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30 pages, 5018 KB  
Article
The Effect of an Earthquake on the Bearing Characteristics of a Soft-Rock-Embedded Bridge Pile with Sediment
by Xuefeng Ye, Xiaofang Ma, Huijuan Wang and Huina Chen
Buildings 2026, 16(2), 341; https://doi.org/10.3390/buildings16020341 - 14 Jan 2026
Abstract
Seismic action significantly affects the mechanical properties and failure characteristics of bridge pile foundations, soft rocks, and sediments. This study, by integrating shaking table tests, numerical simulations, and on-site monitoring, systematically analyzed the influence mechanisms of seismic intensity, sediment characteristics, and pile foundation [...] Read more.
Seismic action significantly affects the mechanical properties and failure characteristics of bridge pile foundations, soft rocks, and sediments. This study, by integrating shaking table tests, numerical simulations, and on-site monitoring, systematically analyzed the influence mechanisms of seismic intensity, sediment characteristics, and pile foundation layout on structural responses. Tests show that the 2.5-layer rock–sand pile exhibits nonlinear bearing degradation under seismic force: when the seismic acceleration increases from 0 to 100 m/s2, the bearing capacity of the pile foundation decreases by 55.3%, and the settlement increases from 3.2 mm to 18.5 mm. When the acceleration is ≥2 m/s2, the cohesion of the sand layer is destroyed, causing a semi-liquefied state. When it is ≥10 m/s2, the resistance loss reaches 80%. The increase in pore water pressure leads to dynamic settlement. When the seismic acceleration is greater than 50 m/s2, the shear modulus of the sand layer drops below 15% of its original value. The thickness of the sediment has a nearly linear relationship with the reduction rate of the bearing capacity. When the thickness increases from 0 to 1.4 cm, the reduction rate rises from 0% to 55.3%. When the thickness exceeds 0.8 cm, it enters the “danger zone”, and the bearing capacity decreases nonlinearly with the increase in thickness. The particle size is positively correlated with the reduction rate. The liquefaction risk of fine particles (<0.1 mm) is significantly higher than that of coarse particles (>0.2 mm). The load analysis of the pile cap shows that when the sediment depth is 140 cm, the final bearing capacity is 156,187.2 kN (reduction coefficient 0.898), and the maximum settlement is concentrated at the top point of the pile cap. Under the longitudinal seismic load of the pile group, the settlement growth rate of the piles containing sediment reached 67.16%, triggering the dual effect of “sediment–earthquake”. The lateral load leads to a combined effect of “torsional inclination”, and the stress at the top of the non-sediment pile reaches 6.41MPa. The seismic intensity (PGA) is positively correlated with the safety factor (FS) (FS increases from 1.209 to 37.654 when 10 m/s2→100 m/s2), while sediment thickness (h) is negatively correlated with FS (FS decreases from 2.510 to 1.209 when 0.05 m→0.20 m). The research results reveal the coupled control mechanism of sediment characteristics, seismic parameters, and pile foundation layout on seismic performance, providing key parameters and an optimization basis for bridge design in high-intensity areas. Full article
(This article belongs to the Section Building Structures)
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15 pages, 3415 KB  
Article
The Influence of Particle Shape and Surface Roughness of Fine Aggregates on the Technological Properties of Glass-Fiber-Reinforced Thin-Layer Concrete
by Ramune Zurauskiene, Asta Kičaitė and Rimvydas Moceikis
Materials 2026, 19(1), 214; https://doi.org/10.3390/ma19010214 - 5 Jan 2026
Viewed by 166
Abstract
Various methods for classifying and evaluating the shape, size, and surface texture of sand particles are examined, highlighting their impact on concrete mixture properties. This study emphasizes the role of particle morphology in determining concrete workability and segregation, particularly in glass-fiber-reinforced (GRC) thin-layer [...] Read more.
