Search Results (398)

This research contributes to advance the sustainable production of biofuels and provides insights into the energy and exergy assessment of bio-oil, which is essential for developing environmentally friendly energy production solutions. Energy and exergy analyses were performed to evaluate the pyrolysis of beech wood biomass at 500 °C in an Auger reactor. To improve the quality of the obtained bio-oil, its catalytic deoxygenation was performed within an in-line fluidized catalytic bed reactor using a catalyst based on HZSM5 zeolite modified with 5 wt.% Iron (5%FeHZSM-5). A thermodynamic analysis of the catalytic and non-catalytic pyrolysis system was carried out, as well as a comparative study of the calculation methods for the energy and exergy evaluation for bio-oil. The required heat for pyrolysis was found to be 1.2 MJ/kg_biomass in the case of non-catalytic treatment and 3.46 MJ/kg_biomass in the presence of the zeolite-based catalyst. The exergy efficiency in the Auger reactor was 90.3%. Using the catalytic system coupled to the Auger reactor, this efficiency increased to 91.6%, leading to less energy degradation. Calculating the total energy and total exergy of the bio-oil using two different methods showed a difference of 6%. In the first method, only the energy contributions of the model compounds, corresponding to the major compounds of each chemical family of bio-oil, were considered. In contrast, in the second method, all molecules identified in the bio-oil were considered for the calculation. The second method proved to be more suitable for thermodynamic analysis. The novelties of this work concern the thermodynamic analysis of a coupled system of an Auger biomass pyrolysis reactor and a fluidized bed catalytic deoxygenation reactor on the one hand, and the use of all the molecules identified in the oily phase for the evaluation of energy and exergy on the other hand. Full article

This study explores the use of chlorography as a natural photographic developing technique that utilizes the decomposition of chlorophyll and other plant pigments through the action of sunlight. The developed images corresponded to previous research on changes in the iconography of the indigenous Salasaka people. In this context, this experimental project on natural photography is oriented toward the conservation of the ancestral knowledge of this community and the understanding of the native flora of Ecuador. We investigated the application of the contact image transfer technique with positive transparencies on leaves and flowers of 30 different species that grow in the Ecuadorian highlands, including leaves of vascular plants, as well as rose petals. The results showed that the clarity and contrast of chlorography depended on the plant species and exposure time. It was observed that fruit-bearing species produced more visible images than the leaves of other plants and rose petals, with species from the Passifloraceae family proving particularly effective. We interpreted these findings within the framework of plant photophysical mechanisms, proposing an inverse relationship between development efficiency and species’ non-photochemical quenching (NPQ) capacity. Furthermore, we interpreted the findings in relation to the photobleaching of pigments and compared chlorography with other natural photographic processes such as anthotypes. Key factors influencing the process were identified, such as the type of leaf, the intensity and duration of light, and the hydration of the plant material. It is concluded that chlorography is a viable, non-toxic, and environmentally friendly photographic alternative with potential applications in art, education, and research, although it presents challenges in terms of image permanence and reproducibility. Full article

The growing environmental concerns associated with petroleum-based plastics require the development of sustainable, biodegradable alternatives. Polyhydroxyalkanoates (PHAs), a family of biodegradable bioplastics, offer a promising potential as eco-friendly substitutes due to their renewable origin and favorable degradation properties. This research investigates the use of synthetic condensate, mimicking the liquid fraction from drying and shredding of household food waste, as a viable substrate for PHA production using mixed microbial cultures. Two draw-fill reactors (DFRs) were operated under different feed organic concentrations (2.0 ± 0.5 and 3.8 ± 0.6 g COD/L), maintaining a consistent carbon-to-nitrogen ratio to selectively enrich microorganisms capable of accumulating PHAs through alternating nutrient availability and deficiency. Both reactors achieved efficient organic pollutant removal (>95% soluble COD removal), stable biomass growth, and optimal pH levels. Notably, the reactor with the higher organic load (DFR-2) demonstrated a modest increase in PHA accumulation (19.05 ± 7.18%) compared to the lower-loaded reactor (DFR-1; 15.19 ± 6.00%), alongside significantly enhanced biomass productivity. Polymer characterization revealed the formation of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV), influenced by the substrate composition. Microbial community analysis showed an adaptive shift towards Proteobacteria dominance, signifying successful enrichment of effective PHA producers. Full article

