Search Results (401)

Agricultural residues and agro-waste are increasingly recognized as valuable reinforcements for sustainable composite materials. Natural fibers derived from these biomasses offer biodegradability, low density, renewability, and potential environmental benefits. However, their performance and sustainability depend strongly on extraction, surface treatment, and processing conditions. Therefore, evaluating the environmental emissions associated with natural fiber biocomposites is essential before claiming sustainability advantages. In this research, flax, jute, kenaf, and bagasse fibers were extracted and treated using an eco-friendly sodium bicarbonate solution, then incorporated into polylactic acid (PLA) matrix to fabricate biocomposites via injection molding. A life cycle assessment (LCA) was conducted using the ReCiPe midpoint (H) method, with a functional unit defined as “per kg” of manufactured biocomposite. The results revealed that jute fiber composites generated the highest emissions across several impact categories, including climate change (1.290 × 10¹ kg CO₂-Eq), terrestrial ecotoxicity (6.327 × 10¹ kg 1,4-DCB-Eq), human toxicity: carcinogenic effects (1.923 kg 1,4-DCB-Eq), and fossil resource use (3.202 kg oil-Eq). Jute also showed a 3.6% increase in terrestrial ecotoxicity and a 19.5% increase in land compared to flax, although it exhibited a 6.5% lower impact related to bagasse. A ±20% electricity-consumption sensitivity analysis further highlighted the dependence of environmental impacts on processing energy demand. Full article

In this research, PLA biocomposites reinforced with 20 wt% flax fibers modified with 1, 5, 10, and 20% concentrations of trans-cinnamic acid (TC) were prepared. The materials were systematically characterized to evaluate their structural, thermal, viscoelastic, surface, and functional properties. Thermal stability and phase transitions were analyzed using thermogravimetric analysis (TG) and differential scanning calorimetry (DSC), while viscoelastic behavior and molecular relaxation processes were investigated by dynamic mechanical analysis (DMA). To elucidate failure mechanisms and interfacial quality, fracture surface morphology after tensile testing was observed using scanning electron microscopy (SEM). Surface wettability was determined through water contact angle measurements, and antibacterial activity against Escherichia coli and Staphylococcus aureus was evaluated to assess the functional potential of the developed biocomposites. The results demonstrated that moderate fiber modification improved interfacial adhesion and enhanced thermo-mechanical performance. The highest contact angles were observed for 5% and 10% TC concentrations, indicating increased surface hydrophobicity, while strong antibacterial activity (R ≥ 6) was achieved for 10% and 20% TC. The research confirms that trans-cinnamic acid concentration governs multiple structure–property relationships, enabling controlled tuning of mechanical reinforcement and antibacterial functionality. Full article

This study presents a machine learning framework for the reconstruction of fatigue life and fracture toughness in natural fiber-reinforced composites, evaluating the predictive accuracy of six regression algorithms—Random Forest, Gradient Boosting, Support Vector Machine, Neural Network, Ridge Regression, and Lasso Regression—using a controlled synthetic dataset of 600 samples generated from established Basquin fatigue and Rule of Mixtures fracture equations, incorporating stochastic noise calibrated to experimental scatter (CV = 15–50%), with log-normal noise standard deviation of 0.20 for fatigue life and Gaussian noise standard deviation of 0.15 for fracture toughness. The dataset encompasses eight natural fiber types (flax, jute, sisal, hemp, bamboo, coconut, banana, and pineapple) and five matrix systems (epoxy, polyester, PLA, vinyl ester, and polyurethane). Models were evaluated using a 70-15-15 train–validation–test split with 5-fold cross-validation and exhaustive grid search hyperparameter optimisation. Gradient Boosting achieved R² = 0.93 for fatigue life and Stacking Ensemble achieved R² = 0.87 for fracture toughness, representing 97% and 89% of their respective noise-ceiling values (theoretical maximum R² of 0.96 and 0.98 given the programmed noise levels). The ML models perform supervised function approximation—learning to reconstruct the programmed generation equations rather than discovering novel physical composite behaviour—and function as automated surrogates for the governing equations. Feature importance analysis identified engineered composite indicators, stress amplitude, and fiber length as the most influential parameters. The framework provides a reproducible ML evaluation pipeline as a methodological template for future experimental composite studies. Full article

