Search Results (8,591)

Rare Earth Elements (REEs) represent strategic and critical raw materials for the energy transition and must therefore be integrated into efficient and functional recycling processes. Their adoption in electric motors is rapidly expanding, raising significant challenges for end-of-life (EoL) management, starting from the collection phase. In this context, this work proposes the integration of an image-based classification framework within the Waste Electrical and Electronic Equipment (WEEE) recycling pipeline to selectively identify electric motors containing permanent magnets (PMs) and direct them toward dedicated recycling processes for rare earth recovery. The proposed methodology relies on a Discriminative Transfer Learning (DTL) approach based on a ResNeXt convolutional neural network (CNN), adapted to a proprietary and heterogeneous dataset of electric motors acquired in an industrial recycling facility. The objective is twofold: first, to identify motors containing PMs; second, to classify motors into construction categories according to their likelihood of incorporating PMs. Experimental results show promising performance in terms of PM-containing motor detection capability, establishing a robust foundation for the automated recovery of REEs at an industrial scale. Furthermore, the model’s generalization capabilities can be further enhanced through the expansion of collaborative datasets and the integration of advanced scanning technologies. Full article

Water electrolysis is a key technology for sustainable hydrogen production and a cornerstone of future low-carbon energy systems. However, large-scale deployment is constrained not only by efficiency and cost, but increasingly by the sustainability and availability of materials used in electrocatalysts and membranes. This review provides a materials-centric assessment of state-of-the-art and emerging electrocatalysts for alkaline (AEL), proton exchange membrane (PEM), and solid oxide electrolysis (SOEC) technologies, emphasizing the interdependence of performance, durability, cost, and sustainability. Electrocatalyst activity and stability are linked to cell- and stack-level efficiency, energy demand, and the levelized cost of hydrogen. Life cycle assessment (LCA) and resource criticality analyses are integrated to quantify environmental impacts, supply risks, and recycling potential of key materials, including platinum group metals, nickel, rare earth elements, and ceramic oxides. Particular attention is given to recycling and circularity strategies, which are essential for mitigating material scarcity and reducing upstream emissions, especially in PEM electrolyzers. Emerging catalyst concepts such as single-atom catalysts, high-entropy alloys, and noble-metal-free systems are discussed as promising pathways to reduce critical material dependence. The review concludes by highlighting the need for integrated material–technology–system approaches to enable efficient, scalable, and truly sustainable hydrogen production. Full article

Against the backdrop of population aging, community parks are important spaces for older adults’ daily activities, and perceived safety plays a key role in shaping their use and spatial satisfaction. This study selected six typical community parks in central Beijing, constructed an indicator system for safety perception needs, and applied an analytical KANO–IPA (Integrated Kano and Importance-Performance Analysis) approach to identify the demand attributes and optimization priorities of safety elements. The results reveal a clear hierarchy in older adults’ safety perception needs. Basic environmental and facility safety factors, such as pavement conditions and facility reliability, function as must-be needs. Elements related to spatial visibility, circulation, lighting, and wayfinding act as one-dimensional needs that steadily influence satisfaction, whereas features including natural surveillance, spatial enclosure, and activity atmosphere mainly enhance spatial experience as attractive needs. Priority analysis further indicates that circulation conditions and facility safety constitute the most critical aspects for improvement. Overall, older adults’ safety perception in community parks results from the combined effects of multiple spatial factors. Hierarchical spatial optimization can enhance user experience and improve resource allocation efficiency. The findings provide theoretical support and decision-making guidance for safety-oriented planning and age-friendly renewal of urban community parks in aging societies. Full article

Over the past few decades, conversions to Islam in Colombia have increased significantly, with Latin American “indigenous” Muslims (converts or direct descendants of converts) now forming the majority in most mosques, congregations and Islamic centers. These conversions arise from various motivations, including spiritual exploration, intellectual curiosity, and relational or emotional factors, often intertwined. A distinction can be drawn between “collective conversions,” where dozens of individuals in a given area embrace Islam together, and “individual conversions,” which are more dispersed and numerous. This article goes beyond examining the motivations and conditions of these conversions to explore the emergence of an “indigenous Islam” in Colombia and the dynamics surrounding the development and assertion of local Muslim communities, primarily composed of converts. Key challenges for these communities include negotiating knowledge and legitimacy within mixed groups of migrants and “indigenous” Muslims, constructing a plural identity that blends local (Latin American) social and cultural elements with Islamic references, including a sense of belonging to the universal Ummah, and contextualizing religious norms and discourses in light of the local social realities. Furthermore, this study delves into the critical issue of sustaining these small, often fragile communities over time. Drawing on fieldwork and qualitative analysis, this paper aims to provide insights into how Islam is being understood, lived, and rooted in a predominantly Catholic and secular Colombian society, contributing to broader discussions on religion, identity, and social change in Latin America. Full article