Sorghum halepense (L.) Pers. (common name Johnson grass) is a perennial invasive weed that causes great harm worldwide, and its allelopathy has been demonstrated in a series of experiments. The present study offers new insights into its organ-specific phytochemical profiles using state-of-the-art metabolomic technology and explores the effects of a methanol extract of S. halepense rhizomes (ShER) and its major bioactive compounds (p-hydroxybenzoic acid and chlorogenic acid) on three noxious weed species. The phytotoxic effects of ShER are reflected through the inhibition of seed germination and reduced seedling growth, which are accompanied by changes in the antioxidant system of seedlings. Phytotoxicity is species specific and concentration dependent, and it is more pronounced against Chenopodiastrum murale (L.) S. Fuentes, Uotila & Borsch and Datura stramonium L. than highly tolerant Amaranthus retroflexus L. Catalase (CAT) is most likely the major mediator in the removal of reactive oxygen species, which are generated during germination and early seedling growth of Ch. murale exposed to ShER. The results of the present study imply the high potential of ShER in the management of amaranthaceous and solanaceous weeds, such as Ch. murale and D. stramonium, respectively. The present study offers an environmentally friendly solution for the biological control of weeds belonging to the families Amaranthaceae and Solanaceae. Also, the results of this research highlight the possibility of effective management of S. halepense by using it as a feedstock for bioherbicide production. Full article

Much U.S. research supports the effectiveness of parenting education delivered via the home visiting method. Home visitors are essential to reaching fathers in this context, but not all have favorable attitudes toward father engagement or feel confident working with fathers. Given that father involvement is important for a wide range of child and adolescent outcomes and that fathers benefit from parenting education, it is important to better understand the forces that shape home visitors’ attitudes toward fathers, and thus their subsequent efforts to include them in publicly funded programming. Using survey data from 95 home visitors in Tennessee, this study explores whether home visitors’ beliefs about fathers and attitudes toward father engagement vary as a function of home visitor or agency characteristics. Results suggest training in social work, reporting father-friendly organizational attitudes and behaviors at one’s agency, and reporting supervisor support specifically for father engagement relate to various favorable fathering attitudes. Home visitors’ strategies to engage fathers in home visiting are presented, including strategies for before, during, and after the home visit. Overall, family service agency administrators are in key positions to make decisions that can improve agency father-friendliness, home visitor attitudes toward fathers, and subsequent outcomes for fathers, mothers, and children. Full article

Enteroviruses of the Picornaviridae family are transmitted primarily by the fecal–oral route. Transmission may occur following hand contact with contaminated fomites and subsequent ingestion of virus conveyed to the mouth by the contaminated hand. The persistence of these viruses on fomites likely plays a role in this transmission scenario. Six echoviruses (1, 2, 3, 5, 6, and 7) that cause frequently reported clinical cases in the United States were studied, along with poliovirus type 1 vaccine strain LSc-2ab. The infectivity half-lives of the enteroviruses deposited on vinyl tile coupons in a 10% fecal solution ranged from 1.7 to 12.6 h. The echovirus serotypes most commonly associated with reported infections persisted longer on the vinyl tiles than the less commonly reported types. This increased persistence on surfaces may favor the transmission of these echoviruses through the fecal–oral route. These results inform the future selection of appropriate model enteroviruses for challenging newly formulated and eco-friendly disinfectants or other strategies in infection prevention and control for enteroviruses. Full article

The widespread discharge of industrial and urban waste has led to significant increases in the environmental concentrations of numerous chemical substances. This work presents the development of a simple and environmentally friendly dispersive liquid–liquid microextraction (DLLME) method based on a hydrophobic natural deep eutectic solvent (NADES) for the determination of selected compounds from benzotriazole, benzothiazole, paraben, and UV filter families in wastewater samples. Of the twelve NADES formulations evaluated, those composed of a 4:1 molar ratio of thymol and menthol presented the highest extraction efficiencies. The influence of key experimental variables such as the pH of the aqueous sample, the ratio of NADES phase to sample volume, and the extraction time on the extraction efficiency was investigated using a multivariate optimization. Under optimal conditions, relative standard deviations below 15% and recoveries for spiked wastewater samples ranged between 82 and 108%, demonstrating the suitability of the method for routine water-quality monitoring. The sustainability and practicality of the developed method was evaluated using the assessment tools ChlorTox, AGREEprep, AGRRE, and BAGI, obtaining scores of 0.005 g in the NADES-DLLME method, 0.70, 0.52, and 72.5, respectively, demonstrating that the method is green and reliable. Full article

