Search Results (101)

Eco-friendly mortars have been manufactured with hybrid binders made of blast furnace slag and a reduced amount of clinker. The objective is to explore new formulations suitable for reinforced structures. Previous studies are mainly focused on activation with sulfates, a salt that is corrosive to reinforcing steel. Sodium nitrate and sodium carbonate, easily implementable in construction, have been used as activators in two different concentrations that involve similar Na content. A Type II PC mortar is used as reference. The dimensional stability of the mortars during curing (at 99% RH) and subsequent drying at 40% RH, has been evaluated, as well as their porosity and mechanical properties. Böhme tests revealed that studied hybrid binders have lower wear resistance than PC mortar. Activation with Na₂CO₃ allows the obtention of mortars with reduced porosity and good compression resistance, but generates microcracking that favors chloride diffusion. Activation with nitrates favors precipitation of AFm phases identified through differential thermal analysis. Nitrates in moderate amounts (4% w/w) allow manufacturing hybrid mortars with good resistance to chloride penetration and reasonably good mechanical properties. Hence, this binder can be a promising option for reinforced structures. Higher amounts of nitrates (8%) for activation give rise to more porous mortars. Full article

Additive manufacturing (AM) has brought significant breakthroughs to the construction sector, such as the ability to fabricate complex geometries, enhance efficiency, and reduce both material usage and construction waste. However, several challenges must still be addressed to fully transition from conventional construction practices to innovative and sustainable green alternatives. This study investigates the use of non-cementitious traditional mixtures for green construction applications through 3D printing using Liquid Deposition Modeling (LDM) technology. To explore the development of mixtures with enhanced physical and mechanical properties, natural pine and cypress wood shavings were added in varying proportions (1%, 3%, and 5%) as sustainable additives. The aim of this study is twofold: first, to demonstrate the printability of these eco-friendly mortars that can be used for conservation purposes and overcome the challenges of incorporating bio-products in 3D printing; and second, to develop sustainable composites that align with the objectives of the European Green Deal, offering low-emission construction solutions. The proposed mortars use hydrated lime and natural pozzolan as binders, river sand as an aggregate, and a polycarboxylate superplasticizer. While most studies with bio-products focus on traditional methods, this research provides proof of concept for their use in 3D printing. The study results indicate that, at low percentages, both additives had minimal effect on the physical and mechanical properties of the tested mortars, whereas higher percentages led to progressively more significant deterioration. Additionally, compared to molded specimens, the 3D-printed mortars exhibited slightly reduced mechanical strength and increased porosity, attributable to insufficient compaction during the printing process. Full article

Previous research on geopolymers has not fully established their porosity and its influence on the matrix structure, as well as its relevance to mechanical and durability properties, supporting the potential of this material as a sustainable alternative to traditional construction materials. In this study, three geopolymer mortar (GM) mixtures were prepared: the first was obtained with fly ash (FA) without mechanical grinding (GM_FA), the second with FA that required crushing and sieving through a #200 sieve (GM_FA_200), and the third was a GM with FA that required crushing and sieving through a #325 sieve (GM_FA_325). The main objective was to evaluate the porosity of the geopolymeric paste and the interfacial transition zone (ITZ) between the aggregate and the geopolymerization products. Due to the susceptibility of this area to develop higher porosity, which leads to reduced mechanical properties and durability, it has become a significant focus of investigation in materials such as concrete and mortar. These analyses were carried out using physical adsorption of gases (PAG), and a methodology for image analysis of GM microporosity was implemented using micrographs obtained from a scanning electron microscope (SEM) and processed with the NI Vision Assistant 8.6 software (VA). The results from both image analysis and physical adsorption demonstrated that the GM_FA_325 matrix exhibited 19% less porosity compared to the GM_FA matrix. The results confirmed that GMs are predominantly mesoporous. It was observed that GM_FA_325 has the lowest total porosity, resulting in a denser and more compact microstructure, which is a key factor in its mechanical performance and potential applications as an eco-friendly construction material for coatings and precast elements such as blocks, panels, and similar products. In addition, image analysis using VA is highlighted as an efficient, cost-effective, and complementary technique to PAG, enabling robust results and resource optimization. Full article

