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20 pages, 5638 KiB  
Article
Influence of Heat Treatment on Precipitate and Microstructure of 38CrMoAl Steel
by Guofang Xu, Shiheng Liang, Bo Chen, Jiangtao Chen, Yabing Zhang, Xiaotan Zuo, Zihan Li, Bo Song and Wei Liu
Materials 2025, 18(15), 3703; https://doi.org/10.3390/ma18153703 - 6 Aug 2025
Abstract
To address the central cracking problem in continuous casting slabs of 38CrMoAl steel, high-temperature tensile tests were performed using a Gleeble-3800 thermal simulator to characterize the hot ductility of the steel within the temperature range of 600–1200 °C. The phase transformation behavior was [...] Read more.
To address the central cracking problem in continuous casting slabs of 38CrMoAl steel, high-temperature tensile tests were performed using a Gleeble-3800 thermal simulator to characterize the hot ductility of the steel within the temperature range of 600–1200 °C. The phase transformation behavior was computationally analyzed via the Thermo-Calc software, while the microstructure, fracture morphology, and precipitate characteristics were systematically investigated using a metallographic microscope (MM), a field-emission scanning electron microscope (FE-SEM), and transmission electron microscopy (TEM). Additionally, the effects of different holding times and cooling rates on the microstructure and precipitates of 38CrMoAl steel were also studied. The results show that the third brittle temperature region of 38CrMoAl steel is 645–1009 °C, and the fracture mechanisms can be classified into three types: (I) in the α single-phase region, the thickness of intergranular proeutectoid ferrite increases with rising temperature, leading to reduced hot ductility; (II) in the γ single-phase region, the average size of precipitates increases while the number density decreases with increasing temperature, thereby improving hot ductility; and (III) in the α + γ two-phase region, the precipitation of proeutectoid ferrite promotes crack propagation and the dense distribution of precipitates at grain boundaries causes stress concentration, further deteriorating hot ductility. Heat treatment experiments indicate that the microstructures of the specimen transformed under water cooling, air cooling, and furnace cooling conditions as follows: martensite + proeutectoid ferrite → bainite + ferrite → ferrite. The average size of precipitates first decreased, then increased, and finally decreased again with increasing holding time, while the number density exhibited the opposite trend. Therefore, when the holding time was the same, reducing the cooling rate could increase the average size of the precipitates and decrease their number density, thereby improving the hot ductility of 38CrMoAl steel. Full article
(This article belongs to the Special Issue Microstructure Engineering of Metals and Alloys, 3rd Edition)
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17 pages, 3157 KiB  
Article
Research on Online Traceability Methods for the Causes of Longitudinal Surface Crack in Continuous Casting Slab
by Junqiang Cong, Qiancheng Lv, Zihao Fan, Haitao Ling and Fei He
Materials 2025, 18(15), 3695; https://doi.org/10.3390/ma18153695 - 6 Aug 2025
Abstract
In the casting and rolling production process, surface longitudinal cracks are a typical casting defect. Tracing the causes of longitudinal cracks online and controlling the key parameters leading to their formation in a timely manner can enhance the stability of casting and rolling [...] Read more.
In the casting and rolling production process, surface longitudinal cracks are a typical casting defect. Tracing the causes of longitudinal cracks online and controlling the key parameters leading to their formation in a timely manner can enhance the stability of casting and rolling production. To this end, the influencing factors of longitudinal cracks were analyzed, a data integration storage platform was constructed, and a tracing model was established using empirical rule analysis, statistical analysis, and intelligent analysis methods. During the initial production phase of a casting machine, longitudinal cracks occurred frequently. The tracing results using the LightGBM-SHAP method showed that the relative influence of the narrow left wide inner heat flow ratio of the mold was significant, followed by the heat flow difference on the wide symmetrical face of the mold and the superheat of the molten steel, with weights of 0.135, 0.066, and 0.048, respectively. Based on the tracing results, we implemented online emergency measures. By controlling the cooling intensity of the mold, we effectively reduced the recurrence rate of longitudinal cracks. Root cause analysis revealed that the total hardness of the mold-cooling water exceeded the standard, reaching 24 mg/L, which caused scaling on the mold copper plates and uneven cooling, leading to the frequent occurrence of longitudinal cracks. After strictly controlling the water quality, the issue of longitudinal cracks was brought under control. The online application of the tracing method for the causes of longitudinal cracks has effectively improved efficiency in resolving longitudinal crack problems. Full article
(This article belongs to the Special Issue Advanced Sheet/Bulk Metal Forming)
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23 pages, 3106 KiB  
Article
Preparation of a Nanomaterial–Polymer Dynamic Cross-Linked Gel Composite and Its Application in Drilling Fluids
by Fei Gao, Peng Xu, Hui Zhang, Hao Wang, Xin Zhao, Xinru Li and Jiayi Zhang
Gels 2025, 11(8), 614; https://doi.org/10.3390/gels11080614 - 5 Aug 2025
Abstract
During the process of oil and gas drilling, due to the existence of pores or micro-cracks, drilling fluid is prone to invade the formation. Under the action of hydration expansion of clay in the formation and liquid pressure, wellbore instability occurs. In order [...] Read more.