Urban green spaces are increasingly recognized as important habitats for pollinators, and wildflower seed mixes marketed as pollinator-friendly are gaining popularity, though their actual conservation value remains poorly understood. This study provides the first systematic screening of commercially available seed mixes in Portugal, evaluating their taxonomic composition, origin, life cycle traits, and potential to support pollinator communities. A total of 229 seed mixes were identified. Although these have a predominance of native species (median 86%), the taxonomic diversity was limited, with 91% of mixes comprising species from only one or two families, predominantly Poaceae and Fabaceae, potentially restricting the range of floral resources available to pollinators. Only 21 seed mixes met the criteria for being pollinator-friendly, based on a three-step decision tree prioritizing native species, extended flowering periods, and visual diversity. These showed the highest percentage of native species (median 87%) and a greater representation of flowering plants. However, 76% of all mixes still included at least one non-native species, although none is considered invasive. Perennial species dominated all seed mix types, indicating the potential for the long-term persistence of wildflower meadows in urban spaces. Despite their promise, the ecological quality and transparency of the seed mix composition remain inconsistent, with limited certification or information on species origin. This highlights the need for clearer labeling, regulatory guidance, and ecologically informed formulations. Seed mixes, if properly designed and implemented, represent a largely untapped yet cost-effective tool for enhancing the pollinator habitats and biodiversity within urban landscapes. Full article

Background/Objectives: Effective diabetes self-management is critical for glycemic management and well-being, yet Latino youth face unique cultural and socioeconomic barriers that are insufficiently explored in the literature. This review mapped existing evidence on diabetes self-management for Latino youth. Methods: Searches were conducted in PubMed, CINAHL, SCOPUS, Web of Science, LILACS, ERIC, and The Cochrane Library, using the gray literature and reference lists, in September 2024, following JBI guidelines. The included studies were qualitative, quantitative, and mixed-methods studies and reviews on diabetes self-management for Latinos aged 0–30 with type 1 or 2 diabetes. Studies including participants over 30 or with gestational diabetes were excluded. Two reviewers independently extracted data using a standardized table and analyzed findings using the Association of Diabetes Care & Education Specialists framework (ADCES7) for self-care behaviors: healthy eating, being active, monitoring, taking medication, problem-solving, reducing risks, and healthy coping. Results: Forty-five studies (forty from the United States) were included from 860 citations. The findings highlighted challenges in adopting diabetes-friendly diets, including cultural preferences, food insecurity, and limited resources. Physical activity improved glycemic control but was hindered by family and school obligations. Continuous glucose monitoring (CGM) enhanced outcomes, though economic barriers limited access. Family-centered education improved medication adherence, while family support strengthened problem-solving. CGMs and insulin pumps reduced complications, and culturally adapted psychological support enhanced emotional well-being and glycemic management. Conclusions: This review underscores persistent disparities in diabetes self-management among Latino youth. While the study designs and settings were heterogeneous, the findings highlight the need for culturally tailored, family-centered interventions that address structural barriers and psychosocial needs to improve care. Full article

MBenes, an emerging family of two-dimensional transition metal boride materials, are gaining prominence in alkali metal-ion battery research owing to their distinctive stratified architecture, enhanced charge transport properties, and exceptional electrochemical durability. This analysis provides a comprehensive examination of morphological characteristics and fabrication protocols for MBenes, with particular focus on strategies for optimizing energy storage metrics through controlled adjustment of interlayer distance and tailored surface modifications. The discussion highlights these materials’ unique capability to host substantial alkali metal ions, translating to exceptional longevity during charge–discharge cycling and remarkable high-current performance in both lithium and sodium battery systems. Current obstacles to materials development are critically evaluated, encompassing precision control in nanoscale synthesis, reproducibility in large-scale production, enhancement of thermodynamic stability, and eco-friendly processing requirements. Prospective research pathways are proposed, including sustainable manufacturing innovations, atomic-level structural tailoring through computational modeling, and expansion into hybrid energy storage-conversion platforms. By integrating fundamental material science principles with practical engineering considerations, this work seeks to establish actionable frameworks for advancing MBene-based technologies toward next-generation electrochemical storage solutions with enhanced energy density and operational reliability. Full article

Cohabiting family dogs form hierarchies, and there are rank-related differences in certain behaviours even in noncompetitive situations. For companion dogs, the main limited resource could be the owner, but this assumption needs further behavioural testing. We hypothesized that dogs’ hierarchical status within multi-dog household is associated with variations in their attachment and dependency behaviours toward their owner. We tested n = 62 cohabiting companion dogs from 31 multi-dog households. The rank score of each subject was determined with a questionnaire (DRA-Q). We used the strange situation test (SST) to assess the dogs’ attachment complex towards their owner. The results show that higher-ranking dogs showed less signs of stress in the SST when their owner was present, but they also showed fewer friendly behaviours towards the stranger. Older dogs also presented fewer stress behaviours; however, they were friendlier with the stranger. This is the first time that dogs’ hierarchy was taken into consideration regarding dog–owner attachment. We can conclude that dogs’ rank and its stability could play a crucial role in creating differences between cohabiting dogs’ attachment patterns. We propose further research into the functional analysis of these behavioural differences. Full article

