Search Results (427)

Geological storage of carbon dioxide in faulted sedimentary basins requires suitability evaluation methods that can address uncertainty, indicator interaction, and limited data availability. This study develops an integrated evaluation framework that combines the Analytic Hierarchy Process, triangular fuzzy numbers, and the Choquet fuzzy integral to assess basin-scale geological carbon dioxide storage suitability. The framework enables structured weight determination, explicit representation of expert uncertainty, and non-additive aggregation of interacting indicators. The evaluation focuses on deep saline aquifers in the Jianghan Basin and is based on seventeen indicators covering geological, structural, hydrogeological, and socio-economic conditions. The assessment integrates seismic interpretation, geological mapping, logging data, and published datasets, and is conducted at the level of tectonic units to support basin-scale screening. The method is applied to the Jianghan Basin using seventeen geological, structural, hydrogeological, and socio-economic indicators. The results indicate that burial depth primarily acts as a threshold condition, whereas caprock sealing capacity, fault system development, and hydrogeological stability dominate suitability differentiation. Interaction analysis reveals pronounced substitution effects among geological indicators, indicating that strong performance in key safety-related factors can compensate for less favorable secondary constraints during early-stage screening. The Qianjiang Sag and Jiangling Sag are identified as the most suitable storage units. The proposed framework provides a transparent and robust tool for basin-scale screening in structurally complex, data-limited sedimentary basins. Full article

The South Sakhalin mud volcano (Sakhalin Island, Russia) emits HCO₃-Cl/Na-Mg water, emanates CO₂ prevailing over CH₄ in the gas phase, and extrudes mud bearing five carbonate mineral species. The study focuses on the distribution, diversity, and origin of the carbonate minerals from the mud volcano (MV) ejecta, in terms of carbon cycle processes. The data presented include a synthesis of field observations, compositions of MV gases and waters, chemistry of carbonate minerals, as well as stable isotope geochemistry of MV waters (δ¹³C, δD, and δ¹⁸O) and carbonates (δ¹³C and δ¹⁸O). The sampled MV waters are isotopically heavy, with δ¹⁸O = +5.7‰ to +7.5‰ VSMOW, δD = −18.0‰ to −11.0‰ VSMOW, and ¹³C (δ¹³C_DIC = +6.9‰ to +8.1‰ VPDB). This composition may be due to the dilution of basinal water with dehydration water released during the diagenetic illitization of smectite. Carbonates in the sampled mud masses belong to three genetically different groups. Mg-rich siderite, (Fe_0.54–0.81Mg_0.04–0.30Ca_0.05–0.23Mn_0.00–0.08)CO₃, disseminated in abundance throughout the mud masses, coexists with common calcite and sporadic ankerite. The trace-element chemistry of Mg-siderite, as well as the oxygen (δ¹⁸O = +34.4‰ to +36.8‰ VSMOW) and carbon (δ¹³C = −1.3‰ to +0.6‰ VPDB) isotopic signatures, confirms its authigenic origin. Siderite formed during early diagenesis of the Upper Cretaceous sandy and clayey marine sediments mobilized by mud volcanism in the area. Another assemblage, composed of dawsonite, siderite, and vein calcite (±kaolinite), represents altered arkose sandstones found as few fragments in the mud. This assemblage may be a marker of later CO₂ flooding into the sandstone aquifer in the geological past. The trace-element chemistry, particular morphology, and heavy C (δ¹³C = +5.5‰ to +7.0‰ VPDB) and O (δ¹⁸O = +39.1‰ to +39.5‰ VSMOW) isotope compositions indicate that aragonite is the only carbonate species that is related to the current MV activity. It crystallized in a shallow reservoir and was maintained by CO₂ released from rapidly ascending liquefied mud and HCO₃-Cl/Na-Mg-type of MV waters. Full article

