Search Results (136)

The transition from conventional silica nanoparticle (SiNP) production based on purified alkoxysilanes and high-temperature flame hydrolysis of silicon tetrachloride to renewable and waste-derived silicon resources requires more than precursor substitution. It requires a mechanistic understanding of how feedstock mineralogy, silicon speciation, impurity chemistry, and processing history propagate through dissolution, nucleation, condensation, gelation, aging, drying, and pore evolution to determine material performance, environmental burden, and manufacturing feasibility. Although previous reviews have established the technical feasibility of producing silica from secondary resources, their predominant organization by feedstock, synthesis route, or application provides limited ability to explain why nominally similar processes generate materials with markedly different structural and functional properties. This review addresses these through a resource-pull, feedstock-to-function framework that links resource chemistry and process design to critical material attributes, application-specific specifications, sustainability, and scale-up requirements. Agricultural residues, industrial by-products, geothermal resources, waste glass, and fluorosilicate streams are critically compared according to silicon form and phase, reactivity, impurity profile, compositional variability, purification demand, and attainable product quality. Particular attention is given to waste-derived alkaline silicate systems, in which molecular, oligomeric, and colloidal silica coexist and therefore require characterization beyond bulk SiO₂ concentration. Established and emerging processing strategies, including controlled combustion and alkaline extraction, alkali fusion, ambient-pressure drying, microwave and mechanochemical activation, biogenic and biomimetic templating, and continuous processing, are evaluated according to their mechanistic effects, technological maturity, structural control, and demands for energy, reagents, water, solvents, effluent treatment, and capital. Across these routes, gelation and aging emerge as critical transfer stages through which feedstock composition is translated into network connectivity, pore architecture, shrinkage behavior, and ultimately functional performance. Evidence from secondary-source aerogels further shows that properly controlled waste-derived systems can attain BET surface areas of approximately 350–500 m² g⁻¹, within the textural range of many alkoxide-derived materials, indicating that feedstock variability, impurity management, and process control are more important constraints than an inherently lower performance ceiling. On this basis, this review proposes a minimum evidence framework comprising feedstock traceability, intermediate-speciation and colloidal characterization, silicon mass balance, gelation and aging metrics, application-specific qualification criteria, performance-normalized life cycle and techno-economic assessment, process analytical control, and staged pilot validation. Collectively, these principles provide a mechanistically grounded basis for moving sustainable silica synthesis beyond isolated proof-of-concept demonstrations toward reproducible, scalable, application-matched, and commercially credible manufacturing platforms. Full article

The characterization of geothermal reservoirs and their genetic mechanisms is critical for understanding geothermal system evolution and evaluating geothermal resource potential. The eastern Gushi Sag of the Weihe Basin hosts three Neogene sandstone geothermal reservoirs, including the Gaoling Group, Lantian–Bahe Formation, and Zhangjiapo Formation; however, their reservoir characteristics and genetic mechanisms remain poorly constrained. This study integrates geological structures, geothermal well logging, core petrophysical properties, and hydrochemical data to characterize reservoir conditions and establish a genetic model. The results show that the Neogene reservoirs are mainly composed of feldspathic sandstone, with the Lantian–Bahe Formation identified as the primary geothermal reservoir due to its moderate porosity, low permeability, large sandstone thickness, and favorable continuity. The geothermal field exhibits an average geothermal gradient of 3.35 °C/100 m with a south-to-north decreasing trend. Hydrochemical evidence suggests that geothermal fluids originate mainly from meteoric water recharged from the northern Qinling Orogenic Belt and paleo-sedimentary water, with deep faults and pore networks controlling fluid migration and accumulation. The Quaternary strata and Zhangjiapo Formation provide effective sealing conditions. This study reveals the coupled controls of thermal conditions, reservoir architecture, fluid circulation, and preservation on sandstone geothermal systems, providing insights into geothermal resource assessment, exploration strategy optimization, and the formation mechanisms of similar sedimentary basin geothermal systems. Full article

