Search Results (23)

A novel processing route of producing CrFeNiMo, Co_0.5CrFeNiMo, and Al_0.5CrFeNiMo high-entropy alloy coatings was proposed in this work. Pre-alloyed HEAs were consolidated by spark plasma sintering (SPS) in order to fabricate electrodes for electrospark deposition (ESD) coatings on carbon steel substrates. Investigations were performed to observe aspects such as phase composition and stability, contamination level, homogeneity, elemental distribution, and microstructural integrity. The results indicated phase stability and lower porosity when increasing the SPS temperature by 50 °C for all cases, with tetragonal distortion related to the HEAs’ severe lattice distortion core effect. The coating surface analysis indicated that a continuous and compact coating was obtained, correlated with the ESD layering count, but microfissures were present after 6 layers were applied due to the reduced ductility combined with rapid cooling under Ar atmosphere. The chemical integrity of both the sintered samples and the coatings was preserved during the processing, revealing a uniform elemental distribution with no contaminations or impurities present. The results indicated successful HEA sintering and deposition, highlighting the potential of the combined SPS-ESD process for high-performance material fabrication with possible applications in aggressive environments. Full article

AlCoCrFeNi coatings were electrospark-deposited (ESD) on H13 steel substrates, and their nano-mechanical and tribological properties under a load of 2 N, 4 N, 6 N, 8 N, and 10 N were investigated by utilizing a nanoindentation instrument and a reciprocating friction and wear tester, respectively. The morphologies, composition, and phase structure of the as-deposited and worn AlCoCrFeNi coating were characterized using SEM (Scanning electron Microscope), EDS (Energy dispersive spectrometer), and XRD (X-Ray Diffraction). The results showed that the as-deposited AlCoCrFeNi coating with a nanocrystalline microstructure mainly consists of a BCC and B2 phase structure, and a gradient transition of elements between the coating and the substrate ensures an excellent bond between the coating and the substrate. The hardness of the AlCoCrFeNi coating exhibits an 8% increase, while its elastic modulus is reduced by 16% compared to the H13 steel. The AlCoCrFeNi coating remarkably increased the tribological property of the H13 steel under various loads, and its wear mechanism belongs to micro-cutting abrasive wear whilst that of the H13 steel can be characterized as severe adhesive wear. The friction coefficient and weight loss of the AlCoCrFeNi coating decrease with increasing load, both following a linear relationship with respect to the applied load. As the load intensifies, the work hardening sensitivity and oxidation degree on the worn surface of the coating are significantly enhanced, which collectively contributes to the improved tribological performance of the AlCoCrFeNi coating. Full article

This work demonstrates the possibility of creating effective composite coatings with a complex structure and phase composition on carbon steel C45 via electrospark deposition (ESD) with multicomponent electrodes with a bonding mass composition of Co-Ni-Cr-B-Si semi-self-fluxing alloys and superhard compounds WC, B₄C and TiB₂. The variation in the roughness, thickness, composition, structure, microhardness and wear at the friction of the coatings as a function of the ratios between the bonding mass and the high-hardness components in the composition of the electrode and of the pulse energy for ESD has been studied. It has been established that with a content of the bonding mass in the electrode of 25–35%, coatings with improved adhesion and simultaneously higher hardness and toughness are obtained. Suitable electrode compositions and optimal pulse energy have been defined, which provide dense and uniform coatings with an increased amount of crystalline-amorphous structures, as well as intermetallic and wear-resistant phases, with thickness, roughness and microhardness that can be changed by the ESD modes in the ranges of δ = 8–65 µm, Ra = 1.5–7 µm, and HV 8.5–15.0 GPa, respectively, and minimal wear of the coated surfaces that is up to 5 times lower than that of the substrate and up to 1.5 times lower than that obtained with conventional WC-Co electrodes. Full article

Tantalum (Ta), along with its compounds and alloys, is extensively applied in the chemical, electronic, biological, and aerospace industries due to its excellent ductility, thermodynamic stability, and corrosion resistance. In recent years, coatings of Ta and its composites, fabricated using methods such as magnetron sputtering (MS), chemical vapor deposition (CVD), electrospark deposition (ESD), and cold spraying (CS), have undergone significant performance enhancements through extensive research efforts. This paper provides a comprehensive overview of the preparation techniques, applications, and improvement techniques associated with Ta and its compounds’ coatings. The preparation process parameters, mechanical properties, and corrosion resistance of Ta alloy coating and Ta non-metallic compound coating are discussed in detail. The findings aim to contribute to the design and development of innovative Ta and its compounds’ coating systems or the refinement of existing systems. Full article

