Sign in to use this feature.

Years

Between: -

Subjects

remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline

Journals

Article Types

Countries / Regions

Search Results (56)

Search Parameters:
Keywords = diagenetic settings

Order results
Result details
Results per page
Select all
Export citation of selected articles as:
22 pages, 11338 KiB  
Article
Genesis of Clastic Reservoirs in the First Member of Yaojia Formation, Northern Songliao Basin
by Junhui Li, Qiang Zheng, Yu Cai, Huaye Liu, Tianxin Hu and Haiguang Wu
Minerals 2025, 15(8), 795; https://doi.org/10.3390/min15080795 - 29 Jul 2025
Viewed by 205
Abstract
This study focuses on the clastic reservoir in the first member of Yaojia Formation within Qijia-Gulong Sag, Songliao Basin. The results indicate that the reservoir in the study area develops within a shallow-water delta sedimentary system. The dominant sedimentary microfacies comprise underwater distributary [...] Read more.
This study focuses on the clastic reservoir in the first member of Yaojia Formation within Qijia-Gulong Sag, Songliao Basin. The results indicate that the reservoir in the study area develops within a shallow-water delta sedimentary system. The dominant sedimentary microfacies comprise underwater distributary channels, mouth bars, and sheet sands. Among these, the underwater distributary channel microfacies exhibits primary porosity ranging from 15.97% to 17.71%, showing the optimal reservoir quality, whereas the sheet sand microfacies has a porosity of only 7.45% to 12.08%, indicating inferior physical properties. During diagenesis, compaction notably decreases primary porosity via particle rearrangement and elastic deformation, while calcite cementation and quartz overgrowth further occlude pore throats. Although dissolution can generate secondary porosity (locally up to 40%), the precipitation of clay minerals tends to block pore throats, leading to “ineffective porosity” (permeability generally < 5 mD) and overall low-porosity and low-permeability characteristics. Carbon–oxygen isotope analysis reveals a deficiency in organic acid supply in the study area, restricting the intensity of dissolution alteration. Reservoir quality evolution is dominantly governed by the combined controls of sedimentary microfacies and diagenesis. This study emphasizes that, within shallow-water delta sedimentary settings, the material composition of sedimentary microfacies and the dynamic equilibrium of diagenetic processes jointly govern reservoir property variations. This insight provides critical theoretical support for understanding diagenetic evolution mechanisms in clastic reservoirs and enabling precise prediction of high-quality reservoir distribution. Full article
(This article belongs to the Section Mineral Exploration Methods and Applications)
Show Figures

Figure 1

33 pages, 48291 KiB  
Article
The Influence of Seasonal Variations in a Continental Lacustrine Basin in an Arid Climate on the Occurrence Characteristics of Gypsum: A Case Study from the Paleogene Bottom Sandstone Member, Tabei Uplift
by Xiaoyang Gao, Wenxiang He, Luxing Dou, Jingwen Yan, Qi Sun, Zhenli Yi and Bin Li
Minerals 2025, 15(6), 639; https://doi.org/10.3390/min15060639 - 12 Jun 2025
Viewed by 356
Abstract
The occurrence of gypsum in clastic rocks of continental saline lake basins reflects complex depositional and diagenetic processes. However, its genesis remains relatively understudied. Based on core descriptions and thin-section analyses, this study investigates the occurrence types and genetic mechanisms of gypsum in [...] Read more.
The occurrence of gypsum in clastic rocks of continental saline lake basins reflects complex depositional and diagenetic processes. However, its genesis remains relatively understudied. Based on core descriptions and thin-section analyses, this study investigates the occurrence types and genetic mechanisms of gypsum in the Bottom Sandstone Member of the northern Tabei Uplift. Five types of gypsum occurrences are identified: layered gypsum, gypsum clasts, spotted gypsum, gypsum nodules, and a mixed deposition of clastic rocks and gypsum. The mixed deposition of clastic rocks and gypsum includes gypsiferous mudstone, muddy gypsum, gypsiferous mudstone containing muddy clasts, and sandy gypsum. Layered gypsum, spotted gypsum, gypsiferous mudstone, and muddy gypsum mainly result from in situ chemical precipitation during periods of high evaporation and reduced runoff. In contrast, gypsum clasts, gypsiferous mudstone containing muddy clasts, and sandy gypsum reflect processes of transportation and reworking induced by flood events. Seasonal variations in hydrodynamic conditions play a critical role in the formation and distribution of gypsum. During dry periods, surface runoff weakens or ceases, and the salinity of lake water or pore water in clastic deposits increases due to intense evaporation, promoting gypsum precipitation. During flood periods, increased runoff can erode previously formed gypsum, which is subsequently transported and deposited as gypsum clasts. The morphology of gypsum varies with its transport distance. These findings enhance our understanding of clastic–evaporite mixed systems in arid continental lacustrine settings and provide insights into sedimentary processes influenced by seasonal climatic fluctuations. Full article
(This article belongs to the Special Issue Deep-Time Source-to-Sink in Continental Basins)
Show Figures

