Search Results (310)

In the present study, glass/ceramic hybrid fibers were chosen as a paper matrix, which effectively balance toughness and high-temperature resistance for soot combustion applications. In order to address the issue of unevenness in the performance of paper-type catalysts caused by the differences in the dispersion behavior of glass fibers and ceramic fibers in water, a facile foam-forming technology was proposed. The obtained glass fiber/mullite composite paper with various mass ratios (1:1, 2:1, 3:1, 4:1, and 5:1) exhibit high evenness, and better high-temperature resistance than the pure glass fibers. After impregnating K-Mn active ingredients, 15K5Mn-GFF-3G1C (GF/CF = 3:1) demonstrates high tensile strength, excellent catalytic activity (T50 = 388 °C), reusability (five cycles), and high-temperature stability (800 °C, 12 h). Full article

Viscoelastic polyurethane foams were prepared using four different bio-based polyols derived from coconut oil (CO), palm oil (PO), duck fat (DF), and pork fat (PF), employing up to 20 wt.% of the polyol component in a conventional formulation. The introduction of bio-polyols into the polyurethane formulation gave rise to an early minor decomposition of modified foams at low temperatures; however, the overall thermal stability improved slightly by the elimination of some intermediate decomposition stages. The glass transition temperature of foams was only moderately influenced and remained in the typical temperature range (around 10 °C). The effect of biopolyol type and content (5–20 wt.%) on the mechanical properties of the foams was investigated over the temperature range −20 to 40 °C. At 20 and 40 °C, all foams exhibited comfortable viscoelastic properties suitable for furniture applications. Hysteresis and the damping behavior of foams were also influenced by biopolyol type and concentration, with CO and DF providing enhanced energy absorption. Overall, these bio-based foams demonstrate potential for eco-friendly, high-performance applications, although their use at temperatures below 10 °C may be limited by increased stiffness. Full article

The growing energy demand in the residential sector, driven by the extensive use of air conditioning systems, poses serious environmental and economic challenges. A sustainable alternative is the use of efficient insulating materials derived from waste resources. This study presents the synthesis of glass–ceramic foams produced from recycled glass (90 wt%), pumice (5 wt%), and limestone (5 wt%), sintered at 800 °C for 10 min. The resulting foams exhibited a low apparent density of 684 kg/${\mathrm{m}}^3$ and thermal conductivity of 0.09 W/m·K. These were incorporated into composite insulating panels composed of 70 wt% ceramic pellets and 30 wt% Portland cement, achieving a thermal conductivity of 0.18 W/m·K. The panels were evaluated in a 64.8 ${\mathrm{m}}^2$ social housing model located in Chihuahua, Mexico, using TRNSYS v.17 to simulate annual energy performance. Results showed that applying a 1.5-inch ceramic foam panel reduced the annual energy demand by 16.9% and the total energy cost by 14.7%, while increasing the panel thickness to 2 in improved savings to 18.4%. Compared with expanded polystyrene (EPS), which achieved 24.9% savings, the proposed ceramic panels offer advantages in fire resistance, durability, local availability, and environmental sustainability. This work demonstrates an effective, low-cost, and circular-economy-based solution for improving thermal comfort and energy efficiency in social housing. Full article

The present work deals with the preparation and characterization of fire-retardant acrylonitrile–butadiene–styrene (ABS) foams incorporating 25 wt% of a phosphorus flame-retardant (PFR) system formed by 50% of ammonium polyphosphate (APP) and 50% of aluminum diethylphosphinate (AlPi). To further enhance performance, 5 wt% of the PFR was replaced by either montmorillonite (MMT) or layered double hydroxide (LDH) nanoparticles, maintaining the overall FR content constant. The formulations were prepared by melt blending, and foams were produced using a one-step supercritical carbon dioxide (sCO₂) dissolution foaming process. The incorporation of the PFR, alone or partially replaced by nanoclays, resulted in foams with smaller cell sizes and higher cell nucleation densities compared to pure ABS, with cell sizes reducing from 60 μm to as low as 40 μm and cell densities reaching values > 10⁷ cells/cm³. The presence of LDH notably modified the thermal decomposition of ABS–PFR, increasing the temperature at 5% mass loss (T_5%) by more than 10 °C and the amount of formed residue by more than 15%. The ABS–PFR/LDH foam also showed a higher glass transition temperature (3 °C increase) and a higher specific storage modulus (920 MPa·cm³/g, a more than 40% increase). Cone calorimetry revealed a very significant reduction in the peak of the heat release rate (PHRR) and increased residue formation for ABS–PFR compared to ABS (from 1672 kW·m⁻² to as low as 483 kW·m⁻²). LDH nanoparticles further decreased HRR during the early quasi-static combustion stage of foams, indicating a more effective condensed-phase flame-retardant action than MMT. Full article

