Search Results (20)

A novel type of multifunctional hybrid membranes combining modified chitosan, functionalized multi-walled carbon nanotubes (MWCNTs), and rare earth element ion-imprinted polymers (REEIIPs) were designed and characterized. The synthesized materials were characterized by thermogravimetric analysis (TGA), scanning electron microscopy (SEM), vibrating sample magnetometry (VSM), X-ray diffraction (XRD), X-ray micro-tomography, and Fourier transform infrared spectroscopy (FTIR). The hybrid membranes were also studied in terms of their mechanical and rheological properties. The key element of the proper preparation of hybrid membranes using the casting method in an external magnetic field was to synthesize membrane components with appropriate magnetic properties. It was found that they showed tunable weak ferromagnetic properties, and the increase in modified nanotube addition caused the rise in the membrane’s saturation magnetization, which for Nd-selective hybrid membranes reached 0.44 emu/g. Also, the increase in thermooxidative stability was noted after introducing functionalized nanotubes into polymer matrices, which, in the case of Gd-selective membranes, were stable even up to 730 °C. The rise in the modified MWCNT addition and selection of appropriate REE ion-imprinted polymers improved mechanical (Rm and E values increase even twice) and rheological parameters (almost double growth of E′ and E″ values) of the tested membranes. Synthesized hybrid membranes showed a high rejection of matrix components and an increase in retention ratio with rising MWCNT-REEIIP addition, ultimately reaching 94.35%, 92.12%, and 90.11% for Nd, Pr, and Gd, respectively. The performed analysis confirmed homogeneous dispersion, phase compatibility, network integration, formation of a complex 3D microstructure, and improved operational stability of created hybrid membranes, which is significant for their future applications in Nd, Pr, and Gd recovery from coal fly ash extracts. Full article

In this study, a novel adsorbent was developed by synthesizing Zn-Al layered double hydroxide (LDH) incorporated with silver nanoparticles (Ag-NPs), and its effectiveness in bromide removal from aqueous solutions was systematically evaluated. The X-ray Diffraction (XRD) and Fourier Transform Infrared Spectroscopy (FTIR) analyses confirmed the integration of Ag-NPs within the LDH, ensuring uniform chemical composition and structural integrity. A series of controlled batch trials, each varying a single parameter (adsorbent dose, contact time, or temperature) confirmed that over 95% of bromide (initially 5320 μg/L) was removed under optimized conditions. LDH/Ag-NPs exhibited superior performance, with kinetics well described by a second-order reaction model. Thermodynamic analysis confirmed the spontaneous and exothermic nature of bromide adsorption, with ΔG° values ranging from −2.03 to −0.73 kJ/mol as the temperature increased from 22 °C to 52 °C. In continuous-flow experiments, packed-bed column tests illustrated that LDH/Ag-NPs maintained more effective bromide removal than LDH alone over extended periods. Conductivity measurements further supported this enhancement, with LDH/Ag-NPs reducing final conductivity to 139 µS/cm, compared to 212 µS/cm for LDH. Furthermore, this study revealed the notable antimicrobial activity of LDH/Ag-NPs, as evidenced by a significant reduction in bacterial growth compared to LDH alone, highlighting its dual functionality for both bromide adsorption and water disinfection. Overall, the incorporation of Ag-NPs into LDH offers a promising strategy for developing multifunctional and sustainable water treatment systems. Full article