During the process of oil and gas drilling, due to the existence of pores or micro-cracks, drilling fluid is prone to invade the formation. Under the action of hydration expansion of clay in the formation and liquid pressure, wellbore instability occurs. In order to reduce the wellbore instability caused by drilling fluid intrusion into the formation, this study proposed a method of forming a dynamic hydrogen bond cross-linked network weak gel structure with modified nano-silica and P(AM-AAC). The plugging performance of the drilling fluid and the performance of inhibiting the hydration of shale were evaluated through various experimental methods. The results show that the gel composite system (GCS) effectively optimizes the plugging performance of drilling fluid. The 1% GCS can reduce the linear expansion rate of cuttings to 14.8% and increase the recovery rate of cuttings to 96.7%, and its hydration inhibition effect is better than that of KCl and polyamines. The dynamic cross-linked network structure can significantly increase the viscosity of drilling fluid. Meanwhile, by taking advantage of the liquid-phase viscosity effect and the physical blocking effect, the loss of drilling fluid can be significantly reduced. Mechanism studies conducted using zeta potential measurement, SEM analysis, contact angle measurement and capillary force assessment have shown that modified nano-silica stabilizes the wellbore by physically blocking the nano-pores of shale and changing the wettability of the shale surface from hydrophilic to hydrophobic when the contact angle exceeds 60°, thereby reducing capillary force and surface free energy. Meanwhile, the dynamic cross-linked network can reduce the seepage of free water into the formation, thereby significantly lowering the fluid loss of the drilling fluid. This research provides new insights into improving the stability of the wellbore in drilling fluids. Full article
(This article belongs to the Special Issue Advanced Gels for Oil Recovery (2nd Edition))
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16 pages, 6744 KiB  
Article
Thermochemical Conversion of Digestate Derived from OFMSW Anaerobic Digestion to Produce Methane-Rich Syngas with CO2 Sorption
by Emanuele Fanelli, Cesare Freda, Assunta Romanelli, Vito Valerio, Adolfo Le Pera, Miriam Sellaro, Giacinto Cornacchia and Giacobbe Braccio
Processes 2025, 13(8), 2451; https://doi.org/10.3390/pr13082451 - 2 Aug 2025
Viewed by 238
Abstract
The energetic valorization of digestate obtained from anaerobic digestion (AD) of the organic fraction of municipal solid waste (OFMSW) was investigated via pyrolysis in a bench-scale rotary kiln. The mass rate of dried digestate to the rotary kiln pyrolyzer was fixed at 500 [...] Read more.