Gold nanoparticles (AuNPs) anchored on graphene oxide (GO) have had a significant interest for their unique optical, electrical, and catalytic properties. This study presents an eco-friendly and sustainable synthesis of AuNPs on GO sheets using L-ascorbic acid (L-aa) as a green reducing agent and polyvinylpyrrolidone (PVP) as a stabilizer. The effect of reductant concentration on nanoparticle morphology was systematically investigated using UV–Visible spectroscopy and transmission electron microscopy (TEM). Results indicate the formation of AuNPs anchored on GO sheets and that an increase in the L-aa amount leads to both an increase in nanoparticle size and a morphological transition from spherical to irregular structures. The simultaneous nucleation and growth processes result in the formation of multiple families of nanostructures, as confirmed by TEM analysis, which reveals two distinct size distributions. At higher L-aa concentrations, the nanoparticles shape evolves into irregular morphologies due to selective growth along a preferential facet. This approach not only enables precise control over AuNP size and shape but also aligns with green chemistry principles, making it a promising route for applications in plasmonics, sensors, and photothermal therapy. Full article

As cities globally prioritize sustainable transportation, understanding gender-differentiated responses to the urban built environment is critical for equitable mobility planning. This study combined the Social Ecological Model (SEM) with the theoretical perspective of Gendered Spatial Experience to explore the differentiated impacts of the Perceived Street Built Environment (PSBE) on the cycling behavior of men and women. Questionnaire data from 285 e-bike and traditional bicycle riders (236 e-bike riders and 49 traditional cyclists, 138 males and 147 females) from Gulou District, Nanjing, between May and October 2023, were used to investigate gender differences in cycling behavior and PSBE using the Mann–Whitney U-test and crossover analysis. Linear regression and logistic regression analyses examined the PSBE impact on gender differences in cycling probability and route choice. The cycling frequency of women was significantly higher than that of men, and their cycling behavior was obviously driven by family responsibilities. Greater gender differences were observed in the PSBE among e-bike riders. Women rated facility accessibility, road accessibility, sense of safety, and spatial comfort significantly lower than men. Clear traffic signals and zebra crossings positively influenced women’s cycling probability. Women were more sensitive to the width of bicycle lanes and street noise, while men’s detours were mainly driven by the convenience of bus connections. We recommend constructing a gender-inclusive cycling environment through intersection optimization, family-friendly routes, lane widening, and noise reduction. This study advances urban science by identifying gendered barriers in cycling infrastructure, providing actionable strategies for equitable transport planning and urban design. Full article

Pet tourism has experienced significant growth in recent years, reflecting changes in the perception of pets as family members. This research examines the factors influencing attitude, travel intention, and payment intention in pet tourism in Chile, specifically analyzing the role of emotional attachment, perceived benefits, prestige, and novelty. Using a quantitative methodology, data were collected through an online survey of pet owners in Chile. The results reveal that perceived benefits and novelty positively influence attitudes toward traveling with pets, while prestige and perceived benefits directly impact travel intention. Surprisingly, emotional attachment did not show a significant influence, which contrasts with previous studies in other cultural contexts. This research also confirms that attitude and travel intention are relevant predictors of willingness to pay more for pet-friendly tourism services. These findings contribute to the literature on pet tourism in Latin America and provide practical implications for developing tourism services tailored to the Chilean market. This study concludes that marketing strategies in the tourism sector should emphasize tangible benefits and novel elements rather than emotional aspects to attract this growing market segment. Full article

Focusing on issues related to SDG 11 (Sustainable Cities and Communities) and SDG 13 (Climate Action), this study aligns with the framework of the 2030 Agenda for Sustainable Development. This study explores the barriers unique to the industry that obstruct the adoption of low-carbon emission solutions in Jordan’s multi-family residential buildings. Multi-family apartments constitute 73% of the total housing stock and account for over 80% of all residential structures. A total of eight main barriers that are preventing the implementation of low-carbon emission techniques were evaluated. The Fuzzy Delphi Method was utilized to gather insights from the Consultancy Council members of the Jordan Housing Investors Association. The results suggest that a major obstacle is the insufficient knowledge among end-users regarding environmental concerns, along with financial limitations, resulting in a lack of enthusiasm for low-carbon multi-family apartments. Moreover, insufficient cooperation between consultants and contractors leads to subpar constructability, which is worsened by the prevailing conventional procurement method that prioritizes cost and schedule above environmental consequences. To further investigate, it is advisable to examine the utilization of contemporary procurement methods, such as Design–Build and Construction Management and modern family contracts such as NEC4 in the housing industry of Jordan. These alternative methods have the potential to solve the current difficulties by promoting more effective and environmentally friendly building practices. Full article