Search Results (481)

Concrete structures are vulnerable to sulfate attacks during their service life, as sulfate ions react with cement hydration products to form expansive phases, generating internal stresses that cause mechanical degradation. In this study, a cementitious capillary crystalline waterproofing material (CCCW) was incorporated into concrete to mitigate sulfate ingress and enhance sulfate resistance. The evolution of compressive strength, ultrasonic pulse velocity, dynamic elastic modulus, and the microstructure of concrete was investigated in sulfate-exposed concretes with varying CCCW dosages and strength grades; the sulfate ion concentration profiles were also analyzed. The results indicate that the enhancement effect of CCCW on sulfate resistance declines progressively with increasing concrete strength. The formation of calcium silicate hydrate and calcium carbonate fills the pores of concrete, hindering the intrusion of sulfate solution. Moreover, the self-healing effect of concrete further inhibits the diffusion of sulfate ions through cracks, improving the sulfate resistance of concrete. These findings provide critical insights and practical guidance for improving concrete resistance to sulfate-induced deterioration. Full article

Investigating the properties of red clay under the action of dry–wet cycles is crucial for mitigating geological disasters and promoting the sustainable development of geotechnical engineering infrastructure. In this paper, red clay from the Yuanmou dry-hot valley in Yunnan Province was selected as the research subject. The investigation focused on examining the effects of dry–wet cycles on its permeability and shear strength. Samples were prepared by controlling the initial moisture content (8%, 11%, 14%, 17%, and 20% for permeability tests; 11%, 14%, and 17% for strength tests) and initial dry density (1.65 g/cm³, 1.70 g/cm³, 1.75 g/cm³, and 1.80 g/cm³). We conducted variable-head permeability tests and direct shear tests on samples undergoing 1–5 dry–wet cycles. The results demonstrated that (1) the saturated moisture content decreased with the increasing number of dry–wet cycles, with the first cycle showing the most significant decrease (decreasing by approximately 15–25% depending on initial conditions). (2) The permeability coefficient decreased continuously with the number of cycles, exhibiting a transition behavior around the optimum moisture content (14%). Samples with lower initial moisture content (8–14%) showed higher permeability reduction (up to 40% decrease) compared to those with higher initial moisture content (14–20%). (3) The dry–wet cycles lead to a significant attenuation of the shear strength, and the first cycle has the largest reduction. The shear strength parameters of red clay exhibit distinct attenuation patterns. The cohesion decreased exponentially with the number of cycles (total attenuation ≈55–60%), and the internal friction angle decreased linearly (total attenuation ≈20–25%). The total attenuation of cohesion was much larger than the internal friction angle. (4) The degradation mechanism is essentially a multi-scale coupling process of cementation dissolution, pore collapse, and fracture expansion of red clay internal structure. These findings provide critical insights for sustainable engineering design and disaster prevention in regions with similar soil conditions, contributing to the resilience and longevity of infrastructure under changing climatic conditions. Full article

Well cementing is an important step in oil and gas development. It uses cement to seal the formation and the casing, preventing fluid leakage. However, when conducting offshore oil well cementing operations, deep-water formations are usually weakly consolidated soils, and it is difficult to form a good cementation between the cement and formation. Therefore, enhancing the strength of the formation is one of the effective measures. This study uses the microbial-induced carbonate precipitation technology to cement sandy formations containing clay minerals. The triaxial tests were conducted to evaluate the consolidation effectiveness in the presence of three clay minerals: montmorillonite, illite, and kaolinite. X-ray computed tomography was utilized to characterize microscopic pore parameters, while thermogravimetric analysis, X-ray diffraction, and surface potential measurements were applied to analyze the mechanisms of clay minerals affecting microbial consolidation. The results showed that microbial mineralization mainly affects the cohesion of the samples. The cohesion of the montmorillonite sample increased from 20 kPa to 65.4 kPa, an increase of up to 3.27 times. The other two samples (illite and kaolinite) had increases of only 0.33 times and 1.82 times. Although the strength of the montmorillonite sample increased the most, unexpected large pores appeared with a diameter of over 120 µm, accounting for 7.1%. This is mainly attributed to the mineral expansion property. The expansion of the minerals will trap more microorganisms in the sample, thereby generating more calcium carbonate. And it also reduced the gaps between sand particles, creating favorable conditions for the connection of calcium carbonate. Although the surface charge of the minerals also affects the attachment of microorganisms, all three minerals have negative charges and a difference of no more than 0.84 mV (pH = 9). Therefore, the expansion property of the minerals is the dominant factor affecting the mechanical and microstructure of the sample. Full article