Eutrophication is a major environmental issue affecting freshwater ecosystems worldwide. While its impact on the composition of dissolved organic matter (DOM) is well recognized, the relationships between DOM’s optical and molecular properties across eutrophication gradients remain underexplored. This review synthesizes recent research on DOM’s optical properties (derived from UV-Vis absorption and fluorescence spectroscopy) and molecular characteristics (analyzed using Fourier-transform ion cyclotron resonance mass spectrometry, FT-ICR MS) in freshwater systems of varying trophic states. Generalized additive model (GAM) analysis was used to assess correlations between DOM’s properties and the trophic state index (TSI). The dissolved organic carbon (DOC), a₂₅₄, SUVA₂₅₄, S_R, HIX, BIX, and FI averaged 11.44 ± 11.97 mg/L, 23.23 ± 16.95 m⁻¹. 2.98 ± 0.99 L·mg⁻¹·m⁻¹, 1.42 ± 0.38, 2.38 ± 1.31, 1.08 ± 0.16, and 2.11 ± 0.44, respectively, from mesotrophic to middle-eutrophic sites. The GAM results revealed a significant linear correlation between DOC and DOM’s optical properties, including a₂₅₄, SUVA₂₅₄, and FI, with the TSI, suggesting that DOM accumulation intensifies with eutrophication. DOM’s molecular properties, such as O/C and H/C ratios, double bond equivalents (DBEs), and CHOS% content, exhibited nonlinear correlations with the TSI. These trends imply a shift in DOM sources from terrestrial and macrophyte-derived inputs to those dominated by algal- and sediment-derived sources as eutrophication progresses. We concluded that DOM’s molecular indices alone may not serve as a reliable indicator of freshwater trophic states; future studies should focus on integrating both optical and molecular indices to offer a more comprehensive assessment of freshwater trophic states. Given the limited number of molecular variables examined in this study, this work only offers a preliminary investigation into the relationship between DOM molecular changes and freshwater eutrophication. More systematic studies focusing on the molecular-level analyses of DOM across varying trophic states on a broader geographic scale are needed. Full article

Indomethacin (INDO) has a mechanism of action based on inhibiting fatty acids cyclooxygenase activity within the inflammation process. The action mechanism could be correlated with possible anticancer activity, but its high toxicity in normal tissues has made therapy difficult. By the coprecipitation method, the drug carried in a layered double hydroxides (LDH) hybrid matrix would reduce its undesired effects by promoting chemotherapeutic redirection. Therefore, different samples containing INDO intercalated in LDH were synthesized at temperatures of 50, 70, and 90 °C and synthesis times of 8, 16, 24, and 48 h, seeking the best structural organization. X-ray diffraction (XRD), vibrational Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), spectrophotometric analysis in UV-VIS, and differential thermogravimetric analysis (TGA/DTA) were used for characterization. Our results indicate that higher temperatures and longer synthesis time through coprecipitation reduce the possibility of INDO intercalation. However, it was possible to establish a time of 16 h and a temperature of 50 °C as the best conditions for intercalation. In vitro results confirmed the cell viability potential and anticancer activity in the LDH-INDO sample (16 h and 50 °C) for gastric cancer (AGP01, ACP02, and ACP03), breast cancer (MDA-MB-231 and MCF-7), melanoma (SK-MEL-19), lung fibroblast (MRC-5), and non-neoplastic gastric tissue (MN01) by MTT assay. Cell proliferation was inhibited, demonstrating higher and lower toxicity against MDA-MB-231 and SK-MEL-19. Thus, a clinical redirection of INDO is suggested as an integral and adjunctive anticancer medication in chemotherapy treatment. Full article

In-line digital holography is a powerful tool widely used for microscopic object imaging. Usually, in-line and out-line configurations are used to implement holographic systems, but in-line-based set-ups are preferable as they are less sensitive to mechanical vibrations and refraction index variations. However, non-desired blurred conjugate images are superposed to the reconstructed object image by using in-line systems. One strategy to remove the conjugate image contribution is to include a double-sideband filter at the Fourier plane of the system. After using the filter, data obtained at the CCD are processed to retrieve the magnitude and phase (hologram) of the diffracted wavefront while removing the conjugated image. Afterwards, a diffraction integral equation is used to digitally propagate the hologram. Despite the above-mentioned factors, there is not a thorough analysis in the literature of magnification parameters associated with the final reconstructed image, this aspect being crucial for the experimental application of the above-stated approach. Under this scenario, a theoretical analysis of the longitudinal and transverse magnifications of the reconstructed images is provided in this work. The method is validated through the simulation and experimental results of different microscopic objects: glass microspheres, a micrometric reticle, and a resolution test chart USAF 1951. The obtained results provide that the combination of magnification relations with methods for hologram propagation and optimal focused image identification is effective for object position determination. This approach could be useful for 3D microparticle localization and monitoring with optimized magnification within real-time applications. Full article