The structural integrity of isolation dams in deep coal mines is critical to preventing underground disasters, particularly those involving water and waste-mixture inrushes. This study presents a forensic root-cause analysis, using reverse-engineering techniques, of a specific isolation-dam rupture to determine the failure mechanism under complex stress conditions and limited data availability. A hybrid investigative methodology was employed, combining sequential post-failure documentation analysis with physical-scale modelling and numerical simulations to reconstruct a deadly disaster for criminal investigation purposes. A 1:5 scale physical model of the excavation and dam was constructed using original construction materials to test the structure’s resistance to hydrostatic pressure. The experimental results demonstrated that the dam maintained integrity under static hydraulic loads representative of real-world conditions, with only minor seepage (“sweating”) and no structural failure over a 7-day monitoring period. To investigate external geomechanical factors, Finite Element Method (FEM) simulations were conducted using ANSYS software. The numerical analysis evaluated the effects of rock mass pressure and convergence on the dam’s stability. The results indicate that while the dam was designed to withstand significant hydraulic head, the failure was precipitated by excessive rock mass pressure at a depth of around 600 m, which induced critical stress concentrations exceeding the masonry’s load-bearing capacity. This study confirms that the dynamic rupture was driven by unforeseen geomechanical forces rather than hydrostatic overload alone, highlighting the necessity of considering rock mass–structure interaction in the safety assessment of underground isolation barriers. This approach enables mutual verification of the results obtained and reduces the ambiguity of interpretation that often accompanies the analysis of accident events in underground mining. It also confirms the application of tested methodology for mining disaster reconstruction as proof at the stage of investigation and in the Court. Full article

This study addresses the dual challenges of low copper recovery and persistent arsenic pollution in the bioleaching of low-grade, high-arsenic copper ores containing enargite (Cu₃AsS₄). Through integrated electrochemical, chemical, and biological investigations, a selective and environmentally sustainable two-stage hybrid leaching process was developed. Electrochemical analysis identified a critical oxidation threshold of ~750 mV governing enargite dissolution. Chemical leaching and X-ray Photoelectron Spectroscopy (XPS) analysis revealed a temperature-dependent sulfur transformation pathway, enabling a staged thermal strategy: flotation below 40 °C to maximize hydrophobic elemental sulfur (S⁰) formation, and bioleaching at 40–55 °C to promote complete sulfur oxidation to sulfate. Optimization produced a two-stage process comprising 10-day chemical pre-leaching with FeSO₄ (10.0 g/L Fe²⁺) followed by bioleaching, achieving 78.3% copper extraction while suppressing arsenic dissolution to approximately 10%. The use of FeSO₄ instead of Fe₂(SO₄)₃ reduces reagent costs by ~70%, saving an estimated CNY 47,250 daily at 1000 t/d scale. Leaching toxicity tests confirm residue As < 0.10 mg/L, meeting non-hazardous waste standards (GB5085.3-2007). This work provides the first integrated demonstration of electrochemical threshold control combined with temperature-dependent sulfur speciation for selective copper extraction from arsenic-bearing enargite ores, offering a scalable, reagent-economical, and environmentally sustainable metallurgical route. Full article

Nonlinear structural analysis serves as a fundamental tool for accurately predicting structural bearing capacity and ultimate strength. The incremental-iterative solution scheme represents the prevailing methodology for tracing nonlinear load–displacement responses and is implemented in most commercial finite element software. To enhance the robustness and computational efficiency of existing schemes, this paper first revisits the incremental-iterative framework, providing a detailed analysis that clarifies the distinct roles of the load increment factor in the predictor and corrector phases. Subsequently, a novel framework of updated orthogonal iterative schemes (UOIS) is established. Within this framework, the current generalized stiffness parameter (CGSP) and a cumulative indicator S_i are introduced in the predictor phase to adaptively control the magnitude and sign of the load increment, respectively. In the corrector phase, four enhanced orthogonal iteration strategies are formulated. Furthermore, to improve computational efficiency, a novel acceleration strategy is proposed, which embeds a secant prediction operator in the predictor phase, thereby circumventing the costly assembly and inversion of the tangent stiffness matrix. The results demonstrate that: (1) compared to the conventional generalized stiffness parameter (GSP), the proposed CGSP exhibits superior stability in tracking stiffness variations, offering a more reliable indicator for adaptive step-size control; (2) the cumulative indicator S_i reliably identifies load limit points and accurately distinguishes between loading and unloading regimes; (3) the UOIS framework demonstrates strong convergence in tracing complex equilibrium paths with multiple critical points and exhibits significantly superior robustness under large increment sizes compared to the generalized displacement control method (GDCM); and (4) the secant-prediction acceleration strategy achieves substantial improvements in computational efficiency without compromising solution accuracy. Full article

