Search Results (77)

The present work investigates the characteristics of fly ash-based geopolymer concrete (GPC) in terms of compressive, splitting, and flexural strength, elasticity modulus, and stress–strain relationship. Datasets including 726 observations were collected from the sorted literature, and regression models were proposed. These models were then validated using experimental results obtained from 12 different mixtures prepared and tested in this research. Finally, the models were compared with the current models of several codes for ordinary Portland cement (OPC) concrete. The proposed models provided good accuracy with a determination coefficient greater than 60% for all models; such a value is considered large enough for big datasets. The behavior of GPC is not well-represented by OPC concrete standards, and GPC also displays a lower elastic modulus at similar strength. A constitutive model is proposed to describe GPC’s full stress–strain response, with the resulting equations providing relatively accurate predictions of its mechanical behavior. Compared to OPC concrete, GPC shows notably greater deformation, characterized by a wider range and higher average for both strain at peak stress (mean 0.00296) and ultimate strain (mean 0.01002). This work’s results may prompt further detailed research on GPC’s mechanical and, importantly, structural behavior. Full article

Geopolymer concrete (GPC) offers reduced carbon emissions and employs industrial by-products such as fly ash and ground granulated blast furnace slag (GGBFS). In this study, the synergistic augmentation of shear carrying capacity in steel-fiber-reinforced rubberized geopolymer concrete (FRGC) incorporating industrial by-products such as fly ash, GGBFS, and recycled rubber for sustainable construction is investigated. The reinforced rubberized geopolymer concrete (RFRGC) mixtures contained 20% rubber crumbs as a partial replacement for fine aggregate, uniform binder, and alkaline activator. The findings revealed that 1.25% steel fiber achieved optimal hardened properties (compressive strength, flexural, and split tensile strength), with 12 M sodium hydroxide and oven curing achieving maximum values. An increase in molarity improved geopolymerization, with denser matrices, while oven curing boosted polymerization, enhancing the bonding between the matrix and the fiber. The effect of steel fiber on the shear carrying capacity of RFRGC beams without stirrups is also discussed in this paper. An increased fiber content led to an increased shear carrying capacity, characterized by an improvement in first crack load and a delayed ultimate failure. These results contribute to sustainable concrete technologies for specifically designed FRGC systems that can balance structural toughness, providing viable alternatives to traditional concrete without compromising strength capacity. Full article

Rubberized concrete is a more environmentally friendly material than natural concrete as it helps to reduce rubber disposal issues and has superior impact resistance. Geopolymer concrete, on the other hand, is an economical concrete with higher mechanical properties than nominal concrete that uses fly ash and slag, among other industrial solid wastes, to lower carbon footprints. Rubberized geopolymer concrete (RuGPC) combines the advantages of both concrete types, and a thorough grasp of its dynamic compressive characteristics is necessary for its use in components linked to impact resistance. Despite the advantages of RuGPC, predicting its mechanical characteristics is sometimes difficult because of variations in binder type and combination. This research investigated the combined effect of ground granulated blast furnace slag (GGBFS) and fly ash (FA) on the workability, compressive strength, and stress–strain characteristics of RuGPC with rubber at 0%, 10%, and 20% fine aggregate replacement. Thereafter, energy absorption and ductile characteristics were evaluated through the concrete toughness and ductility index. Numerical models were proposed for the cube compressive strength, modulus of elasticity, and peak strain of RuGPC at different percentages of crumb rubber. It was found that RuGPC made with GGBFS/FA had similar stress–strain characteristics to FA- and MK-based RuGPC. At 20% of crumb rubber aggregate replacement, the workability, compressive strength, modulus of elasticity, and peak stress of RuGPC reduced by 8.33%, 34.67%, 43.42%, and 44.97%, while Poisson’s ratio, peak, and ultimate strain increased by 30.34%, 8.56%, and 55.84%, respectively. The concrete toughness and ductility index increased by 22.4% and 156.67%. The proposed model’s calculated results, with R² values of 0.9508, 0.9935, and 0.9762, show high consistency with the experimental data. RuGPC demonstrates high energy absorption capacity, making it a suitable construction material for structures requiring high-impact resistance. Full article