Severe phenomena of across range-Doppler unit (ARDU) and decoherence occur when radar detects high-speed and high-maneuvering targets, causing degradation in detection performance of traditional FFT radar detection methods. The improvement in radar resolution causes a multi-dimensional spread phenomenon, where different scattering centers of the target are distributed on different range units, along with motion parameters such as velocity and acceleration. Unfortunately, current radar detection methods focus solely on range spread targets and cannot handle multi-dimensional spread, leading to a significant decline in detection performance. To overcome this problem, this paper proposes several methods to achieve high detection performance for multi-dimensional spread target detection with ARDU phenomenon. Firstly, the generalized likelihood ratio test (GLRT) is derived, and the energy integration generalized Rayleigh Fourier transform (EI-GRFT) is introduced to improve the detection performance of range spread cross-unit targets. Additionally, the double-threshold based hybrid GRFT (DT-HGRFT) is presented as an enhancement of EI-GRFT, enabling long-time integration along slow time and integration among multiple scatters by using HGRFT and multi-dimensional sliding double-threshold detection, respectively. Furthermore, a method for joint detections of multiple DT-HGRFTs is provided to handle the case where the number of scattering centers of multi-dimensional spread targets is unknown. Finally, a detailed theoretical analysis of the performance of the proposed method is presented, along with extensive simulations and practical experiments to demonstrate the effectiveness of the proposed methods. Full article

The hybrid modular multilevel converter (MMC) consisting of half-bridge submodules (HBSMs) and full-bridge submodules (FBSMs) is a promising solution for overhead lines high-voltage direct current systems (HVDC) due to the advantages of direct current short circuit fault ride-through (DC-FRT) capability. This paper proposes an improved phase-disposition pulse width modulation (PDPWM) method for the hybrid modular multilevel converter. The number of carriers can be reduced from 3N (N is the number of submodules in each arm) to 6. The theoretical harmonic analysis of the improved PDPWM method for hybrid MMC is performed by using double Fourier integral analysis. The influence of three carrier displacement angles between HBSMs and FBSMs in the upper and lower arms on harmonic characteristics is investigated. The output voltage harmonics minimization PDPWM scheme and circulating current harmonics cancellation PDPWM scheme can be achieved by selecting the optimum carrier displacement angles, respectively. The proposed method for hybrid MMC is verified by the simulation and experimental results. Full article

This study aimed to provide a static solution to the boundary value problem presented by symmetric (0°/90°/0°) and antisymmetric (0°/90°) cross-ply composite, moderately thick shallow shells and plates (a special case of the shells) subjected to mixed-type unsolved boundary conditions. The boundary-discontinuous double Fourier series (BDM) method, in which displacements are expressed in trigonometric functions, is employed in a well-established framework. The analytical solution obtained using the BDM is compared with the successful integration of the generalized differential quadrature (GDQ) method for the static analysis of composite shells with a roller skate-type boundary condition prescribed on two opposite edges, while the remaining two edges are subjected to simply supported constraints. Comprehensive results are presented in order to show the effects of curvature on the deflections and stresses of moderately thick shallow shells made up of symmetric and antisymmetric cross-ply laminated composite materials. The validity of the proposed model is authenticated through the available HSDT-based literature review, and the convergence characteristics are demonstrated. The changing trends of displacements and stresses are explained in detail by investigating the effect of various parameters such as lamination, material properties, the effect of curvature, etc. Based on the results obtained using the proposed static solution, analytical BDM results were found to be in very close agreement with the numerical GDQ method, especially for symmetric lamination. However, the results obtained using the BDM and GDQ methods for antisymmetric lamination show differences, possibly due to the presence of a discontinuity in the derivatives originating from the bending–stretching matrix in antisymmetric lamination. Important numerical results presented include the sensitivity of the predicted response quantities of interest to material properties, lamination, and thickness effects, as well as their interactions. The results presented here may also serve as benchmark comparison points with numerical solutions such as finite elements, boundary elements, etc. Full article