The energetic valorization of digestate obtained from anaerobic digestion (AD) of the organic fraction of municipal solid waste (OFMSW) was investigated via pyrolysis in a bench-scale rotary kiln. The mass rate of dried digestate to the rotary kiln pyrolyzer was fixed at 500 gr/h. The effect of the pyrolysis temperature was investigated at 600, 700, and 800 °C. The pyrolysis products, char, oil, and gas, were quantified and chemically analyzed. It was observed that with the increase in the temperature from 600 to 800 °C, the char decreased from 60.3% to 52.2% and the gas increased from 26.5% to 35.3%. With the aim of increasing the methane production and methane concentration in syngas, the effect of CaO addition to the pyrolysis process was investigated at the same temperature, too. The mass ratio CaO/dried digestate was set at 0.2. The addition of CaO sorbent has a clear effect on the yield and composition of pyrolysis products. Under the experimental conditions, CaO was observed to act both as a CO2 sorbent and as a catalyst, promoting cracking and reforming reactions of volatile compounds. In more detail, at the investigated temperatures, a net reduction in CO2 concentration was observed in syngas, accompanied by an increase in CH4 concentration. The gas yield decreased with the CaO addition because of CO2 chemisorption. The oil yield decreased as well, probably because of the cracking and reforming effect of the CaO on the volatiles. A very promising performance of the CaO sorbent was observed at 600 °C; at this temperature, the CO2 concentration decreased from 32.2 to 13.9 mol %, and the methane concentration increased from 16.1 to 29.4 mol %. At the same temperature, the methane production increased from 34 to 63 g/kgdigestate. Full article
(This article belongs to the Section Chemical Processes and Systems)
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19 pages, 2359 KiB  
Article
Research on Concrete Crack Damage Assessment Method Based on Pseudo-Label Semi-Supervised Learning
by Ming Xie, Zhangdong Wang and Li’e Yin
Buildings 2025, 15(15), 2726; https://doi.org/10.3390/buildings15152726 - 1 Aug 2025
Viewed by 214
Abstract
To address the inefficiency of traditional concrete crack detection methods and the heavy reliance of supervised learning on extensive labeled data, in this study, an intelligent assessment method of concrete damage based on pseudo-label semi-supervised learning and fractal geometry theory is proposed to [...] Read more.
To address the inefficiency of traditional concrete crack detection methods and the heavy reliance of supervised learning on extensive labeled data, in this study, an intelligent assessment method of concrete damage based on pseudo-label semi-supervised learning and fractal geometry theory is proposed to solve two core tasks: one is binary classification of pixel-level cracks, and the other is multi-category assessment of damage state based on crack morphology. Using three-channel RGB images as input, a dual-path collaborative training framework based on U-Net encoder–decoder architecture is constructed, and a binary segmentation mask of the same size is output to achieve the accurate segmentation of cracks at the pixel level. By constructing a dual-path collaborative training framework and employing a dynamic pseudo-label refinement mechanism, the model achieves an F1-score of 0.883 using only 50% labeled data—a mere 1.3% decrease compared to the fully supervised benchmark DeepCrack (F1 = 0.896)—while reducing manual annotation costs by over 60%. Furthermore, a quantitative correlation model between crack fractal characteristics and structural damage severity is established by combining a U-Net segmentation network with the differential box-counting algorithm. The experimental results demonstrate that under a cyclic loading of 147.6–221.4 kN, the fractal dimension monotonically increases from 1.073 (moderate damage) to 1.189 (failure), with 100% accuracy in damage state identification, closely aligning with the degradation trend of macroscopic mechanical properties. In complex crack scenarios, the model attains a recall rate (Re = 0.882), surpassing U-Net by 13.9%, with significantly enhanced edge reconstruction precision. Compared with the mainstream models, this method effectively alleviates the problem of data annotation dependence through a semi-supervised strategy while maintaining high accuracy. It provides an efficient structural health monitoring solution for engineering practice, which is of great value to promote the application of intelligent detection technology in infrastructure operation and maintenance. Full article
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21 pages, 5609 KiB  
Article
Carbonation and Corrosion Durability Assessment of Reinforced Concrete Beam in Heavy-Haul Railways by Multi-Physics Coupling-Based Analytical Method
by Wu-Tong Yan, Lei Yuan, Yong-Hua Su, Long-Biao Yan and Zi-Wei Song
Materials 2025, 18(15), 3622; https://doi.org/10.3390/ma18153622 - 1 Aug 2025
Viewed by 235
Abstract
The operation of heavy-haul railway trains with large loads results in significant cracking issues in reinforced concrete beams. Atmospheric carbon dioxide, oxygen, and moisture from the atmosphere penetrate into the beam interior through these cracks, accelerating the carbonation of the concrete and the [...] Read more.