Sustainable architectural heritage conservation focuses on preserving historical buildings while promoting environmental sustainability. It involves using eco-friendly materials and methods to ensure that the cultural value of these structures is maintained while minimizing their ecological impact. In this paper, the use of the hydroxyapatite (HAp) in various combinations on masonry samples is presented, with the aim of identifying the ideal solution to be applied to an entire historical building in Banloc monument. The new solution has various advantages: compatibility with historical lime mortars (chemical and physical), increased durability under aggressive environmental conditions, non-invasive and reversible, aligning with conservation ethics, bioinspired material that avoids harmful synthetic additives, preservation of esthetics—minimal visual change to treated surfaces, and nanostructural (determined via SEM and AFM) reinforcement to improve cohesion without altering the porosity. An innovative approach involving hydroxiapatite addition to commercial mortars is developed and presented within this paper. Physico-chemical, mechanical studies, and architectural and economic trends will be addressed in this paper. Some specific tests (reduced water absorption, increased adhesion, high mechanical strength, unchanged chromatic aspect, high contact angle, not dangerous freeze–thaw test, reduced carbonation test), will be presented to evidence the capability of hydroxyapatite to be incorporated into green renovation efforts, strengthen the consolidation layer, and focus on its potential uses as an eco-material in building construction and renovation. The methodology employed in evaluating the comparative performance of hydroxyapatite (HAp)-modified mortar versus standard Baumit MPI25 mortar includes a standard error (SE) analysis computed column-wise across performance indicators. To further substantiate the claim of “optimal performance” at 20% HAp addition, independent samples t-tests were performed. The results of the independent samples t-tests were applied to three performance and cost indicators: Application Cost, Annualized Cost, and Efficiency-Cost-Performance (ECP) Index. This validates the claim that HAp-modified mortar offers superior overall performance when considering efficiency, cost, and durability combined. Full article

The construction industry generates large amounts of waste and high CO₂ emissions, especially from cement production. Sustainable alternatives, such as geopolymers, help reduce these impacts by promoting eco-friendly materials. This study aimed to develop geopolymer mortar using ignimbrite (IG) residues from the Arequipa region, Peru, combined with metakaolin (MK). The raw materials were characterized by X-ray diffraction (XRD), X-ray fluorescence (XRF), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM) with energy dispersive spectroscopy (EDS) to assess the chemical composition, structure, and morphology. Geopolymeric mortars were synthesized with varying MK/IG ratios while maintaining a fixed fine sand proportion. An activating solution of 9 mol/L NaOH was used with different liquid-to-solid ratios. Geopolymers cured at room temperature for 28 days exhibited lower compressive strength than those dried at 50 °C for 48 h or sequentially at 50 °C for 48 h followed by 90 °C for 12 h. The highest IG-content mixture achieved a compressive strength of 18 MPa, while the MK-based geopolymer reached 12 MPa, both under high-temperature curing. An increase in the SiO₂/Al₂O₃ molar ratio was also associated with improved mechanical performance, reinforcing the influence of precursor composition on geopolymerization. These results highlight the potential of regional ignimbrite for the production of geopolymer mortar, promoting sustainable and innovative building materials. Full article

The pressing need for sustainable construction materials has identified alkali-activated materials (AAMs) as eco-friendly alternatives to conventional Portland cement. This study explores the synergistic performance of alkaline-activated natural pozzolan and limestone powder (AANL) blends against sulfate attack, evaluating mortar specimens immersed in sodium sulfate, magnesium sulfate, and a combined sulfate solution over 12 months. The samples were synthesized using natural pozzolan (NP) and limestone powder (LSP) in three distinct binder combinations to evaluate the influence of varying precursor ratios on the material’s performance, as follows: NP: LSP = 40:60 (AN₄₀L₆₀), 50:50 (AN₅₀L₅₀), and 60:40 (AN₆₀L₄₀). At the same time, the alkaline activators of 10 M NaOH_(aq) and Na₂SiO_3(aq) were combined in a ratio of 1:1 and cured at 75 °C. The research examines the weight variations of the samples, their residual compressive strength, and microstructural characteristics under exposure to magnesium sulfate, sodium sulfate, and a combined sulfate solution. In terms of weight change, samples exposed to Na₂SO₄ gained weight slightly, with AN₄₀L₆₀ recording the highest gain (3.2%) due to the ingress of sulfate ions and pore filling. Under MgSO₄, AN₆₀L₄₀ had the lowest weight gain (29%), while AN₄₀L₆₀ reached 54%. In mixed sulfate, AN₆₀L₄₀ showed negligible weight gain (0.11%); whereas, AN₅₀L₅₀ and AN₄₀L₆₀ gained 2.43% and 1.81%, respectively. Compressive strength retention after one year indicated that mixes with higher NP content fared better. AN₆₀L₄₀ exhibited the highest residual strength across all solutions—16.12 MPa in Na₂SO₄, 12.5 MPa in MgSO₄, and 19.45 MPa in the mixed solution. Conversely, AN₄₀L₆₀ showed the highest strength degradation, losing 47.22%, 58.11%, and 55.89%, respectively. SEM-EDS and FTIR analyses confirm that LSP’s vulnerability to sulfate attack diminishes with increased NP incorporation, highlighting a synergistic interaction that mitigates degradation and retains structural integrity. The combination of 60% NP and 40% LSP demonstrated superior resistance to all sulfate environments, as evidenced by visual durability, minimized weight gain, and retained compressive strength. This study highlights the potential of tailored NP-LSP combinations in developing durable and sustainable AAMs, paving the way for innovative solutions in sulfate-prone environments, while reducing environmental impact and promoting economic efficiency. Full article

