Search Results (23)

Despite the fact that doping nanoparticles into insulating transformer oil has proven to be an effective method of enhancing its dielectric and electrical properties, it remains unclear how different types and surface conditions of nanoparticles may affect their dielectric and electrical properties. Therefore, the effect of doping various types of BN nanoparticles (nanosphere, nanotube, and nanosheet) in insulating mineral oil (MO) on the diffusion properties of water molecules and electrical properties across the BN/MO interface was investigated using molecular dynamics (MD) and Density Functional Theory (DFT) simulations. Our results show that different surface morphology and grafted functional groups in different types of BN nanoparticles have a significant impact both on the water diffusion behavior and the interfacial potential barrier across the interface between BN and MO. In the MO system directly doped by BN nanospheres, water diffusion behavior is not significantly restricted. However, grafting -NH₂ polar groups onto the BN nanoparticle surface may significantly limit the diffusion behavior of water due to the strong attraction between the -NH₂ polar groups and water molecules; the most significant effect is with nanospheres, followed by nanotubes and nanosheets. In terms of electrical properties across the interface between BN and MO, the h-BN surface (derived from BN nanosheets and nanotubes) acts as a trap for electrons in MO (−0.59 eV), while the c-BN surface (derived from BN nanospheres) acts as a potential barrier for electrons in MO (1.45 eV), and it is noteworthy that the presence of water molecules near the interface between BN and MO has little impact on the potential barriers. Advancing a fundamental understanding of the electrical and water diffusion properties of MO in correlation with the surface morphology of different types of nanoparticles is key to improving the insulation properties of oil-impregnated power transformers. Full article

Current optical tweezering techniques are actively employed in the manipulation of nanoparticles, e.g., biomedical cells. However, there is still huge room for improving the efficiency of manipulating multiple nanoparticles of the same composition but different shapes. In this study, we designed an array of high-index all-dielectric disk antennas, each with an asymmetric open slot for such applications. Compared with the plasmonic counterparts, this all-dielectric metasurface has no dissipation loss and, thus, circumvents the Joule heating problem of plasmonic antennas. Furthermore, the asymmetry-induced excitation of quasi-bound states in continuum (QBIC) mode with a low-power intensity (1 mW/µm²) incidence imposes an optical gradient force of −0.31 pN on 8 nm radius nanospheres, which is four orders of magnitude stronger than that provided by the Fano resonance in plasmonic antenna arrays, and three orders of magnitude stronger than that by the Mie resonance in the same metasurface without any slot, respectively. This asymmetry also leads to the generation of large optical moments. At the QBIC resonance wavelength, a value of 88.3 pN-nm will act on the nanorods to generate a rotational force along the direction within the disk surface but perpendicular to the slot. This will allow only nanospheres but prevent the nanorods from accurately entering into the slots, realizing effective sieving between the nanoparticles of the two shapes. Full article

We theoretically and numerically investigate the temporal dynamics of a nanodimer system consisting of a pair of graphene-wrapped dielectric nanospheres with tunable radii. Considering that symmetry breaks on resonant frequencies, we derive the temporal kinetic equations in an asymmetric form by utilizing the dispersion relation method in dipole limit. The bifurcation diagrams achieved via the analysis on the linear instability and numerical solutions can quantitatively characterize the complex coexistences of stationary and dynamical behaviors in this dimer system, and the asymmetry apparently can increase the number of regimes with the periodic self-oscillation state or chaos. Furthermore, we find that the indefinite switching not only can be triggered among the stationary steady solutions, but it also universally exists among all the possible solutions in a coexistent regime. The switching can be tuned by applying a hard excitation signal with different durations and saturation values. Our results may provide new paths to realize a nonlinear nanophotonic device with tunable dynamical responses or even multi-functionalities. Full article