In cold regions, flexible pavements are vulnerable to frost-induced damage, necessitating effective insulation strategies. Foam glass aggregate (FGA) insulation layers, made from recycled glass, offer promising thermal insulation properties but are mechanically fragile and susceptible to permanent deformation under repeated loading. Manufacturers provide technical recommendations, particularly regarding load limits for installation and the dimensions of the thermal protection layer. These are considered insufficient to assist pavement designers in their work. The definition of critical criteria for permissible loads was deemed necessary to design mechanically durable structures using this alternative technology. This study investigates the critical stress conditions that FGA layers can tolerate within flexible pavement systems to ensure long-term structural integrity. Laboratory cyclic triaxial tests and full-scale accelerated pavement testing using a heavy vehicle simulator were conducted to evaluate the resilient modulus and permanent deformation behavior of FGA. The results show that FGA exhibits stress-dependent elastoplastic behavior, with resilient modulus values ranging from 70 to 200 MPa. Most samples exhibited plastic creep or incremental collapse behavior, underscoring the importance of careful stress management. A strain-hardening model was calibrated using both laboratory and full-scale data, incorporating a reliability level of 95%. This study identifies critical deviatoric stress thresholds (15–25 kPa) to maintain stable deformation behavior (Range A) under realistic confining pressures. FGA performs well as a lightweight, insulating, and draining layer, but design criteria remain to be defined for the design of multi-layer road structures adapted to local materials and traffic conditions. Establishing allowable critical stress levels would help designers mechanically validate the geometry, particularly the adequacy of the overlying layers. These findings support the development of mechanistic design criteria for FGA insulation layers, ensuring their durability and optimal performance in cold climate pavements. Full article

In this study, syntactic composite foams were developed by incorporating cenosphere (CS) particles recovered from recycled fly ash into a one-component polyurethane (PU) foam system. During production, CS was added to the spray-applied PU foam at specific ratios, and the foaming reaction was simultaneously initiated via manual mixing. This approach minimized particle settling caused by the filler–matrix density difference and promoted a more homogeneous structure. Two types of CS, with mean sizes of approximately 70 µm and 130 µm, were incorporated at five loadings ranging from 5 wt% to 15 wt%. The resulting composites were evaluated for their acoustic, mechanical, and thermal performance. Thermal analyses revealed that CS addition increased the glass-transition temperature (Tg) by ≈12 °C and delayed the 5% mass-loss temperature (T₅%) by ≈30–35 °C compared with the neat N2 foam, confirming the stabilizing role of cenospheres. The refoaming process with manual mixing promoted finer cell diameters and thicker walls, enhancing the sound absorption coefficient (α), particularly at medium and high frequencies. Moreover, increasing the filler content improved both the sound transmission loss (STL) and compressive strength, alongside density, although further gains in α and STL were limited beyond a 10 wt% filler content. Significant enhancements in compressive strength were achieved at filler ratios above 12.5 wt%. Unlike conventional two-component PU foams, this study demonstrates a sustainable one-component PU system reinforced with recycled cenospheres that simultaneously achieves acoustic, mechanical, and thermal multifunctionality. To the best of our knowledge, this is the first report on incorporating recycled cenospheres into a one-component PU foam system, overcoming dispersion challenges of conventional two-component formulations and presenting an environmentally responsible route for developing versatile insulation materials. Full article

This study focuses on the behavior of hybrid polymer composites made from glass fiber and natural fiber-based flax fabric when subjected to low velocity drop-weight impacts. With the rise in the utilization of composites in structural components in various industries like the marine, aerospace and automotive industries, it is of paramount importance to study the effects of low velocity drop-weight impacts and their damage assessment on the composites. Low velocity drop-weight impacts can occur due to a tool falling on a composite part or due to an impact with a small object. The experimental tests were carried out according to ASTM standards with a drop-weight impact testing machine. Simulations were done to replicate the tests using explicit finite element software LS-DYNA. The experimental tests were carried out on samples of thickness ~2.5 mm and the energy at impact was 50 J. Upon comparing the experimental results, it was seen that an error percentage in the deformation varied between a minimum of 3.32% and a maximum of 8.93%, and the maximum force at impact varied between a minimum of 0.06% and a maximum of 17.14%. The variations between the experimental and simulated values can be attributed to the presence of voids or other defects that would have inadvertently crept in while making the composite. Additionally, composite laminates lined with a layer of EPS (expanded polystyrene) foam were tested and compared with composite laminates which were not lined with the foam. An improvement in the performance of the composite laminates lined with the EPS foam was observed. Full article