The operation of heavy-haul railway trains with large loads results in significant cracking issues in reinforced concrete beams. Atmospheric carbon dioxide, oxygen, and moisture from the atmosphere penetrate into the beam interior through these cracks, accelerating the carbonation of the concrete and the corrosion of the steel bars. The rust-induced expansion of steel bars further exacerbates the cracking of the beam. The interaction between environmental factors and beam cracks leads to a rapid decline in the durability of the beam. To address this issue, a multi-physics field coupling durability assessment method was proposed, considering concrete beam cracking, concrete carbonation, and steel bar corrosion. The interaction among these three factors is achieved through sequential coupling, using crack width, carbonation passivation time, and steel bar corrosion rate as interaction parameters. Using this method, the deterioration morphology and stiffness degradation laws of 8 m reinforced concrete beams under different load conditions, including those of heavy and light trains in heavy-haul railways, are compared and assessed. The analysis reveals that within a 100-year service cycle, the maximum relative stiffness reduction for beams on the heavy train line is 20.0%, whereas for the light train line, it is only 7.4%. The degree of structural stiffness degradation is closely related to operational load levels, and beam cracking plays a critical role in this difference. Full article
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16 pages, 3072 KiB  
Article
Process Development to Repair Aluminum Components, Using EHLA and Laser-Powder DED Techniques
by Adrienn Matis, Min-Uh Ko, Richard Kraft and Nicolae Balc
J. Manuf. Mater. Process. 2025, 9(8), 255; https://doi.org/10.3390/jmmp9080255 - 31 Jul 2025
Viewed by 224
Abstract
The article presents a new AM (Additive Manufacturing) process development, necessary to repair parts made from Aluminum 6061 material, with T6 treatment. The laser Directed Energy Deposition (DED) and Extreme High-Speed Directed Energy Deposition (EHLA) capabilities are evaluated for repairing Al large components. [...] Read more.
The article presents a new AM (Additive Manufacturing) process development, necessary to repair parts made from Aluminum 6061 material, with T6 treatment. The laser Directed Energy Deposition (DED) and Extreme High-Speed Directed Energy Deposition (EHLA) capabilities are evaluated for repairing Al large components. To optimize the process parameters, single-track depositions were analyzed for both laser-powder DED (feed rate of 2 m/min) and EHLA (feed rate 20 m/min) for AlSi10Mg and Al6061 powders. The cross-sections of single tracks revealed the bonding characteristics and provided laser-powder DED, a suitable parameter selection for the repair. Three damage types were identified on the Al component to define the specification of the repair process and to highlight the capabilities of laser-powder DED and EHLA in repairing intricate surface scratches and dents. Our research is based on variation of the powder mass flow and beam power, studying the influence of these parameters on the weld bead geometry and bonding quality. The evaluation criteria include bonding defects, crack formation, porosity, and dilution zone depth. The bidirectional path planning strategy was applied with a fly-in and fly-out path for the hatching adjustment and acceleration distance. Samples were etched for a qualitative microstructure analysis, and the HV hardness was tested. The novelty of the paper is the new process parameters for laser-powder DED and EHLA deposition strategies to repair large Al components (6061 T6), using AlSi10Mg and Al6061 powder. Our experimental research tested the defect-free deposition and the compatibility of AlSi10Mg on the Al6061 substrate. The readers could replicate the method presented in this article to repair by laser-powder DED/EHLA large Al parts and avoid the replacement of Al components with new ones. Full article
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22 pages, 3440 KiB  
Article
Probabilistic Damage Modeling and Thermal Shock Risk Assessment of UHTCMC Thruster Under Transient Green Propulsion Operation
by Prakhar Jindal, Tamim Doozandeh and Jyoti Botchu
Materials 2025, 18(15), 3600; https://doi.org/10.3390/ma18153600 - 31 Jul 2025
Viewed by 203
Abstract
This study presents a simulation-based damage modeling and fatigue risk assessment of a reusable ceramic matrix composite thruster designed for short-duration, green bipropellant propulsion systems. The thruster is constructed from a fiber-reinforced ultra-high temperature ceramic matrix composite composed of zirconium diboride, silicon carbide, [...] Read more.