Flax Fiber Reinforced Polymer (FFRP), as a green material with nonlinear large deformation characteristics, is used in the reinforcement of timber structures. Due to the similar elastic moduli of FFRP, adhesive, and timber, stress concentration at the interface is significantly reduced, demonstrating favorable interfacial performance. This study investigates the effects of adhesive layer thickness and FFRP laminate thickness on the strain distribution, bond-slip relationship, and stress distribution at the FFRP-timber interface through two different types of single-lap shear tests, thereby revealing the bonding mechanism at the FFRP-timber interface. The results show that both the ultimate load and the ultimate strain at the loaded end decrease with increasing adhesive thickness. For instance, increasing the adhesive thickness from 0.5 mm to 3 mm led to a 68.6% reduction in peak interfacial shear stress. The thickness of the adhesive has a minor influence on the overall trend of the bond-slip relationship curve for the FFRP-timber interface, with the curve consisting of an ascending branch, a descending branch, and a horizontal plateau. The distribution patterns of interfacial shear stress for different adhesive layer thicknesses are similar: at the initial loading stage, the maximum shear stress appears at the loaded end and gradually decreases toward the free end; as the load increases, the peak shear stress shifts from the loaded end toward the free end. With an increase in the number of fiber layers in the FFRP laminate, the strain transfer efficiency first increases and then decreases, reaching its maximum when the number of fiber layers reaches 30. The maximum stress increases with the number of FFRP fiber layers, and the stress transfer efficiency peaks at 30 layers. Full article

Thermoplastic hybrid composites reinforced with flax and glass fibers offer a sustainable, high-performance alternative for structural applications by balancing stiffness and energy absorption. This study investigated the impact of low-pressure plasma treatment on the thermal, mechanical, and microstructural properties of two polypropylene-based laminate configurations, PFGFP (polypropylene–flax–glass–flax–polypropylene) and PFGGFP (polypropylene–flax–glass–glass–flax–polypropylene), to optimize fiber–matrix interfacial adhesion. Materials were characterized using differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), tensile testing, and scanning electron microscopy (SEM). The plasma treatment significantly enhanced the lignocellulosic fibers’ surface energy, reducing the flax contact angle from 93.5° to 56.1°. DSC analysis revealed a matrix crystallinity of 35.41%, while TGA confirmed flax thermal stability up to 250 °C. The PFGFP configuration exhibited superior mechanical performance (Tensile strength = 61.69 MPa; Young’s modulus = 518.62 MPa), attributed to its symmetric architecture and efficient fiber impregnation. Conversely, PFGGFP showed reduced strength and microstructural voids due to incomplete wetting in dense reinforcement regions. These findings conclude that the synergy between plasma surface modification and optimized laminate architecture is critical for the design of high-performance sustainable composites, providing an objective basis for improving interfacial compatibility in hybrid systems. Full article

The rising environmental concerns over cement-based construction materials have led to the development of sustainable alternatives. Among these, geopolymers represent a promising class of low-carbon binders offering environmental benefits and competitive mechanical properties; however, their intrinsic brittleness limits their tensile and post-cracking performance. This study investigates the adoption of flax fibers as natural reinforcement to enhance ductility and post-peak behavior of metakaolin-based geopolymers. The performance of metakaolin-based geopolymers with flax fibers (MKFLAX) was experimentally evaluated in terms of strength, stiffness, toughness, and failure behavior. The addition of flax fibers enhanced ductility, toughness, and post-peak load-carrying capacity while slightly improving stiffness due to the bridging of cracks and the fiber pull-out mechanism. In comparison with the available literature on sisal, flax, and jute fibers, flax fibers showed improved performance due to the better dispersion within the matrix and higher tensile modulus. These findings highlight that flax fiber-reinforced metakaolin geopolymers show enhanced post-cracking behavior at the laboratory scale and could be of interest for sustainable cementitious materials, subject to further validation at the structural scale. Furthermore, a nonlinear finite element model was adopted based on damage mechanics to simulate the damage localization, stress–strain response and post-peak behavior of geopolymer composites. The numerical results showed a reasonable agreement with the experimental trends, particularly in the elastic and early softening phases. The findings are limited to the studied material system, fiber content, and small-scale samples and should be viewed as trend-level observations rather than generalized performance claims. Full article