The contour intersection method is a new method used to invert the complex refractive index of small particles. Research has yet to be reported on using this method to invert the complex refractive index of nanoparticles. This paper reports the feasibility and reliability of the contour intersection method in the inversion of the complex refractive index of nanoparticles using Au-Ag alloy nanospheres. The Mie theory and the size-dependent dielectric function are used to calculate the light scattering and absorption efficiency of Au-Ag alloy nanospheres corresponding to the complex refractive index. The complex refractive index of the particles is obtained by inversion with the contour intersection method. The backscattering efficiency constraint method is used to determine the unique solution when multiple valid solutions from the contour intersection method appear. The effects of the Au component percentage, particle size, and measurement errors on the inversion results are quantitatively analyzed. Finally, the inversion accuracy is compared and analyzed with the traditional iterative method. The results show that as long as the light scattering efficiency, light absorption efficiency, and backscattering efficiency of Au nanospheres can be measured, the accurate complex refractive index can also be calculated by inversion using the contour intersection method. The accuracy of the inversion results can be ensured when the measurement error is less than 5%. The results of inversion using the contour intersection method are better than those of the iterative methods under the same conditions. This study provides a simple and reliable inversion method for measuring the complex refractive index of Au-Ag alloy nanospheres. Full article

In this paper, we discuss the preparation of Li-doped ZnO nanostructures through combustion and report on their structural, morphological, optical, and electrocatalysis properties. X-ray diffraction analyses show that the samples have a structure crystallized into the usual hexagonal wurtzite ZnO structure according to the P63mc space group. The scanning electron microscope images conceal all samples’ nanosphere bundles and aggregates. The reflectance spectra analysis showed that the direct bandgap values varied from 3.273 eV (for pure ZnO, i.e., ZnL1) to 3.256 eV (for high Li-doped ZnO). The measured capacitance concerning frequency has estimated the variation of dielectric constant, dielectric loss, and AC conductivity against AC electric field frequency. The dielectric constant variations and AC conductivity are analyzed and discussed by well-known models such as Koop’s phenomenological theory and Jonscher’s law. The Raman spectra have been recorded and examined for the prepared samples. Rhodamine B was electro-catalytically degraded in all prepared samples, with the fastest time for ZnL5 being 3 min. Full article

Yttria-stabilized zirconia (YSZ) nanospheres were synthesized by calcination at 900 °C after the adsorption of Y³⁺ ions into the pores of a zirconium-based metal–organic framework (MOF). The synthesized 3YSZ (zirconia doped with 3 mol% Y₂O₃), 8YSZ (8 mol% Y₂O₃), and 30YSZ (30 mol% Y₂O₃) nanospheres were found to exhibit uniform sizes and shapes. Complex permittivity and complex permeability were carried out in K-band (i.e., 18–26.5 GHz) to determine their suitability for use as low-k materials in 5G communications. The real and imaginary parts of the permittivity of the sintered 3YSZ were determined to be 21.24 and 0.12, respectively, while those of 8YSZ were 22.80 and 0.16, and those of 30YSZ were 7.16 and 0.38. Control of the real part of the permittivity in the sintered YSZ was facilitated by modifying the Y₂O₃ content, thereby rendering this material an electronic ceramic with potential for use in high-frequency 5G communications due to its excellent mechanical properties, high chemical resistance, and good thermal stability. In particular, it could be employed as an exterior material for electronic communication products requiring the minimization of information loss. Full article

MnO-Co@C nanospheres were fabricated by in situ polymerizing and high-temperature carbonizing processes. This unique synthesis method does not require any template or reducing gas. The synthesized multicore-shell structure has a shell of about 500 nm and multiple nuclei of several tens of nanometers. Subsequently, extensive experiments were conducted to adjust the material composition of the nanospheres by adjusting the amount of resorcinol and formaldehyde. The results showed that the obtained material performed best when resorcinol and formaldehyde were added to 0.2 g MnCo₂O₄ at 0.3 g and 0.42 mL, respectively. The efficient absorption bandwidth (EAB) value reaches 3.3 GHz when the absorber thickness is 3 mm. The reflection loss (RL) is up to −23.8 dB when the frequency is at 8.6 GHz. The unique yolk core-shell structure gives the material a heterogeneous interface, and the enhanced interfacial polarization loss causes the enhanced dielectric loss. The carbon layer with microporosity also causes conduction loss and multiple reflections. The composite structure formed by metallic Co, MnO, and carbon has better impedance matching and improved microwave absorption capability. Full article