The construction industry urgently requires sustainable alternatives to conventional concrete to reduce its environmental impact. This study addresses this challenge by developing machine learning-optimized geopolymer concrete (GPC) using industrial waste fly ash as cement replacement. An integrated Taguchi–Grey relational analysis (GRA) and artificial neural network (ANN) approach was developed to simultaneously optimize mechanical properties and environmental performance. The methodology analyzes over 1000 data points from 83 studies to identify key mix parameters including fly ash content, NaOH/Na₂SiO₃ ratio, and curing conditions. Results indicate that the optimized FA-GPC formulation achieves a 78% reduction in CO₂ emissions, decreasing from 252.09 kg/m³ (GRC rank 1) to 55.0 kg/m³, while maintaining a compressive strength of 90.9 MPa. The ANN model demonstrates strong predictive capability, with R² > 0.95 for strength and environmental impact. Life cycle assessment reveals potential savings of 3941 tons of CO₂ over 20 years for projects using 1000 m³ annually. This research provides a data-driven framework for sustainable concrete design, offering practical mix design guidelines and demonstrating the viability of fly ash-based GPC as high-performance, low-carbon construction material. Full article

The increasing demand for sustainable construction materials has driven the exploration of alternatives to traditional cement-based concrete. In this context, this study investigates a cement-less material, specifically an alkali-activated or geopolymer concrete (GPC), which presents potential environmental benefits. The material has been characterized with respect to both its fresh and hardened properties, providing groundwork for future structural applications. A key focus of the research is the bond behavior between GPC and reinforcing bars, including both steel and non-metallic fiber-reinforced polymer (FRP) bars. The use of non-metallic bars is particularly relevant as they offer the potential to enhance the durability of structures by mitigating issues such as corrosion. Current research lacks comprehensive studies on factors affecting stress transfer at the GPC-reinforcing bar interface, such as bar diameter, bond length, and surface finish. This study aims to expand knowledge on the bond between GPC and steel/FRP rebars through experimental and analytical approaches. The tests, which included different bar types and bond lengths, showed that GPC exhibited similar bond behavior with steel and ribbed glass FRP bars in terms of bond strength and stress-slip curves. The results indicate that GPC exhibits comparable bond strength and stress-slip behavior when reinforced with either steel or ribbed glass FRP bars. Full article

As cement production causes large amounts of CO₂ emissions and is not sustainable, there is a growing worldwide interest in developing cleaner construction materials by reducing carbon emissions and reusing existing industrial waste. Also, antimicrobially active construction materials are gaining attention due to enhancing structural longevity. By preventing microbial growth, these materials help to improve indoor air quality and occupant health. Geopolymer mortars/concretes (GPM/GPC) with high mechanical, physical and durability properties are considered as an eco-friendly alternative to ordinary Portland cement (OPC) mortars/concretes. In this study, the composition, microstructural, mechanical and antimicrobial properties of geopolymers produced at different curing temperatures (60, 80, 100 and 120 °C) were investigated. Low-lime fly ash was used as binder and sodium silicate and sodium hydroxide were used as the alkaline solution in geopolymer production. Although X-ray fluorescence (XRF) results showed an increase in geopolymerization products with increasing temperature, SEM analysis showed that the crack formation that occurs in the microstructure of geopolymers cured above 100 °C leads to decreased mechanical properties. The strength and antimicrobial performance test results for geopolymer mortars showed that the optimum temperature was 100 °C, and the highest compressive strength (48.41 MPa) was reached at this temperature. A decrease in strength was observed due to cracks occurring in the microstructure at higher temperatures. The agar diffusion method was used to determine the antimicrobial activity of GPMs against four bacteria and one fungus species. The antimicrobial activity test results showed that the samples subjected to thermal curing at 100 °C formed the highest inhibition zones (38.94–49.24 mm). Furthermore, the alkalinity of the components/mixtures has a direct relationship with antimicrobial activity. As a result, GPMs with superior antimicrobial and mechanical properties can be considered as promising building materials, especially for construction applications where hygiene is a priority and for structures that are likely to be exposed to microbial corrosion. Full article

