growth of nanostructured artificial high-Tc superlattices (AHTSs) with tailor-made superconducting functional properties by quantum design. Here, we report the growth by molecular beam epitaxy (MBE) of a superlattice of Mott insulator metal interfaces (MIMIs) made of nanoscale superconducting layers of quantum confined-space charge in the Mott insulator La₂CuO₄ (LCO), with thickness L intercalated by normal metal La_1.55Sr_0.45CuO₄ (LSCO) with period d. The critical temperature shows the superconducting dome with Tc as a function of the geometrical parameter L/d showing the maximum at the magic ratio L/d = 2/3 where the Fano–Feshbach resonance enhances the superconducting critical temperature. The normal state transport data of the samples at the top of the superconducting dome exhibit Planckian T-linear resistivity. For L/d > 2/3 and L/d < 2/3, the heterostructures show a resistance following Kondo universal scaling predicted by the numerical renormalization group theory for MIMI nanoscale heterostructures. We show that the Kondo temperature, T_K, and the Kondo scattering amplitude, R_0K, vanish at L/d = 2/3, while T_K and R_0K increase at both sides of the superconducting dome, indicating that the T-linear resistance regime competes with the Kondo proximity effect in the normal phase of MIMIs. Full article

The recent advancements in the field of superconductivity have been significantly driven by the development of nitride superconductors, particularly niobium nitride (NbN). Multicomponent nitrides offer a promising platform for achieving high-temperature superconductivity. Beyond their high superconducting transition temperature (Tc), niobium-based compounds are notable for their superior superconducting and mechanical properties, making them suitable for a wide range of device applications. In this work, machine learning is used to identify ternary and quaternary nitrides, which can surpass the properties of binary NbN. Specifically, Nb_0.35Ta_0.23Ti_0.42N shows an 84.95% improvement in Tc compared to base NbN, while the ternary composition Nb_0.55Ti_0.45N exhibits a 17.29% improvement. This research provides a valuable reference for the further exploration of high-temperature superconductors in diversified ternary and quaternary compositions. Full article

In our review, we analyze the scaling of the condensation energy $E_{\mathsf{\Delta }}$ divided by $\gamma$, $E_{\mathsf{\Delta }}/\gamma \simeq N\left(0\right){\mathsf{\Delta }}_1^2/\gamma$, and quasiparticles of both conventional and unconventional superconductors, where $N\left(0\right)$ is the density of states at zero temperature $T=0$, ${\mathsf{\Delta }}_1$ is the maximum value of the superconducting gap, and $\gamma$ is the Sommerfeld coefficient. It is shown that Bogoliubov quasiparticles act in superconducting states of unconventional and conventional superconductors. At the same time, quasiparticles are also present in the normal state of unconventional superconductors. We briefly describe the difference between unconventional superconductors and conventional ones, such as the resistivity in normal states and the difference in superfluid density in superconducting states. For the first time, we theoretically show that the universal scaling of $E_{\mathsf{\Delta }}/\gamma \propto T_c^2$ applies equally to both conventional and unconventional superconductors. Our consideration is based on two experimental facts: Bogoliubov quasiparticles act in conventional and non-conventional superconductors and the corresponding flat band is deformed by the non-conventional superconducting state. As a result, our theoretical observations based on the theory of fermion condensation agree well with the experimental facts. Full article