Antireflection and light-trapping coatings are important parts of photovoltaic architectures, which enable the reduction of parasitic optical losses, and therefore increase the power conversion efficiency (PCE). Here, we propose a novel approach to enhance the efficiency of perovskite solar cells using a light-trapping electrode (LTE) with non-reciprocal optical transmission, consisting of a perforated metal film covered with a densely packed array of nanospheres. Our LTE combines charge collection and light trapping, and it can replace classical transparent conducting oxides (TCOs) such as ITO or FTO, providing better optical transmission and conductivity. One of the most promising applications of our original LTE is the optimization of efficient bifacial perovskite solar cells. We demonstrate that with our LTE, the short-circuit current density and fill factor are improved for both front and back illumination of the solar cells. Thus, we observe an 11% improvement in the light absorption for the monofacial PSCs, and a 15% for the bifacial PSCs. The best theoretical results of efficiency for our PSCs are 27.9% (monofacial) and 33.4% (bifacial). Our study opens new prospects for the further efficiency enhancement for perovskite solar cells. Full article

High-index dielectrics have recently been regarded as promising building blocks in nanophotonics owing to optical electric and magnetic Mie resonances. In particular, silicon is gaining great interest as the backbone of modern technology. Here, silicon dimer nanocavities with different sizes of silicon nanospheres were constructed using a probe nanomanipulation method and interacted with a few-layered R6G membrane to investigate the enhancement of electric and magnetic mode coupling. The evidence of the enhancement of fluorescence and slightly prolonged lifetime of R6G indicated the existence of nanocavities. In addition, the simulated electric and magnetic field distributions and decomposed mode of nanocavity were used to analyze the contribution of electric and magnetic modes to the R6G enhanced fluorescence. Such silicon dimer is a flexible nanocavity with electric and magnetic mode enhancement and has promising applications in sensing and all-dielectric metamaterials or nanophotonic devices. Full article

In the framework of the generalized Lorenz–Mie theory (GLMT), the optical force and torque on a graphene-coated gold nanosphere by a vector Bessel beam are investigated. The core of the particle is gold, whose dielectric function is given by the Drude–Sommerfeld model, and the coating is multilayer graphene with layer number N, whose dielectric function is described by the Lorentz–Drude model. The axial optical force $F_z$ and torque $T_z$ are numerically analyzed, and the effects of the layer number N, wavelength $\lambda$, and beam parameters (half-cone angle ${\alpha }_0$, polarization, and order l) are mainly discussed. Numerical results show that the optical force and torque peaks can be adjusted by increasing the thickness of the graphene coating, and can not be adjusted by changing ${\alpha }_0$ and l. However, ${\alpha }_0$ and l can change the magnitude of the optical force and torque. The numerical results have potential applications involving the trapped graphene-coated gold nanosphere. Full article

The bulk and surface refractive index sensitivities of LSPR biosensors, consisting of coupled plasmonic nanosphere and nano-ellipsoid dimers, were investigated by simulations using the boundary element method (BEM). The enhancement factor, defined as the ratio of plasmon extinction peak shift of multi-particle and single-particle arrangements caused by changes in the refractive index of the environment, was used to quantify the effect of coupling on the increased sensitivity of the dimers. The bulk refractive index sensitivity (RIS) was obtained by changing the dielectric medium surrounding the nanoparticles, while the surface sensitivity was modeled by depositing dielectric layers on the nanoparticle in an increasing thickness. The results show that by optimizing the interparticle gaps for a given layer thickness, up to ~80% of the optical response range of the nanoparticles can be utilized by confining the plasmon field between the particles, which translates into an enhancement of ~3–4 times compared to uncoupled, single particles with the same shape and size. The results also show that in these cases, the surface sensitivity enhancement is significantly higher than the bulk RI sensitivity enhancement (e.g., 3.2 times vs. 1.8 times for nanospheres with a 70 nm diameter), and thus the sensors’ response for molecular interactions is higher than their RIS would indicate. These results underline the importance of plasmonic coupling in the optimization of nanoparticle arrangements for biosensor applications. The interparticle gap should be tailored with respect to the size of the used receptor/target molecules to maximize the molecular sensitivity, and the presented methodology can effectively aid the optimization of fabrication technologies. Full article