Leakage inductance is one of the key parameters of a transformer, and it is often intentionally integrated into transformers. Rogowski’s equation is generally used for leakage inductance calculation; however, it is only applicable to concentric winding transformers where windings have the same height. Consequently, it has limited applications. This paper proposes a transformer leakage inductance calculation method using a double Fourier series. The limitation of Rogowski’s leakage inductance equation was analyzed in practical applications, and a new model for calculating the leakage inductance of a double-group-overlapping winding transformer was derived. Experimental prototypes of transformers were developed, and their simulation models were built in Ansys. The correctness of the proposed calculation method for transformer leakage inductance using a double Fourier series was verified by comparing the calculation results with the simulation and measured ones. A sensitivity analysis was also conducted by studying the variations in different parameters that might affect the leakage inductance value. The proposed calculation model gives an intuitive and simple method with less calculation and design effort while maintaining reasonable accuracy for leakage inductance calculation. In addition, the featured double Fourier series approach has a wider range of applications than Rogowski’s equation. Full article

The photo-oxidative studies of ethylene vinyl acetate copolymer (EVA) matrix, filled with Layered Double Hydroxide (LDH) modified with methacrylic anion (MA), were herein reported, together with gas permeation tests. The formulation of nano-hybrid LDHs was characterized using X-ray diffractometry (XRD) and thermogravimetric analysis (TGA), demonstrating the partial intercalation of the 30% of MA anion between the LDH’s galleries. The as-modified filler was introduced into an EVA matrix by mechanical milling, producing free-standing films subjected to accelerated aging. Fourier transform infrared spectroscopy (FT-IR) results suggested that the nanohybrid presence determined a stabilizing effect up to 45 days of UV irradiation, especially if compared to the EVA/LDH references for all formulated EVA hybrid nanocomposites. Conversely, the presence of nanohybrid in the matrix did not significantly change the thermal stability of EVA samples. The dispersion of modified MA-LDH in the EVA matrix produces defect-free samples in the whole range of investigated loadings. The samples show a slight decrease in gas permeability, coupled with a substantial stabilization of the original CO₂/O₂ selectivity, which also proves the integrity of the films after 30 days of UV irradiation. Full article

This investigation focused on the design of an injectable nano-enabled thermogel (nano-thermogel) system to attain controlled delivery of p11 anti-angiogenic peptide for proposed effective prevention of neovascularisation and to overcome the drawbacks of the existing treatment approaches for ocular disorders characterised by angiogenesis, which employ multiple intravitreal injections of anti-vascular endothelial growth factor (anti-VEGF) antibodies. Synthesis of a polyethylene glycol-polycaprolactone-polyethylene glycol (PEG-PCL-PEG) triblock co-polymer was undertaken, followed by characterisation employing Fourier-transform infrared (FTIR) spectroscopy, nuclear magnetic resonance (NMR) spectroscopy and differential scanning calorimetry (DSC) to ascertain the chemical stability and integrity of the co-polymer instituted for nano-thermogel formulation. The p11 anti-angiogenic peptide underwent encapsulation within poly(lactic-co-glycolic acid) (PLGA) nanoparticles via a double emulsion solvent evaporation method and was incorporated into the thermogel following characterisation by scanning electron microscopy (SEM), zeta size and zeta-potential analysis. The tube inversion approach and rheological analysis were employed to ascertain the thermo-sensitive sol-gel conversion of the nano-thermogel system. Chromatographic assessment of the in vitro release of the peptide was performed, with stability confirmation via Tris-Tricine PAGE (Polyacrylamide Gel Electrophoresis). In vitro biocompatibility of the nano-thermogel system was investigated employing a retinal cell line (ARP-19). A nanoparticle size range of 100–200 nm and peptide loading efficiency of 67% was achieved. Sol-gel conversion of the nano-thermogel was observed between 32–45 °C. Release of the peptide in vitro was sustained, with maintenance of stability, for 60 days. Biocompatibility assessment highlighted 97–99% cell viability with non-haemolytic ability, which supports the potential applicability of the nano-thermogel system for extended delivery of peptide for ocular disorder treatment. Full article