Various methods for classifying and evaluating the shape, size, and surface texture of sand particles are examined, highlighting their impact on concrete mixture properties. This study emphasizes the role of particle morphology in determining concrete workability and segregation, particularly in glass-fiber-reinforced (GRC) thin-layer concrete for building facade panels. The effects of different aggregate types on concrete workability and segregation are analyzed, showing that aggregates with spherical particles and a lower elongation index improve mixture consistency and reduce segregation. Three types of fine aggregates were used (instead of quartz sand in the mixtures, natural sand and granite screenings were chosen, which would be a sustainable alternative to quartz sand), and thin-layer glass-fiber-reinforced concrete using aggregates of different shapes was characterized by layering the mixture. The workability and segregation of fine-grained fiberglass-reinforced concrete mixtures depend on the aggregate particles’ shape. Up to 50% of quartz sand can be replaced with granite siftings or natural sand, as measured by the segregation index, as calculated according to the method proposed in this paper. Increasing the amount of natural sand from 10% to 50% also increases the segregation index from 1.9 to 2.6, and when using granite sifting aggregates, it rises from 2.6 to 3.5. Aggregates with spherical particles are more suitable for this thin-layer GRC concrete, if we examine the consistency parameters of fresh concrete and the possibilities of working with it in real production conditions. Full article
(This article belongs to the Section Construction and Building Materials)
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27 pages, 20165 KB  
Article
Genetic and Sealing Mechanisms of Calcareous Sandstones in the Paleogene Zhuhai–Enping Formations, Panyu A Sag, Pearl River Mouth Basin
by Yong Zhou, Guangrong Peng, Wenchi Zhang, Xinwei Qiu, Zhensheng Li, Ke Wang, Xiaoming Que and Peimeng Jia
Minerals 2025, 15(12), 1285; https://doi.org/10.3390/min15121285 - 7 Dec 2025
Viewed by 313
Abstract
Calcareous sandstones, acting as sealing layers, play a crucial role in hydrocarbon accumulation of formations with high sand content (sand content > 80%). However, the genetic mechanisms, sealing mechanisms, and effectiveness of calcareous sandstones remain unclear. This study takes the Zhuhai–Enping formations in [...] Read more.
Calcareous sandstones, acting as sealing layers, play a crucial role in hydrocarbon accumulation of formations with high sand content (sand content > 80%). However, the genetic mechanisms, sealing mechanisms, and effectiveness of calcareous sandstones remain unclear. This study takes the Zhuhai–Enping formations in the Panyu A Sag as an example. By comprehensively analyzing data from well logs, cores, cast thin sections, elemental geochemical analysis and carbon–oxygen isotopes, the genetic mechanisms, development patterns, and controlling effects on hydrocarbon accumulation of calcareous cement layers are investigated. The main findings are as follows: (1) The calcareous sandstone cements are mainly composed of dolomite, ankerite, and anhydrite. With increasing burial depth, dolomite transitions from micritic dolomite to silt-sized and fine-crystalline dolomite, and finally to coarse-crystalline dolomite. (2) The local transgression provided ions such as Ca2+ and Mg2+, forming the material basis for early dolomite formation. As burial depth increased, the diagenetic environment shifted from acidic to alkaline, leading to the dolomitization of early-formed calcite and the formation of ankerite. (3) The high source-reservoir displacement pressure difference effectively seals hydrocarbon accumulation. Vertically interbedded tight calcareous sandstones and thin marine transgressive mud-stones collectively control efficient hydrocarbon preservation and enrichment. This research addresses the current limits in the study of “self-sealing sandstone layers,” and provides new geological insights and predictive models for hydrocarbon exploration in sand-rich settings. Full article
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16 pages, 14514 KB  
Article
The Effect of Admixing Different Types of Fine Particles into the Coarse-Grained Layer on a Capillary Barrier Cover’s Water Storage Capacity: A Laboratory Study
by Chong Sun, Junjie Yang, Qiang Liu, Yalei Wu and Jiali Miao
Sustainability 2025, 17(22), 10301; https://doi.org/10.3390/su172210301 - 18 Nov 2025
Cited by 1 | Viewed by 266
Abstract
Capillary barrier covers (CBCs) have gained widespread application as engineered surface layers in landfill systems, agricultural water retention infrastructures, and slope protection designs due to their superior water storage capacity and lateral drainage characteristics. During the long-term service of CBCs, fine particles may [...] Read more.