The construction industry’s escalating environmental footprint, coupled with the underutilization of construction waste streams, necessitates innovative approaches to sustainable material design. This study investigates the dual functionality of recycled clay brick powder (RCBP) as both a supplementary cementitious material (SCM) and an alkali–silica reaction (ASR) inhibitor in hybrid mortar systems incorporating recycled glass (RG) and recycled clay brick (RCB) aggregates. Leveraging the pozzolanic activity of RCBP’s residual aluminosilicate phases, the research quantifies its influence on mortar durability and mechanical performance under varying substitution scenarios. Experimental findings reveal a nonlinear relationship between RCBP dosage and mortar properties. A 30% cement replacement with RCBP yields a 28-day activity index of 96.95%, confirming significant pozzolanic contributions. Critically, RCBP substitution ≥20% effectively mitigates ASRs induced by RG aggregates, with optimal suppression observed at 25% replacement. This threshold aligns with microstructural analyses showing RCBP’s Al³⁺ ions preferentially reacting with alkali hydroxides to form non-expansive gels, reducing pore solution pH and silica dissolution rates. Mechanical characterization reveals trade-offs between workability and strength development. Increasing RCBP substitution decreases mortar consistency and fluidity, which is more pronounced in RG-RCBS blends due to glass aggregates’ smooth texture. Compressively, both SS-RCBS and RG-RCBS mortars exhibit strength reduction with higher RCBP content, yet all specimens show accelerated compressive strength gain relative to flexural strength over curing time. Notably, 28-day water absorption increases with RCBP substitution, correlating with microstructural porosity modifications. These findings position recycled construction wastes and glass as valuable resources in circular economy frameworks, offering municipalities a pathway to meet recycled content mandates without sacrificing structural integrity. The study underscores the importance of waste synergy in advancing sustainable mortar technology, with implications for net-zero building practices and industrial waste valorization. Full article

In response to the high cost and environmental impact of backfill materials in Xinjiang mines, an eco-friendly, large-volume composite was developed by bonding desert-sand mortar to waste concrete. A rock-filled concrete process produced a highly flowable mortar from desert sand, cement, and fly ash. Waste concrete blocks served as coarse aggregate. Specimens were cured for 28 days, then subjected to uniaxial compression tests on a mining rock-mechanics system using water-to-binder ratios of 0.30, 0.35, and 0.40 and aggregate sizes of 30–40 mm, 40–50 mm, and 50–60 mm. Mechanical performance—failure modes, stress–strain response, and related properties—was systematically evaluated. Crack propagation was tracked via digital image correlation (DIC) and acoustic emission (AE) techniques. Failure patterns indicated that the pure-mortar specimens exhibited classic brittle fractures with through-going cracks. Aggregate-containing specimens showed mixed-mode failure, with cracks flowing around aggregates and secondary branches forming non-through-going damage networks. Optimization identified a 0.30 water-to-binder ratio (Groups 3 and 6) as optimal, yielding an average strength of 25 MPa. Among the aggregate sizes, 40–50 mm (Group 7) performed best, with 22.58 MPa. The AE data revealed a three-stage evolution—linear-elastic, nonlinear crack growth, and critical failure—with signal density positively correlating to fracture energy. DIC maps showed unidirectional energy release in pure-mortar specimens, whereas aggregate-containing specimens displayed chaotic energy patterns. This confirms that aggregates alter stress fields at crack tips and redirect energy-dissipation paths, shifting failure from single-crack propagation to a multi-scale damage network. These results provide a theoretical basis and technical support for the resource-efficient use of mining waste and advance green backfill technology, thereby contributing to the sustainable development of mining operations. Full article