Global decarbonization represents one of the defining challenges of the 21st century. Geothermal energy offers a robust alternative for reducing fossil fuel dependency for both residential and industrial heating and cooling. While shallow geothermal systems are versatile and high-performing, comprehensive Life Cycle Assessments (LCA) remain scarce in the literature. This study evaluates the environmental impact of the manufacturing and installation processes of next-generation coaxial probes featuring a galvanized steel outer tube and an internal polyethylene pipe. The LCA identifies material composition as the primary environmental driver: steel production accounts for 41% of the total impact, while the hot-dip galvanization process contributes 30%, significantly affecting the “climate change” and the “resource use” categories. A comparative LCA with conventional double U-tube installations shows similar overall environmental impacts. A sensitivity analysis on the coaxial probes was conducted to explore potential mitigation strategies aimed at reducing the associated environmental impacts, providing indications for sustainable eco-design. The LCA results demonstrate that optimizing the design, specifically by reducing the steel quantity in the coaxial outer tube and avoiding the zinc coating process, results in a 34% reduction in total environmental impact, confirming that LCA is a fundamental tool for supporting the environmental sustainability of developing technologies. Full article

Natural lithium-bearing brines are gaining strategic importance as an alternative to traditional hard-rock deposits. Approximately 78% of the identified global lithium resources are hosted in hydromineral environments, including continental brines, oilfield formation waters, and geothermal fluids. The Shu–Sarysu sedimentary basin in southern Kazakhstan is one of the most extensive, yet poorly studied, brine provinces in Central Asia. This study provides a comprehensive hydrogeochemical characterization of lithium-bearing brines in the Moiynkum structural zone of the Shu–Sarysu basin, based on regional field sampling, multielement analysis, and GIS data integration. Water samples were collected from four deep gas production wells (perforation depths of 2029–2290 m) at the Ayrakty and Amangeldy fields. Analytical data demonstrate highly concentrated chloride–calcium–sodium brines with total dissolved constituent concentrations (TDS, calculated as the sum of analyzed ions) ranging from 140.1 to 272.1 g/L, with lithium content of 24.46–55.11 mg/L, strontium 680.5–1648.2 mg/L, rubidium 4.31–8.42 mg/L and cesium 0.317–0.420 mg/L. Piper and Durov diagrams classify the samples as highly evolved Na–Ca–Cl to Ca–Na–Cl formation brines typical of deep, long-residence sedimentary formation waters. Lithium enrichment is interpreted to reflect the combined influence of several processes: water–rock leaching of Li-bearing lithologies, evaporative concentration of ancestral brines, clay-mineral ion exchange, and possible deep fluid contributions, whose relative roles remain to be constrained by isotopic data. The compiled GIS-integrated database, combining new analytical data with archival hydrogeochemical records, delineates two promising lithium-bearing provinces and identifies priority areas for further exploration. The results indicate that the Shu–Sarysu Basin is a prospective region for further exploration of lithium-bearing formation waters in Kazakhstan. The recorded Li concentrations fall within the lower range of sedimentary-basin brines currently being evaluated for lithium extraction, although their economic and technological feasibility remains to be established. Full article

The transition to low-carbon energy systems is expanding the use of subsurface resources for heat extraction, energy storage, carbon management, and infrastructure reuse. This review examines hydraulic fracturing as a context-dependent engineering intervention across enhanced geothermal systems, geothermal reuse of depleted reservoirs and wells, unconventional gas, underground hydrogen storage, CO₂-based subsurface engineering, and natural hydrogen. We synthesize how stimulation can improve permeability, connectivity, heat exchange, injectivity, and deliverability, while evaluating constraints related to water use, induced seismicity, leakage, well and caprock integrity, life-cycle emissions, and public acceptance. The central trade-off is that higher stimulation efficiency does not necessarily produce greater sustainability. Short-term gains in flow or energy delivery can increase long-term risks to containment, thermal performance, seismic safety, and environmental accountability. Evidence is strongest for enhanced geothermal systems and commercial unconventional gas, whereas field support remains limited for porous-media hydrogen storage, CO₂-based fracturing, and natural hydrogen. Responsible deployment therefore requires site-specific boundaries, real-time monitoring, multi-physics and data-driven modeling, life-cycle assessment, and adaptive governance. Hydraulic fracturing can enable selected sustainable subsurface applications, but its value depends on balancing engineering performance against long-term environmental and integrity constraints. Full article