Capillary barrier covers (CBCs) have gained widespread application as engineered surface layers in landfill systems, agricultural water retention infrastructures, and slope protection designs due to their superior water storage capacity and lateral drainage characteristics. During the long-term service of CBCs, fine particles may enter into the coarse-grained layer, which affects the water storage capacity and even causes CBCs to fail. Therefore, this study investigated the influence of admixing different types of soils (into the coarse-grained layer) and their proportions on water storage capacity through laboratory soil column experiments. The results indicate the following: (1) A method is proposed to determine the failure of the capillary barrier by utilizing the variation pattern of volumetric water content (VWC) at the fine–coarse-grained layer interface. (2) An effective capillary barrier can only be formed if the saturated permeability coefficient of the coarse-grained layer is at least one order of magnitude greater than that of the fine-grained layer. (3) When the saturated hydraulic conductivity of the fine particles incorporated into the coarse-grained layer is less than 10−5 cm/s, the matric potential of the fine-grained layer consistently exhibits a CBC line type. When the saturated hydraulic conductivity of the fine particles is greater than 10−5 cm/s, the matric potential of the fine-grained layer shows a homogeneous line type at an incorporation ratio of 1:0.6. (4) When the particle size of the fine particles mixed into the coarse-grained layer (quartz sand, silt, and diatomite with admixture ratios of 1:0.1, 1:0.3, 1:0.6, and 1:1) is smaller than that of the particles in the fine-grained layer, the water storage capacity of CBCs is only affected by the proportion of fine particles added to the coarse-grained layer and is independent of the type of fine particle used. Full article
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26 pages, 12277 KB  
Article
Prediction of Concrete Abrasion Depth in Hydraulic Structures Using an Interpretable Hybrid Ensemble Model Based on Meta-Heuristic Algorithms
by Changhai He, Xiaodong Liu, Ao Xu, Qingfu Li, Xiang Wang and Xiyu Ma
Buildings 2025, 15(22), 4086; https://doi.org/10.3390/buildings15224086 - 13 Nov 2025
Viewed by 323
Abstract
The concrete protective layer in hydraulic tunnels is prone to abrasion by high-velocity sand-laden water, reducing structural durability. Accurate prediction of abrasion depth is key to rational hydraulic structure design. Existing studies have limitations: classical empirical models consider only a single factor, while [...] Read more.
The concrete protective layer in hydraulic tunnels is prone to abrasion by high-velocity sand-laden water, reducing structural durability. Accurate prediction of abrasion depth is key to rational hydraulic structure design. Existing studies have limitations: classical empirical models consider only a single factor, while early machine learning models fail to cover two core abrasion mechanisms (friction and impact) and lack meta-heuristic algorithm-based parameter optimization, leading to insufficient generalization and stability. This study aims to (1) establish a multi-source database with 690 cases (463 friction-dominated, 227 impact-dominated) covering multiple test standards (ASTM C944, ASTM C779, BIS: 1237-1980, ASTM C1138); (2) optimize hyperparameters of LightGBM, XGBoost, and CatBoost using Genghis Khan Shark Optimizer (GKSO) to build a hybrid ensemble model; (3) verify model performance and identify key factors via SHAP analysis. After preprocessing, input features were simplified to five: water–cement ratio, FA/CA (fine aggregate/coarse aggregate), age, T/V (test duration/velocity), and WRA content. Results show that GKSO-CatBoost performed best (test set R2 = 0.982, RMSE = 0.1231 mm). SHAP analysis identified T/V and the water–cement ratio as key influencing features, providing clear directions for optimizing concrete mix proportions under different standard scenarios. This study provides a new method for hydraulic concrete abrasion prediction and a scientific basis for durability design oriented to specific test standards. Full article
(This article belongs to the Section Construction Management, and Computers & Digitization)
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23 pages, 6557 KB  
Article
Analysis of Particle Distribution and Aggregation Characteristics in a Hydrocyclone with a Complex Curved Inlet Structure
by Huaibin Yang, Fanping Meng, Shuilin Wang, Zhitao Liang, Lizhao Wei, Yu Ge, Yuting Fu and Feng Li
Processes 2025, 13(11), 3540; https://doi.org/10.3390/pr13113540 - 4 Nov 2025
Viewed by 392
Abstract
The utilization of hydrocyclones dates back more than a century. As the key channel for multiphase flow, the inlet chamber exerts a notable influence on the separation efficiency of hydrocyclones. Conventional feed bodies mainly adopt straight lines as guidelines. During the transition of [...] Read more.