Biochar, serving as a carbon sequestration material, has garnered significant attention. In this study, the effects of water-to-cement (W/C) and sand-to-binder (S/B) ratio on the macroscopic mechanical properties, dry-shrinkage behavior, and water transport properties of biochar mortar, as well as the microstructure of the mortar, are described. The results indicate that the compressive strength of the mortar decreases gradually with increases in the S/B ratio, while its flexural strength increases gradually with increases in the S/B ratio. Meanwhile, with increases in W/C and S/B, the drying shrinkage rate decreases, and the extent of water loss tends to be comparable to the drying shrinkage rate. The water absorption of biochar mortar increases as the W/C and S/B ratios increase. This is also reflected in the depth of water ingress in biochar mortars, which increases significantly with rising W/C and S/B ratios. Moreover, the water absorption coefficients of different mortars vary significantly only in the first few hours, and their final water absorption coefficients and ingress depths are similar. The SEM results indicate that biochar can provide nucleation points for hydration products to form a unique binding mechanism between them and the cement matrix. In addition, when the sand-to-cement ratio reaches 1.15, biochar reduces CO₂ emissions by 104.57 kg, and biochar mortar shows good potential for CO₂ sequestration. Full article

Cement is widely used as the primary binder in concrete; however, growing environmental concerns and the rapid expansion of the construction industry have highlighted the need for more sustainable alternatives. Geopolymers have emerged as promising eco-friendly binders due to their lower carbon footprint and potential to utilize industrial byproducts. Geopolymer mortar, like other cementitious substances, exhibits brittleness and tensile weakness. Basalt fibers serve as fracture-bridging reinforcements, enhancing flexural and tensile strength by redistributing loads and postponing crack growth. Basalt fibers enhance the energy absorption capacity of the mortar, rendering it less susceptible to abrupt collapse. Basalt fibers have thermal stability up to about 800–1000 °C, rendering them appropriate for geopolymer mortars designed for fire-resistant or high-temperature applications. They assist in preserving structural integrity during heat exposure. Fibers mitigate early-age microcracks resulting from shrinkage, drying, or heat gradients. This results in a more compact and resilient microstructure. Using basalt fibers improves surface abrasion and impact resistance, which is advantageous for industrial flooring or infrastructure applications. Basalt fibers originate from natural volcanic rock, are non-toxic, and possess a minimal ecological imprint, consistent with the sustainability objectives of geopolymer applications. This study investigates the mechanical and thermal performance of a geopolymer mortar composed of metakaolin and red mud as binders, with basalt powder and limestone powder replacing traditional sand. The primary objective was to evaluate the effect of basalt fiber incorporation at varying contents (0.4%, 0.8%, and 1.2% by weight) on the durability and strength of the mortar. Eight different mortar mixes were activated using sodium hydroxide (NaOH) and sodium silicate (Na₂SiO₃) solutions. Mechanical properties, including compressive strength, flexural strength, and ultrasonic pulse velocity (UPV), were tested 7 and 28 days before and after exposure to elevated temperatures (200, 400, 600, and 800 °C). The results indicated that basalt fiber significantly enhanced the performance of the geopolymer mortar, particularly at a content of 1.2%. Specimens with 1.2% fiber showed up to 20% improvement in compressive strength and 40% in flexural strength after thermal exposure, attributed to the fiber’s role in microcrack bridging and structural densification. Subsequent research should concentrate on refining fiber type, dose, and dispersion techniques to improve mechanical performance and durability. Examinations of microstructural behavior, long-term durability under environmental settings, and performance following high-temperature exposure are crucial. Furthermore, investigations into hybrid fiber systems, extensive structural applications, and life-cycle evaluations will inform the practical and sustainable implementation in the buildings. Full article

The cement industry is a major contributor to global CO₂ emissions, driving the research for sustainable alternatives. Olive biomass ash (OBA), a byproduct from burning all types of biomass from the olive tree, has emerged as a potential supplementary cementitious material (SCM). This study investigates the effects of incorporating olive pomace ash (OPA) as a partial cement substitute (0% to 50% by weight) on mortar properties over extended curing periods. Workability, compressive and flexural strengths, water absorption, and freeze–thaw resistance were evaluated. Up to 20% OPA replacement improved workability while maintaining acceptable strength and durability. Beyond this level, mechanical properties and frost resistance decreased significantly. Correlation analyses revealed strong relationships between flow time and wet bulk density (R² = 0.93), an exponential relationship between 28-day compressive strength and water absorption (R² = 0.87), and linear correlations between pre- and post-freeze–thaw mechanical properties (R² ≥ 0.99 for both compressive and flexural strengths). The results demonstrate that optimal OPA incorporation enhances mortar performance without compromising structural integrity and provides a viable strategy for valorizing agricultural waste. Full article