For the development of effective and secure methods for plant genetic resources preservation, different storage treatments of fiber flax seeds were compared. Seeds of the flax variety Orshanskiy-2 in aluminum foil bags were stored at different low temperatures, including in liquid nitrogen. Agronomic characters of plants grown from them and next-generation seeds were compared. Plants grown from frozen seeds changed 14 out of 31 evaluated characters in comparison with the non-frozen control. The biggest changes were detected after gradual freezing in liquid nitrogen, due to mechanical damage of the seed coat, and storage at −10 °C for 24 years. Freezing had a negative effect on production characters (straw, fiber and seed) because of the reduction of the germinated plant number. Seeds stored for 24 years at −10 °C, compared to control plants, ripened earlier, grew higher, produced a greater yield of straw and fiber, but had reduced fiber quality and increased seed size. Plants of the next generation showed a tendency toward attenuation of the storage time influence on flax characters. However, it is unknown how many years this process will take. For seed preservation in GeneBanks, it is recommended to use several variants of storage conditions and use rapid cooling and/or cryoprotectors. The latter two methods, which have been successfully used for other crops, should be implemented only after preliminary experiments. Full article

The development of high-performance, sustainable biocomposites requires biodegradable matrices and optimized natural reinforcements. In this study, flax fiber-reinforced polylactic acid (PLA) hybrid biocomposites incorporating waste pistachio nut shells (WPNS), waste tea leaf fiber (WTLF), and waste quail eggshell (WQES) were developed and evaluated, with direct comparison to previously reported jute-based hybrid systems to assess the benefits of fiber substitution. The composites were fabricated via compression molding and characterized for their mechanical, thermal, acoustic, surface, and moisture-related properties. Replacing the jute with flax resulted in a consistent performance enhancement. Among the hybrids, the flax–WPNS composite exhibited the highest tensile and flexural performance, achieving tensile strength improvements of approximately 30–40% over neat PLA due to effective stress transfer and crack deflection. The flax–WTLF composite showed superior acoustic behavior, attaining a maximum sound absorption coefficient of approximately 0.65–0.70 at mid-to-high frequencies, attributed to its porous microstructure. In contrast, the flax–WQES composite demonstrated the highest thermal conductivity (0.54 W/(mK)) and apparent density (2.24 g/cm³), reflecting dense packing and the presence of CaCO₃-rich particles. Scanning electron microscopy revealed distinct microstructural mechanisms governing these property-specific responses, including differences in interfacial bonding, void distribution, and filler packing efficiency. An integrated fuzzy CRITIC–COPRAS multicriteria decision-making approach identified the flax–WPNS hybrid as the optimal overall formulation. The results clearly demonstrate that flax fibers outperform jute as a reinforcement in PLA-based hybrid biocomposites, and that targeted combinations of flax and waste-derived fillers enable multifunctional performance optimization for sustainable engineering applications. Full article

Flax (Linum usitatissimum L.) is a crop widely cultivated for fiber and oil production. The screening method for flax breeding must effectively address the biochemical characteristics of flaxseeds. In this study, to characterize flax cultivars, we extracted oil, defatted kernel, hull, and mucilage from whole seeds for the ATR-FT-MIR and FT-Raman spectroscopic measurements. In addition, for ATR-FT-MIR analysis, oil samples were obtained by pressing the flaxseed directly onto the crystal surface. After removing any seed residues, a grease stain was used for the measurement, allowing for the acquisition of the oil spectrum from a single seed. This method also enabled the detection of free fatty acids, serving as evidence of seed damage. Both methods effectively estimated the degree of unsaturation as a cultivar marker. The vibrational spectra of defatted kernels showed strong protein features; polysaccharide bands dominated in hull and mucilage spectra. Discrimination of flax cultivars using principal component analysis of vibrational spectra in specific regions was the most promising for flaxseed oil and mucilage. Multivariate analysis of a set of selected variables sensitive to the flaxseed oil composition successfully distinguished all flax cultivars of this study. The strong correlation observed between ATR-FT-MIR and FT-Raman results confirmed that these methods are comparable for characterizing different grades of flaxseed oil. Full article