The utilization of hydrocyclones dates back more than a century. As the key channel for multiphase flow, the inlet chamber exerts a notable influence on the separation efficiency of hydrocyclones. Conventional feed bodies mainly adopt straight lines as guidelines. During the transition of fluid from linear motion to circumferential motion, significant kinetic energy loss and particle misalignment are exhibited, resulting in relatively low classification accuracy of the hydrocyclone. Therefore, in this study, a hydrocyclone featuring a complex curved inlet chamber structure was designed, and numerical analysis was employed to examine the particle distribution and aggregation characteristics within both the inlet chamber and the hydrocyclone. Supplemented with RSM/VOF/TFM simulations and quartz sand experimental validation, this study compares the separation performance of the complex curved inlet with the conventional linear inlet. The results indicate the following: when particle sizes are small, particles are dispersed throughout the hydrocyclone and inlet chamber, exhibiting a disordered state, which leads to poor classification performance. As particle size increases, particles gradually form layers along the radial direction; larger particles tend to accumulate on the hydrocyclone wall. When the particle concentration is maintained within a specific range, it promotes the migration of fine particles toward the center, thereby reducing the likelihood of fine particles entering the outer vortex and allowing for more precise classification of fine particles. As the particle concentration increases, the cutting ability of the hydrocyclone progressively diminishes; when the concentration exceeds 20%, the maximum underflow recovery rate for particles smaller than 50 µm is only 60%, resulting in significant coarse overflow and a notable decrease in classification precision. Furthermore, as the inlet concentration increases, the dispersion index for 0.5 µm particles ranges from 0.6 to 1.6, for 4 µm particles from 0.6 to 1.4, and for 60 µm particles from 0.6 to 1. The decreasing dispersion index indicates an increasing classification force, which aids in the formation of a coarse particle layer on the wall. The conclusions and data obtained provide a theoretical foundation and empirical support for the design of innovative inlet chamber structures. Full article
(This article belongs to the Special Issue Advanced Separation and Purification Processes)
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32 pages, 9507 KB  
Article
Forensic Investigation of the Seepage-Induced Flow Failure at La Luciana Tailings Storage Facility (1960 Spain)
by Aldo Onel Oliva-González, Joanna Butlanska, José Antonio Fernández-Merodo and Roberto Lorenzo Rodríguez-Pacheco
Minerals 2025, 15(11), 1131; https://doi.org/10.3390/min15111131 - 29 Oct 2025
Cited by 1 | Viewed by 566
Abstract
This study presents a forensic investigation of the catastrophic failure of the La Luciana Tailings Storage Facility (TSF) in Reocín, Spain, in 1960. The collapse released approximately 300,000 m3 of tailings, causing 18 fatalities, extensive flooding of farmland and lakes, and the [...] Read more.
This study presents a forensic investigation of the catastrophic failure of the La Luciana Tailings Storage Facility (TSF) in Reocín, Spain, in 1960. The collapse released approximately 300,000 m3 of tailings, causing 18 fatalities, extensive flooding of farmland and lakes, and the contamination of the Besaya River, leading to long-term environmental degradation. The analysis integrates historical documentation, cartographic evidence, in situ testing, laboratory analyses, and numerical modelling to reconstruct the failure sequence and identify its causes. Geotechnical characterization based on cone penetration tests (CPTs), shear wave velocity profiles, and laboratory testing revealed pronounced heterogeneity, with alternating contractive and dilative layers. Hydraulic analyses indicate permeabilities from 10−5 m/s in sand dam materials to 10−9 m/s in fine-grained pond deposits, with evidence of capillary saturation exceeding 20 m, favouring excess pore-pressure accumulation. Limited equilibrium and finite element analyses show that when the decant pond was within ~20 m of the dam, the factor of safety dropped to unity, triggering retrogressive flowslides consistent with field evidence. The results underline critical lessons for TSF governance: maintaining unsaturated tailings, ensuring efficient drainage and decant systems, and monitoring pond proximity to the dam. These are essential to prevent flow failures. This research also demonstrates a replicable forensic methodology applicable to other historical TSF failures, enhancing predictive models and informing modern frameworks such as the EU Directive 2006/21/EC and the Global Industry Standard on Tailings Management (GISTM). Full article
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19 pages, 2721 KB  
Article
Land Unit Delineation Based on Soil-Forming Factors: A Tool for Soil Survey in Mountainous Protected Areas
by William Trenti, Mauro De Feudis, Massimo Gherardi, Gilmo Vianello and Livia Vittori Antisari
Land 2025, 14(8), 1683; https://doi.org/10.3390/land14081683 - 20 Aug 2025
Viewed by 1297
Abstract
The present study applied a GIS-based methodology for assessing soil diversity in a protected mountain area of Italy. Using QGIS, morphological (i.e., altitude and slope), lithological, climatic, and land use layers were intersected to delineate 16 land units (LUs), each representing relatively homogeneous [...] Read more.