Wet–dry cycles are a key factor aggravating the durability degradation of foam concrete. To address this issue, this study prepared bentonite slurry–steel slag foam concrete (with steel slag and cement as main raw materials, and bentonite slurry as admixture) using the physical foaming method. Based on 7-day unconfined compressive strength tests with different mix proportions, the optimal mix proportion was determined as follows: mass ratio of bentonite to water 1:15, steel slag content 10%, and mass fraction of bentonite slurry 5%. Based on this optimal mix proportion, dry–wet cycle tests were carried out in both water and salt solution environments to systematically analyze the improvement effect of steel slag and bentonite slurry on the durability of foam concrete. The results show the following: steel slag can act as fine aggregate to play a skeleton role; after fully mixing with cement paste, it wraps the outer wall of foam, which not only reduces foam breakage but also inhibits the formation of large pores inside the specimen; bentonite slurry can densify the interface transition zone, improve the toughness of foam concrete, and inhibit the initiation and propagation of matrix cracks during the dry–wet cycle process; the composite addition of the two can significantly enhance the water erosion resistance and salt solution erosion resistance of foam concrete. The dry–wet cycle in the salt solution environment causes more severe erosion damage to foam concrete. The main reason is that, after chloride ions invade the cement matrix, they erode hydration products and generate expansive substances, thereby aggravating the matrix damage. Scanning Electron Microscopy (SEM) analysis shows that, whether in water environment or salt solution environment, the fractal dimension of foam concrete decreased slightly with an increasing number of wet–dry cycle times. Based on fractal theory, this study established a compressive strength–porosity prediction model and a dense concrete compressive strength–dry–wet cycle times prediction model, and both models were validated against experimental data from other researchers. The research results can provide technical support for the development of durable foam concrete in harsh environments and the high-value utilization of steel slag solid waste, and are applicable to civil engineering lightweight porous material application scenarios requiring resistance to dry–wet cycle erosion, such as wall bodies and subgrade filling. Full article

This research evaluates the stabilization of a clay collected from the northern expansion zone of Cartagena de Indias, Colombia. Laboratory analyses, including particle size distribution, Atterberg limits, compaction, specific gravity, and XRF/XRD, classified the soil as a highly plastic clay (CH) with moderate dispersivity, as confirmed by pinhole and crumb tests. The soil was treated with 3–9% lime, with and without the addition of NaCl (0% and 2%), and tested for unconfined compressive strength (q_u), small-strain stiffness (G_o), and microstructural properties under curing periods of 14 and 28 days at two compaction densities. Results showed that lime significantly improved mechanical behavior, while the inclusion of NaCl further enhanced q_u (up to 185%) and G_o (up to 3-fold), particularly at higher lime contents and curing times. Regression models demonstrated that both q_u and G_o follow power-type relationships with the porosity-to-lime index, with consistent exponents (−4.75 and −5.23, respectively) and high coefficients of determination (R² > 0.79). Normalization of the data yielded master curves with R² values above 0.90, confirming the robustness of the porosity-to-lime framework as a predictive tool. The G_o/q_u ratio obtained (3737.4) falls within the range reported for cemented geomaterials, reinforcing its relevance for comparative analysis. SEM observations revealed the transition from a porous, weakly aggregated structure to a dense matrix filled with C–S–H and C–A–H gels, corroborating the macro–micro correlation. Overall, the combined use of lime and NaCl effectively converts dispersive clays into non-dispersive, mechanically improved geomaterials, providing a practical and sustainable approach for stabilizing problematic coastal soils in tropical environments. Full article

Mineral expansive from FDG—flue-gas desulfurization—blended with calcium aluminate cement CAC was analyzed as mitigation shrinkage of alkali-activated residual mortars AAM. The AAM mortars were composed of red mud (RM) and bottom ash (BA), as precursors of a metakaolin MK-based system. MK replacement (0, 50, 70%) in alkaline solution (10M) and ratio 1:2 (binder/sand) was studied. Engineering properties were performed, and included mechanical strength, setting times, and dry shrinkage (HR 60%), as well as the microstructure formed at 7 d and 28 days. A total of 10% CAC-FGD dosage was the most efficient, reducing drying shrinkage by 23% and autogenous shrinkage by up to 30%. The findings showed that this addition also improved mechanical strength by approximately 16% at 28 days. Under the addition of CAC-FGD, the results suggest the presence of aluminosilicate gels of the (Na,C)-(A)-S-H type and the formation of ettringite, which are possibly responsible for ensuring good performance and a controlled expansion that, in turn, compensates for the shrinkage of the activated mortars. Full article