Aimed at solving the problems of single control measures in the electro-spark deposition (ESD) process, difficulty controlling the micro-process using heterogeneous materials (for the electrode and matrix), and the unstable quality and reliability of repairs to the deposition layer, a method of magnetic-field-assistance electro-spark deposition (MFESD) was proposed. An MFESD device was built, and a Ni electrode was used for deposition on the surface of 45 steel under the conditions of deposition voltages of 30 V, 60 V, and 90 V, respectively. This study examined the impact of the magnetic field’s intensity and frequency on the microstructure and mechanical properties of electro-spark deposition layers. The results show that the sputtering and protrusion of the electrode material on the surface of the deposition layer gradually decrease with an increase in the magnetic field’s intensity and frequency, defects such as pores and cracks are obviously improved, and the structure is uninterrupted and compact. The surface roughness of the deposited layer decreases with an increase in the magnetic field’s intensity and frequency, and its surface roughness decreases by 44.3%. The cross-section effect of the deposited layer is improved. The thickness of the deposited layer increases with an increase in the magnetic field’s intensity and frequency; the thickness of the deposited layer increases by 13.39%, and its maximum thickness can reach 54.396 μm. At the same time, the microhardness of the deposited layer increases with an increase in the two aforementioned properties of the magnetic field, and its hardness increases by 5.32%. Using a magnetic field to control ESD can effectively control the microscopic process of deposition and obtain high-quality deposition coatings, which have important significance in the surface remanufacturing of key components of high-end equipment. Full article

Titanium carbide (TiC) coatings were prepared on the surface of AlFeCoCrNiCu high-entropy alloy blocks using electro-spark deposition (ESD). The microhardness and corrosion resistance of the TiC coatings prepared under different voltage and capacitance process parameters were studied. The research shows that the maximum microhardness of the TiC coating on sample 4 (working voltage of 20 V, working capacitance of 1000 μF) is 844.98 HV, which is 81.5% higher than the microhardness of the substrate. This is because the deposition energy increases with the increase in voltage, and the adhesion and aggregation between the coating and the substrate are enhanced, increasing the hardness of the coating. It is worth noting that excessive deposition energy can increase surface defects and reduce the microhardness of the coating surface. Electrochemical testing analysis shows that the corrosion current density of the TiC coating is the lowest (9.475 × 10⁻⁷ ± 0.06 × 10⁻⁷), and the coating impedance is the highest (2.502 × 10³ Ω·com²). The absolute phase angle value is the highest (about 72°). The above indicates that the TiC coating prepared with a working voltage of 20 V and a working capacitance of 1000 μF has better microhardness and corrosion resistance. Full article

As a surface-strengthening technology, electro-spark deposition (ESD) is widely used in the strengthening and repair of key components of high-end equipment. In this paper, a fusion and solidification model of ESD coating is established. The method of heat–fluid–solid interaction is adopted to simulate the material’s flow and fusion process in the droplet dropping into the molten pool. The distribution law of the coating-matrix material inside the coating was studied. Through the heat transfer between the molten material and the matrix material, the condensation and solidification process of the coating-matrix material is simulated, the temperature change in the coating area during the solidification process is analyzed, and the solidification law of the molten material is studied. The results show that the deposition time reaches 80 μs, and the content of electrode material at the bottom of the molten pool reaches 4.5%. The content of electrode material in the upper region of the material gushing out of the molten pool is higher than that in the bottom region. The material outside the molten pool solidifies first, and the molten material in the molten pool gradually solidifies from the bottom up; the shape of the solidification interface is similar to the boundary of the molten pool. Through the single-point deposition experiment of electro-spark deposition, the surface morphology of the deposition point was observed. The depth of the concave part of the contour can reach 16 μm. The difference between the two contour curves in the horizontal direction is not much; the error of the diameter is about 4%. The element distribution of the surface and the section of the deposition point are analyzed. The diffusion distance in the depth direction of the coating is about 4μm, and the transverse diffusion distance inside the coating is 364 μm. The error is 7.6% compared with the experimental results. The cross-section structure of the deposition point was observed, and the error between the experimental results and the simulation results in diameter is about 11%. It was found that the material distribution in the sedimentary area is basically consistent with the simulation results, and the simulation results are verified from the side. Full article