This study presents a simulation-based damage modeling and fatigue risk assessment of a reusable ceramic matrix composite thruster designed for short-duration, green bipropellant propulsion systems. The thruster is constructed from a fiber-reinforced ultra-high temperature ceramic matrix composite composed of zirconium diboride, silicon carbide, and carbon fibers. Time-resolved thermal and structural simulations are conducted on a validated thruster geometry to characterize the severity of early-stage thermal shock, stress buildup, and potential degradation pathways. Unlike traditional fatigue studies that rely on empirical fatigue constants or Paris-law-based crack-growth models, this work introduces a simulation-derived stress-margin envelope methodology that incorporates ±20% variability in temperature-dependent material strength, offering a physically grounded yet conservative risk estimate. From this, a normalized risk index is derived to evaluate the likelihood of damage initiation in critical regions over the 0–10 s firing window. The results indicate that the convergent throat region experiences a peak thermal gradient rate of approximately 380 K/s, with the normalized thermal shock index exceeding 43. Stress margins in this region collapse by 2.3 s, while margin loss in the flange curvature appears near 8 s. These findings are mapped into green, yellow, and red risk bands to classify operational safety zones. All the results assume no active cooling, representing conservative operating limits. If regenerative or ablative cooling is implemented, these margins would improve significantly. The framework established here enables a transparent, reproducible methodology for evaluating lifetime safety in ceramic propulsion nozzles and serves as a foundational tool for fatigue-resilient component design in green space engines. Full article
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18 pages, 8192 KiB  
Article
Microstructure, Mechanical Properties, and Tribological Behavior of Friction Stir Lap-Welded Joints Between SiCp/Al–Fe–V–Si Composites and an Al–Si Alloy
by Shunfa Xiao, Pinming Feng, Xiangping Li, Yishan Sun, Haiyang Liu, Jie Teng and Fulin Jiang
Materials 2025, 18(15), 3589; https://doi.org/10.3390/ma18153589 - 30 Jul 2025
Viewed by 240
Abstract
Aluminum matrix composites provide an ideal solution for lightweight brake disks, but conventional casting processes are prone to crack initiation due to inhomogeneous reinforcement dispersion, gas porosity, and inadequate toughness. To break the conventional trade-off between high wear resistance and low toughness of [...] Read more.
Aluminum matrix composites provide an ideal solution for lightweight brake disks, but conventional casting processes are prone to crack initiation due to inhomogeneous reinforcement dispersion, gas porosity, and inadequate toughness. To break the conventional trade-off between high wear resistance and low toughness of brake disks, this study fabricated a bimetallic structure of SiCp/Al–Fe–V–Si aluminum matrix composite and cast ZL101 alloy using friction stir lap welding (FSLW). Then, the microstructural evolution, mechanical properties, and tribological behavior of the FSLW joints were studied by XRD, SEM, TEM, tensile testing, and tribological tests. The results showed that the FSLW process homogenized the distribution of SiC particle reinforcements in the SiCp/Al–Fe–V–Si composites. The Al12(Fe,V)3Si heat-resistant phase was not decomposed or coarsened, and the mechanical properties were maintained. The FSLW process refined the grains of the ZL101 aluminum alloy through recrystallization and fragmented eutectic silicon, improving elongation to 22%. A metallurgical bond formed at the joint interface. Tensile fracture occurred within the ZL101 matrix, demonstrating that the interfacial bond strength exceeded the alloy’s load-bearing capacity. In addition, the composites exhibited significantly enhanced wear resistance after FSLW, with their wear rate reduced by approximately 40% compared to the as-received materials, which was attributed to the homogenized SiC particle distribution and the activation of an oxidative wear mechanism. Full article
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13 pages, 4261 KiB  
Article
Research on Comparative Marine Atmospheric Corrosion Behavior of AZ31 Magnesium Alloy in South China Sea
by Tianlong Zhang, Shuai Wu, Hao Liu, Lihui Yang, Tianxing Chen, Xiutong Wang and Yantao Li
Materials 2025, 18(15), 3585; https://doi.org/10.3390/ma18153585 - 30 Jul 2025
Viewed by 171
Abstract
In this study, the atmospheric corrosion behavior of AZ31 magnesium alloy exposed in Sanya and Nansha for one year was investigated. While existing studies have characterized marine corrosion of magnesium alloys, the synergistic corrosion mechanisms under extreme tropical marine conditions (simultaneous high Cl [...] Read more.