The usage of geopolymer-based materials (GPBMs) in concrete structures has been broadly promoted by the current construction sector. GPBMs have an outstanding influence on enhancing concrete mechanical properties. Geopolymers (GPs) also have a potential impact on reducing the carbon dioxide emissions emitted by the current cement production procedure. Therefore, this paper aims to evaluate the impact of some variables that affect green and mechanical properties of fly ash-based geopolymer concretes (FA–GPCs), i.e., different silica fume (SF) contents, alkaline activator solution (AAS) percentages, sodium silicate-to-sodium hydroxide (SS/SH) ratios, sodium hydroxide (NaOH) molarity, and additional water. A slump test was used to evaluate the concrete workability to assess the green properties of the designed fly ash-geopolymer concrete mixes (FA–GPCMs). The 14- and 28-day compressive strengths were used to evaluate the concrete’s mechanical properties. Results indicate that the workability of prepared FA–GPCMs reduced with improving SF content (5% to 30%), SS/SH ratio (1% to 3%), and NaOH molarity (10 M to 16 M), while reducing alkaline activator percentages to 35% resulted in a decrease in the FA–GPCMs’ workability. Also, increasing SF replacement percentages from 5% to 15% in FA–GPCMs resulted in significant 14- and 28-day FA–GP compressive strength enhancements compared to FA–GPCM produced with 0% SF, while SF contents of 20%, 25%, and 30% led to a decline in the 14- and 28-day FA–GPC compressive strength compared to that of G1–SF15%. Full article

Awareness of environmental sustainability is driving the shift from conventional Portland cement, a major contributor to carbon dioxide emissions, to more sustainable alternatives. This study focuses on developing a geopolymer concrete by optimizing geopolymer concrete mixtures with various ratios of Ground Granulated Blast Furnace Slag (GGBS) and pulverized fly ash (PFA) as precursors, aiming to find a mix that maximizes strength while minimizing environmental impacts. The precursor was activated using a laboratory-synthesized silica fume (SF)-derived sodium silicate solution in combination with NaOH at a molarity of 10M. This study aims to find the optimal geopolymer concrete mix with a 0.55 water-to-binder ratio, a 0.40 alkali-to-precursor ratio, and a 1:1 sodium silicate to sodium hydroxide ratio. Ordinary Portland cement was used as the control mix binder (C), while the geopolymer mixes included varying GGBS-PFA compositions [CL0 (50% GGBS—50% PFA), CL1 (60% GGBS—40% PFA), CL2 (70% GGBS—30% PFA), CL3 (80% GGBS—20% PFA), and CL4 (90% GGBS—10% PFA)]. The engineering performance of the mixtures was assessed using slump, unconfined compressive strength, split tensile, and flexural strength tests in accordance with their relevant standards. Observations showed that GPC specimens exhibited similar or slightly higher strength values than conventional concrete using PC. In addition to strength, geopolymers have a smaller environmental footprint, consuming less energy and reducing greenhouse gas emissions. These qualities make geopolymer concrete a sustainable construction option that aligns with global efforts to reduce carbon emissions and conserve resources. Full article

Geopolymer concrete (GPC) can be produced by the chemical activation of industrial by-products and processed natural minerals that contain aluminosilicates with the presence of an alkaline activator. Raw components are one of the critical parameters affecting geopolymer performance. On the other hand, the mixing procedure of geopolymer concrete is not any less important. Few demonstrative constructions have been built using GPC as a greener alternative to Portland cement concrete. Numerous variables affect GPC manufacture, such as raw material specification, activator type and dosage, and curing regimes. Despite the conventions of the building industry, the lack of proper mix design methods limits the wide acceptance of GPC in the industry. This report conducted experimental trials on GGBS-based GPC to optimize a mixing design procedure to achieve best mechanical strength and structural integrity. Geopolymer concrete properties were evaluated through slump and unconfined compressive strength tests. The laboratory trials in this report revealed that all geopolymer mixes, except SD0HV and 1W-SG, exhibited high workability values. Also, the presence of an alkaline activator was vital to attain satisfactory compressive strength values. The alkaline activator could be used when cooled and reached room temperature after two hours of preparation and was not necessary after 24 h. Mix G-(0.5W-S) with a 0.5A.A. (alkaline activator)/precursor (GGBS) ratio, SSA (sodium silicate alternative)/SH (sodium hydroxide with 10 M molarity) ratio of 1:1, and 0.55 W/B (water to binder) ratio is recommended to achieve best mechanical performance and structural integrity. Full article