(Cu,C)Ba₂Ca₃Cu₄O_y is a nontoxic cuprate superconducting material with a superconducting transition temperature of about 116 K. Recently, it was found that bulk samples of this material synthesized under high pressure hold the highest irreversibility line among all the superconductors, which is very promising for its application in the liquid nitrogen temperature field. In this work, high-temperature (Cu,C)Ba₂Ca₃Cu₄O_y superconducting films with large irreversible fields were prepared on SrLaAlO₄(00l) substrates by pulsed laser deposition. The substrate temperature during deposition proved to be the most important parameter determining the morphology and critical temperature of the superconductors, with 680 °C considered to be the optimum temperature. X-ray diffraction (XRD) results showed that the (Cu,C)Ba₂Ca₃Cu₄O_y films prepared under optimal conditions exhibited epitaxial growth with the a-axis perpendicular to the film surface and the b- and c-axes parallel to the substrate, with no evidence of any other orientation. In addition, resistivity measurements showed that the onset transition temperature (T_c^onset) was approximately 116 K, the zero-resistance critical temperature (T_c0) was around 53 K, and the irreversible field (H_irr) was about 9 T at 37 K for (Cu,C)Ba₂Ca₃Cu₄O_y films under optimal temperature. This is the first example of the successful growth of superconducting (Cu,C)Ba₂Ca₃Cu₄O_y films on SrLaAlO₄(00l) substrates. This will facilitate high-performance applications of (Cu,C)Ba₂Ca₃Cu₄O_y superconducting materials in the liquid nitrogen temperature field. Full article

Recently, superconductivity with T_c ≈ 80 K was discovered in La₃Ni₂O₇ under extreme hydrostatic pressure (>14 GPa). For practical applications, we needed to stabilize this state at ambient pressure. It was proposed that this could be accomplished by substituting La with Ba. To put this hypothesis to the test, we used the state-of-the-art atomic-layer-by-layer molecular beam epitaxy (ALL-MBE) technique to synthesize (La_1−xBa_x)₃Ni₂O₇ films, varying x and the distribution of La (lanthanum) and Ba (barium). Regrettably, none of the compositions we explored could be stabilized epitaxially; the targeted compounds decomposed immediately into a mixture of other phases. So, this path to high-temperature superconductivity in nickelates at ambient pressure does not seem promising. Full article

This paper analyzes the viability of different solutions to passively augment the axial stiffness of a horizontal axis radial levitation passive magnetic bearing (PMB) with a previously studied topology. The zero-field cooling (ZFC) of high-temperature superconductor (HTS) bulks promotes higher magnetic impulsion and levitation forces and lower electromagnetic losses than those with field-cooling (FC) but, on the other hand, the guiding stability is much lower than those with FC. Because of stability reasons, FC was adopted in most superconducting maglev systems. The trend of this research group has been to develop a horizontal axis HTS ZFC radial levitation PMB presenting notable levitation forces with reduced electromagnetic losses, defined by a topology that creates guiding stability. Previous work has shown that optimizing the bearing geometry to maximize magnetic guidance forces might not be enough to guarantee the axial stiffness required for many applications. First, the extent to which guidance forces are augmented by increasing the number of HTS bulks in the stator is evaluated. Then, the axial stiffness augmentation by passively adding two limiting permanent magnet (PM) rings is evaluated. The results show that the axial stiffness is highly augmented by adding limiting PM rings with no significant additional investment. This change enables the use of the studied ZFC superconducting PMB in high-precision axial stability applications, such as precision gyroscopes, horizontal axis propellers, and turbines. Full article

As a highly regarded superconducting material with a concise layered structure, MgB₂ has attracted significant scientific attention and holds vast potential for applications. However, its limited current-carrying capacity under high magnetic fields has greatly hindered its practical use. To address this issue, we have enhanced the superconducting performance of MgB₂ by incorporating inhomogeneous phase nanostructures of p-n junctions with electroluminescent properties. Through temperature-dependent measurements of magnetization, electronic specific heat, and Hall coefficient under various magnetic fields, we have confirmed the crucial role of inhomogeneous phase electroluminescent nanostructures in improving the properties of MgB₂. Experimental results demonstrate that the introduction of electroluminescent inhomogeneous phases effectively enhances the superconducting performance of MgB₂. Moreover, by controlling the size of the electroluminescent inhomogeneous phases and optimizing grain connectivity, density, and microstructural uniformity, we can further improve the critical temperature (T_C) and flux-pinning capability of MgB₂ superconducting materials. Comprehensive studies on the physical properties of MgB₂ superconducting structures added with p-n junction electroluminescent inhomogeneous phases also confirm the general effectiveness of electroluminescent inhomogeneous phases in enhancing the performance of superconducting materials. Full article

