Search Results (2,268)

This paper presents an analytical framework for the preliminary design of stringer-stiffened composite panels subjected to low-velocity impact. The formulation combines First-Order Shear Deformation Theory with a two-degree-of-freedom spring–mass model, while the super-stringer is represented as a Euler–Bernoulli beam whose bending contribution is transferred to the skin mid-surface through the parallel axis theorem. This provides a computationally efficient tool for rapid parametric assessment of stiffened configurations at the early design stage. To support laminate selection, a Specific Impact Energy Index (SIEI) is introduced to rank configurations according to their elastic energy storage efficiency relative to the product of skin and stringer thicknesses. The tool is validated against both published experimental results and a finite element dynamic explicit model, demonstrating a good approximation of the impact response. It is then applied to identify the optimum laminate configuration for a super-stringer case study within the design space considered. Full article

Waste electronic components are valuable secondary resources containing various metals. Analyzing their elemental distribution is crucial for developing recycling methods. Micro- X-ray fluorescence (μ-XRF) is commonly used for this purpose, but traditional polychromatic X-ray excitation creates high background scattering. This masks trace element signals, impairing detection limits and accurate identification of minor valuable or hazardous elements. To address this, this study developed a monochromatic μ-XRF spectrometer using a low-power molybdenum-target X-ray tube. The system integrates polycapillary lenses for X-ray regulation and a flat crystal for monochromatization, producing a micron-sized monochromatic X-ray spot with high power density. This design eliminates scattered background from the primary continuous spectrum and enhances excitation efficiency by concentrating photon flux, enabling high-brightness monochromatic beams even at low tube power. The spectrometer was validated by analyzing a waste printed circuit board. High-resolution elemental mapping successfully revealed clear distribution patterns of major elements like copper, nickel, and iron, consistent with their physical structures. These images allowed intuitive differentiation of compositional differences across functional regions. This technique effectively overcomes the background interference caused by polychromatic excitation and is expected to further enhance the quality and reliability of elemental distribution imaging. It provides a powerful tool for formulating precise, scientific recycling strategies for waste electronics. Full article

In this paper, we consider a series of new compact A-π-D photoinitiators consisting of donor aromatic fragments (naphthalene, anthracene, phenanthrene, pyrene and perylene) and a strong acceptor tricyanoethylene group—aryltricyanoethylenes (ArTCNEs). Spectral, photophysical, and electrochemical characteristics of ArTCNEs are studied. One-photon (with LED@405 nm) and two-photon (λ = 780 nm, impulse duration of 100 fs) photopolymerization of PETA can be effectively initiated by ArTCNEs with the tertiary amine N,N-dimethylcyclohexylamine DMCHA and/or the iodonium salt diphenyliodonium chloride Iod. Based on results of experiments on photodegradation, photopolymerization and EPR spectroscopy, a photoinitiation mechanism of radical photopolymerization was proposed for two-component (AntTCNE/DMCHA) and three-component (AntTCNE/DMCHA/Iod) initiating systems. The composition containing PerTCNE/DMCHA as a photoinitiator demonstrated the best reactivity under two-photon nanolithography conditions: the polymerization threshold was 2 mW at a laser beam scanning speed of 100 μm/s, and the widest fabrication window of 11 mW was typical for it. As an example, 3D “cage” structures were fabricated using the AntTCNE-based composition, and the test structure resolution parameters, such as the minimum line width and the distance between lines of 80 and 400 nm, respectively, were achieved. MTT experiments with human dermal fibroblasts showed promising preliminary biocompatibility of the resulting polymers, which opens up possibilities for using the obtained materials in biological applications. Full article

Multilayer zirconias have recently been introduced as dental biomaterials to combine improved translucency with sufficient mechanical reliability by implementing yttria-driven gradients in phase composition. Such materials can be considered functionally graded ceramics, where local phase stabilization influences strength and crack resistance. However, manufacturer-specific gradient profiles and their structure–property relationships remain insufficiently characterized. This study investigated two commercially available multilayer zirconias with distinct gradient concepts: IPS e.max^® ZirCAD Prime (continuous gradient) and KATANA™ Zirconia YML (stepwise gradient). Ten equidistant sections along the blank height were analyzed using quantitative X-ray diffraction and Rietveld refinement to quantify zirconia phase fractions and estimate local Y₂O₃ content. Mechanical behavior was evaluated by biaxial flexural strength testing (ball-on-three-balls method) and fracture toughness testing using the chevron-notched beam technique. Both materials exhibited pronounced yttria- and phase-dependent gradients consistent with their reported layer designs. Regions with increased yttria content showed higher t″ fractions and reduced fracture toughness and strength, whereas deeper regions displayed increased mechanical performance associated with higher fractions of transformable tetragonal phase. These findings emphasize that multilayer zirconias exhibit spatially dependent mechanical properties, which should be considered in biomaterial selection and restoration design, particularly when balancing aesthetic demands and fracture resistance. Full article