Figure 1

22 pages, 12129 KiB  
Article
Metallogenic Age and Tectonic Setting of the Haigou Gold Deposit in Southeast Jilin Province, NE China: Constraints from Magmatic Chronology and Geochemistry
by Zhongjie Yang, Yuandong Zhao, Cangjiang Zhang, Chuantao Ren, Qun Yang and Long Zhang
Minerals 2025, 15(6), 582; https://doi.org/10.3390/min15060582 - 29 May 2025
Viewed by 379
Abstract
Haigou deposit, located in Dunhua City, southeast Jilin Province, NE China, is a large-scale gold deposit. The gold ore body is categorized into two types: quartz-vein type and altered rock type, with the quartz-vein type being predominant. The vein gold ore body primarily [...] Read more.
Haigou deposit, located in Dunhua City, southeast Jilin Province, NE China, is a large-scale gold deposit. The gold ore body is categorized into two types: quartz-vein type and altered rock type, with the quartz-vein type being predominant. The vein gold ore body primarily occurs within the monzonite granite and monzonite rock mass in the Haigou area and is controlled by fault structures trending northeast, northwest, and near north-south. In order to constrain the age and tectonic setting of quartz vein-type gold mineralization, we conducted a detailed underground investigation and collected samples of monzonite granite and pyroxene diorite porphyrite veins related to quartz-vein-type gold mineralization for LA-ICP-MS zircon U-Pb dating and whole-rock main trace element data testing to confirm that monzonite granite is closely related to gold mineralization. Pyroxene diorite porphyry and gold mineralization were found in parallel veins. The zircon U-Pb weighted mean ages of monzonite and pyroxene diorite porphyrite veins are 317.1 ± 3.5 Ma and 308.8 ± 3.0 Ma, respectively, indicating that gold mineralization in monzonite, pyroxene diorite porphyrite veins, and quartz veins occurred in the Late Carboniferous. The monzonite granite and pyroxene diorite porphyrite veins associated with quartz vein-type gold mineralization have high SiO2, high K, and high Al2O3 and are all metaluminous high-potassium calc-alkaline rock series. Both of them are relatively enriched in light rare earth elements (LREE) and macroionic lithophile elements (LILE: Rb, Ba, K, etc.), but deficient in heavy rare earth elements (HREE) and high field strength elements (HFSE: Nb, Ta, P, Ti, etc.), the monzonitic granite Eu is a weak positive anomaly (δEu = 1.15–1.46), the pyroxene diorite porphyre dyke Eu is a weak positive anomaly (δEu = 1.09–1.13), and the Nb and Ta are negative anomalies. The Th/Nb values are 0.28–0.73 and 1.48–2.05, and La/Nb are 2.61–4.74 and 4.59–5.43, respectively, suggesting that diagenetic mineralization is the product of subduction in an active continental margin environment. In recent years, scholarly research on Sr, Nd, and Pb isotopes in Haigou rock masses has indicated that the magmatic source region in the Haigou mining areas is complex. It is neither a singular crustal source nor a mantle source but rather a mixed crust-mantle source, primarily resulting from the partial melting of lower crustal materials, with additional contributions from mantle-derived materials. In summary, the metallogenic characteristics, chronology data, geochemical characteristics, and regional tectonic interpretation indicate that at least one phase of magmatic-hydrothermal gold mineralization was established in the Late Carboniferous as a result of the subduction of the Paleo-Asian ocean plate at the northern margin of the North China Craton. Full article
Show Figures

Figure 1

39 pages, 30751 KiB  
Article
Pore Structure Differences and Influencing Factors of Tight Reservoirs Under Gravity Flow–Delta Sedimentary System in Linnan Subsag, Bohai Bay Basin
by Lanxi Rong, Dongxia Chen, Yuchao Wang, Jialing Chen, Fuwei Wang, Qiaochu Wang, Wenzhi Lei and Mengya Jiang
Appl. Sci. 2025, 15(11), 5800; https://doi.org/10.3390/app15115800 - 22 May 2025
Cited by 1 | Viewed by 390
Abstract
In tight reservoirs deposited in diverse sedimentary settings, the pore structure governs tight oil enrichment features and sweet-spot distribution. Taking the tight sandstone reservoirs of the lower third member of the Shahejie Formation in the Linnan Subsag of Bohai Bay Basin in China [...] Read more.
In tight reservoirs deposited in diverse sedimentary settings, the pore structure governs tight oil enrichment features and sweet-spot distribution. Taking the tight sandstone reservoirs of the lower third member of the Shahejie Formation in the Linnan Subsag of Bohai Bay Basin in China as an example, this study employs XRD to delineate petrological characteristics, while porosity and permeability measurements are used to quantify physical properties. In addition, thin section, SEM, HPMI, NMR, fractal theory, and cathodoluminescence experiments are applied to investigate pore structure characteristics and influencing factors. The results reveal two sedimentary systems: turbidity current and delta front deposits. Turbidite reservoirs exhibit the coarse pore-coarse throats (Type A), medium pore-medium throats (Type B), and fine pore-medium throats (Type C) pore structures. Delta front reservoirs are characterized by medium-pore-coarse-throat (Type D), medium-pore-fine-throat (Type E), and fine-pore-fine-throat (Type F) pore structures. Turbidite reservoirs show more favorable pore structures for oil exploration compared to delta fronts, in which lithofacies and diagenetic facies are the key influences. A genetic model identifies the highest-quality Type A forms in fine sandstone lithofacies under medium compaction–medium cementation–strong dissolution, with pore diameters averaging 10.84 μm in turbidite reservoirs. Conversely, the poorest Type F forms in argillaceous layered siltstone lithofacies under strong compaction, cementation, and weak dissolution diagenetic facies in delta fronts, with pore diameters averaging 0.88 μm. Consequently, the control effect of the pore quality means that Type A has the highest and Type F has the lowest oil-bearing capacity. These findings provide valuable guidance for the classification, evaluation, and exploration of tight oil sweet spots. Full article
Show Figures