China’s carbon emission trading market (CETM), initially covering only power generators, is expanding to include key carbon emitters, like steel and cement enterprises. These high-energy-consuming industries also participate in the electricity market as major consumers. Current research lacks a systemic analysis of multi-market, multi-entity coupling under CETM coverage expansion. This study employs system dynamics to model coupling among steel, cement, thermal power, and renewable energy enterprises within both electricity and carbon markets. Multi-scenario analysis examines key indicator changes as the policy deepens. The results indicate that the impact of CETM coverage expansion unfolds in two phases: initial and deepening stages. Policy deepening will significantly influence key indicators, such as carbon prices and grid feed-in tariffs. Allowance tightening will lead to a pronounced rise in carbon prices, and the carbon trading costs for steel enterprises are significantly higher than those for cement enterprises. The increase in Renewable Portfolio Standards obligations will affect the supply–demand dynamics in the electricity market and contribute to reducing carbon trading costs for high-emission enterprises. All entities should tailor their strategies according to their specific characteristics to proactively adapt to the market changes induced by the CETM coverage expansion. Full article

In this study, xanthan gum (XG)-modified coal-fly-ash-based cementitious materials were synthesized to realize the resource utilization of coal fly ash and to develop a low-carbon emission cementitious sealing material that can substitute cement-based sealing material to prevent coal fires. The optimal formulation for coal-fly-ash-based mining cementitious sealing material was developed using response surface methodology based on Box–Behnken Design. The optimized formulation was obtained with a coal fly ash-to-precursor ratio of 0.65, alkali-activator modulus of 1.4, and alkali-activator dosage of 7.5%. Under the optimal conditions, the initial and final setting time were 26 min and 31 min, respectively, fluidity was 245 mm, and the 7-day compressive strength approached 36.60 MPa, but there were still thermal shrinkage and cracking phenomena after heating. XG was then introduced to improve the thermal shrinkage and cracking of coal-fly-ash-based cementitious materials. Incorporating 1 wt.‰ XG was found to decrease the fluidity while maintaining the setting time and increasing the 1-day and 7-day compressive strength by 15.44% and 1.97%, respectively. The results demonstrated that the gels generated by XG cross-linking and coordinating with Al³⁺/Ca²⁺ were interspersed in the original C(N)-A-S-H gel network, which not only made the 1 wt.‰ XG modified coal-fly-ash-based cementitious material show minor expansion at ambient temperatures, but also improved the residual compressive strength, thermal shrinkage resistance and cracking resistance in comparison to unmodified cementitious material. However, due to the viscosity of XG and the coordination of Al³⁺ and non-terminal carboxyl groups in XG breaking the gel network, XG incorporation should not exceed 1 wt.‰ as the compressive strength and fluidity are decreased. Full article

Microbial Induced Carbonate Precipitation (MICP) is regarded as a promising eco-friendly alternative to traditional Portland cement for soil stabilization. However, the feasibility of applying bio-cemented soil as a road base material remains inadequately studied, particularly in terms of the relationships between MICP treatment parameters—such as solution content, curing age, and the ratio of bacterial solution (BS) to cementation solution (CS) —and key mechanical and durability properties under realistic road conditions. In this study, an optimal curing condition for bio-cemented sand was first determined through unconfined compression strength (UCS) tests and calcium carbonate content (CCC) determination. Subsequently, dynamic triaxial tests were conducted to evaluate its resistance to cyclic loading. Further road performance tests, including splitting tensile strength, freeze-thaw resistance, temperature shrinkage, and arch expansion assessments, were carried out to comprehensively evaluate the material’s applicability. Scanning electron microscopy (SEM) was employed to elucidate the microstructural mechanisms underlying strength development. The results show that the strength (4.28 MPa) of bio-cemented sand cured under optimal conditions (12% bio-cured solution content, a BS-to-CS ratio of 1:4 and 7-d curing age) satisfies the criteria for road base applications. MICP treatment significantly improved the dynamic properties of aeolian sand (AS), reducing the cumulative plastic axial strain (ε_p) by nearly 11–46% and increasing the dynamic elastic modulus (E_d) by approximately 7–31% compared to untreated sand. The material also demonstrates satisfactory performance across all four road performance metrics. Microstructural analysis reveals enhanced interparticle bonding due to calcium carbonate precipitation, with samples prepared near the optimum moisture content exhibiting superior integrity and strength. Overall, bio-cemented sand demonstrates excellent potential as a sustainable road base material. These findings provide a theoretical foundation for practical applications of similar bio-cemented soils in road engineering. Full article