The reliance on a single evaluation parameter represents a major limitation in traditional geothermal reservoir assessment models, hindering accurate and effective evaluation of geothermal extraction performance. Moreover, mechanical deformation induced by cold fluid injection exerts a significant influence on both fluid flow behavior and geothermal energy recovery. In this study, a thermo-hydraulic–mechanical (THM)-coupled single-fracture model is developed based on the physical properties of the solid matrix and the seepage characteristics of the fluid, using a finite-element framework for heat and mass transfer. This model enables a multi-parameter evaluation of geothermal extraction efficiency as well as reservoir rock deformation. The simulation results indicate that reservoir temperature decreases progressively from the injection well to the production well, resulting in a gradual decline in the outlet temperature after an initial stable production period of approximately 200 days. The presence of a preferential “fastest flow path” between the injection and production wells plays a critical role in sustaining the stable production phase, whereas the development of a tongue-shaped isotherm pattern is a primary factor responsible for the reduction in outlet temperature during the later stages of extraction. In addition, thermally induced rock deformation further modifies geothermal extraction efficiency, mainly through its effects on reservoir permeability and top vertical displacement. Overall, this study provides reliable and effective fundamental data for geothermal exploitation in specific geological reservoirs, thereby supporting the role of geothermal energy as a viable supplement to fossil fuel resources. Full article

Offshore geothermal energy and the reuse of decommissioned oil and gas platforms are emerging as linked pathways for reducing the carbon intensity of marine energy supply while extending the value of mature offshore assets. This review examines offshore geothermal development from a full-chain perspective that connects resource assessment, platform and wellbore reuse, heat extraction, medium- and low-temperature conversion, multi-energy coupling, techno-economic evaluation and environmental risk management. The paper first clarifies the resource logic of offshore geothermal systems, especially sedimentary-basin resources that spatially overlap with mature petroleum provinces. It then analyzes two principal engineering routes: the reuse of existing offshore platforms as energy hubs and the reutilization of abandoned wells as open-loop or closed-loop heat-extraction systems. The review finds that platform and wellbore reuse can reduce drilling demand, shorten offshore construction cycles and lower life-cycle environmental burdens, but engineering feasibility remains constrained by wellbore integrity, thermal losses, corrosion and scaling, platform life extension, regulatory liability and the limited availability of field-scale demonstration data. Coupling geothermal energy with offshore wind power, hydrogen production, OTEC and desalination can improve system stability and equipment utilization; however, standardized assessment boundaries and comparable cost models are still insufficient. Future research should focus on resource-engineering-economic integrated assessment, standardized reuse packages, long-term offshore reliability databases, corrosion-resistant material systems, auditable TEA/LCA models and risk-based regulatory frameworks. This review provides a technical basis for offshore geothermal pilot projects and for the low-carbon transformation of offshore oil and gas infrastructure. Full article

Deep-mining operations are increasingly challenged by severe thermal hazards, which have become a critical bottleneck for achieving safe, efficient, and sustainable mineral extraction. While research on deep-mine cooling and heat hazard mitigation has proliferated, the field lacks a systematic, critical review that explicitly examines these advances through the lens of sustainability science. To address this gap, this study conducted a comprehensive bibliometric analysis of 432 publications (1994–2024) retrieved from the Web of Science Core Collection. The methodology employs Bibliometrix, Vosviewer, and CiteSpace to map the intellectual landscape, research hotspots, and evolving frontiers of the field. The results reveal a clear three-stage development trajectory and identify China, the USA, South Africa, and Canada as leading contributors, with national research emphases on ventilation, energy conservation, and refrigeration, respectively. Crucially, keyword clustering and burst detection uncover a notable paradigm shift: the focus has moved from isolated cooling techniques toward integrated, multi-objective strategies—including geothermal energy co-exploitation, phase-change material applications, and system-level energy optimization—signaling a growing alignment with resource efficiency and low-carbon mining principles. However, a critical finding is that the literature remains predominantly techno-centric, overwhelmingly evaluating performance through operational energy savings while largely neglecting life-cycle environmental impacts, holistic sustainability assessment metrics, and the influence of policy drivers. This review thus not only provides a structured overview of the domain, but, more importantly, exposes these critical knowledge gaps. We argue that future research must pivot toward a multi-dimensional sustainability framework that integrates technical, economic, and environmental dimensions, thereby guiding the next generation of research toward truly sustainable deep-mining practices. Full article