Figure 1

18 pages, 4412 KiB  
Article
Pore Structure and Its Controlling Factors of Cambrian Highly Over-Mature Marine Shales in the Upper Yangtze Block, SW China
by Dadong Liu, Mingyang Xu, Hui Chen, Yi Chen, Xia Feng, Zhenxue Jiang, Qingqing Fan, Li Liu and Wei Du
J. Mar. Sci. Eng. 2025, 13(5), 1002; https://doi.org/10.3390/jmse13051002 - 21 May 2025
Viewed by 430
Abstract
Highly over-mature marine shales are distributed worldwide with substantial resource potential, yet their pore structure characteristics and controlling mechanisms remain poorly understood, hindering accurate shale gas resource prediction and efficient development. This study focuses on the Cambrian Niutitang Formation shales in the Upper [...] Read more.
Highly over-mature marine shales are distributed worldwide with substantial resource potential, yet their pore structure characteristics and controlling mechanisms remain poorly understood, hindering accurate shale gas resource prediction and efficient development. This study focuses on the Cambrian Niutitang Formation shales in the Upper Yangtze region of South China. To decipher the multiscale pore network architecture and its genetic constraints, we employ scanning electron microscopy (SEM) pore extraction and fluid intrusion methods (CO2 and N2 adsorption, and high-pressure mercury intrusion porosimetry) to systematically characterize pore structures in these reservoirs. The results demonstrate that the shales exhibit high TOC contents (average 4.78%) and high thermal maturity (average Ro 3.64%). Three dominant pore types were identified: organic pores, intragranular pores, and intergranular pores. Organic pores are sparsely developed with diameters predominantly below 50 nm, displaying honeycomb, slit-like, or linear morphologies. Intragranular pores are primarily feldspar dissolution voids, while intergranular pores exhibit triangular or polygonal shapes with larger particle sizes. CO2 adsorption isotherms (Type I) and low-temperature N2 adsorption curves (H3-H4 hysteresis) indicate wedge-shaped and slit-like pores, with pore size distributions concentrated in the 0.5–50 nm range, showing strong heterogeneity. Pore structure shows weak correlations with TOC and quartz content but a strong correlation with feldspar abundance. This pattern arises from hydrocarbon generation exhaustion and graphitization-enhanced organic pore collapse under high compaction stress, which reduces pore preservation capacity. The aulacogen tectonic setting engenders proximal sediment provenance regimes that preferentially preserve labile minerals such as feldspars. This geological configuration establishes optimal diagenetic conditions for the subsequent development of meso- and macro-scale of dissolution pores. Our findings demonstrate that feldspar-rich shales, formed in a proximal depositional system with well-developed inorganic pores, serve as favorable reservoirs for the exploration of highly over-mature marine shale gas. Full article
Show Figures