The present study applied a GIS-based methodology for assessing soil diversity in a protected mountain area of Italy. Using QGIS, morphological (i.e., altitude and slope), lithological, climatic, and land use layers were intersected to delineate 16 land units (LUs), each representing relatively homogeneous conditions for soil formation, according to Jenny’s equation. To obtain the soil map units, a total of 112 soil profiles were analyzed, including 79 from previous studies and 33 that were newly excavated during 2023–2024 to fill gaps in underrepresented LU types. Most soils were classified as Inceptisols/Cambisols, occurring in both Dystric and Eutric variants, mainly in relation to lithology (i.e., arenaceous or pelitic facies). Alfisols, Umbrisols, and hydromorphic soils were also identified. The physicochemical properties showed marked variability among LUs, with sand content ranging from 39 to 798 g kg−1, pH from 4.4 to 7.9, and organic carbon content from 1.6 to 6.1%. This LU-based framework allowed efficient field sampling, if compared to grid-based surveys, while retaining information on fine-scale pedodiversity. No quantitative accuracy assessment (e.g., boundary precision, internal homogeneity metrics) was conducted, even if the spatial coherence of the delineated LUs was supported by the distribution of soil profiles, which provided empirical validation of the LU framework. Full article
(This article belongs to the Special Issue Feature Papers for "Land, Soil and Water" Section)
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24 pages, 5703 KB  
Article
Controlling Factors of Productivity in the Fuyu Oil Reservoir of the Lower Cretaceous Songliao Basin, Northeast China
by Wenjie Li, Zhengkai Liao, Peng Lai, Jijun Tian and Shitao Du
Processes 2025, 13(8), 2623; https://doi.org/10.3390/pr13082623 - 19 Aug 2025
Viewed by 596
Abstract
The Mindong–Changchunling region is situated in the central portion of the Songliao Basin, Northeast China. The primary target stratum in this area is the Fuyu Oil Layer of the Lower Cretaceous Quantou 4 Member. This reservoir is predominantly composed of fine sandstone and [...] Read more.
The Mindong–Changchunling region is situated in the central portion of the Songliao Basin, Northeast China. The primary target stratum in this area is the Fuyu Oil Layer of the Lower Cretaceous Quantou 4 Member. This reservoir is predominantly composed of fine sandstone and siltstone, with minor interbedded medium sandstone. Variations in provenance, sedimentation, and diagenesis are identified as the main controlling factors for the distribution of high-quality reservoirs in the Mindong–Changchunling region. The sand body distribution in the Changchunling area is influenced by the eastern near-source provenance. The reservoir properties of these sand bodies are impacted by the poor sorting and high mud content typical of near-source delta sand bodies. Nonetheless, reservoir quality is enhanced by late-stage uplift and surface water dissolution-leaching. In contrast, sand body distribution in the Mindong area is governed by the southwestern far-source provenance. Far-source delta sand bodies are characterized by better sorting but high mud content, with their reservoir properties primarily impaired by carbonate cementation. During the early-middle diagenetic stage, feldspar dissolution by organic acids improves sand body reservoir quality. Due to variations in sedimentation and diagenesis, the following three favorable reservoir zones with distinct genetic types have developed in the Mindong–Changchunling area: the Chang107–Chang104–Chang52 well block, the Fu155–Fu161–Fu157 well block, and the Min103–Min31 well block. Full article
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19 pages, 4348 KB  
Article
Manufacturing of Polymer–Metal Composite by Fused Filament Fabrication: Adhesion of PLA and PETG on Aluminum
by Miguel Campos-Jurado, Óscar Rodríguez-Alabanda and Guillermo Guerrero-Vacas
Polymers 2025, 17(16), 2210; https://doi.org/10.3390/polym17162210 - 13 Aug 2025
Viewed by 1609
Abstract
The formation of metal–polymer composites by 3D printing PLA and PETG onto EN AW-5182 H111 aluminum substrates without the use of adhesives was investigated. Four surface treatments were evaluated on the metal substrate (fine sanding, coarse sanding, abrasive blasting, and acid etching), over [...] Read more.