Aeolian sand is the primary geological material for construction in desert regions, and its stabilization with industrial solid wastes-based geopolymer (ISWG) provides an eco-friendly treatment replacing cement. This study comparatively investigated the enhancement effects of chemical activators and expansive agents on compressive strength of aeolian sand stabilized by ISWG (ASIG). Three chemical activators—NaOH, Ca(OH)₂, and CaCl₂—along with two expansive agents—desulfurized gypsum and bentonite—were considered. Through X-ray diffraction, thermogravimetric analysis, scanning electron microscopy, mercury intrusion porosimetry and pH values tests, the enhancement mechanisms of the additives on ASIG were elucidated. Results demonstrate that the expansive agent exhibits significantly superior strengthening effects on ASIG compared to the widely applied chemical activators. Chemical activators promoted ISWs dissolution and hydration product synthesis, thereby densifying the hydration product matrix but concurrently enlarged interparticle pores. Desulfurized gypsum incorporation induced morphological changes in ettringite, and excessive desulfurized gypsum generated substantial ettringite that disrupted gel matrix. In contrast, bentonite demonstrated superior pore-filling efficacy while densifying gel matrix through a compaction effect. These findings highlight bentonite superior compatibility with the unique microstructure of aeolian sand compared to conventional alkaline activators or expansive agents, and better effectiveness in enhancing the strength of ASIG. Full article

Heat-curing processes are often used to ensure the production rate of precast concrete elements, as this process increases the early strength of the material. However, the increase in curing temperature can negatively affect the final mechanical properties since cracking, and especially high porosity, may occur under these conditions. In order to compensate for the expected loss in mechanical and durability-related properties, the cement content is typically increased. This solution raises the cost of the final product and reduces its sustainability. Thus, in this study, the development of expansive self-compacting concretes (SCCs) is proposed to achieve higher final mechanical properties without increasing cement contents. The mechanical properties, expansive performance, and porous microstructure have been evaluated under different curing regimes. The obtained results show that it is possible to obtain similar or even better mechanical performance in expansive concretes cured at high temperatures than in those cured in standard conditions, particularly when using ettringite-based expansive agents (EAs). Moreover, the use of limestone filler (LF) proved to be more suitable than the use of fly ashes in the working conditions evaluated in the present study. In this sense, the compressive strength at 28 days of SCC with LF and ettringite-based EAs is 4.3% higher than the one obtained under standard curing; moreover, the total porosity is reduced (5%), and the drying shrinkage is also limited. These aspects have not been previously reported in non-expansive heat-cured concretes and represent a unique opportunity to reduce the cement content and, therefore, the carbon footprint of precast concretes without reducing their mechanical properties. When using CaO-based EAs, the results are also better than those of non-expansive SCC, although the improvement is less pronounced than in the previous case. Full article

Chloride-based deicing salt solutions have been contacted with concrete pastes containing slag cement at different conditions, such as slag replacement (20–80%), type (CaCl₂, MgCl₂, NaCl), and concentration (1 M–5 M) of the deicing salt, as well as temperature (ambient & −18 °C), and the extent of their reactions have been studied using XRD and ICP-OES. Also, solubility of Friedel salt (FS) has been measured in different types and concentrations of deicing salt solutions. It has been observed that the chemical deterioration arising from the formation and then dissolution of FS is more significant than the damage caused by the formation and expansion of oxychlorides in the pastes containing slag. While calcium oxychloride in its dried form can linger inside the paste for a long time, FS undergoes incongruent dissolution in CaCl₂ and MgCl₂ solutions and leaves the system. Presence of higher levels of AFm phases in pastes containing slag will further underscore this phenomenon. The extent of this chemical deterioration is relatively lower in NaCl solutions. Also, it was found that the nature of the chemical interaction changes with the concentration of the salt, as some disappeared phases might reappear and then disappear again. Using XRD and ICP-OES, this study provides a mechanistic understanding of salt-induced chemical deterioration in slag cement pastes by identifying phase-specific vulnerabilities and tracking the formation, transformation, and dissolution of key phases, such as Friedel’s salt and calcium oxychloride; additionally, the influence of various parameters have been studied, and chemical mechanisms have been proposed. Full article