Figure 1

20 pages, 3455 KiB  
Article
Pore Structure Characterization of Jurassic Sandstones in the Northeastern Ordos Basin: An Integrated Experimental and Inversion Approach
by Haiyang Yin, Tongjun Chen, Yueyue Li, Haicheng Xu and Wan Li
Minerals 2025, 15(5), 547; https://doi.org/10.3390/min15050547 - 20 May 2025
Viewed by 339
Abstract
Although Mercury Intrusion Porosimetry (MIP) and Nuclear Magnetic Resonance (NMR) are widely used for pore characterization, their effectiveness is fundamentally constrained by theoretical limitations. This study investigated the pore structure characteristics of coal-bearing sandstones from the northeastern Ordos Basin using an integrated approach [...] Read more.
Although Mercury Intrusion Porosimetry (MIP) and Nuclear Magnetic Resonance (NMR) are widely used for pore characterization, their effectiveness is fundamentally constrained by theoretical limitations. This study investigated the pore structure characteristics of coal-bearing sandstones from the northeastern Ordos Basin using an integrated approach combining experimental measurements and model-based inversion. The experimental measurements comprised a stress-dependent acoustic velocity test (P- and S-wave velocities), X-ray diffraction (XRD) mineralogical analysis, and NMR relaxation T2 spectra characterization. For model-based inversion, we developed an improved Mori-Tanaka (M-T) theoretical framework incorporating stress-sensitive pore geometry parameters and dual-porosity (stiff/soft) microstructure representation. Systematic analysis revealed four key findings: (1) excellent agreement between model-inverted and NMR-derived total porosity, with a maximum absolute error of 1.09%; (2) strong correlation between soft porosity and the third peak of T2 relaxation spectra; (3) stiff porosity governed by brittle mineral content (quartz and calcite), while soft porosity showing significant correlation with clay mineral abundance and Poisson’s ratio; and (4) markedly lower elastic moduli (28.78%–51.85%) in Zhiluo Formation sandstone compared to Yan’an Formation equivalents, resulting from differential diagenetic alteration despite comparable depositional settings. The proposed methodology advances conventional NMR analysis by simultaneously quantifying both pore geometry parameters (e.g., aspect ratios) and the stiff-to-soft pore distribution spectra. This established framework provides a robust characterization of the pore architecture in Jurassic sandstones, yielding deeper insights into sandstone pore evolution within the Ordos Basin. These findings provide actionable insights for water hazard mitigation and geological CO2 storage practices. Full article
(This article belongs to the Section Mineral Exploration Methods and Applications)
Show Figures

Figure 1

21 pages, 8878 KiB  
Article
Significance of Adakitic Plutons for Mineralization in Wubaduolai Copper Deposit, Xizang: Evidence from Zircon U-Pb Age, Hf Isotope, and Geochemistry
by Ke Gao, Zhi Zhang, Linkui Zhang, Peiyan Xu, Yi Yang, Jianyang Wu, Yingxu Li, Miao Sun and Wenpeng Su
Minerals 2025, 15(5), 500; https://doi.org/10.3390/min15050500 - 8 May 2025
Viewed by 463
Abstract
The Wubaduolai copper deposit, a newly discovered porphyry-type deposit located in the western section of the Gangdese metallogenic belt, shows great potential for mineralization. Investigating the ore-bearing potentiality of the adakitic granite in this area is crucial for identifying concealed ore bodies and [...] Read more.
The Wubaduolai copper deposit, a newly discovered porphyry-type deposit located in the western section of the Gangdese metallogenic belt, shows great potential for mineralization. Investigating the ore-bearing potentiality of the adakitic granite in this area is crucial for identifying concealed ore bodies and assessing the metallogenic potential. This paper presents the zircon U-Pb dating, Hf isotope analysis, and whole-rock major and trace geochemical analysis of the plutons in the Wubaduolai mining area. The results indicate that the zircon U-Pb concordia age of the monzogranite is 15.7 ± 0.1 Ma, while the granodiorite porphyry has a concordia age of 15.9 ± 0.2 Ma, both corresponding to a Miocene diagenesis. The geochemical data show that both plutons belong to the high-K calc-alkaline series, characterized by a relative enrichment of large-ion lithophile elements (K, Rb, Ba, and Sr) and a depletion of high-field-strength elements (Nb, Ta, and Ti). Both plutons are characterized by low Y, low Yb, and high Sr/Y values, displaying the typical geochemical characteristics of adakites. Their mineral composition is similar to that of adakite. The εHf(t) values of the monzogranite and granodiorite porphyry range from −5.34 to −2.3 and −5.2 to −3.43, respectively, with two-stage model ages (TDM2) of 1246–1441 Ma and 1318–1432 Ma. Based on the regional data and this study, the plutons in the Wubaduolai mining area formed in a post-collision setting following the India–Asia continental collision. The magma source is identified as the partial melting of a thickened, newly formed lower crust. The above characteristics are consistent with the diagenetic and metallogenic ages, magma source, and dynamic backgrounds of the typical regional deposits. Full article
Show Figures