This article presents an experimental investigation of the effect of water aging on the static mechanical behavior and damage mechanisms of bio-based sandwich structures with auxetic cores using acoustic emission (AE) monitoring. Both the skins and the core are manufactured by 3D printing using polylactic acid (PLA) reinforced with short flax fibers. Four auxetic core configurations, differing in the number of unit cells across the core width, are considered. The specimens are immersed in water at room temperature to characterize their absorption behavior, which follows a Fickien’s diffusion law model with different saturation levels. Static three-point bending tests are performed at various immersion times to evaluate the influence of moisture on mechanical performance. The results show a progressive degradation of mechanical properties with increasing water exposure time, with the four-cell core configuration exhibiting the highest mechanical performance. Acoustic emission (AE) monitoring is employed to analyze damage evolution as a function of hydrothermal aging. AE parameters such as amplitude, energy, and cumulative event count are used to identify and classify the different damage mechanisms. This approach highlights the effectiveness of acoustic emission for structural health monitoring and for assessing the durability of auxetic core sandwich structures subjected to moisture. Full article

Wave Energy Converter (WEC) buoys operate in aggressive marine environments that impose demanding requirements on structural materials, particularly in terms of moisture resistance, mechanical reliability, and long-term durability. Conventional glass fiber reinforced composites meet these performance requirements but raise sustainability concerns due to their high environmental footprint and limited recyclability. This study addresses this challenge by introducing a systematic, application-driven multi-criteria decision-making (MCDM) framework specifically tailored for material selection in marine renewable energy devices. The novelty of this work lies in the integration of marine durability-dominated criteria weighting with sustainability metrics, moving beyond cost-driven selection approaches commonly reported in the literature. Four cellulosic natural fibers, flax, hemp, kenaf, and sisal, are evaluated as reinforcements for polymer composites intended for point-absorber WEC buoy structures, using conventional E-glass as a baseline reference. Ten performance criteria covering mechanical properties, environmental durability, manufacturing feasibility, and sustainability are defined and objectively weighted using the entropy method to minimize subjective bias. Moisture resistance emerges as the most influential criterion with a weight of 0.142, underscoring its role as a primary degradation mechanism in marine environments, while material cost receives the lowest weight of 0.057, reflecting the prioritization of long-term performance over initial cost. The results identify flax as optimal reinforcement, achieving the highest aggregated score of 4.022 by effectively balancing mechanical performance, resistance to marine exposure, and environmental sustainability. This work introduces a novel decision-support tool for the sustainable design of buoy structures using natural fiber-reinforced composites and establishes a foundation for future optimization of such composites in wave energy applications. Full article

Recently, with concern for the environment and the request for sustainable materials, more researchers and manufacturers have focused on the substitute solution of synthetic fiber reinforcement composites in industry applications. Green hybrid composites with natural components can present excellent sustainability, possess superior mechanical behavior, and reduce hazards. Hybridization technology allows new materials to inherit their raw materials’ characteristics and generate new properties. The current study designed novel double-walled shell structures (DS1R4L, DS2R8L, and DS5R12L), containing two thin walls and different numbers of ring and longitudinal stiffeners, as unmanned maritime vehicle (UMV) components. A normal single-walled cylindrical shell was used as a control. These models will be made of hybrid kenaf/flax/glass-fiber-reinforced composites, GKFKG and GFKFG, created in the ANSYS Workbench. The mechanical responses (deformation, stress, and strain characteristics) of models were examined under three loading conditions (end force, end torque, and hydrostatic pressure) to evaluate the influence of both material change and structural configuration. Compared to the single-walled structure, the double-walled configurations display minimized deflection and torsional angle. Moreover, GKFKG-made structures are better than GFKFG-made ones. The research contributes positively to advancing the application of hybrid kenaf/flax/glass-fiber-reinforced composites in UMV structures and promotes the development of green sustainable materials. Full article