The development process of electrospark deposition (ESD) technology is reviewed, and the principles and differences of ESD technology are discussed in this review. Based on the research status regarding the ESD of titanium alloys, the promotion effect of ESD technology on wear resistance, corrosion resistance, oxidation resistance at high temperatures, and the biocompatibility of titanium alloys was elaborated on. For example, with the use of ESD technology to prepare Ti–Al, TiN, Ni–Cr, and other hardening coatings with high hardness, the maximum hardness of the deposited layer is six times higher than that of the substrate material, which greatly reduces the loss of the material surface in the process of friction in service, and has a high wear–resistance effect. The preparation of a single–phase lamellar coating is more beneficial for improving the oxidation resistance of the substrate. Carbide and a nano–porous coating can effectively enhance the bone integration ability of implants and promote biocompatibility. The application of ESD technology in the surface modification of titanium alloys is reviewed in detail. Finally, the development direction of ESD technology for titanium alloys is proposed. Full article

The electrospark deposition (ESD) technique is a low-heat-input process that has great potential for coating applications and the restoration of damaged high-value parts. Carbon steels are commonly used as a substrate material for ESD coatings. However, we demonstrated that carbon steels could be used successfully as the electrode tool for the ESD process. Furthermore, ESD coatings commonly have a high as–deposited roughness. In view of this, in order to reduce the roughness of the ESD coatings, electrodeposition as a tool to alter surface morphology was investigated. Hence, the micro-leveling power of several electrolytes for Ni, Fe-W, Fe, and Cr electrodeposition were evaluated. The maximum leveling effect was detected for Ni electroplated from the Watts electrolyte. Thus, the novel hybrid coatings based on an ESD layer and a subsequent layer of electrodeposited Ni were obtained. ESD layers were obtained by using the following electrode tools as anodes: several types of carbon steels (St20, St30, and St45), alloys T15K6 (WC + TiC + Co), CuNiZn; and NiCr. The morphology and structure of the obtained hybrid coatings with an electrodeposited Ni top-layer was analyzed and compared to ESD coatings from the point of view of their wear and corrosion behavior. The wear rate of the novel ESD coatings based on carbon steels was comparable with coatings obtained using the NiCr electrode tool. Moreover, for all the studied cases, the corrosion resistance of the hybrid coatings was higher than for their ESD counterparts and close to electrolytic chromium. Full article

Worn cemented carbide tool bits are often discarded because of the difficulty of their repair, resulting in a great deal of waste. Surface strengthening technology often extends the service life of worn tools. Electro-spark deposition (ESD) coating and matrix materials are metallurgically and closely bonded, and the approach has the characteristics of small heat input, a small heat-affected zone, and low repair cost, so it is suitable for strengthening the surface of cemented carbide tools. As the surface of cemented carbide tools is often not flat, which affects the uniformity of the deposited layer, the surface needs to be polished before ESD. Therefore, this paper proposed a method involving the electro-spark additive and subtractive repair of worn cemented carbide. Experiments involving the ultrasonic-assisted EDM grinding (UEDG) of cemented carbide were carried out. The effect of brass, 45 steel, and tungsten electrode materials on the removal rate, tool wear, and surface roughness were investigated. The results showed that the material removal rate of the tungsten electrode could reach 3.27 mm³/min, while the electrode loss was only 8.16%, and the average surface roughness was only 2.465 μm, which was better than the other two electrodes. Thus, the tungsten electrode exhibited a high material removal rate, low electrode loss, and good surface quality. The effects of the TiC, TiN, and TC4 electrodes on cemented carbide ESD were studied using optical 3D surface topography and other instruments, and the surface roughness, thickness, and hardness of the deposited layer were compared. The results showed that the surface roughness of the TC4 material reached 52.726 μm, which was better than that of the TiN and TiC materials. The thickness of the TiC deposition layer was 172.409 μm and the hardness value was 2231.9 HV; thus, the thickness and hardness of the TiC material’s sedimentary layer were better than those of the TiN and TC4 materials. Full article

In the present work, abrasive and erosive wear of wear-resistant composite coatings with a complex structure and different phase compositions deposited on titanium surfaces was studied. The coatings were obtained by electrospark deposition (ESD) using two types of hard-alloy compositions: WC–TiB₂–B₄C–Co–Ni–Cr–Si–B and TiB₂–TiAl reinforced with dispersed nanoparticles of ZrO₂ and NbC. The influence of the ESD process parameters on the roughness, thickness, composition, structure and coefficient of friction of the coated surfaces was investigated, and their role in protecting the titanium surfaces from wear was clarified. Dense coatings with the presence of newly formed wear-resistant phases and crystalline-amorphous structures were obtained, with roughness, thickness and microhardness that can be varied by the ESD modes in the range Ra = 2.5 ÷ 4.5 µm, δ = 8 ÷ 30 µm and HV 8.5 ÷ 14.0 GPa. The new coatings were found to reduce the abrasive and erosive wear of the coated surfaces by up to four times. The influence of the geometric characteristics, composition and structure of coatings on the wear intensity and wear resistance of coatings was studied. Full article