Figure 1

16 pages, 30990 KiB  
Article
Reservoir Characterization of Tight Sandstone Gas Reservoirs: A Case Study from the He 8 Member of the Shihezi Formation, Tianhuan Depression, Ordos Basin
by Zihao Dong, Xinzhi Yan, Jingong Zhang, Zhiqiang Chen and Hongxing Ma
Processes 2025, 13(5), 1355; https://doi.org/10.3390/pr13051355 - 29 Apr 2025
Viewed by 441
Abstract
Tight sandstone gas reservoirs, characterized by low porosity (typically < 10%) and ultra-low permeability (commonly < 0.1 × 10⁻3 μm2), represent a critical transitional resource in global energy transition, accounting for over 60% of total natural gas production in regions [...] Read more.
Tight sandstone gas reservoirs, characterized by low porosity (typically < 10%) and ultra-low permeability (commonly < 0.1 × 10⁻3 μm2), represent a critical transitional resource in global energy transition, accounting for over 60% of total natural gas production in regions such as North America and Canada. In the northern Tianhuan Depression of the Ordos Basin, the Permian He 8 Member (He is the abbreviation of Shihezi) of the Shihezi Formation serves as one of the primary gas-bearing intervals within such reservoirs. Dominated by quartz sandstones (82%) with subordinate lithic quartz sandstones (15%), these reservoirs exhibit pore systems primarily supported by high-purity quartz and rigid lithic fragments. Diagenetic processes reveal sequential cementation: early-stage quartz cementation provides a framework for subsequent lithic fragment cementation, collectively resisting compaction. Depositionally, these sandstones are associated with fluvial-channel environments, evidenced by a sand-to-mud ratio of ~5.2:1. Pore structures are dominated by intergranular pores (65%), followed by dissolution pores (25%) formed via selective leaching of unstable minerals by acidic fluids in hydrothermal settings, and minor intragranular pores (10%). Authigenic clay minerals, predominantly kaolinite (>70% of total clays), act as the main interstitial material. Reservoir properties average 7.01% porosity and 0.5 × 10⁻3 μm2 permeability, defining a typical low-porosity, ultra-low-permeability system. Vertically stacked sand bodies in the He 8 Member display large single-layer thicknesses (5–12 m) and moderate sealing capacity (caprock breakthrough pressure > 8 MPa), hosting gas–water mixed-phase occurrences. Rock mechanics experiments demonstrate that fractures enhance permeability by >60%, significantly controlling reservoir heterogeneity. Full article
Show Figures

Figure 1

31 pages, 16566 KiB  
Article
The Role of Fluid Chemistry in the Diagenetic Transformation of Detrital Clay Minerals: Experimental Insights from Modern Estuarine Sediments
by Anas Muhammad Salisu, Abdulwahab Muhammad Bello, Abduljamiu O. Amao and Khalid Al-Ramadan
Minerals 2025, 15(3), 317; https://doi.org/10.3390/min15030317 - 19 Mar 2025
Viewed by 697
Abstract
The diagenetic transformation of detrital clay minerals significantly influences sandstone reservoir quality, with fluid chemistry and temperature playing key roles in dictating transformation pathways during burial diagenesis. While these processes are well-documented in basinal settings, the diagenetic alterations of sediments in dynamic environments [...] Read more.
The diagenetic transformation of detrital clay minerals significantly influences sandstone reservoir quality, with fluid chemistry and temperature playing key roles in dictating transformation pathways during burial diagenesis. While these processes are well-documented in basinal settings, the diagenetic alterations of sediments in dynamic environments like estuaries remain underexplored. This study investigates the impact of fluid composition on the transformation of modern estuarine sediments through hydrothermal experiments using sediments from the Gironde estuary, SW France. A range of natural and synthetic solutions including seawater (SW), 0.1 M KCl (SF1), 0.1 M NaCl, KCl, CaCl2·2H2O, MgCl2·6H2O (SF2), estuarine water (EW), and 0.1 M Na2CO3 (SF3) were used under temperatures from 50 °C to 250 °C for 14 days, with a fixed fluid-to-sediment ratio of 10:1. The results revealed distinct mineralogical transformations driven by fluid composition. Dissolution of detrital feldspars and clay materials began at lower temperatures (<100 °C). The authigenic formation of smectite and its subsequent illitization in K-rich fluids (SW, SF1) occurred between 150 °C and 250 °C, replicating potassium-driven illitization processes observed in natural sandstones. Additionally, chlorite formation occurred through the conversion of smectite in SF2 and EW. Geochemical analysis showed that SF2 produced Mg-rich chlorites, while EW yielded Fe-rich chlorites. This aligns with diagenetic trends in coastal environments, where Fe-rich chlorites are typically associated with estuarine systems. The resulting authigenic illite and chlorite exhibited morphological and chemical characteristics similar to those found in natural sandstones, forming through dissolution-crystallization and solid-state transformation mechanisms. In contrast to illite and chlorite, SF3 produced entirely different mineral phases, including halite and analcime (zeolite), attributed to the high alkalinity and Na-rich composition of the solution. These findings provide valuable insights into the role of fluid chemistry in the diagenetic alteration of modern sediments and their implications for the evolution of sandstone reservoirs, which is critical for energy exploration and transition. Full article
(This article belongs to the Section Clays and Engineered Mineral Materials)
Show Figures