This study investigated the relationship between the superconducting properties, electrical properties, sputtering process parameters, and post-growth annealing of NbN films. Four series of NbN films were deposited by DC magnetron sputtering using different process parameters. With the assistance of a four-probe method, the superconducting performance presented first an increase and then a decreasing trend as the resistance of the prepared films increased, which could be attributed to the variation of the N/Nb ratio in the films. This correlation implied that it is very challenging to fabricate films with both high Tc and high resistance or high Tc and low resistance by adjusting the sputtering process parameters. In order to overcome these bottlenecks, a series of films were deposited on Si, GaN/Si, SiN/Si, AlN/Si, and AlN/sapphire substrates, and the film deposited on Si was annealed at 900 °C. Annealing reduced the stress of the films on the buffer layer and increased the grain size and crystallinity of the films, except for the films on the GaN/Si substrates. This resulted in a significant decrease in the resistivity of the film and a significant increase in the superconducting transition temperature. Full article

The multifaceted inductive technique of AC magnetic susceptibility (ACMS) provides versatile and reliable means for the investigation of the respective properties of magnetic and superconducting materials. Here, we explore, both mathematically and experimentally, the ACMS set-up, based on four coaxial pick-up coils assembled in the second-derivative configuration, when employed in the investigation of differently shaped superconducting specimens of poly-crystalline YBa₂Cu₃O_7−δ and Bi_2−xPb_xSr₂Ca₂Cu₃O_10+y and single-crystalline YBa₂Cu₃O_7−δ. Through the mathematical modeling of both the ACMS set-up and of linearly responding superconducting specimens, we obtain a closed-form relation for the DC voltage output signal. The latter is translated directly to the so-called extrinsic ACMS of the studied specimen. By taking into account the specific characteristics of the studied high-T_c specimens (such as the shape and dimensions for the demagnetizing effect, porosity for the estimation of the superconducting volume fraction, etc.), we eventually draw the truly intrinsic ACMS of the parent material. Importantly, this is carried out without the need for any calibration specimen. The comparison of the mathematical modeling with the experimental data of the aforementioned superconducting specimens evidences fair agreement. Full article

We have successfully synthesized a series of Bi-doped BaFe₂As₂ high-quality single crystals for the first time. X-ray diffraction (XRD) patterns show an expansion of lattice parameter c with Bi doping, indicating a negative pressure effect. By investigating the resistivity, a Fermi liquid (FL) to non-Fermi liquid (NFL) crossover is observed from normal state to antiferromagnetic order state, accompanied by three superconducting transitions labeled as SC I, SC II and SC III, which are supposed to be induced by three superconducting realms with various Bi concentrations. Thus, we propose that the NFL behavior is closely related to the presence of superconductivity. The magnetic susceptibility measurements further speculate that the SC I and SC III phases should exhibit filamentary superconductivity while the SC II exhibits a possible bulk superconductivity of T_C~7 K. Full article

The exploration initiated by the discovery of the topological insulator (Bi_xSb_1−x)₂Te₃ has extended to unlock the potential of quantum anomalous Hall effects (QAHEs), marking a revolutionary era for topological quantum devices, low-power electronics, and spintronic applications. In this study, we present the epitaxial growth of Cr-doped (Bi_0.4Sb_0.6)₂Te₃ (Cr:BST) thin films via molecular beam epitaxy, incorporating various Cr doping concentrations with varying Cr/Sb ratios (0.025, 0.05, 0.075, and 0.1). High-quality crystalline of the Cr:BST thin films deposited on a c-plane sapphire substrate has been rigorously confirmed through reflection high-energy electron diffraction (RHEED), X-ray diffraction (XRD), and high-resolution transmission electron microscopy (HRTEM) analyses. The existence of a Cr dopant has been identified with a reduction in the lattice parameter of BST from 30.53 ± 0.05 to 30.06 ± 0.04 Å confirmed by X-ray diffraction, and the valence state of Cr verified by X-ray photoemission (XPS) at binding energies of ~573.1 and ~583.5 eV. Additionally, the influence of Cr doping on lattice vibration was qualitatively examined by Raman spectroscopy, revealing a blue shift in peaks with increased Cr concentration. Surface characteristics, crucial for the functionality of topological insulators, were explored via Atomic Force Microscopy (AFM), illustrating a sevenfold reduction in surface roughness as the Cr concentration increased from 0 to 0.1. The ferromagnetic properties of Cr:BST were examined by a superconducting quantum interference device (SQUID) with a magnetic field applied in out-of-plane and in-plane directions. The Cr:BST samples exhibited a Curie temperature (T_c) above 50 K, accompanied by increased magnetization and coercivity with increasing Cr doping levels. The introduction of the Cr dopant induces a transition from n-type ((Bi_0.4Sb_0.6)₂Te₃) to p-type (Cr:(Bi_0.4Sb_0.6)₂Te₃) carriers, demonstrating a remarkable suppression of carrier density up to one order of magnitude, concurrently enhancing carrier mobility up to a factor of 5. This pivotal outcome is poised to significantly influence the development of QAHE studies and spintronic applications. Full article