One of the important findings of the recent decades in the construction industry is composite sandwich panels (CSPs), which have benefits of being lightweight, providing thermal insulation, and aiding the economy; they are transforming continuously through many add-ons as needed by the industry. With the demand for sustainability in the field, CSPs need structural and sustainable enhancement. In the present study, an approach for the same has been attempted with geopolymer concrete (GPC) and novel nylon fibre to improve the sustainability and structural benefits, respectively. With various material combinations including GPC reinforced with fibres, six CSPs were cast and studied. The inherent limitations of GPC have been addressed by the nylon fibre reinforcement instead of using steel fibres, which have a similar strength, considering the aim of maintaining the density of the wythe material. A comparison of the flexural behaviour of the CSPs through the parameters of load–deflection, ductility, and toughness was made using the four-point loading test. The results of the test specify that the fibres enhance the performance of the CSPs under flexural loading. Full article

Climate change poses a significant threat to the durability of reinforced concrete (RC) bridges, which are particularly vulnerable to chloride-induced corrosion of steel reinforcements. The main problem for the current research is the increase in the projected maximum temperature values, especially for the high emission scenario in the future because of climate change, applied to the upper part of the RC bridge deck made of geopolymer concrete (GPC) composed of 50% fly ash and 50% slag. This will reduce the corrosion initiation time and the safety and durability of the RC bridge deck structure. Despite extensive research on chloride-induced corrosion, there is a scientific gap in understanding how future climate variations will influence the rate of corrosion in RC bridges. Specifically, comprehensive studies assessing the effect of maximum temperature on the probability of the corrosion initiation process in RC bridge decks made of GPC exposed to chloride environments are lacking. This study used the Monte Carlo simulation method to assess the probability of corrosion initiation (PCI) under various future climate scenarios for Toronto City, Canada. This research examines the impact of the maximum temperature and relative humidity on the diffusion coefficient of chloride ions in concrete. It assesses the PCI for different concrete cover thicknesses in RC decks made of geopolymer concrete composed of 50% fly ash and 50% slag over specified periods, dealing with the sensitivity analysis for this parameter among different parameters defined in the performance function. The results indicate a substantial increase in the PCI for a 40 mm concrete cover compared with a 50 mm cover in various years. Furthermore, maximum temperatures ranging from 40 °C to 45 °C significantly increase the PCI compared with temperatures between 25 °C and 35 °C for a 50 mm concrete cover. Finally, polynomial functions have been deduced to investigate the reliability index and PCI as a function of various coefficients of variations for mean concrete covers made of GPC at various maximum temperature values in different years. These findings provide important information for the design and maintenance of RC structures, ensuring their longevity in the face of climate change. Full article

The use of geopolymer as a cementitious material for geopolymer concrete (GPC) is beneficial for the sustainable development and green transformation of the construction industry. Geopolymer concrete has many advantages, such as high strength, heat and corrosion resistance, low hydration heat, and carbon emissions. This paper adopted the water–binder ratio, alkaline activator modulus, and slag replacement as the influencing factors, and used the 28-day compressive strength and flexural strength of geopolymer concrete as the response values to seek a reasonable mix design. In addition, through microstructure analysis, the mechanism of geopolymer on concrete was studied. The results indicated that as the water–binder ratio increased, the compressive strength first increased and then decreased, while the flexural strength continuously decreased. As the amount of slag replacement increased, the compressive strength and flexural strength would also increase. The effect of alkaline activator modulus on compressive strength and flexural strength was not significant. Through response surface methodology (RSM) analysis, the optimal design of geopolymer concrete was determined to have a water–cement ratio of 3.50, a modulus of 1.54 for alkaline activator solution, and a slag substitution rate of 47%. The microstructure analysis showed that the water–binder ratio and slag replacement improved the pore structure and density of concrete, thereby enhancing the macroscopic mechanical properties of concrete. This paper can provide a theoretical basis for the application of geopolymer concrete in engineering. Full article