Graphical abstract

30 pages, 7429 KiB  
Article
Isotope Geochemistry and Metallogenic Model of the Bailugou Vein-Type Zn-Pb-Ag Deposit, Eastern Qinling Orogen, China
by Yan Yang, Hui Chen, Nana Guo, Donghao Wu, Zhenshan Pang and Yanjing Chen
Minerals 2024, 14(12), 1244; https://doi.org/10.3390/min14121244 - 6 Dec 2024
Cited by 1 | Viewed by 902
Abstract
The large-scale vein-type Zn-Pb-Ag deposit in the Eastern Qinling Orogen (EQO) has sparked a long-standing debate over whether magmatism or metamorphism was the primary control or factor in its formation. Among the region’s vein-type deposits, the large-sized Bailugou deposit offers a unique opportunity [...] Read more.
The large-scale vein-type Zn-Pb-Ag deposit in the Eastern Qinling Orogen (EQO) has sparked a long-standing debate over whether magmatism or metamorphism was the primary control or factor in its formation. Among the region’s vein-type deposits, the large-sized Bailugou deposit offers a unique opportunity to study this style of mineralization. Similar to other deposits in the area, the vein-type orebodies of the Bailugou deposit are hosted in dolomitic marbles (carbonate–shale–chert association, CSC) of the Mesoproterozoic Guandaokou Group. Faults control the distribution of the Bailugou deposit but do not show apparent spatial links to the regional Yanshanian granitic porphyry. This study conducted comprehensive H–O–C–S–Pb isotopic analyses to constrain the sources of the ore-forming metals and metal endowments of the Bailugou deposit. The δ34SCDT values of sulfides range from 1.1‰ to 9.1‰ with an average of 4.0‰, indicating that the sulfur generated from homogenization during the high-temperature source acted on host sediments. The Pb isotopic compositions obtained from 31 sulfide samples reveal that the lead originated from the host sediments rather than from the Mesozoic granitic intrusions. The results indicate that the metals for the Bailugou deposit were jointly sourced from host sediments of the Mid-Late Proterozoic Meiyaogou Fm. and the Nannihu Fm. of the Luanchuan Group and Guandaokou Group, as well as lower crust and mantle materials. The isotopic composition of carbon, hydrogen, and oxygen collectively indicate that the metallogenic constituents of the Bailugou deposit were contributed by ore-bearing surrounding rocks, lower crust, and mantle materials. In summary, the study presents a composite geologic-metallogenic model suggesting that the Bailugou mineral system, along with other lead-zinc-silver deposits, porphyry-skarn molybdenum-tungsten deposits, and the small granitic intrusions in the Luanchuan area, are all products of contemporaneous hydrothermal diagenetic mineralization. This mineralization event transpired during a continental collision regime between the Yangtze and the North China Block (including syn- to post-collisional settings), particularly during the transition from collisional compression to extension around 140 Ma. The Bailugou lead-zinc-silver mineralization resembles an orogenic-type deposit formed by metamorphic fluid during the Yanshanian Orogeny. Full article
Show Figures

Figure 1

19 pages, 10871 KiB  
Article
The Development of Dolomite Within a Sequence Stratigraphic Framework: Cambrian Series 2 Changping Formation, Xiaweidian, China
by Shan Zhong, Zhaoqian Liu, Zhenkui Jin, Hongyu Tian, Madaki Agwom Istifanus and Simon C. George
Minerals 2024, 14(12), 1189; https://doi.org/10.3390/min14121189 - 22 Nov 2024
Cited by 1 | Viewed by 1154
Abstract
The Lower Cambrian Changping Formation in the Western Hills of Beijing hosts tidal flat and lagoonal carbonates comprising dolomites, limestones, and dolomitic limestones, reflecting the processes of dolomite cementation and dolomitization within a sedimentary framework. Based on petrographic textures, two types of dolomites [...] Read more.
The Lower Cambrian Changping Formation in the Western Hills of Beijing hosts tidal flat and lagoonal carbonates comprising dolomites, limestones, and dolomitic limestones, reflecting the processes of dolomite cementation and dolomitization within a sedimentary framework. Based on petrographic textures, two types of dolomites were identified: microcrystalline dolomite and fine-mesocrystalline dolomite. Integrating petrological and geochemical data unveils two diagenetic stages. The initial dolomite formation, attributed to hypersaline fluids, occurred in a supratidal-sabkha setting during the early Cambrian. The dolomitization at the top of the Changping Formation, driven by evaporatively concentrated brines from the overlying Mantou Formation, altered peritidal carbonates. This study evaluates the original sedimentary environment and dolomitization within a sequence stratigraphic context, revealing a correlation between dolomitization episodes and the stratigraphic framework in the study area. Factors influencing this framework profoundly impact depositional environments and material composition, leading to micromorphological differences in dolomites. Sabkha dolomite formation, associated with evaporative pumping, predominates near the base of transgressive systems tracts. Seepage reflux dolomite, often linked with evaporative pumping dolomite, constitutes a vertical cycle in the sequence framework. The sequence from bottom to top is sabkha microcrystalline dolomite, limestone and dolomitic limestone, seepage reflux saccharoidal dolostone, and sabkha dolomite. Full article
Show Figures