In this work, TiCrNiVSi_0.1 coatings were prepared on TC4 alloy by CNC-controlled automatic electro-spark deposition (ESD). The TOPSIS-based Taguchi method was applied for multi-criteria optimization of ESD coating quality. Frequency (f), capacitance (c), and electrode moving speed (v) were considered process parameters for optimizing the coating quality criteria, which included coating thickness, coating coverage, and porosity in the coating. The optimized parametric setting of the ESD process (f = 700 Hz, c = 270 μF, v = 150 mm/min) was obtained. MPEA coatings with a thickness of about 70 um, a coverage rate almost reaching 100%, and porosity as low as about 1% were prepared. The wear- and burn-resistance functions of the TiCrNiVSi_0.1 ESD coatings were investigated. The wear rates of the coating at room temperature and 400 °C are one-sixth and one-fourth of the TC4 alloy, respectively. A TiCrNiVSi_0.1 alloy coating was deposited and significantly improved the burn resistance of the TC4 alloy. Full article

The need to use components with improved surface characteristics in relation to severe operating conditions, together with the aim of cost reduction associated with the replacement of damaged components, has led to an increasing use of coatings and repairing processes. The most common deposition processes are generally characterized by high equipment costs and, sometimes, by long deposition time. Furthermore, some repair technologies, especially those characterized by high heat input, are not suitable for alloys used in aerospace applications due to the degradation of their mechanical characteristics. In the last decades, a novel eco-friendly method capable of overcoming the limits set out above emerged: the electrospark deposition (ESD) technology. Thanks to its efficiency, simplicity, cost-effectiveness, and low heat input, this technology has proved to be suitable both for improving surface properties, such as thermo and wear resistance, higher hardness and corrosion resistance, and for the repair of high-value components. The aim of this review is to describe in detail some aspects of the ESD technique to understand the ESD processing preparation of alloys normally considered difficult to weld by traditional processes and to give some important clues to the readers to contribute to the defect-free repair of damaged areas and coatings deposition. Full article

Coatings were produced on the EP741NP nickel alloy substrates by electrospark deposition (ESD) in argon using an MoSi₂-MoB-HfB₂ electrode. In situ high-resolution transmission electron microscopy and X-ray diffraction analysis studies have identified the temperature above which the strengthening Mo₂Ni₃Si Laves phase is formed in the coatings. At 25 °C, the coatings with a predominant content of the Laves phase are characterized by enhanced wear resistance, as well as a lower coefficient of friction compared to the non-annealed coatings containing binary silicides. At 700 °C, the EP741NP substrate was characterized by the lowest friction coefficient (Ktr = 0.35), and its wear was approximately at the same level as the wear of both coatings. Full article

Antifriction materials, such as silver, copper, Babbitt B83, and graphene oxide (GO), were used to prepare running-in coatings on the surface of bronze QSn10-1 by electro-spark deposition (ESD). The analyses of mass transfer, roughness, thickness, morphology, composition, nanoindentation, and tribological properties of the coatings were investigated. The results showed that the running-in coatings were dense with refined grains that were uniformly distributed and in a metallurgical bond state with the tin bronze substrate. At optimum process parameters, the mass transfer was 244.2 mg, the surface roughness was 15.9 μm, and the thickness of the layers was 160 μm. The diffraction peaks clearly indicated the phases corresponding to α-Sn, SbSn, Cu₆Sn₅, and Cu, and a phase of Ag₃Sn appeared. The modulus and the hardness of the running-in coatings were 24.9% and 14.2% of the substrate, and the deformation ratio of the coatings was 10.2% higher than that of the substrate. The friction coefficient of the running-in coatings was about 0.210 after the running-in stage, which was 64.8% of that of the substrate (0.324). The main wear mechanism of the running-in coatings under optimal process parameters is plastic deformation, scratching, and slight polishing. The running-in coating deformation under the action of high specific loads provides the automatic adjustment of parts and compensation for manufacturing errors. Full article