Drought tolerance is critical for plant survival and productivity and is tightly linked to redox homeostasis and senescence regulation. SENESCENCE-SUPPRESSED PROTEIN PHOSPHATASE (SSPP), a negative regulator of leaf senescence, has previously been implicated in salt stress tolerance. However, whether SSPP functions in drought stress responses remains unknown. Here, we demonstrate that SSPP enhances drought tolerance in Arabidopsis thaliana. Although drought represses SSPP transcription, drought treatment attenuated N⁷-mediated SSPP degradation, in which N⁷, the N-terminal 1–14 amino acids of AtACS7, functions as a conditional degradation signal, resulting in stress-responsive accumulation of SSPP protein in N⁷-SSPP-overexpressing plants. Both SSPP- and N⁷-SSPP-overexpressing plants exhibited enhanced drought tolerance, with survival rates after rewatering reaching approximately 95% and 70%, respectively, whereas the sspp-1 mutant displayed pronounced drought sensitivity. Mechanistically, SSPP overexpression upregulated reactive oxygen species (ROS)-scavenging genes, enhanced antioxidant enzyme activities, and reduced drought-induced ROS accumulation, thereby mitigating oxidative damage. Notably, the N⁷ element enables conditional accumulation of SSPP under adverse conditions while preventing growth inhibition under normal conditions. Together, our findings reveal SSPP as a regulator connecting senescence-associated processes with drought stress adaptation and highlight the N⁷-SSPP fusion as a versatile strategy for improving stress resilience without compromising plant growth. Full article

Late Early Jurassic continental arc magmatism in the northern Greater Khingan Range enables the investigation of complicated tectonic processes associated with the subduction and closure of the Mongol–Okhotsk Ocean. To further clarify the timing, genesis, and geodynamic mechanisms driving the magmatic activity during this period, the present study addresses these critical questions by integrating zircon U–Pb geochronological, geochemical, and isotopic analyses of a wide variety of igneous rocks, including gabbro, gabbro-diorite, granodiorite, porphyritic monzogranite, and biotite-bearing monzogranite from the Fushan region. Zircon U–Pb geochronology constrains the timing of magmatic activity to 184–179 Ma, coinciding with active subduction phases. Geochemical data reveal arc-like signatures characterized by enrichment in light rare-earth elements (LREEs) and large-ion lithophile elements (LILEs), together with pronounced depletion in high field strength elements (HFSEs). A comprehensive analysis of geochemical and Sr–Nd–Hf isotopic signatures suggests that the mafic rocks originated from an enriched lithospheric mantle modified by subduction-related fluids and sediment-derived melts. By contrast, the granodiorite and porphyritic monzonite exhibit adakitic characteristics, indicating partial melting of the thickened Mesoproterozoic lower crust with contributions from mantle-derived or newly formed crustal material. The biotite-bearing monzogranite, with its pronounced Eu anomaly and lower zircon saturation temperatures, reflects advanced magmatic differentiation from a shallower source. These findings indicate extensive crust–mantle interactions during the southward subduction of the Mongol–Okhotsk Ocean, driven by high-angle subduction and slab rollback. Full article