The current study presents the development and optimisation of foam glass manufactured from recycled glass shards and expanded ground perlite, targeting enhanced structural and thermal performance for sustainable building applications. By investigating various particle size fractions (“125 μm”, “250 μm”, “500 μm”) and sintering temperatures (800–850 °C), we achieved a foam glass with superior compressive strength and uniform porosity. Notably, samples utilising a homogeneous 500 μm particle fraction sintered at 850 °C exhibited the highest compressive strength of 2.17 MPa, coupled with open porosity uniformity and stable structural matrix formation. Density values in this fraction decreased from 321 to 263 kg/m³, indicating effective foaming and well-developed open porosity that balances mechanical integrity and thermal insulation. The optimised thermal regime minimised crystalline phase formation, preserving low thermal conductivity and mechanical stability. Compared to heterogeneous composites, the homogeneous fractions demonstrated significantly improved strength-to-porosity ratios, ensuring predictable mechanical performance and competitive thermal insulation properties. These findings underline the material’s potential as a cost-effective, environmentally friendly insulation solution that meets or exceeds existing standards, with promising applications in energy-efficient construction. Full article

Standardized pharmaceutical-grade cultivation of Cannabis sativa L. increasingly relies on soilless systems for precision, reproducibility, and regulatory compliance. This review examines the role of inert and semi-inert growing media in indoor cannabis production, focusing on their physical properties, agronomic performance, and sustainability. A systematic literature search was conducted using databases such as Scopus, Web of Science, and Google Scholar, emphasizing peer-reviewed original research, experimental trials, and relevant review articles. Evaluated substrates include rockwool, coconut coir, peat-based blends, perlite, vermiculite, expanded clay, foamed glass, phenolic foam, and biochar. Findings show that substrate selection strongly affects vegetative growth, rooting, and flower yield, while cannabinoid concentrations remain primarily genotype-driven under stable environmental and nutritional conditions. Substrate-specific traits such as aeration, water-holding capacity, and nutrient buffering significantly influence biomass production and resource-use efficiency. Rockwool remains the industry standard due to its uniformity and compatibility with fertigation systems, but renewable alternatives like coconut coir and biochar are gaining traction. This review underscores the importance of substrate selection in cannabis cultivation and identifies research gaps in genotype-specific responses and the development of sustainable growing media. Full article

Wrinkling is a localized buckling phenomenon that significantly compromises the structural integrity of lightweight sandwich structures. The objective of this study was to validate the experimental design of a sandwich beam to observe the initiation of wrinkling under compression and, more specifically, under shear stresses. The specimen under consideration consists of glass fibre–epoxy skins with polymethacrylimide (PMI) ROHACELL^® foam cores. The experimental tests were monitored using Digital Image Correlation (DIC) techniques, in conjunction with displacement and force sensors. A linear buckling simulation was performed using Finite Element Analysis (FEA) in ABAQUS and was compared with both the experimental test results and analytical predictions. The simulations demonstrated a good correlation with both the experimental data and analytical models for compression wrinkling. In the case of shear wrinkling, the numerical analysis significantly overestimated the wrinkling load in comparison to the experimental results. Full article

Lightweight Aggregate Reinforced Concrete (LWARC) is increasingly used in structural systems to reduce dead load, especially in flat slabs. This study focuses on LWARC-incorporating polystyrene foam as a partial aggregate replacement, achieving a dry unit weight reduction from 23.0 kN/m³ to 19.0 kN/m³. While beneficial for lowering dead loads, this substitution exacerbates punching shear vulnerability, necessitating innovative strengthening solutions. Fiber-Reinforced Polymers (FRPs), recognized for their high strength-to-weight ratio, corrosion resistance, and adaptability, are employed to address these limitations. This paper evaluates the punching shear strengthening of LWARC flat slabs using externally bonded carbon fiber-reinforced polymer (CFRP) sheets, embedded through-section (ETS) steel bars, and ETS glass fiber-reinforced polymer (GFRP) bars. Ten specimens were tested under concentric loading, including an unstrengthened control slab. Experimental results were compared with predictions from ECP 203-2023, ACI 318-19, and BS 8110 to assess code applicability. Strengthened specimens demonstrated significant improvements in punching capacity and ductility. The ETS steel bar technique increased punching strength by 41% compared to the control, while inclined reinforcement configurations outperformed vertical layouts by 24% due to optimized shear transfer. Full article