The synergistic utilization of post-mining spaces and geothermal energy through underground seasonal thermal energy storage (USTES) provides a promising pathway for sustainable heating and the low-carbon redevelopment of mining regions. To advance the thermal management and reveal the thermo-hydraulic evolution patterns within these repurposed environments, this study proposes an integrated approach that utilizes post-mining roadways as heat storage reservoirs, within the scope of a single idealized case study. A comprehensive USTES heating system model was established to systematically evaluate operational characteristics and environmental impacts under diverse conditions assuming homogeneous rock properties and idealized thermal boundaries. Results demonstrate that the surrounding ground temperature and the low thermal conductivity of the rock mass contribute to limiting heat dissipation and maintaining stable seasonal storage performance. For a roadway with a 20,000 m³ water storage capacity and an optimal 3900 m² solar collector area, the system successfully satisfies the thermal demand of 30,000 m² of building area. The configuration achieves 1239 MWh of cumulative heat storage over a 245-day cycle, maintaining a direct heating-to-heat-pump-upgraded heating ratio of 1.02. Furthermore, the implementation of variable-frequency thermal management strategies demonstrates remarkable economic and environmental superiority, yielding a 35.8% cost reduction compared to coal-fired heating, an overall energy saving rate of 77.5% relative to electric heating systems and a 13.5% decrease in CO₂ emissions relative to gas-fired systems. This research provides fundamental design parameters for the synergistic exploitation of mineral and geothermal resources, advancing the development of green heating and the sustainable utilization of post-mining spaces. Full article

Geothermal energy, a clean and reliable renewable resource, is attracting growing global attention. Predicting geothermal productivity is essential for the sustainable management of geothermal systems in conventional pumping tests, but the water level has a highly nonlinear correlation with reservoir physical conditions, and traditional numerical simulation methods fail to capture their intrinsic relationship. This study proposes a novel hybrid deep learning model of Graph Convolutional Networks (GCN) and Transformers for geothermal pumping tests, which efficiently predicts water level under nonlinear physical constraints: GCN learns the nonlinear mapping between water level depth and physical constraints, while Transformer preserves the temporal sequence correlations of production data via self-attention mechanism. Validation with test data showed that the model achieved an R² of 0.97 and an RMSE of 0.1635 m for production wells, and an R² of 0.94 and an RMSE of 3.9057 m for reinjection wells under different geological conditions. Its R² showed improvements of 13.82%, 7.83%, and 5.95% compared with the LSTM, Transformer, and GCN–LSTM models, respectively. This study provides an accurate and efficient technical approach for geothermal productivity prediction, supporting the optimization of pumping test schemes and production capacity evaluation in preliminary geothermal resource development. Full article