Multiphase drives are entering the spotlight of the research community for transportation applications with their high power density and the possibility of high fault tolerance. The multi three-phase drive is one of the main types of multiphase drives that allows for the direct adoption of commercial three-phase converters and high control flexibility. The elimination of high-frequency current harmonics will reduce the flux linkage harmonics, torque ripple, vibration and noise in machine drives. Therefore, this work introduces a new method to the modelling of equivalent phase current in multi three-phase drives with the double integral Fourier analysis method. A new carrier-based pulse-width modulation (CPWM) method is introduced to reduce the equivalent phase current harmonics by applying proper carrier phase angle to each subsystem in the multi three-phase drives. The proposed angles of carrier signals are analyzed for quadruple three-phase drives, and the corresponding experimental results confirm the significance of the proposed phase-shifted CPWM method to eliminate the equivalent phase current harmonics. Full article

It is necessary to develop a sustainable food production system to ensure future food security around the globe. Cropping intensity and sowing month are two essential parameters for analyzing the food–water–climate tradeoff as food sustainability indicators. This study presents a global-scale analysis of cropping intensity and sowing month from 2000 to 2015, divided into three groups of years. The study methodology integrates the satellite-derived normalized vegetation index (NDVI) of 16-day composite Moderate Resolution Imaging Spectroradiometer (MODIS) and daily land-surface-water coverage (LSWC) data obtained from The Advanced Microwave Scanning Radiometer (AMSR-E/2) in 1-km aggregate pixel resolution. A fast Fourier transform was applied to normalize the MODIS NDVI time-series data. By using advanced methods with intensive optic and microwave time-series data, this study set out to anticipate potential dynamic changes in global cropland activity over 15 years representing the Millennium Development Goal period. These products are the first global datasets that provide information on crop activities in 15-year data derived from optic and microwave satellite data. The results show that in 2000–2005, the total global double-crop intensity was 7.1 million km², which increased to 8.3 million km² in 2006–2010, and then to approximately 8.6 million km² in 2011–2015. In the same periods, global triple-crop agriculture showed a rapid positive growth from 0.73 to 1.12 and then 1.28 million km², respectively. The results show that Asia dominated double- and triple-crop growth, while showcasing the expansion of single-cropping area in Africa. The finer spatial resolution, combined with a long-term global analysis, means that this methodology has the potential to be applied in several sustainability studies, from global- to local-level perspectives. Full article

This paper presents a 2D hybrid steady-state magnetic field model, capable of accurately modeling the electromagnetic behavior in a linear induction motor, including primary slotting, finite yoke length, and longitudinal end-effects by primary motion. This model integrates a complex harmonic modeling technique with a discretized magnetic equivalent circuit model. The Fourier model is applied to regions with homogeneous material properties, e.g., air regions and the track of the motor, while the magnetic equivalent circuit (MEC) approach is used for the regions containing non-homogeneous material properties, e.g., the primary of the linear induction motor (LIM). By only meshing the domains containing highly-permeable materials, the computational effort is reduced in comparison with the finite element method (FEM). The model is applied to a double-layer single-sided LIM, and the resulting thrust and normal forces show an excellent agreement with respect to finite element analysis and measurement data. Full article

The dynamic response of a simply supported double-beam system under moving loads was studied. First, in order to reduce the difficulty of solving the equation, a finite sin-Fourier transform was used to transform the infinite-degree-of-freedom double-beam system into a superimposed two-degrees-of-freedom system. Second, Duhamel’s integral was used to obtain the analytical expression of Fourier amplitude spectrum function considering the initial conditions. Finally, based on finite sin-Fourier inverse transform, the analytical expression of dynamic response of a simply supported double-beam system under moving loads was deduced. The dynamic response under successive moving loads was calculated by the analytical method and the general FEM software ANSYS. The analysis results show that the analytical method calculation results are consistent with ANSYS’ calculation, thus validating the analytical calculation method. The simply supported double-beam system had multiple critical speeds, and the flexural rigidity significantly affected both peak vertical displacement and critical speed. Full article