Graphical abstract

21 pages, 15199 KiB  
Article
Tracking Depositional Architecture and Diagenetic Evolution in the Jurassic Carbonates, Trans Indus Ranges, NW Himalayas
by Muhammad Jamil, Ihsan Ullah, Hamad Ur Rahim, Imran Khan, Wahid Abbas, Mohib Ur Rehman, Alidu Rashid, Muhammad Umar, Asad Ali and Numair Ahmed Siddiqui
Minerals 2024, 14(11), 1170; https://doi.org/10.3390/min14111170 - 18 Nov 2024
Cited by 5 | Viewed by 1426
Abstract
The evolution of Jurassic carbonates is globally significant for understanding the depositional framework, diagenetic phases and sedimentary characteristics of shallow marine shelf deposits. For this purpose, two outcrop sections of the Jurassic carbonates with a road distance of 121 km in the Trans [...] Read more.
The evolution of Jurassic carbonates is globally significant for understanding the depositional framework, diagenetic phases and sedimentary characteristics of shallow marine shelf deposits. For this purpose, two outcrop sections of the Jurassic carbonates with a road distance of 121 km in the Trans Indus Ranges, NW Himalayas, were included in this study. Geological fieldwork was conducted for sedimentological data, and representative samples were collected for microfacies analysis and diagenetic evolution complemented by carbon and oxygen isotope analysis. Results show that eight microfacies were identified in both sections where mudstone microfacies was only present in the Chichali section, whereas wackestone and packstone facies widely existed in both sections. The diagenetic evolution interpreted that dolomitization and stylolization were pronounced in the Paniala section, while micritization and calcite cementation were prevalent in the Chichali section. The interpreted depositional setting implies the wide range from supratidal to outer ramp shallow marine for the Chichali section, suggesting a wide range and relatively deeper environment, alongside merely intertidal to middle ramp settings for Paniala section. Diagenetic evolution suggests marine to meteoric influence in the Chichali section, while burial and uplift phases were dominant in the Paniala section. The diagenetic events were also validated by the isotopic analysis, where most of the samples with values up to −4‰ VPDB δ18O, corresponding to a carbon isotope range of up to +4‰, were interpreted as the burial phase of diagenesis; meanwhile, a few samples with −2 δ13C and −7‰ VPDB δ18O isotope signatures were marked as meteoric influx in the Paniala section. This study indicates the diversity of the depositional environment and diagenetic heterogeneity by integration of thin sections using isotope data, which are quite applicable to shallow marine carbonates. Full article
Show Figures

Figure 1

18 pages, 3641 KiB  
Article
Distribution, Origin, and Impact on Diagenesis of Organic Acids in Representative Continental Shale Oil
by Wenjun Pang, Jing Li, Shixin Zhou, Yaoyu Li, Liangliang Liu, Hao Wang and Gengrong Chen
Processes 2024, 12(10), 2092; https://doi.org/10.3390/pr12102092 - 26 Sep 2024
Cited by 1 | Viewed by 1085
Abstract
This investigation focuses on the prevalent continental oil shale within the Triassic Chang 7, a member of the Yanchang Formation in the Ordos Basin and the Permian Lucaogou Formation in the Junggar Basin of western China, and delves into the impacts of hydrocarbon [...] Read more.
This investigation focuses on the prevalent continental oil shale within the Triassic Chang 7, a member of the Yanchang Formation in the Ordos Basin and the Permian Lucaogou Formation in the Junggar Basin of western China, and delves into the impacts of hydrocarbon generation and the derived organic acids on the physical attributes of oil shale reservoirs. Water-soluble organic acids (WSOAs) were extracted via Soxhlet extraction and analyzed by a 940 ion chromatograph (Metrohm AG), supplemented with core observations, thin-section analyses, pyrolysis, and trace element assays, as well as the qualitative observation of pore structures via FIB-SEM scanning electron microscopy. The study discloses substantial disparities in the types and abundances of organic acids within the oil shale strata of the two regions, with mono-acids being conspicuously more prevalent than dicarboxylic acids. The spatial distribution of organic acids within the oil shale strata in the two regions is non-uniform, and their generation is inextricably correlated with the type of organic matter, thermal maturity, and depth at which they are buried. During diverse stages of diagenesis, the hydrocarbons and organic acids produced from the pyrolysis of organic matter not only exert an impact on the properties of pore fluids but also interact with diagenetic processes such as compaction, dissolution, and metasomatism to enhance the reservoir quality of oil shale. The synergy between chemical interactions and physical alterations collectively governs the migration and distribution patterns of organic acids as well as the characteristics of oil shale reservoirs. Furthermore, the sources of organic acids within the oil shale series in the two regions demonstrate pronounced dissimilarities, which are intimately associated with the peculiarities of their sedimentary milieu. The oil shale of the Yanchang Formation was formed in a warm and humid freshwater lacustrine basin environment, while the oil shale of the Lucaogou Formation was deposited in a brackish to saline lacustrine setting under an arid to semi-arid climatic regime. These variances not only illuminate the intricacy and multiplicity of the sedimentary attributes of oil shale but also accentuate the impact of the sedimentary environment on the genesis and distribution of organic acids, especially the transformation and optimization of reservoir dissolution by organic acids generated during hydrocarbon generation—a factor of paramount significance for the precise identification and effective development of the “sweet spot” area of shale oil. These areas, characterized by an abundance of organic matter, their maturity, and superior reservoir properties, are the foci of the efficient exploration and development of continental shale oil. Full article
(This article belongs to the Section Chemical Processes and Systems)
Show Figures