We theoretically study the multiple sharp Fano resonances produced by the near-field coupling between the multipolar narrow plasmonic whispering-gallery modes (WGMs) and the broad-sphere plasmon modes supported by a deep-subwavelength spherical hyperbolic metamaterial (HMM) cavity, which is constructed by five alternating silver/dielectric layers wrapping a dielectric nanosphere core. We find that the linewidths of WGMs-induced Fano resonances are as narrow as 7.4–21.7 nm due to the highly localized feature of the electric fields. The near-field coupling strength determined by the resonant energy difference between WGMs and corresponding sphere plasmon modes can lead to the formation of the symmetric-, asymmetric-, and typical Fano lineshapes in the far-field extinction efficiency spectrum. The deep-subwavelength feature of the proposed HMM cavity is verified by the large ratio (~5.5) of the longest resonant wavelength of WGM_1,1 (1202.1 nm) to the cavity size (diameter: 220 nm). In addition, the resonant wavelengths of multiple Fano resonances can be easily tuned by adjusting the structural/material parameters (the dielectric core radius, the thickness and refractive index of the dielectric layers) of the HMM cavity. The narrow linewidth, multiple, and tunability of the observed Fano resonances, together with the deep-subwavelength feature of the proposed HMM cavity may create potential applications in nanosensors and nanolasers. Full article

The preparation of yolk–shell microwave absorption materials with low density and excellent microwave absorption property requires reasonable design and economical manufacture. In this study, an efficient strategy without any templates or reducing gases has been designed to fabricate multi-core yolk–shell Co@C nanospheres by high temperature carbonization. The results showed that Co₃O₄ was completely reduced by the carbon shell to metal cobalt at temperatures above 750 °C. This unique multi-core yolk–shell structure with shell of 600 nm and multiple cores of tens of nanometers can provide sufficient interface and space to reflect and scatter electromagnetic waves. At the same time, the metal cobalt layer and carbon layer provide magnetic loss ability and dielectric loss ability, respectively, making the composite show good wave absorption performance. The minimal RL value of samples carbonized at 750 °C reaches −40 dB and the efficient absorption band reaches 9 GHz with the thickness ranges from 2–9 mm. Therefore, this is a facile, effective and economical strategy to prepare yolk–shell structure, which provides a new idea for the preparation of microwave absorption materials. Full article

We study theoretically the Fano resonances (FRs) produced by the near-field coupling between the lowest-order (dipolar) sphere plasmon resonance and the dipolar cavity plasmon mode supported by an Ag nanoshell or the hybrid mode in a simple three-layered Ag nanomatryushka constructed by incorporating a solid Ag nanosphere into the center of Ag nanoshell. We find that the linewidth of dipolar cavity plasmon resonance or hybrid mode induced FR is as narrow as 6.8 nm (corresponding to a high Q-factor of ~160 and a long dephasing time of ~200 fs) due to the highly localized feature of the electric-fields. In addition, we attribute the formation mechanisms of typical asymmetrical Fano line profiles in the extinction spectra to the constructive (Fano peak) and the destructive interferences (Fano dip) arising from the symmetric and asymmetric charge distributions between the dipolar sphere and cavity plasmon or hybrid modes. Interestingly, by simply adjusting the structural parameters, the dielectric refractive index required for the strongest FR in the Ag nanomatryushka can be reduced to be as small as 1.4, which largely reduces the restriction on materials, and the positions of FR can also be easily tuned across a broad spectral range. The ultranarrow linewidth, highly tunability together with the huge enhancement of electric fields at the FR may find important applications in sensing, slow light, and plasmon rulers. Full article

Resonant optical modes arising in all-dielectric metasurfaces have attracted much attention in recent years, especially when so-called bound states in the continuum (BICs) with diverging lifetimes are supported. With the aim of studying theoretically the emergence of BICs, we extend a coupled electric and magnetic dipole analytical formulation to deal with the proper metasurface Green function for the infinite lattice. Thereby, we show how to excite metasurface BICs, being able to address their near-field pattern through point-source excitation and their local density of states. We apply this formulation to fully characterize symmetry-protected BICs arising in all-dielectric metasurfaces made of Si nanospheres, revealing their near-field pattern and local density of states, and, thus, the mechanisms precluding their radiation into the continuum. This formulation provides, in turn, an insightful and fast tool to characterize BICs (and any other leaky/guided mode) near fields in all-dielectric (and also plasmonic) metasurfaces, which might be especially useful for the design of planar nanophotonic devices based on such resonant modes. Full article