Precise control of optical intensity distributions is important for beam shaping, optical trapping, and optical potential engineering. We implement a digital micromirror device (DMD)-based programmable beam-shaping platform for generating high-fidelity optical intensity distributions with user-defined geometries. The approach combines precise system calibration, Fourier-plane spatial filtering via an optimized pinhole, and an iterative intensity feedback algorithm to transform imperfect Gaussian input beams into flat-top, lattice, and composite intensity distributions. The feedback loop typically converges within seven iterations, producing highly uniform flat-top profiles with 98.7% uniformity (corresponding to a root-mean-square error (RMSE) of 1.3%). Systematic studies identify the optimal Fourier-plane aperture that balances diffraction suppression with optical throughput. These results demonstrate a practical route to programmable beam shaping and optical intensity control. Full article

SiSn alloys have attracted growing interest for group-IV bandgap engineering, although their epitaxial growth remains challenging due to the extremely low equilibrium solubility of Sn in Si. In this work, fully strained (pseudomorphic) SiSn epitaxial layers were grown on Si (001) substrates by means of molecular beam epitaxy. A systematic investigation reveals a strong inverse correlation between growth temperature and Sn incorporation efficiency. Despite a constant Sn flux, the incorporated Sn composition decreases from 5.5% to 3.2% as the growth temperature increases, indicating a pronounced temperature dependence of Sn incorporation. Reflection high-energy electron diffraction indicates a gradual transition of the growth from two-dimensional to three-dimensional with increasing film thickness. Structural characterization by means of X-ray diffraction, atomic force microscopy, and transmission electron microscopy confirms the pseudomorphic growth and smooth surface morphology and reveals twins and stacking faults near the surface region. These results establish a quantitative reference for SiSn growth kinetics and provide guidance for future studies of SiSn and SiGeSn alloys in silicon-compatible electronic and optoelectronic applications. Full article

This study aims to present a parametric analysis in the optimization problem for steel-concrete composite cellular beams with steel deck slabs. A comparative analysis was carried out considering two scenarios, namely, (i) in the first scenario, the slab span and applied loads were varied, adopting slab configurations from a manufacturer’s catalog for spans of 10 m to 20 m with a step of 2.5 m; (ii) in the second scenario, the same span and loading conditions were considered; however, slab optimization was performed by introducing reinforcement in order to evaluate the resulting impacts on the structural design. In both analyzed scenarios, the objective function was defined as the composite system’s CO₂ emissions. The design constraints were defined based on literature recommendations, and to solve the optimization problem, the Particle Swarm Optimization (PSO) algorithm was also adopted. The results demonstrate that the PSO algorithm was effective in identifying optimal solutions and that the introduction of slab reinforcement, combined with optimal design, led to CO₂ emission reductions of up to 25% at the highest load levels analyzed. Full article

This study investigates the residual stresses developed during the curing process of polymer fiber-reinforced composites and their influence on fracture behavior, particularly the initiation and propagation of interlaminar cracks. The main objective is to quantify how different curing histories, including incomplete cure, alter the spatial distribution of residual stresses and, in turn, affect the mode-I fracture response of carbon-fiber/epoxy laminates. A transient thermal–structural finite element framework incorporating an autocatalytic cure kinetics model was used to simulate the curing process and predict residual stress development in a unidirectional carbon-fiber/epoxy laminate with an edge crack, considering thermal, chemical, and geometric effects. The cure model was calibrated using isothermal differential scanning calorimetry data to determine the degree of cure under different thermal conditions. The key novelty of this work is the integration of a validated cure-kinetics-based curing simulation with fracture analysis, enabling direct correlation of thermal history and degree of cure with spatially varying residual stresses at the crack front and their effect on fracture toughness. Numerical load–displacement predictions were compared with double cantilever beam experimental results and showed good agreement for the curing profiles examined. The results demonstrate that residual stresses generated by different cure cycles, including hold conditions and incomplete curing, significantly influence fracture toughness. In particular, the incomplete-cure profile produced an approximately 40% reduction in toughness compared with profiles that achieved complete cure, highlighting the importance of cure history in determining final structural performance. Full article