The formation of metal–polymer composites by 3D printing PLA and PETG onto EN AW-5182 H111 aluminum substrates without the use of adhesives was investigated. Four surface treatments were evaluated on the metal substrate (fine sanding, coarse sanding, abrasive blasting, and acid etching), over which a polymer primer—prepared from PLA and PETG solutions—was applied. Subsequently, test specimens were fabricated using the same polymer through material extrusion (MEX) with filaments. Adhesion strength between the printed polymer and the metal substrate was assessed through perpendicular tensile, lap shear, and three-point bending tests. The 16-condition experimental matrix combined surface treatment, primer thickness, and bed temperature and was replicated for each test. Peak tensile and shear strengths confirmed the effectiveness of the proposed strategy, with PETG consistently showing a higher interfacial performance than PLA. ANOVA analysis identifies primer layer thickness (p = 0.023) and loading type (p = 0.031) as statistically significant variables. The results suggest that either abrasive or acid pretreatment, combined with a primer thickness ≥ 80 µm and moderate bed temperatures (65 °C for PLA and 90 °C for PETG), enables the fabrication of robust metal–polymer joints, which are particularly resistant to shear stress and suitable for industrial applications. Full article
(This article belongs to the Section Polymer Composites and Nanocomposites)
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34 pages, 4629 KB  
Article
Evaluation of Infiltration Swale Media Using Small-Scale Testing Techniques and Its SWMM Modeling Considerations
by Diego Armando Ramírez Flórez, Yuting Ji, Parker J. Austin, Michael A. Perez, Xing Fang and Wesley N. Donald
Water 2025, 17(16), 2390; https://doi.org/10.3390/w17162390 - 12 Aug 2025
Viewed by 1161
Abstract
Impervious surfaces reduce natural infiltration, leading to increased runoff, erosion, and pollutant transport. The Alabama Department of Transportation (ALDOT) relies on implementing infiltration swales, a linear bioretention-based practice, along roadside drainage channels to reduce surface runoff. This study developed and constructed modified permeameters [...] Read more.
Impervious surfaces reduce natural infiltration, leading to increased runoff, erosion, and pollutant transport. The Alabama Department of Transportation (ALDOT) relies on implementing infiltration swales, a linear bioretention-based practice, along roadside drainage channels to reduce surface runoff. This study developed and constructed modified permeameters and infiltrometers to evaluate and optimize media used to construct infiltration swales. The average measured falling head infiltration rate of sandy topsoil used in the media matrix was 0.63 ft/day (0.19 m/day). A series of amended topsoil mixtures were tested to improve the infiltration rate of the media. In particular, the mixture of 80% topsoil and 20% pine bark fines (by weight) significantly improved the infiltration rates of the swale media. Through iterative testing, the F3 design with 6 in. (15.2 cm) mixture and 10 in. (25.4 cm) sand achieved up to 13.73 ft/day (4.18 m/day) of infiltration rate under constant head, far surpassing the infiltration rate of the current ALDOT design. SWMM bioretention cell models were developed to understand the swale infiltration process and revealed that the infiltration rates obtained from column tests were the saturated hydraulic conductivities of the soil layer when there was no other restriction on vertical flow. The simulated swale hydrological performance depends not only on variations in soil conductivity but also on other swale characteristics under field conditions. Findings from this research can be used to enhance the performance of infiltration-based stormwater practices. Full article
(This article belongs to the Special Issue Urban Drainage Systems and Stormwater Management)
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17 pages, 3612 KB  
Article
Effects of Nitrogen and Phosphorus Supplementation on Responses of Trembling Aspen and White Spruce Seedlings in Reclamation Soils Amended by Non-Segregating Oil Sands Tailings
by Xuehui Sun, Wen-Qing Zhang and Janusz J. Zwiazek
Soil Syst. 2025, 9(3), 90; https://doi.org/10.3390/soilsystems9030090 - 11 Aug 2025
Viewed by 917
Abstract
Oil sands mining in northeastern Alberta, Canada, has disturbed large areas of the northern boreal forest which must be restored to pre-disturbance levels through reclamation. The oil sands tailings have high pH and elevated levels of Na+ which are harmful to plants. [...] Read more.