This study examined the drilling performance of five polymer composite systems: three natural fiber (jute, flax, hemp) composites with aluminum particle-reinforced epoxy, one glass fiber-reinforced composite with the same matrix, and an unreinforced aluminum particle-filled epoxy (Al–epoxy). Drilling experiments were performed at spindle speeds of 1500 and 3000 rpm with feed rates of 50, 75, and 100 mm/min in order to evaluate the effect of cutting parameters on the drilling performance. Cutting zone temperatures were measured using thermocouples embedded within the drill bit’s cooling channels, while thrust forces were recorded with a dynamometer. Additionally, hole exit damage and inner hole surface roughness were evaluated to assess machining quality. The results showed that increasing spindle speed reduces thrust forces due to thermal softening of the matrix, whereas natural fiber-reinforced composites generally exhibit higher thrust forces and slightly rougher inner hole surfaces compared to synthetic counterparts. During drilling, the measured thrust forces ranged from 320 to 693 N for the glass fiber-reinforced specimen and from 335 to 702 N for the Al–epoxy specimen, while for natural fiber-reinforced composites the thrust force values were 352–679 N for hemp, 241–719 N for jute, and 571–732 N for flax specimens. Synthetic specimens (glass fiber and Al–epoxy) exhibited comparable cutting temperature ranges (288–371 °C and 248–327 °C, respectively), whereas natural fiber-reinforced composites showed higher and broader temperature ranges of 311–389 °C for hemp, 368–374 °C for jute, and 307–379 °C for flax specimens. The overall results indicated that lower forces were generated during the drilling of synthetic glass fiber-reinforced composites, while among natural fiber-reinforced plastics, flax fiber-reinforced composites stood out by exhibiting a balanced machining response. Full article

Ultraviolet (UV) curable resins are widely used in photopolymerization-based 3D printing due to their rapid curing and compatibility with high-resolution processes. However, their brittleness and limited mechanical performance restrict their applicability, particularly in impact-resistant high-performance 3D-printed structures. Inspired by the mantis shrimp’s exceptional energy absorption and impact resistance, attributed to its helicoidal fiber architecture, we developed a Bouligand flax fiber-reinforced composite laminate. By constructing biomimetic helicoidal composites based on Bouligand arrangements, the mechanical performance of flax fiber-reinforced UV-curable resin was systematically investigated. The influence of flax fiber orientation was assessed using mechanical testing combined with the digital image correlation (DIC) method. The results demonstrate that a 45° interlayer angle of flax fiber significantly enhanced the fracture energy of the resin from 1.67 KJ/m² to 15.41 KJ/m², an increase of ~823%. Moreover, the flax fiber-reinforced helicoidal structure markedly improved the ultimate tensile strength of the resin, with the 90° interlayer angle of flax fiber exhibiting the greatest enhancement, increasing from 5.32 MPa to 19.45 MPa. Full article

This study compares fly-ash-based geopolymers reinforced with short glass fibers (GF) or flax fibers (FF). Four mixes were produced: reference (FA), 1 wt% GF, 1 wt% FF, and a hybrid (0.5 wt% GF + 0.5 wt% FF). These compositions were cast into prism and cube molds, cured at 75 °C for 24 h, and tested after 28 days. Mechanical testing included compressive strength and three-point bending, phase composition by XRD, and microstructure by optical and SEM microscopy. The GF composite showed the highest compressive strength (mean up to ~28–34 MPa versus ~17 MPa for the reference), while FF gave intermediate values (~11–22 MPa). During bending, the reference achieved the highest flexural strength (~5.5 MPa); fiber-reinforced mixes ranged from ~2.9 to 4.4 MPa. XRD indicated a typical amorphous aluminosilicate gel over crystalline remnants; SEM/optical observations revealed a denser, more compact matrix with fewer voids for GF systems, whereas FF and hybrid mixes exhibited localized porosity and fiber pull-out imprints affecting crack initiation/propagation. Overall, 1 wt% GF effectively enhances compressive performance and matrix densification, while fiber addition at the tested dosages does not improve flexural strength; optimizing fiber content/dispersion and interfacial treatment is recommended. Full article