To enable non-destructive quantitative characterization of constituent content in C/C–SiC ceramic-matrix composites, this study develops a physics-guided framework based on multispectral photon-counting X-ray detection. In practical photon-counting measurements, multispectral attenuation features are jointly distorted by detector-response non-idealities, including charge sharing, K-escape, and finite energy resolution, as well as by beam-hardening effects from the polychromatic X-ray source. To address this coupled problem, a Geant4 11.2-based detector-response model was incorporated into a unified correction workflow together with beam-hardening compensation, so that physically consistent multispectral attenuation vectors could be recovered for subsequent constituent inversion rather than merely for spectrum restoration. On this basis, a fine-grained theoretical database covering different SiC mass fractions was established, and quantitative constituent inversion was achieved by matching the corrected attenuation features to the database. Experimental results show that the proposed framework effectively suppresses thickness-dependent bias in attenuation measurements and yields an average relative error below 3% for pure aluminum. For C/C–SiC composites, the SiC mass fraction can be quantified with an accuracy better than 3 wt%. These results demonstrate that the proposed method provides a practical non-destructive route for constituent-content characterization in heterogeneous ceramic-matrix composites and is valuable for manufacturing quality control and in-service assessment. Full article

Steel–UHPC composite beams are widely used in bridge engineering due to their high strength, durability, and suitability for prefabricated construction. However, the mechanical performance of shear connectors in UHPC differs significantly, and the uniform use of a single connector type along the beam span may result in a mismatch between connector mechanical characteristics and regional force demands, leading to suboptimal force transfer and inefficient utilization of connector capacity along the beam span. While previous studies have mainly focused on the local behavior of individual connectors, a system-level design strategy considering regional force demands is still limited. This study proposes a system-level design method for combined shear connectors in steel–UHPC composite beams, in which headed stud connectors and trapezoidal composite dowel connectors are arranged according to bending moment distribution and interface shear demand, thereby integrating connector mechanical characteristics with the spatial variation in internal forces along the beam span. The design procedure includes shear span division, longitudinal interface shear calculation, and resistance verification of different connector types. The method is applied to a practical steel–UHPC composite beam in a long-span approach bridge. Results show that headed studs provide reliable uplift resistance and ductile behavior in negative bending regions, whereas composite dowel connectors are shown to be more suitable for shear-dominated positive bending regions due to their higher shear capacity and stiffness. The combined system ensures effective composite action under different stress states and reduces total connector steel consumption compared with a stud-only layout. The proposed approach advances connector design toward performance-oriented and system-level structural optimization, providing a practical framework for connector arrangement in steel–UHPC composite beams. Full article

Objective: To determine the most suitable core build-up materials based on their mechanical and physical properties, different resin based materials were evaluated for flexural strength (FS), flexural modulus (E), modulus of resilience (R), water sorption (WS), and solubility (SO). Materials and Methods: Three dual-cure resins (CosmeCore DC Automix, CCC; Clearfil DC Core Plus, CCP; MultiCore Flow, CMC) and two bulk fill composites (Filtek One Bulk Fill Restorative, BFO; Filtek Bulk Fill Flowable, BFF) were tested, with Filtek Supreme Ultra (FSU) as the control. All tests followed ISO 4049. Beam specimens (25 × 2 × 2 mm, n = 12) were used to determine FS and E after 24 h storage in 37 °C deionized water, using a three-point bending test. Disc specimens (15 × 1 mm, n = 5) were used for WS and SO by measuring mass changes before and after water storage. Data were analysed using one way ANOVA and Tukey post hoc tests (p < 0.05). Results: CCC exhibited the highest FS and lowest WS. BFF showed the lowest E, while BFO exhibited the highest R. FSU demonstrated the lowest FS and R, along with the highest WS. No significant differences in SO were observed among groups. Conclusions: The evaluated materials showed considerable variation in mechanical and physical properties. CCC and BFO demonstrated the most favourable performance, suggesting they are the most suitable candidates for core build up procedures among the materials tested. Full article

In response to the shortcomings still observed in polyethylene (PE)/ethylene-vinyl acetate (EVA)/styrene-butadiene-styrene (SBS) composite modified bitumen regarding storage stratification and low-temperature performance, this paper further introduces furfural extract, elemental sulphur, stabilisers and Z-6036 into this ternary system, and employs orthogonal design to screen the additive ratios. Tests were conducted on conventional physical properties, rotational viscosity, dynamic shear rheology and bending beam rheology, focusing on the material’s temperature sensitivity, rheological behaviour, low-temperature creep resistance and phase characteristics. The modification effects were analysed using fluorescence microscopy, scanning electron microscopy and infrared spectroscopy. Compared with the control group composed of 4% PE, 4% EVA and 2% SBS, the samples obtained from the orthogonal design showed an increase in elongation at 5 °C ranging from 52.5% to 213.9%; the difference in softening points decreased from 35.2 °C to a minimum of 0.1 °C, indicating improved storage stability. The temperature sensitivity of all sample groups was reduced, with the optimal group achieving a VTS of −0.4413, representing a 46.7% improvement over the control group. At −12 °C, the m-values of all nine orthogonal samples were higher than those of the control group, with seven groups reaching m ≥ 0.3, indicating improved low-temperature stress relaxation capability. A comprehensive analysis of the experimental results indicates that the selected chemical additives are beneficial for optimising the dispersion state and compatibility of the SBS/PE/EVA ternary modified bitumen, whilst also balancing rheological properties and low-temperature crack resistance to a certain extent. Microscopic and spectroscopic analyses further suggest that internal interactions within the system have been enhanced and the phase distribution has become more uniform; however, the current evidence is insufficient to conclusively determine that a specific form of chemical cross-linking reaction has occurred. Full article