Water from mountain regions is a crucial natural resource because of its major economic, social, and environmental significance. Wildfires may disrupt the normal functioning of the hydrological cycle, limiting water resources for nearby areas and degrading water quality in mountainous regions as contaminants enter water systems from the burning of vegetation and soil. In August 2022, the Serra da Estrela mountain, situated in the Mediterranean biogeographical region, was affected by a large wildfire that consumed 270 km² of the Serra da Estrela Natural Park, often resulting in severe vegetation burn, although the soil burn severity was low to moderate in most of the area. The research objective is to assess the impact of this wildfire on the hydrogeochemistry of groundwater and surface water in the Manteigas-Covão da Ametade sector of Serra da Estrela in the context of a wildfire with limited soil burn severity. Groundwater and surface water samples were collected from October 2022 to September 2023 and were analyzed for pH, Total Organic Carbon, electrical conductivity, major ions, potentially toxic elements, iron (Fe), and Polycyclic Aromatic Hydrocarbons. A stormy event in mid-September 2022, occurring before the first sampling campaign, removed most of the ash layer and likely caused transient hydrogeochemical changes in streams. However, the analytical results from the sampled waters revealed that the post-wildfire hydrogeochemical effects are not evident. In fact, the hydrogeochemical changes observed in groundwater and surface water appear to be primarily influenced by the regular hydrological behaviour of aquifers and streams. The low to moderate soil burn severity, the high soil hydrophobicity, and the temporal distribution of precipitation explain why the hydrogeochemistry was primarily influenced by groundwater flow paths, the types and weathering of local lithologies, soil types, dilution effects following wet periods, and seasonal changes in the tributaries feeding into streams, rather than by post-wildfire effects. These outcomes provide valuable insights for water resource management and for developing strategies to mitigate wildfire impacts in mountainous environments. Full article

Springs fed by carbonate-fractured/karst aquifers support spring-dependent ecosystems and provide drinking water in the Italian Apennines, where complex hydro-meteorological environments are increasingly affected by prolonged droughts. The aim of this study was to investigate the hydrogeological behavior of two springs (Alzabove and Lupa) on the mountain ridge of Central Italy, using monthly reanalysis datasets to support sustainable water management. The Master Recession Curves based on the 1998–2023 recession periods highlighted a slightly higher average recession coefficient for Lupa (α = −0.0053 days⁻¹) than for Alzabove (α = −0.0020 days⁻¹). The hydrogeological settings of the Lupa recharge area led to a less resilient response to prolonged, extreme droughts as detected via the Standardized Precipitation-Evapotranspiration Index (SPEI) computed at different time scales using ERA-5 Land datasets. The SPEI computed at a 6-month scale (SPEI₆) showed the best correlation with monthly spring discharge, with a 1-month delay time. A parsimonious linear regression model was built using the antecedent monthly spring discharge values and SPEI₆ as independent variables. The best modeling performance was achieved for the Alzabove spring, with some overestimation of spring discharge during extremely dry conditions (e.g., 2002–2003 and 2012), especially for the Lupa spring. The findings are encouraging as they reflect the use of a simple tool developed to support decisions on the sustainable management of springs in mountain environments, although issues related to evapotranspiration underestimation during extreme droughts remain. Full article

Northwestern Jiangxi Province is rich in metasilicic acid (as H₂SiO₃) mineral water resources. Investigating their hydrogeochemical characteristics and formation mechanism is crucial for the rational utilization of water resources and the sustainable development of the local mineral water industry. Taking the Taoping water source area in northwestern Jiangxi as a case study, 11 sets of groundwater and surface water samples were systematically collected. By comprehensively applying mathematical statistics, ionic ratios, and isotopic analyses, the hydrogeochemical characteristics and formation processes of metasilicic acid-type mineral water were examined. The results indicate that: (1) The mineral waters in the area are weakly alkaline and belong to the metasilicic acid type, with concentrations ranging from 22.0 to 67.0 mg/L, of which 75% exceed 30 mg/L. (2) The primary hydrochemical types are HCO₃⁻–Ca·Na, HCO₃⁻–Ca·Mg, and HCO₃⁻–Ca. Analysis of stable isotopes (δ¹⁸O and δ²H) and tritium (³H) indicates that metasilicic acid mineral water is primarily recharged by atmospheric precipitation, with an apparent groundwater age of approximately 60 years. (3) The enrichment of metasilicic acid primarily results from the weathering and leaching of silicate minerals, coupled with cation exchange. K⁺ and Na⁺ are mainly derived from silicate minerals such as feldspars and halite, whereas Ca²⁺ and Mg²⁺ originate primarily from carbonate minerals like calcite and dolomite. During recharge, atmospheric precipitation infiltrates the aquifer, dissolving aluminosilicate and siliceous minerals in the surrounding rocks, thereby releasing metasilicic acid into the groundwater and ultimately forming the metasilicic acid-type mineral water. Full article