In this study, the atmospheric corrosion behavior of AZ31 magnesium alloy exposed in Sanya and Nansha for one year was investigated. While existing studies have characterized marine corrosion of magnesium alloys, the synergistic corrosion mechanisms under extreme tropical marine conditions (simultaneous high Cl, rainfall, and temperature fluctuations) remain poorly understood—particularly regarding dynamic corrosion–product evolution. The corrosion characteristics and behavior of AZ31 magnesium alloy exposed in Sanya and Nansha were evaluated using X-ray photoelectron spectroscopy, X-ray diffraction, electrochemical measurements, scanning electron microscopy, and weight loss tests. The results showed that the main components of corrosion products were MgCO3·xH2O(x = 3, 5), Mg5(CO3)4(OH)2·4H2O, Mg2Cl(OH)3·4H2O, and Mg(OH)2. The corrosion rate exposed in the Nansha was 26.5 μm·y−1, which was almost two times than that in Sanya. Localized corrosion is the typical corrosion characteristic of AZ31 magnesium alloy in this tropical marine atmosphere. This study exposes the dynamic crack–regeneration mechanism of corrosion products under high-Cl-rainfall synergy. The corrosion types of AZ31 magnesium alloy in this tropical marine atmosphere were mainly represented by pitting corrosion and filamentous corrosion. Full article
(This article belongs to the Special Issue Future Trend of Marine Corrosion and Protection)
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21 pages, 3663 KiB  
Article
A Study on the Road Performance of the Self-Healing Microcapsule for Asphalt Pavement
by Pei Li, Rongyi Ji, Chenlong Zhang, Jinghan Xu, Mulian Zheng and Xinghan Song
Materials 2025, 18(15), 3483; https://doi.org/10.3390/ma18153483 - 25 Jul 2025
Viewed by 332
Abstract
Asphalt pavement cracking is an important factor affecting its service life. Under certain conditions, the self-healing behavior of asphalt itself can repair pavement cracks. However, the self-healing ability of asphalt itself is limited. In order to strengthen the self-healing ability of asphalt, the [...] Read more.
Asphalt pavement cracking is an important factor affecting its service life. Under certain conditions, the self-healing behavior of asphalt itself can repair pavement cracks. However, the self-healing ability of asphalt itself is limited. In order to strengthen the self-healing ability of asphalt, the microcapsule wrapped with a repair agent is pre-mixed into the asphalt mixture. When the crack occurs and spreads to the surface of the microcapsule, the microcapsule ruptures and the healing agent flows out to realize the self-healing of the crack. Current microcapsules are mostly prepared with healing agents and bio-oil as core materials, and their high-temperature resistance to rutting is poor. While the epoxy resin contains a three-membered cyclic ether, it can undergo ring-opening polymerization to bond and repair the asphalt matrix. In addition, research on microcapsules mainly focuses on the self-healing properties of microcapsule-modified asphalt. In fact, before adding microcapsules to asphalt to improve its self-healing performance, it is necessary to ensure that the asphalt has a good road performance. On this basis, the self-healing performance of asphalt is improved, thereby extending the service life of asphalt pavement. Therefore, two-component epoxy self-healing microcapsules (E-mic and G-mic) were first prepared in this paper. Then, a temperature scanning test, rheological test of bending beams, and linear amplitude scanning test were, respectively, conducted for the microcapsule/asphalt to evaluate its road performance, including the high-temperature performance, low-temperature crack resistance, and fatigue performance. Finally, the self-healing performance of microcapsules/asphalt was tested. The results showed that the self-developed epoxy self-healing microcapsules were well encapsulated and presented as spherical micron-sized particles. The average particle size of the E-mic was approximately 23.582 μm, while the average particle size of the G-mic was approximately 22.440 μm, exhibiting a good normal distribution. In addition, they can remain intact and unbroken under high-temperature conditions. The results of road performance tests indicated that the microcapsule/asphalt mixture exhibits an excellent high-temperature resistance to permanent deformation, low-temperature crack resistance, and fatigue resistance. The self-healing test demonstrated that the microcapsule/asphalt exhibited an excellent self-healing performance. When the microcapsule content was 4%, the self-healing rate reached its optimal level of 67.8%, which was 149.2% higher than that of the base asphalt. Full article
(This article belongs to the Special Issue Innovative Approaches in Asphalt Binder Modification and Performance)
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12 pages, 16238 KiB  
Article
Degradation of HVOF-MCrAlY + APS-Nanostructured YSZ Thermal Barrier Coatings
by Weijie R. Chen, Chao Li, Yuxian Cheng, Hongying Li, Xiao Zhang and Lu Wang
Coatings 2025, 15(8), 871; https://doi.org/10.3390/coatings15080871 - 24 Jul 2025
Viewed by 278
Abstract
The degradation process of HVOF-MCrAlY + APS-nanostructured YSZ (APS-nYSZ) thermal barrier coatings, produced using gas turbine OEM-approved MCrAlY powders, is investigated by studying the TGO growth and crack propagation behaviors in a thermal cycling environment. The TGO growth yields a parabolic mechanism on [...] Read more.