The precast segmental column (PSC) has been proposed for reducing onsite construction time and minimizing impacts on traffic and the environment. It has been proven to have good seismic performance according to previous studies. However, due to the rocking behavior of the column, the toe of the bottom segment could experience excessive compressive damage. In addition, the commonly used steel rebars in the PSC could experience corrosion problems during the service life of the structure. Moreover, ordinary Portland cement concrete (OPC) is normally used in the construction of the PSC, but the manufacturing processes of the OPC could emit a lot of carbon dioxide. This paper investigates the seismic performance of PSCs incorporating Basalt Fiber Reinforced Polymer (BFRP) bars and geopolymer concrete (GPC) segments. To mitigate the concrete crushing damage of the segment, the BFRP sheet was used to wrap the bottom segment of one of the specimens. The results revealed that the BFRP-reinforced geopolymer concrete PSC exhibited good seismic performance with minimal damage and small residual displacement. Strengthening the bottom segment with BFRP wrapping proved to be effective in reducing concrete damage. As a result, the column with BFRP wrap demonstrated the ability to withstand ground motions with higher Peak Ground Acceleration (PGA) compared to the column without strengthening. Full article

Sustainability and the quest for a more robust construction material cannot be divorced from each other. While Portland cement has revolutionized the construction sector, its environmental toll, particularly in greenhouse gas emissions and global warming, cannot be ignored. Addressing this dilemma requires embracing alternatives like geopolymer cement/geopolymer binder (GPC/GPB). Over the last few decades, considerable strides have been achieved in advancing GPC as a sustainable construction material, including its utilization in pavement construction. Despite these advances, gaps still exist in GPC optimal potential in pavement construction, as most studies have concentrated on specific attributes rather than on a comprehensive evaluation. To bridge this gap, this review adopts a novel, holistic approach by integrating environmental impacts with performance metrics. To set the stage, this review first delves into the geopolymer concept from a chemistry perspective, providing an essential broad overview for exploring GPC’s innovations and implications in pavement applications. The findings reveal that GPC not only significantly reduces greenhouse gas emissions and energy consumption compared to Portland cement but also enhances pavement performance. Further, GPC concrete pavement exhibits superior mechanical, durability, and thermal properties to ensure its long-term performance in pavement applications. However, challenges to GPC utilization as a pavement material include the variability of raw materials, the need for suitable hardeners, the lack of standardized codes and procedures, cost competitiveness, and limited field data. Despite these challenges, the process of geopolymerization presents GPC as a sustainable material for pavement construction, aligning with Sustainable Development Goals (SDGs) 3, 9, 11, and 12. Full article

Concrete-filled built-up cold-formed steel (CFS) columns offer enhanced load-carrying capacity, improved strength-to-weight ratios, and delayed buckling through providing internal resistance and stiffness due to the concrete infill. Integrating sustainable alternatives like self-compacting geopolymer concrete (SCGC) with low carbon emissions is increasingly favoured for addressing environmental concerns in construction. This review aims to explore the current knowledge regarding CFS built-up composite columns and the performance of SCGC within them. While research on geopolymer concrete-filled steel tubes (GPCFSTs) under various loads has demonstrated high strength and ductility, investigations into built-up sections remain limited. The literature suggests that geopolymer concrete’s superior compressive strength, fire resistance, and minimal shrinkage render it highly compatible with steel tubular columns, providing robust load-bearing capacity and gradual post-ultimate strength, attributed to the confinement effect of the outer steel tubes, thereby preventing brittle failure. Additionally, in built-up sections, connector penetration depth and spacing, particularly at the ends, enhances structural performance through composite action in CFS structures. Consequently, understanding the importance of using a sustainable and superior infill like SCGC, the cross-sectional efficiency of CFS sections, and optimal shear connections in built-up CFS columns is crucial. Moreover, there is a potential for developing environmentally sustainable built-up CFS composite columns using SCGC cured at ambient temperatures as infill. Full article