Global cement manufacturing generated 1.6 billion metric tons of CO₂ in 2022 and relies heavily on non-renewable raw materials. Utilizing agro-industrial waste as supplementary cementitious material (SCM) can help mitigate the demand for these resources. SCMs have been integrated into cement production to deliver both technical and environmental benefits to mortars and concrete. This study examines mortar blends containing blast furnace slag (BFS), Brazilian calcined clay (BCC), and bamboo leaf ash (BLA). While BFS and BCC are already established in the cement industry, recent research has highlighted BLA as a promising pozzolanic material. The SCMs were characterized, and mortars were produced to assess their flexural and compressive strength, as well as durability indicators such as electrical resistivity, chloride diffusion, migration coefficient, and carbonation resistance. The findings reveal significant performance enhancements. Partial cement replacement (20% and 40%) maintained the strength of both binary and ternary mortars, demonstrating statistical equivalence to the reference mortar (p > 0.05). It also contributed to an improved pore structure, reducing the migration coefficient by up to four times in the 20BLA20BCC mix (which replaces 20% of cement with BLA and 20% with BCC) compared to the reference mix. Chemically, the SCMs enhanced the chloride-binding capacity of the cementitious matrix by up to seven times in the case of the 20BCC mortar, thereby improving its durability. Therefore, all tested compositions—binary and ternary—showed mechanical and durability advantages over the reference while also contributing to the reduction in environmental impacts associated with the cement industry. Full article

This study examines the thermal insulation capacity, mechanical performance, and high-temperature resistance of geopolymer composites reinforced with 5%, 10%, and 20% hemp fiber. This research aims to develop sustainable, high-performance construction materials with enhanced thermal efficiency and structural integrity. Thermal conductivity, compressive strength, and flexural strength tests were conducted on geopolymer mortar specimens to evaluate their performance. The results indicate that increasing hemp fiber content improves thermal insulation, with the 20% hemp fiber mixture achieving the lowest thermal conductivity. However, hemp fiber reinforcement leads to reductions in both compressive and flexural strength while maintaining structural stability. These findings highlight the potential of hemp fiber-reinforced geopolymers as eco-friendly alternatives to conventional insulation materials, particularly for applications requiring fire resistance and thermal efficiency, despite the observed decrease in mechanical properties. This research contributes to the advancement of sustainable construction materials and underscores the viability of hemp fiber-reinforced geopolymer mortars for industrial applications. Further studies are recommended to optimize mix designs and assess long-term durability under various environmental conditions. Full article

The incorporation of industrial by-products such as fly ash (FA) into cementitious materials plays a vital role in promoting environmental sustainability during cement production. This study evaluates the feasibility of using siliceous fuel fly ash, sourced from thermal power stations in the Rhenish region of Germany, as a partial cement replacement in mortar formulations. Mortar specimens with FA replacement levels ranging from 5 wt% to 30 wt% were prepared and tested. Data were collected through standardized laboratory testing of mechanical properties (compressive and flexural strength), physical characteristics (porosity, sorptivity) and microstructural analysis via SEM and XRD. The results showed that increasing FA content generally led to reductions in strength and increases in porosity and sorptivity, due to the mineralogical composition and higher water demand linked to the porous FA structure. However, when FA was used at levels not exceeding 10 wt%, the physical and mechanical properties remained within acceptable limits for construction applications. Additionally, the use of plasticizing admixtures proved effective in mitigating workability and strength issues by reducing the water-to-binder ratio. These findings highlight that, despite certain limitations, siliceous FA can be safely and effectively used in low percentages, contributing to sustainable mortar production and reducing reliance on Portland cement. In addition, the use of fly ash contributes to reduced CO₂ emissions and lower production costs, promoting sustainable and cost-efficient construction solutions. Full article

This study presents a comprehensive review of various advanced methodologies that have been used to enhance the structural and thermal performance of masonry walls through innovative and sustainable retrofitting/upgrading techniques. Focusing on three primary approaches—mechanical/structural retrofitting, thermal retrofitting, and integrated (structural and thermal) retrofitting, this paper critically examines various masonry-strengthening strategies. Retrofitting techniques are categorized by material use and objectives. Fiber-based solutions include insulation materials, fiber composite mortar for strength, FRP for high-strength reinforcement, and TRM for durability. According to the relevant objectives, retrofitting can enhance structural stability (FRP, TRM), improve thermal insulation, or combine both for integrated performance. Particular emphasis is placed on the effectiveness of TRM systems, with a comparative analysis of man-made (glass, steel textile) and natural fiber-based TRM solutions. Regarding integrating natural fibers into TRM systems, this study highlights their potential as eco-friendly alternatives that reduce environmental impact while maintaining or improving structural integrity. Furthermore, it highlights and examines techniques for testing masonry walls. In this context, this review highlights the applicability of natural fiber as a sustainable building material in various retrofitting/upgrading solutions. Full article