With the rapid expansion of underground rail transit construction in China, the high carbon emissions associated with subway tunnels and stations have become an increasing concern. This study systematically examines the carbon emissions of prefabricated concrete–filled steel pipe columns (PCSPCs) during the construction phase of a Beijing subway station built via the pile beam arch (PBA) method, applying the life cycle assessment (LCA) methodology as a case study. An analytical framework for the synergistic optimization of carbon emissions and costs was developed. By systematically adjusting key design parameters—such as the column diameter, wall thickness, and concrete strength—it was possible to minimize both carbon emissions and project costs while meeting the ultimate load-bearing capacity requirements. The results indicate that the production phase of PCSPCs accounts for as much as 98.845% of total carbon emissions, with labor, materials, and machinery contributing 10.342%, 88.724%, and 0.934%, respectively. A sensitivity analysis revealed that steel plates have the greatest impact on carbon emissions, followed by steel reinforcement, whereas concrete and cement exhibit relatively lower sensitivities. The ultimate load-bearing capacity of PCSPCs increases with larger column diameters, thicker walls, and higher concrete strength grades, with the relationships displaying a nonlinear trend. The damage modes and performance of PCSPCs under different design parameters were further verified through finite element analysis. On the basis of the optimization algorithm used to adjust the design parameters, the carbon emissions and costs of the PCSPCs were reduced by 10.32% and 21.55%, respectively, while still meeting the load-bearing capacity requirements. Full article

The destabilizing damage of rock structures in coal beds engineering is greatly influenced by the bearing rupture features and energy evolution laws of rock–coal assemblages with varying height ratios. In this study, we used PFC3D to create rock–coal assemblages with rock–coal height ratios of 2:8, 4:6, 6:4, and 8:2. Uniaxial compression simulation was then performed, revealing the expansion properties and damage crack dispersion pattern at various bearing phases. The dispersion and migration law of cemented strain energy zoning; the size and location of the destructive energy level and its spatiotemporal evolution characteristics; and the impact of height ratio on the load-bearing characteristics, crack extension, and evolution of multiple energies (strain, destructive, and kinetic energies) were all clarified with the aid of a self-developed destructive energy and strain energy capture and tracking Fish program. The findings indicate that the assemblage’s elasticity modulus and compressive strength slightly increase as the height ratio increases, that the assemblage’s cracks begin in the coal body, and that the number of crack bands inside the coal body increases as the height ratio increases. Also, the phenomenon of crack bands penetrating the rock through the interface between the coal and rock becomes increasingly apparent. The total number of cracks, including both tensile and shear cracks, decreases as the height ratio increases. Among these, tensile cracks are consistently more abundant than shear cracks, and the proportion between the two types remains relatively stable regardless of changes in the height ratio. The acoustic emission ringing counts of the assemblage were not synchronized with the development of bearing stress, and the ringing counts started to increase from the yield stage and reached a peak at the damage stage (0.8${\sigma }_{\mathrm{c}}$) after the peak of bearing stress. The larger the rock–coal height ratio, the smaller the peak and the earlier the timing of its appearance. The main body of strain energy accumulation was transferred from the coal body to the rock body when the height ratio exceeded 1.5. The peak values of the assemblage’s strain energy, destructive energy, and kinetic energy curves decreased as the height ratio increased, particularly the energy amplitude of the largest destructive energy event. In order to prevent and mitigate engineering disasters during deep mining of coal resources, the research findings could serve as a helpful reference for the destabilizing properties of rock–coal assemblages. Full article

Rapid pavement repair demands materials that combine accelerated strength gains, dimensional stability, long-term durability, and sustainability. However, finding materials or formulations that offer these balances remains a critical challenge. This study systematically evaluates two polymer-modified belitic calcium sulfoaluminate (CSA) concretes—CSAP (powdered polymer) and CSA-LLP (liquid polymer admixture)—against a traditional Type III Portland cement (OPC) control under both laboratory and realistic outdoor conditions. Laboratory specimens were tested for fresh properties, early-age and later-age compressive, flexural, and splitting tensile strengths, as well as drying shrinkage according to ASTM standards. Outdoor 5 × 4 × 12-inch slabs mimicking typical jointed plain concrete panels (JPCPs), instrumented with vibrating wire strain gauges and thermocouples, recorded the strain and temperature at 5 min intervals over 16 weeks, with 24 h wet-burlap curing to replicate field practices. Laboratory findings show that CSA mixes exceeded 3200 psi of compressive strength at 4 h, but cold outdoor casting (~48 °F) delayed the early-age strength development. The CSA-LLP exhibited the lowest drying shrinkage (0.036% at 16 weeks), and outdoor CSA slabs captured the initial ettringite-driven expansion, resulting in a net expansion (+200 µε) rather than contraction. Approximately 80% of the total strain evolved within the first 48 h, driven by autogenous and plastic effects. CSA mixes generated lower peak internal temperatures and reduced thermal strain amplitudes compared to the OPC, improving dimensional stability and mitigating restraint-induced cracking. These results underscore the necessity of field validation for shrinkage compensation mechanisms and highlight the critical roles of the polymer type and curing protocol in optimizing CSA-based repairs for durable, low-carbon pavement rehabilitation. Full article