Figure 1

17 pages, 23803 KiB  
Article
Experimental Study on Acoustic Emission Features and Energy Dissipation Properties during Rock Shear-Slip Process
by Zhengnan Zhang, Xiangxin Liu, Kui Zhao, Zhengzhao Liang, Bin Gong and Xun You
Materials 2024, 17(19), 4684; https://doi.org/10.3390/ma17194684 - 24 Sep 2024
Viewed by 1074
Abstract
The features of rock shear-slip fracturing are closely related to the stability of rock mass engineering. Granite, white sandstone, red sandstone, and yellow sandstone specimens were selected in this study. The loading phase of “shear failure > slow slip > fast slip” was [...] Read more.
The features of rock shear-slip fracturing are closely related to the stability of rock mass engineering. Granite, white sandstone, red sandstone, and yellow sandstone specimens were selected in this study. The loading phase of “shear failure > slow slip > fast slip” was set up to explore the correlation between fracture type, acoustic emission (AE) features, and energy dissipation during the rock fracturing process. The results show that there is a strong correlation between fracture type, energy dissipation, and AE features. The energy dissipation ratio of tension-shear (T-S) composite, shear, and tensile types is 10:100:1. The fracture types in the shear failure phase are mainly tensile and TS composite types. The differential mechanism of energy dissipation of different rocks during the shear-slip process is revealed from the physical property perspectives of mineral composition, particle size, and diagenetic mode. These results provide a necessary research basis for energy dissipation research in rock failure and offer an important scientific foundation for analyzing the fracture propagation problem in the shear-slip process. They also provide a research basis for further understanding the acoustic emission characteristics and crack type evolution during rock shear and slip processes, which helps to better understand the shear failure mechanism of natural joints and provides a reference for the identification of precursors of shear disasters in geotechnical engineering. Full article
Show Figures

Figure 1

35 pages, 18094 KiB  
Article
Multi-Phase Dolomitization in the Jurassic Paleo-Oil Reservoir Zone, Qiangtang Basin (SW China): Implications for Reservoir Development
by Ruilin Hao, Liyin Pan, Nana Mu, Xi Li, Xiaodong Fu, Shaoyun Xiong, Siqi Liu, Jianfeng Zheng, Min She and Axel Munnecke
Minerals 2024, 14(9), 908; https://doi.org/10.3390/min14090908 - 5 Sep 2024
Viewed by 1097
Abstract
The age and dolomitization processes in the Paleo-oil reservoir zone, which is composed of massive dolostones found in the Qiangtang Basin (SW China), are still debated. In this research, the Long’eni-Geluguanna Area was selected. Macroscopic information, thin sections, and geochemical methods were used [...] Read more.
The age and dolomitization processes in the Paleo-oil reservoir zone, which is composed of massive dolostones found in the Qiangtang Basin (SW China), are still debated. In this research, the Long’eni-Geluguanna Area was selected. Macroscopic information, thin sections, and geochemical methods were used to investigate the dolomitization characteristics and the processes that controlled dolomitization. Five types of replacive dolomites and two types of dolomite cement were observed. Some of the dolomites displayed ghosts of primary sedimentary structures. Saddle dolomites were prevalent, occurring in the interparticle and moldic pores of the limestone which should have been filled at an early diagenetic stage. Ten microfacies types were identified. The foraminifera assemblage provides evidence that the studied interval is of Early Jurassic age. The δ13C values are similar to the contemporaneous seawater signature. The REE+Y patterns of limestones and dolostones exhibit similarities to that of seawater. The mean Na and Sr values are comparable to those of other near-normal seawater dolomites. The δ18O values of all lithologies are markedly depleted. The dolomitization started penecontemporaneously, with deposition. A general sand shoal setting with patch reefs developed. The dolomitizing fluids, near-normal seawater, was probably formed by slight evaporation on top of the shoal. Saddle dolomites in the interparticle and moldic pores might indicate hydrothermal activity, which also caused the recrystallization of some pre-existing dolomites. The recrystallization might have slightly increased the crystal size, demolished the ghost structures, formed saddle dolomites, and altered the REE+Y patterns. The recrystallization extent diminished with increasing distance from the fluids-providing fracture. Furthermore, the existence of protected areas within the sand shoal settings could enhance the vertical and horizontal heterogeneity of dolostone reservoirs. Full article
Show Figures

Figure 1

Back to TopTop