Though it has early modern roots, contemporary “Ignatian spirituality” represents a reconfiguration of nineteenth- and twentieth-century Jesuit spiritual culture. This article offers a genealogical account of a key element in that modern construction: the growing emphasis on Ignatius Loyola as a mystic and the eclipse of earlier, more ascetical understandings of both Ignatius and his Spiritual Exercises. The essay begins by examining key contributions of Jan Philipp Roothaan (1785–1855), the long-serving superior general of the Society of Jesus in the decades following its Restoration. Roothaan’s explicitly non-mystical and decidedly ascetical reading of the Exercises at once reflected and helped shape nineteenth-century Jesuit spiritual culture. The article then traces how this vision came under criticism in the early twentieth century. Renewed Catholic interest in mysticism, and increased attention to Jesuit sources—newly available in critical editions via the Monumenta Historica Societatis Iesu—fostered a reevaluation of Ignatius as a mystic in his own right. Over time, this shift came to color the interpretation of the Spiritual Exercises. Rather than a school of self-conquest, they came to be understood as a kind of mystical pedagogy. Changes in spiritual theology have had concrete implications for how the Exercises are given, as a concluding case study of the Ignatian Examen helps illustrate. Full article

Purpose: Despite extensive evidence supporting synoptic reporting in adult surgical oncology, the pediatric surgical oncology evidence base remains sparse, institution-dependent, and implementation-limited, resulting in a critical translational gap. This systematic review evaluates the implementation and effectiveness of synoptic operative reports (SR) in improving documentation completeness in pediatric oncology surgery compared with traditional narrative reports (NR). Methods: Prospective and retrospective studies evaluating operative report completeness in pediatric oncology surgery were identified through a comprehensive search of PubMed, Scopus, and Web of Science. Of 1926 screened records, 11 articles underwent full-text review, and 4 studies met inclusion criteria. Results: The four included studies analyzed 341 operative reports (217 NRs and 124 SRs). Documentation completeness was the primary outcome. Across all evaluated intraoperative elements, synoptic reports were associated with approximately tenfold higher odds of complete documentation compared with narrative reports (pooled OR for NR vs. SR, 0.10; 95% CI, 0.07–0.14; p < 0.001). Conclusions: Synoptic reporting consistently improves the completeness of pediatric oncologic operative documentation compared with narrative formats; however, adoption in pediatric surgical oncology remains limited. Multicenter and implementation-focused research is needed to assess scalability, integration within electronic medical record (EMR) systems, and the impact of synoptic reporting on communication and clinical decision-making. Full article

RNA editing is a critical post-transcriptional modification that contributes to transcriptomic and proteomic diversity. The most common A-to-I (recognized as G) RNA editing enzymes are adenosine deaminases acting on RNA 1 and 2 (ADAR1 and ADAR2, respectively), which mediate alterations across all regions of mRNA molecules. However, a systematic cross-tissue view of RNA editing and its molecular correlates is still lacking. Here, we developed a rapid method for ADAR editing assessment based on 24 frequently edited positions in coding regions, which enables faster estimation of RNA editing levels than previous methods. We applied this metric to assess RNA editing in normal and cancerous lung and colorectal tissues. We analyzed RNA and whole exome sequencing profiles of experimental 172 colorectal and 144 lung cancer samples, and literature 646 colorectal and 1037 lung cancer samples. We also examined two types of control tissues: tumor-matched normal tissues (51 colorectal and 108 lung samples) and healthy tissues (6 colorectal and 7 lung samples). Overall ADAR-mediated RNA editing levels were ~2.9- and ~4.7-fold higher in healthy controls than in colorectal and lung cancers, respectively. In addition to their well-known association with immune cells, we identified positive correlations of ADAR editing with 740 molecular pathways including those responsible for extracellular matrix organization, RAS-MAPK axis and G2/M phase cell cycle arrest, and negative—with 139 pathways responsible for DNA repair, apoptosis, expression of transposable elements, and other factors. Full article

Pyruvate decarboxylase (PDC) is an intracellular non-oxidizing enzyme that relies on thiamine pyrophosphate (TPP), which is important for plant survival under anaerobic conditions and increasingly recognized for its role in broader stress reaction. However, the PDC gene family of tomato (Solanum lycopersicum), an important waterlogging-sensitive agricultural product, has not yet been discovered. In this study, eight SlPDC genes were discovered within the tomato genome. Gene structure analysis revealed that SlPDC members exhibited varying intron–exon configurations, with SlPDC8 possessing the most complex structure containing seven introns. Promoter analysis revealed a multitude of cis-acting elements responsive to light, hormones, and various stresses. Particularly, the promoter of SlPDC8 contains both ABRE and TGACG/CGTCA-motif. Tissue-specific expression profiles showed that SlPDC8 was mainly highly expressed in the roots. Expression profiling demonstrated that SlPDC genes respond divergently to different abiotic stresses, including salt, hydrogen peroxide (H₂O₂), drought, waterlogging, cold, heat, darkness, and UV radiation stresses. Notably, SlPDC1, SlPDC7, and SlPDC8 were significantly upregulated by waterlogging, with SlPDC8 showing the most robust induction. Functional validation through VIGS proved that SlPDC8-silenced plants exhibited significantly impaired growth, decreased photosynthetic pigment content, severe leaf wilting, and poor root development under waterlogging conditions compared to control plants. Furthermore, silencing SlPDC8 led to increased malondialdehyde (MDA) levels and decreased antioxidant enzyme activities, indicating heightened oxidative damage under waterlogging stress. We conclusively demonstrate that SlPDC8 plays a critical positive regulatory role in waterlogging tolerance by maintaining cellular homeostasis and enhancing antioxidant capacity. Full article