Lightweight aggregate concrete is known for its potential to decrease overall building load and cost. Aero Aggregates’ Aerolite is a foamed glass aggregate (FGA) available in seven different sizes which has the potential to replace normal weight aggregates to create lightweight concrete. This research analyzes the feasibility of using FGAs in optimized concrete mix designs and employing those designs in a full-scale building. Nine different mix designs were created using optimization methods, including the Tarantula Curve and 0.45 power chart, to determine the ideal aggregate proportions. All mixes were cast in 0.1 m diameter, 0.2 m tall cylinders and tested after 7 and 28 days to determine unit weight (density), compressive strength, and modulus of elasticity. After testing, the optimal design was identified as 65% coarse and 15% fine aggregates to be replaced with FGAs because it gave the best unit weight and compressive strength for structural lightweight concrete. The optimal concrete mix design was used to create an example building model in RAM Structural Systems to prove that FGA concrete can reduce cost, materials required, and carbon emissions on a larger scale. Full article

Waste glass recycling generates waste streams such as fine glass fraction, waste ceramics containing fine glass, and waste polyethylene plastics. All of the aforementioned streams contain contaminants of organic and inorganic origin that are difficult to remove. This research was conducted to determine technological processes aimed at achieving a circular economy (CE) in the recycling of waste glass. Foam glass was made from the fine-grained, multicolored fraction of contaminated glass, an effective method for recycling glass waste at a low cost. A frothing system based on manganese oxide (MnO₂) and silicon carbide (SiC) was proposed, and an optimum weight ratio of MnO₂/SiC equal to 1.0 was determined. The possibility of controlling the process to achieve the desired foam glass densities was demonstrated. Statistical analysis was used to determine the effect of the MnO₂/SiC ratio and MnO₂ content on the density of the resulting foam glass products. Waste ceramics contaminated with different-colored glass were transformed into ceramic–glass granules. The characteristic temperature curve of the technological process was determined. The metal content in water extracts from ceramic–glass granules and pH value indicate their potential use for alkalizing areas degraded by industry and agriculture. Waste polyethylene-based plastics were converted into polyethylene waxes by thermal treatment carried out in two temperature ranges: low temperature (155–175 °C) and high temperature (optimum in 395 °C). The melting temperature range of the obtained waxes (95–105 °C) and their FTIR spectral characteristics indicate the potential application of these materials in the plastics and rubber industries. The integrated management of all material streams generated in the glass recycling process allowed for the development of a CE model for the glass recycling plant. Full article

To mitigate the issue of accumulating glass waste, an advanced process has been developed for the production of glass foams via alkaline activation, employing industrial glass cullet as the primary raw material. This method contributes to circular economy strategies by enabling high-value upcycling of secondary raw materials. The aim of the study is to conduct an environmental assessment of this recycling process using the Life Cycle Assessment (LCA). The analysis is performed with SimaPro software, adopting the ReCiPe impact assessment method, which allows for the quantification of 18 impact categories. Four distinct foaming processes were compared to determine the most environmentally preferable option and a sensitivity analysis was conducted to assess how variations in energy sources influence the environmental performance. The findings indicate that the scenario involving hardening at 40 °C for seven days results in the highest environmental burdens. Specifically, in the Human Carcinogenic Toxicity category, the normalized impacts for this process are approximately an order of magnitude greater. Electricity consumption is identified as the primary contributor to the overall impact. The sensitivity analysis underscores that utilizing photovoltaic panels reduces impacts. Future developments will focus on expanding the system boundaries to provide a more comprehensive understanding and supporting informed decision-making. Full article

The recycling of glass presently poses several challenges, predominantly to the heterogeneous chemical compositions of various glass types, along with the waste glass particle size distribution, both of which critically influence the efficiency and feasibility of recycling operations. Numerous studies have elucidated the potential of converting non-recyclable glass waste into valuable materials thanks to the up-cycling strategies, including stoneware, glass wool fibres, glass foams, glass-ceramics, and geopolymers. Among the promising alternatives for improving waste valorisation of glass, alkali-activated materials (AAMs) emerge as a solution. Waste glasses can be employed both as aggregates and as precursors, with a focus on its application as the sole raw material for synthesis. This overview systematically explores the optimisation of precursor selection from a sustainability standpoint, specifically addressing the mild alkali activation process (<3 mol/L) of waste glasses. The molecular mechanisms governing the hardening process associated with this emerging class of materials are elucidated. Formulating sustainable approaches for the valorisation of glass waste is becoming increasingly critical in response to the rising quantities of non-recyclable glass and growing priority on circular economy principles. In addition, the paper highlights the innovative prospects of alkali-activated materials derived from waste glass, emphasising their emerging roles beyond conventional structural applications. Environmentally relevant applications for alkali-activated materials are reported, including the adsorption of dyes and heavy metals, immobilisation of nuclear waste, and an innovative technique for hardening as microwave-assisted processing. Full article