In this paper influence of the excess Ca and Cu cations on the critical temperature (Tc) and critical transport current density (J_c) of high-temperature superconducting ceramics of the compositions (HTSC) Bi_1.6Pb_0.4Sr₂Ca_2.1Cu_3.1O_y, Bi_1.6Pb_0.4Sr₂Ca_2.25Cu_3.25O_y and Bi_1.6Pb_0.4Sr₂Ca₃Cu₄O_y synthesized by the glass-ceramic method has been studied. The synthesis of superconducting ceramics was carried out on the basis of the glass phase, obtained by ultra-fast quenching of the melt. Melting of the mixture of starting components was carried out without the use of a crucible under the influence of IR radiant heating. Analysis of the elemental composition of the samples of the initial precursors showed a significant deviation from stoichiometry in oxygen (increase), as well as a decrease in calcium content. The synthesis of HTSC ceramics was carried out at a temperature of 849–850 °C for 96 h with intermediate grinding every 24 h. Studies of the phase composition of ceramic samples by X-ray diffraction have shown that HTSC ceramics consist only of a superconducting high-temperature phase Bi-2223. Studies of current-carrying characteristics by the four-point probe method according to the criterion of 1 µV/cm² have shown that high-temperature superconducting ceramics of the compositions Bi_1.6Pb_0.4Sr₂Ca_2.1Cu_3.1O_y, Bi_1.6Pb_0.4Sr₂Ca_2.25Cu_3.25O_y and Bi_1.6Pb_0.4Sr₂Ca₃Cu₄O_y have an increased density of critical transport current of 9.12 A/cm², 7.62 A/cm² and 7.26 A/cm², respectively. At the same time, it was found that with a decrease in the content of Ca and Cu cations in HTSC ceramics, an increase in the critical current density is observed. Full article

While the search for new high-temperature superconductors had been driven by the empirical “trials and errors” method for decades, we now report the synthesis of Artificial High-T_c Superlattices (AHTS) designed by quantum mechanics theory at the nanoscale. This discovery paves the way for engineering a new class of high-temperature superconductors, following the predictions of the Bianconi Perali Valletta (BPV) theory recently implemented in 2022 by Mazziotti et al. including Rashba spin-orbit coupling to create nanoscale AHTS composed of quantum wells. The high-T_c superconducting properties within these superlattices are controlled by a conformational parameter of the superlattice geometry, specifically, the ratio L/d which represents the thickness of La₂CuO₄ layers (L) relative to the superlattice period (d). Using molecular beam epitaxy, we have successfully grown numerous AHTS samples. These samples consist of initial layers of stoichiometric La₂CuO₄ units with a thickness L, doped by interface space charge, and intercalated with second layers of non-superconducting metallic material, La_1.55Sr_0.45CuO₄ with thickness denoted as W = d − L. This configuration forms a quantum superlattice with periodicity d. The agreement observed between the experimental dependence T_c (the superconducting transition temperature) versus L/d ratio and the predictions of the BPV theory for AHTS in the form of the superconducting dome validates the hypothesis that the superconducting dome arises from the Fano–Feshbach or shape resonance in multigap superconductivity driven by quantum nanoscale confinement. Full article