It is a challenge in experimental studies today to accurately predict the trapping mechanisms in saline aquifers that influence the long-term CO₂ storage capacities. The inability in current experimental studies to quantify the effects of combined processes of solubility, hysteresis, and mineralization as a means of affecting saline aquifer properties that influence CO₂ trapping mechanisms makes this topic interesting. A systematic framework in CMG-GEM compositional simulation studies is proposed in this article to assess the effects of gradually modelled trapping mechanisms on CO₂ storage performance. Simulation studies are conducted under identical constraints, trapping mechanisms, as well as operational factors in a sequential process that activates (i) solubility, (ii) solubility + hysteresis, and (iii) solubility + hysteresis + mineralization. The findings demonstrate distinct differences in trapping process behaviors as well as simulation stability under various modes: hysteresis effects largely improve immobile reserves as well as decrease plume migration, and, on the other hand, mineralization adds long-term dynamics of capacity increase as well as porosity-permeability alterations, especially in carbonate reservoirs. Through long-term post-injection simulations (up to 1000 years), the findings demonstrate that various trapping processes trigger over distinct time periods—years for immobile reserves, decades for dissolution, and centuries in the case of mineralization. This contribution is able to point out the computational efficiency as well as defective model behavior of concern to various physics levels, providing a practical guide to modelers in making a well-informed decision on what constitutes a minimum set of physics in long-term trustworthy CO₂ storage. Full article

Utilizing saline aquifers for carbon mineralization has proven to be a reliable approach for CO₂ storage. However, less attention has been given to CO₂ mineralization and geomechanical response at engineering durations and spatial scales. The objective of the study is to evaluate the feasibility of a potential CO₂ sequestration site in the Ordos Basin, located at a depth of approximately 1100 m, using the CMG-GEM numerical simulator. A coupled hydraulic–mechanical–chemical model was formulated, accounting for multiphase fluid flow, geochemical reactions, and geomechanical response. The simulation results indicated the following: (1) When CO₂ is injected into a saline formation, it can react with minerals. These chemical reactions may lead to the precipitation of certain minerals (e.g., calcite, kaolinite) and the dissolution of others (e.g., anorthite), potentially affecting the porosity and permeability of the storage formation; however, the study found that the effect on porosity is negligible, with only a 1.2% reduction observed. (2) The extent of ground uplift caused by CO₂ injection is strongly influenced by the injection rate. The maximum vertical ground displacements after 25 years is 6.1 cm at an injection rate of 16,000 kg/day; when the rate is increased to 24,000 kg/day, the maximum displacement rises to 9.4 cm, indicating a 54% increase. Full article

Water quality assessment is crucial for the sustainable use and management of groundwater resources. This study was carried out in the irrigated plains of Vehari District, Punjab, Pakistan, to evaluate groundwater suitability for a managed aquifer recharge (MAR) project. Twenty groundwater samples were collected in June 2021 from an area of 1522 km² and analysed for major physicochemical parameters including electrical conductivity (EC), total dissolved solids (TDS), pH, turbidity, calcium (Ca), magnesium (Mg), chloride (Cl), alkalinity (Alk), bicarbonate (HCO₃⁻), hardness, potassium (K), sulphate (SO₄²⁻), sodium (Na), and nitrate (NO₃⁻). Water quality was assessed using WHO and PID standards, alongside derived hydrochemical indices such as sodium percentage (%Na), Kelly’s ratio (KR), sodium adsorption ratio (SAR), residual sodium carbonate (RSC), and the water quality index (WQI). The dataset was interpreted using geo-statistical, geospatial, multivariate, and correlation analyses. Cations and anion dominance followed the order Na⁺ > Ca²⁺ > Mg²⁺ > K⁺ and HCO₃⁻ > SO₄²⁻ > Cl⁻ > NO₃⁻. According to the WQI analysis, 35% of the water samples are classified as “poor,” half (50%) as “very poor,” and the remaining 15% as “unsuitable” for drinking purposes. However, irrigation suitability indices confirmed that groundwater is generally acceptable for agricultural use, though unfit for drinking. The outcomes of this study provide essential insights for groundwater management in the region, where the Punjab Irrigation Department (PID) has initiated a MAR project. Considering that the irrigation sector is the major groundwater consumer in the area, the compatibility of groundwater and surface water quality supports the implementation of MAR to enhance agricultural sustainability. Full article