Binary-cycle geothermal plants are inherently limited by thermodynamics, forcing operators to reinject fluids at temperatures that are still valuable for direct heating. This process results in substantial exergetic waste. While prior research has examined efficiency at the level of individual plants, this study introduces a regional-scale framework to convert these facilities into multi-purpose energy hubs. The research focuses on Türkiye’s Western Anatolia Graben, a region with high geothermal activity that, paradoxically, remains dependent on fossil fuels. By combining meteorological records with operational plant data, we evaluated the existing housing stock of 983,277 residences across 14 districts and modeled the heating requirements for a targeted capacity of 468,719 residences that the proposed system can serve. The results indicate that the currently wasted thermal load in 10 specific districts, including key centers such as Sarayköy and Alaşehir, is sufficient to cover peak winter heating demands without fossil fuel backup. Although the infrastructure requires a significant initial investment of $4.51 billion, the project demonstrates long-term viability with a Levelized Cost of Heat (LCOH) of 62.94 USD/MWh and a payback period of 10.43 years. Beyond economic considerations, the system serves as a major decarbonization tool, capable of cutting residential CO₂ emissions by 1.7 million tons annually (a 47.7% reduction). These findings suggest that policy incentives should move away from electricity-only models toward integrated reservoir management to maximize resource efficiency. Full article

The newly identified greisen-hosted Nb-Ta mineralization in the Qidashan iron deposit, Liaoning Province, China, offers a unique opportunity to explore how hydrothermal processes contribute to the enrichment of critical metals. In this study, an integrated analytical approach of petrographic observation and scanning electron microscopy–energy-dispersive spectrometer (SEM-EDS), electron probe microanalyzer (EPMA), and laser ablation inductively coupled plasma mass spectrometer (LA-ICP-MS) U-Pb dating of columbite-group minerals (CGMs) were employed to systematically decipher the paragenetic sequence, micro-structure, elemental composition and mineralization age of CGMs, aiming at the genesis of greisen-hosted Nb-Ta mineralization. The mineralization is characterized by the abundant occurrence of CGMs. Three generations of CGMs and two mineralization stages are distinguished: stage I contains CGM Is and CGM IIs, with Nb₂O₅ ranging from 25.7 to 69.56 wt.% and Ta₂O₅ from 5.8 to 52.5 wt.%; stage II contains CGM IIIs, with Nb₂O₅ between 59.5 and 71.5 wt.% and Ta₂O₅ between 3.5 and 16.2 wt.%. CGM Is consist of euhedral, homogeneous crystals of more than 100 μm, exhibit low Ta/(Nb + Ta) ratios (0.05–0.06) and high Mn/(Fe + Mn) ratios (0.19–0.26), and belong to columbite-Fe. CGM IIs generally overgrow on CGM Is with hydrothermal overprinting textures, and show significant compositional gaps compared to CGM Is, exhibiting higher Ta/(Nb + Ta) ratios (0.13–0.55) and restricted Mn/(Fe + Mn) ratios (0.15–0.18), with some belonging to columbite-Fe and others to tantalite-Fe, which reveals a transition from magma to “hydrosilicate fluid”. CGM IIIs are mainly anhedral and homogeneous, with a grain size of less than 50 μm. However, some CGM IIIs overgrow on CGM IIs and/or CGM Is with patchy textures indicative of subsequent hydrothermal overprinting of hydrosilicate fluid, forming a coarse-grain size over 100 μm. CGM IIIs are characterized by lower Ta/(Nb + Ta) ratios (0.03–0.14) and variable Mn/(Fe + Mn) ratios (0.08–0.26), and they belong to columbite-Fe. LA-ICP-MS U-Pb dating yields weighted mean ²⁰⁶Pb/²³⁸U ages of 2646 ± 15 Ma for stage I and 2500 ± 28 Ma for stage II, indicating two-stage Nb-Ta mineralization. The early mineralization may correlate with the partial melting of volcanic–sedimentary rocks due to the geothermal anomalies associated with ~2.7 Ga submarine volcanism, and the late mineralization formed by the magmatic hydrothermal activities related to emplacement of the Qidashan granite in 2.5 Ga. We therefore propose that the two-stage greisen-hosted Nb-Ta mineralization probably widely occurred in these sedimentary–metamorphic iron deposits in the Anshan–Benxi area and even in the northern edge of the North China Craton, and it may provide new insights for evaluating the Nb-Ta resource potential in similar Algoma-type iron deposits globally. Full article