This study developed a biomimetic jumping robot inspired by frogs to enhance its obstacle-crossing capabilities. The biological principles underlying the jumping biomechanics of frog hindlimbs were integrated into the robotic mechanism; quantitative analysis of the bionic structure and its jumping performance not only provides mechanical engineering insights for investigating frog locomotion mechanics but also offers practical design references for the development of biomimetic mobile robots. Through theoretical calculations and application scenario analysis, a six-bar linkage mechanism was designed to simulate the force generation of frog hindlimbs, with tension springs mimicking the elastic energy storage function of the semimembranosus and gastrocnemius muscles. A reducer was integrated into the trunk to enable energy storage, and an adjustable single-hinge structure was adopted for the forelegs to realize take-off angle adjustment and shock absorption. Finite element simulations were conducted to validate the load-bearing capacity and strength of critical components. Multi-body dynamics and the particle swarm optimization (PSO) algorithm were employed to explore the relationship between input parameters and output performance metrics (jumping height and jumping distance), while orthogonal experimental analysis was used for comprehensive parameter evaluation. Finally, a physical prototype was fabricated, and its performance parameters were tested. The prototype has a mass of 150 g, generates a ground push force of 50 N, attains a jumping height of 380 mm, and achieves a maximum jumping distance of 500 mm. This study establishes a biologically inspired working principle for jumping robots and provides a novel practical prototype for research into biomimetic mobile robots. Full article

Arsenic (As) and mercury (Hg) are trace elements of major environmental and public health concern. Their relevance is due to their well-documented toxicological effects. In rapidly urbanizing port-industrial cities, soil contamination by these elements represents a critical challenge. This situation compromises sustainable urban development and environmental governance. This study had three main objectives: First, to evaluate the contamination status of As and Hg in urban soils using multiple geochemical indices; Second, to assess the potential human health risks associated with exposure in the urban environment of Talcahuano; Third, to identify the relative contributions of geogenic and anthropogenic sources based on spatial distribution patterns. A total of 420 soil samples were collected. These included 140 topsoil samples (TS; 0–10 cm), 140 subsoil samples (SS; 10–20 cm), and 140 deep-soil samples (DS; 150 cm). Arsenic concentrations were determined using hydride-generation atomic absorption spectrometry (HG-AAS). Mercury concentrations were measured by cold-vapour atomic absorption spectrometry (CV-AAS). Median As concentrations were 2.7 mg kg⁻¹ in TS, 3.1 mg kg⁻¹ in SS, and 2.5 mg kg⁻¹ in DS. The corresponding median Hg concentrations were 0.2 mg kg⁻¹ in TS and 1.4 mg kg⁻¹ in both SS and DS. Spatial distribution maps were generated through ordinary kriging interpolation. Geochemical baseline values were calculated using the median + 2 × MAD approach. The resulting baseline values were 7.8 mg kg⁻¹ for As and 3.6 mg kg⁻¹ for Hg. Contamination assessment was conducted using the geoaccumulation index (Igeo), enrichment factor (EF), and contamination factor (Cf). Results indicate that most soils are classified as uncontaminated. Enrichment levels were minimal and contamination factors were low. Nevertheless, isolated outliers were identified. These included one significantly enriched As sample and several moderately enriched or slightly contaminated Hg samples. Human health risk assessment incorporated the Hazard Index (HI) and Total Carcinogenic Risk (TCR). Results indicate that neither non-carcinogenic nor carcinogenic risks exceed acceptable thresholds at any investigated soil depth. Spatial analysis suggests that anthropogenic activities are the dominant sources of As and Hg in the study area. Traffic emissions and industrial activities appear to be the primary contributors. Full article