The degradation process of HVOF-MCrAlY + APS-nanostructured YSZ (APS-nYSZ) thermal barrier coatings, produced using gas turbine OEM-approved MCrAlY powders, is investigated by studying the TGO growth and crack propagation behaviors in a thermal cycling environment. The TGO growth yields a parabolic mechanism on the surfaces of all HVOF-MCrAlYs, and the growth rate increases with the aluminum content in the “classical” MCrAlYs. The APS-nYSZ layer comprises micro-structured YSZ (mYSZ) and nanostructured YSZ (nYSZ) zones. Both mYSZ/mYSZ and mYSZ/nYSZ interfaces appear to be crack nucleation sites, resulting in crack propagation and consequent crack coalescence within the APS-nYSZ layer in the APS-nYSZ/HVOF-MCrAlY vicinity. Crack propagation in the TBCs can be characterized as a steady-state crack propagation stage, where crack length has a nearly linear relationship with TGO thickness, and an accelerating crack propagation stage, which is apparently a result of the coalescence of neighboring cracks. All TBCs fail in the same way as APS-/HVOF-MCrAlY + APS-conventional YSZ analogs, but the difference in thermal cycling lives is not substantial, although the HVOF-low Al-NiCrAlY encounters chemical failure in the early stage of thermal cycling. Full article
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14 pages, 731 KiB  
Article
Readhesion of Tongue-Tie Following Neonatal Frenotomy: Incidence and Impact of Postoperative Exercises in a Prospective Observational Study
by Beatriz Valle-Del Barrio, Silvia Maya-Enero, Jordi Prat-Ortells, María Ángeles López-Vílchez and Júlia Candel-Pau
Children 2025, 12(8), 971; https://doi.org/10.3390/children12080971 - 24 Jul 2025
Viewed by 295
Abstract
Background/Objectives: Frenotomy is the procedure of choice for treating ankyloglossia. The literature reports that readhesion of the frenulum occurs in 2.6–13% of cases. There is no published evidence to support performing tongue exercises to prevent it. We aimed to determine the readhesion rate [...] Read more.