Oil sands mining in northeastern Alberta, Canada, has disturbed large areas of the northern boreal forest which must be restored to pre-disturbance levels through reclamation. The oil sands tailings have high pH and elevated levels of Na+ which are harmful to plants. A novel non-segregating tailing (NST) was developed to accelerate consolidation of fine tailings, yet its effects on boreal plant species are not well characterized. In oil sands reclamation, a capping layer—either forest mineral soil mix (FMM), salvaged from upland boreal forest sites, or peat mineral mix (PMM), sourced from peatlands—is typically applied over overburden materials and coarse tailings sands prior to revegetation. Plants in oil sands revegetation sites frequently experience nutrient deficiencies, such as nitrogen and phosphorus, and impaired physiological processes due to the high pH and soil salinity. In this study, we examined the effects of nitrogen and phosphorus supplements in the NST-amended reclamation soils on growth and physiological parameters of trembling aspen (Populus tremuloides) and white spruce (Picea glauca) seedlings. We found that the growth and physiological responses of seedlings were superior in the mixture of NST and FMM compared with NST and PMM. Phytotoxicity of NST was associated with elevated boron levels. Trembling aspen exhibited greater sensitivity to NST but showed stronger growth improvements with increased nitrogen and phosphorus supplementation compared to white spruce. High levels of nitrogen and phosphorus supplementation alleviated the adverse effects on both species that were caused by mineral nutrient imbalance. Full article
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15 pages, 5382 KB  
Article
An Adaptive Graph Convolutional Network with Spatial Autocorrelation for Enhancing 3D Soil Pollutant Mapping Precision from Sparse Borehole Data
by Huan Tao, Ziyang Li, Shengdong Nie, Hengkai Li and Dan Zhao
Land 2025, 14(7), 1348; https://doi.org/10.3390/land14071348 - 25 Jun 2025
Viewed by 764
Abstract
Sparse borehole sampling at contaminated sites results in sparse and unevenly distributed data on soil pollutants. Traditional interpolation methods may obscure local variations in soil contamination when applied to such sparse data, thus reducing the interpolation accuracy. We propose an adaptive graph convolutional [...] Read more.
Sparse borehole sampling at contaminated sites results in sparse and unevenly distributed data on soil pollutants. Traditional interpolation methods may obscure local variations in soil contamination when applied to such sparse data, thus reducing the interpolation accuracy. We propose an adaptive graph convolutional network with spatial autocorrelation (ASI-GCN) model to overcome this challenge. The ASI-GCN model effectively constrains pollutant concentration transfer while capturing subtle spatial variations, improving soil pollution characterization accuracy. We tested our model at a coking plant using 215 soil samples from 15 boreholes, evaluating its robustness with three pollutants of varying volatility: arsenic (As, non-volatile), benzo(a)pyrene (BaP, semi-volatile), and benzene (Ben, volatile). Leave-one-out cross-validation demonstrates that the ASI-GCN_RC_G model (ASI-GCN with residual connections) achieves the highest prediction accuracy. Specifically, the R for As, BaP, and Ben are 0.728, 0.825, and 0.781, respectively, outperforming traditional models by 58.8% (vs. IDW), 45.82% (vs. OK), and 53.78% (vs. IDW). Meanwhile, their RMSE drop by 36.56% (vs. Bayesian_K), 38.02% (vs. Bayesian_K), and 35.96% (vs. IDW), further confirming the model’s superior precision. Beyond accuracy, Monte Carlo uncertainty analysis reveals that most predicted areas exhibit low uncertainty, with only a few high-pollution hotspots exhibiting relatively high uncertainty. Further analysis revealed the significant influence of pollutant volatility on vertical migration patterns. Non-volatile As was primarily distributed in the fill and silty sand layers, and semi-volatile BaP concentrated in the silty sand layer. At the same time, volatile Ben was predominantly found in the clay and fine sand layers. By integrating spatial autocorrelation with deep graph representation, ASI-GCN redefines sparse data 3D mapping, offering a transformative tool for precise environmental governance and human health assessment. Full article
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21 pages, 3031 KB  
Article
Microstructural Characterization of the Mn Lepidolite Distribution in Dark Red Clay Soils
by Simona Elena Avram, Lucian Barbu Tudoran, Gheorghe Borodi and Ioan Petean
Appl. Sci. 2025, 15(12), 6445; https://doi.org/10.3390/app15126445 - 8 Jun 2025
Cited by 6 | Viewed by 1308
Abstract
Lepidolite is one of a small number of minerals that contains a significant amount of lithium. Some areas, like the Apuseni and Metalifer Mountains in Romania, present dark red layers intercalated with reddish-yellow clay soils with interesting aspects. X-ray diffraction (XRD) analysis coupled [...] Read more.