This study re-evaluates the hydrogeological framework of the Bohemian Cretaceous Basin (Czech Republic), where preliminary surveys unexpectedly identified old groundwater in several springs and abstraction wells. Traditional distinction into a Cenomanian (A) and a single Turonian (C) aquifer failed to explain the observed hydraulic head discrepancies and the occurrence of old groundwater. By integrating the spatial correlations of hundreds of well logs with hydraulic head data, environmental tracers (chemistry, ²H, ³H, ¹³C, ¹⁴C, ¹⁸O, ³⁹Ar, ⁸⁵Kr, CFCs, SF₆, and noble gases), and field measurements, we objectively delineated the hydrostratigraphic architecture of the basin. The results demonstrate three distinct aquifers (A, Ca, and Cb), challenging long-standing interpretations. Several flow systems were identified, with mean residence times of the old water exceeding 300 years. The hydrogeochemical and isotopic evidence confirmed mixing of Holocene groundwater between Ca and Cb aquifers while excluding Last Glacial Period fossil groundwater that is typical of the A aquifer. These findings highlight the necessity of a multi-proxy approach to validate conceptual models in seemingly “well-understood” regions. The newly characterized subdivision of Turonian aquifers is critical for protecting old groundwater resources, optimizing the design of geothermal and water supply wells to prevent hydraulic short-circuiting, and identifying previously unrecognized groundwater resources currently discharging to the Jizera River. Full article

Geothermal energy is a clean, renewable, and baseload-stable resource of strategic importance for carbon neutrality. Hot dry rock (HDR) reservoirs are characterized by high temperatures, great depths, and abundant reserves. However, their extremely low natural permeability requires artificial fracturing to establish effective heat exchange networks. Conventional hydraulic fracturing in enhanced geothermal systems (EGS) faces major challenges under HDR conditions, including excessive water consumption, strong water–rock interactions, and elevated induced seismicity risks, limiting its engineering applicability. Waterless or low-water fracturing technologies offer alternative stimulation pathways due to their distinctive physicochemical properties. Existing reviews have mainly addressed individual aspects, such as specific fracturing media or proppant transport, without systematically integrating recent advances in supercritical CO₂ fracturing, foam fracturing, liquid nitrogen fracturing, and hybrid-fluid fracturing technologies, or comprehensively evaluating their engineering implications. This review systematically analyzed the fracturing mechanisms, heat exchange performance, environmental risks, and HDR-specific engineering challenges of these technologies. Results indicate that waterless/low-water fracturing technologies enhance heat extraction efficiency by generating complex fracture networks while mitigating seismic and reservoir damage risks. However, large-scale application requires further advances in the high-temperature stability of fracturing media, material durability, multiphase flow control, and field validation. Full article

The geothermal system in the Jiaodong Peninsula is situated within a continent–ocean transition zone, where complex interactions among meteoric water, geothermal fluids, and seawater produce diverse hydrogeochemical and isotopic signatures, complicating geothermal resource assessment and sustainable development. To constrain recharge sources and seawater mixing mechanisms, geothermal water samples were systematically collected from 15 geothermal fields and analyzed using integrated hydrogeochemical methods and multi-isotope tracers (δD–δ¹⁸O, δ³⁴S-SO₄²⁻, ⁸⁷Sr/⁸⁶Sr, and ³H). The results show that geothermal waters are predominantly recharged by meteoric precipitation, with δD–δ¹⁸O values distributed along the meteoric water line, while low d-excess values indicate prolonged circulation and significant water–rock interaction. Seawater mixing exhibits marked spatial heterogeneity: only 5 of the 15 fields show detectable marine influence. Chloride-based calculations suggest apparent seawater fractions of up to ~34% in BQ and <4% in DY, whereas the remaining fields show negligible mixing. Sulfur and strontium isotopes indicate contributions from external sulfate sources and continued water–rock interaction rather than simple mixing with modern seawater. Low tritium contents further imply involvement of deeply circulated paleo-seawater. The system is therefore interpreted as a fault-controlled seawater-mixing geothermal system, providing insights into coastal geothermal evolution and resource evaluation. Full article