Background/Objectives: Frenotomy is the procedure of choice for treating ankyloglossia. The literature reports that readhesion of the frenulum occurs in 2.6–13% of cases. There is no published evidence to support performing tongue exercises to prevent it. We aimed to determine the readhesion rate of ankyloglossia, the benefits of tongue exercises to prevent it, and the characteristics of patients who experienced readhesion. Methods: This is a prospective, observational study of neonates who underwent a frenotomy between January and August 2024. Following the frenotomy, we recommended that all parents perform a series of exercises 6–8 times daily over 15 days. Patients were re-evaluated 10–15 days post-procedure for signs of ankyloglossia using the Hazelbaker tool and clinical variables such as nipple pain or cracks. Results: We enrolled 212 patients; thirty patients underwent a refrenotomy (14.1%). The raw risk of readhesion in our study was 0.335 (95%CI 0.275–0.401), and for symptomatic readhesion, 0.156 (95%CI 0.113–0.211). Adjusted by sex, the risk of readhesion for female patients was 0.236 (95%CI 0.155–0.344), and for males, 0.390 (95%CI 0.312–0.474). The appearance and function Hazelbaker scores were significantly lower before the frenotomy than post-procedure in all cases. In females, not following the exercise protocol multiplied the risk of readhesion by 1.61 (95%CI 1.03–2.56), whereas in males the risk was multiplied by 1.47 (95%CI 1.03–2.08). Symptomatic readhesion was significantly correlated with age at frenotomy and Hazelbaker score. Conclusions: Readhesion of tongue-tie was higher than previously published (33.5%); however, symptomatic readhesion was less frequent (15.6%). Proper adherence to post-frenotomy exercises significantly reduces the risk of readhesion, although it has less impact on symptomatic readhesion. Full article
(This article belongs to the Section Pediatric Neonatology)
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18 pages, 3257 KiB  
Article
Experimental Study on the Effects of Loading Rates on the Fracture Mechanical Characteristics of Coal Influenced by Long-Term Immersion in Mine Water
by Xiaobin Li, Gan Feng, Mingli Xiao, Guifeng Wang, Jing Bi, Chunyu Gao and Huaizhong Liu
Appl. Sci. 2025, 15(15), 8222; https://doi.org/10.3390/app15158222 - 24 Jul 2025
Viewed by 236
Abstract
Underground pumped storage hydropower stations (UPSH) are of great significance for energy structure adjustment, and coal mine underground reservoirs are an integral part of UPSH. This study investigates the fracture mechanics behavior of coal in mine water immersion environments with varying loading rates [...] Read more.
Underground pumped storage hydropower stations (UPSH) are of great significance for energy structure adjustment, and coal mine underground reservoirs are an integral part of UPSH. This study investigates the fracture mechanics behavior of coal in mine water immersion environments with varying loading rates and layer direction. Three types of samples were analyzed: Crack-arrester, Crack-splitter, and Crack-divider types. The immersion duration extended up to 120 days. The results indicate that, after immersion in mine water for 120 days, the fracture toughness (KIC), fracture modulus (ES), and absorbed energy (UT) of coal decreased by 60.87%, 53.38%, and 63.21%, respectively, compared to the unsaturated coal samples. An immersion period of 30 days significantly weakens the mechanical properties of coal fractures. The KIC, ES, and UT of coal demonstrate a positive correlation with loading rate, primarily influenced by the duration of coal damage. At the same loading rate, the order of fracture toughness among the three coal types is as follows: Crack-divider > Crack-arrester > Crack-splitter. This hierarchy is determined by the properties of the coal matrix and bedding planes, as well as the mechanical structures composed of them. This study holds significant implications for the safe construction and operational design of underground water reservoirs in coal mines. Full article
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17 pages, 5746 KiB  
Article
The Influence of Hydrogen-Charging Current Density and Temperature on Hydrogen Permeation and Hydrogen Embrittlement Susceptibility of 4130X Steel
by Caijun Xu, Fang Wang and Jiaqing Li
Materials 2025, 18(15), 3448; https://doi.org/10.3390/ma18153448 - 23 Jul 2025
Viewed by 250
Abstract
Chromium-molybdenum steels are extensively used in manufacturing large-volume seamless hydrogen storage vessels, but they still suffer from the hydrogen embrittlement problem. In this study, electrochemical cathodic hydrogen charging is utilized to investigate the hydrogen embrittlement of 4130X steels, with emphasis on the influence [...] Read more.
Chromium-molybdenum steels are extensively used in manufacturing large-volume seamless hydrogen storage vessels, but they still suffer from the hydrogen embrittlement problem. In this study, electrochemical cathodic hydrogen charging is utilized to investigate the hydrogen embrittlement of 4130X steels, with emphasis on the influence of charging current density and temperature on hydrogen permeation and hydrogen embrittlement susceptibility. The hydrogen penetration rate and hydrogen diffusion coefficient of 4130X steel both increase with an increase in hydrogen-charging current density and temperature. The results demonstrate that the degree of hydrogen-induced degradation in tensile ductility is more marked with increasing hydrogen-charging current density, while the hydrogen embrittlement index exhibits a peak at a temperature of 308 K, in which brittle patterns like quasi-cleavage surfaces and crack formations occur. These findings are crucial for understanding hydrogen-induced embrittlement and determining test temperatures of hydrogen-related engineering material applications. Full article
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