Lepidolite is one of a small number of minerals that contains a significant amount of lithium. Some areas, like the Apuseni and Metalifer Mountains in Romania, present dark red layers intercalated with reddish-yellow clay soils with interesting aspects. X-ray diffraction (XRD) analysis coupled with polarized light optical microscopy (POM) revealed that this dark red soil contains a large amount of fine microstructured lepidolite (24–35%) mixed with quartz sand and fine traces of kaolinite and muscovite. Scanning electron microscopy (SEM) elemental analysis revealed a typical clay composition with Mn traces (specific to red lepidolite), confirming POM observation. SEM also revealed fine tabular platelets of lepidolite with a maximum size of 1.5 µm surrounding quartz particles (5–50 µm), indicating the presence of numerous nano fractions. Their presence was confirmed by atomic force microscopy (AFM), which showed particle sizes ranging from 40 to 60 nm, closely matching the crystallite size estimated using the Scherrer formula. The finest fraction allows easy separation from the quartz sand through bi-distilled water washing. Quartz particles settle at the bottom of the container, while the finest lepidolite particles are easily separated. Water evaporation ensures their recovery. Thus, the enriched lepidolite powder could be utilized for specific applications in the lithium industry. On the other hand, the large number of the finest particles found in the samples investigated presents the risk of PM1, PM2.5m, and PM10 emission, with impacts on atmospheric environmental safety. Full article
(This article belongs to the Special Issue Latest Research on Geotechnical Engineering)
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24 pages, 4411 KB  
Article
Characterization of Historical Tailings Dam Materials for Li-Sn Recovery and Potential Use in Silicate Products—A Case Study of the Bielatal Tailings Dam, Eastern Erzgebirge, Saxony, Germany
by Kofi Moro, Nils Hoth, Marco Roscher, Fabian Kaulfuss, Johanes Maria Vianney and Carsten Drebenstedt
Sustainability 2025, 17(10), 4469; https://doi.org/10.3390/su17104469 - 14 May 2025
Cited by 3 | Viewed by 1671
Abstract
The characterization of historical tailings bodies is crucial for optimizing environmental management and resource recovery efforts. This study investigated the Bielatal tailings dam (Altenberg, Germany), examining its internal structure, material distribution influenced by historical flushing technology, and the spatial distribution of valuable elements. [...] Read more.
The characterization of historical tailings bodies is crucial for optimizing environmental management and resource recovery efforts. This study investigated the Bielatal tailings dam (Altenberg, Germany), examining its internal structure, material distribution influenced by historical flushing technology, and the spatial distribution of valuable elements. To evaluate the tailings resource potential, drill core sampling was conducted at multiple points at a depth of 7 m. Subsequent analyses included geochemical characterization using sodium peroxide fusion, lithium borate fusion, X-ray fluorescence (XRF), and a scanning electron microscope with energy dispersive X-ray spectroscopy (SEM-EDX). Particle size distribution analysis via a laser particle size analyzer and wet sieving was conducted alongside milieu parameter (pH, Eh, EC) analysis. A theoretical assessment of the tailings’ potential for geopolymer applications was conducted by comparing them with other tailings used in geopolymer research and relevant European standards. The results indicated average concentrations of lithium (Li) of 0.1 wt%, primarily hosted in Li-mica phases, and concentrations of tin (Sn) of 0.12 wt%, predominantly occurring in cassiterite. Particle size analysis revealed that the tailings material is generally fine-grained, comprising approximately 60% silt, 32% fine sand, and 8% clay. These textural characteristics influenced the spatial distribution of elements, with Li and Sn enriched in fine-grained fractions predominantly concentrated in the dam’s central and western sections, while coarser material accumulated near injection points. Historical advancements in mineral processing, particularly flotation, had significantly influenced Sn distribution, with deeper layers showing higher Sn enrichment, except for the final operational years, which also exhibited elevated Sn concentrations. Due to the limitations of X-ray fluorescence (XRF) in detecting Li, a strong correlation between rubidium (Rb) and Li was established, allowing Li quantification via Rb measurements across varying particle sizes, redox conditions, and geological settings. This demonstrated that Rb can serve as a reliable proxy for Li quantification in diverse contexts. Geochemical and mineralogical analyses revealed a composition dominated by quartz, mica, topaz, and alkali feldspars. The weakly acidic to neutral conditions (pH 5.9–7.7) and reducing redox potential (Eh, 570 to 45 mV) of the tailings material indicated a minimal risk of acid mine drainage. Preliminary investigations into using Altenberg tailings as geopolymer materials suggested that their silicon-rich composition could serve as a substitute for coal fly ash in construction; however, pre-treatment would be needed to enhance reactivity. This study underscores the dual potential of tailings for element recovery and sustainable construction, emphasizing the importance of understanding historical processing techniques for informed resource utilization. Full article
(This article belongs to the Special Issue Geological Engineering and Sustainable Environment)
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