Steel–concrete composite beams are widely used in building and bridge engineering; however, the impact response of Steel–Coarse Aggregate–Ultra-High Performance Concrete (Steel–CA–UHPC) composite beams remains insufficiently quantified, and no beam-specific dynamic capacity formula is available. To address this gap, companion static testing and drop-weight impact tests were performed on full-scale simply supported steel–CA–UHPC composite beams under single and repeated impacts, followed by development of a strain-rate-dependent dynamic increase factor (DIF) model and a capacity prediction framework. The companion static specimen reached 448 kN, whereas the 5 m impact cases produced peak forces of 930.0–940.4 kN, corresponding to 2.08–2.10 times the static level, with the initial peak forming within 1.0–1.1 ms. Dynamic failure was marked by rapid mid-span cracking of the CA–UHPC slab and brittle shear fracture of studs, while repeated impacts mainly accelerated cumulative damage before the final high-energy strike. Static–dynamic displacement comparison further revealed much more abrupt deformation concentration under impact loading. A revised static capacity formula reduced the prediction error from 4.46% for the code-based method and 1.00% for the literature model to 0.74%. Combined with the fitted DIF–strain-rate relation, the proposed framework reproduced the measured dynamic capacities with errors of −4.63% to 9.75%. The study provides member-level evidence and a practical DIF-based method for evaluating the impact resistance of steel–CA–UHPC composite beams. Full article

The increasing occurrence of antibiotic residues in poultry meat represents a serious food safety concern associated with antimicrobial resistance and potential risks to human health. This study investigated the effects of electron beam irradiation on antibiotic residues and nutritional quality parameters of poultry meat. All experiments and data collection were carried out in 2025. Fresh poultry samples were irradiated using an ILU-10 pulsed linear electron accelerator at doses of 2, 4, 6, 8, and 10 kGy. Antibiotic residues were determined by HPLC-DAD, amino acid composition was analyzed using HPLC, and fatty acid profiles were evaluated by gas chromatography. Electron beam irradiation produced significant dose-dependent changes in the chemical composition of poultry meat. Total amino acid content decreased progressively with increasing irradiation dose, with reductions of up to 60–73% at 10 kGy depending on tissue type. Branched-chain and essential amino acids showed similar trends. Fatty acid analysis revealed a shift toward higher proportions of saturated fatty acids and a decline in monounsaturated and polyunsaturated fatty acids. The PUFA/SFA ratio decreased from 0.48 in control samples to 0.25 at 10 kGy. Tetracycline residues were not detected in any samples, whereas chloramphenicol residues were present in control meat but were progressively reduced after irradiation and became undetectable at doses ≥ 8 kGy. These results demonstrate that electron beam irradiation can effectively reduce antibiotic residues in poultry meat; however, higher irradiation doses may significantly alter amino acid and lipid composition. Therefore, optimization of irradiation parameters is necessary to balance improvements in food safety with the preservation of nutritional quality for the production of safe and sustainable food products. Optimization of irradiation parameters is therefore necessary to balance food safety benefits with preservation of nutritional quality. Furthermore, this research contributes to the achievement of Sustainable Development Goal (SDG) 2, while the obtained results also support SDG 3 by promoting safer food systems and protecting public health. Full article

As the trend towards larger wind turbines continues, the increasing length of wind turbine blades imposes higher demands on their structural properties. Long flexible wind turbine blades at the hundred-meter scale now typically employ composite materials. In recent engineering practice, wind turbine blade accidents occur frequently. As a result, the method for optimizing composite material layup of large wind turbine blade is attracting attention from both researchers and engineers. In the current research, thin-walled beam structural theory combined with pattern search algorithms are utilized to optimize the composite layup of large wind turbine blade structures under different loading cases. Utilizing the proposed optimization algorithm, the blade structure is capable of reducing weight while satisfying structural strength requirements. Based on the proposed optimization method, the impact of external loading on the structural optimization results are compared. The trailing edge section on the transition region is critical for wind turbine blade structural design. Increasing the thickness of the layup on spar caps is a feasible way to resist the flapwise loading. These findings provide valuable guidance for the structural design optimization of ultra-long flexible blades in large wind turbines and have positive significance for the safety and economy of wind farm operation, offering a more scientific, efficient, and practical approach to their design. Full article