The Upper Olifants River Catchment in the Mpumalanga Province has experienced water contamination in the past few decades due to existing land use and land cover. This study employed hydrochemical and environmental isotopes to investigate the water quality and understand the sources of contaminants within tertiary catchments B11F and B11G of the Upper Olifants River Catchment. The hydrochemistry results indicate that the shallow weathered aquifers are more susceptible to contamination with major pollutants being TDS, SO₄, Ca, Mg, Fe, and Mn, which can be associated with the geology and coal mining activities in the area. Additionally, the environmental isotopes suggest that the climate, fractionation, and elevation play a major role in the evolution of the water. The correlation of major ion ratios suggests that processes such as silicate and carbonate weathering and cation exchange reactions play a significant role in making the water vulnerable to pollution. In general, the overall water quality index of the study area indicates poor water quality falling within the range of 0 < WQI ≤ 44, making it undesirable for domestic use. Furthermore, approximately 35% of the samples are not suitable for irrigation purposes based on the SAR and PI. Full article

Understanding hydrochemical evolution and apportioning pollution sources are prerequisites for effective groundwater protection at the regional scale; nevertheless, the governing processes and anthropogenic drivers in arid regions remain poorly constrained. Here, we present a comprehensive geochemical survey of the Datong River Basin, a representative arid catchment in north-western China. Thirty-seven groundwater samples were analyzed with hydrochemical methods and Positive-Matrix Factorization (PMF) to delineate natural controls and contaminant sources. Results showed that the aquifer is dominated by HCO₃–Ca(Mg) water controlled predominantly by silicate and carbonate weathering, modified locally by evapo-concentration and human activities. Water-quality indices classify 70.3% of the samples as excellent, but spatially restricted degradation is evident. PMF resolved three independent sources: a natural end-member enriched in Mn, Na⁺ and Cl⁻; a mixed source reflecting domestic wastewater, agricultural fertilizers and rock weathering; and an industrial source dominated by Fe. The mixed source contributes most major ions and chemical oxygen demand (COD), whereas the industrial source accounts for 75.7% of total Fe. These findings provide a robust scientific basis for groundwater management and pollution mitigation in arid regions under similar hydrogeological settings. Full article

District heating networks (DHNs) are a key technology in the transition toward sustainable heat supply, increasingly integrating renewable sources and thermal energy storage. High-temperature aquifer thermal energy storage (HT-ATES) can enhance DHN efficiency by shifting heat production over time, potentially reducing both costs and greenhouse gas emissions. However, most life cycle assessments (LCAs) remain static, rely on average data, and neglect temporal dispatch dynamics and marginal substitution among heat sources for environmental evaluation. This study introduces a dynamic life cycle inventory framework that explicitly links HT-ATES-operation scheduling in DHNs with marginal life cycle data. The framework expands system boundaries to capture time-varying changes in heat composition, combines a district heating merit-order representation (distinguishing must-run and flexible capacities) with linear programming to determine least-cost dispatch, and translates marginally displaced technologies into environmental and economic consequences. Foreground inputs are derived from an existing third-generation DHN (heat demand, generation assets, efficiencies) and publicly available energy carrier cost data and are linked to consequential background inventory datasets (ecoinvent). The framework is demonstrated for one year of operation for an HT-ATES concept with 50 GWh of injected heat. Hourly resolved results identify the marginally displaced technologies and indicate annual reductions of 5.86 kt CO₂e alongside cost savings of EUR 1.09 M. A comparison of alternative operation schedules shows strong sensitivity of both economic and environmental performance to operational strategy. Overall, the proposed framework provides a replicable and adaptable basis for consequential assessment of HT-ATES operation in DHNs and supports strategic decision-making on seasonal thermal storage deployment in low-carbon heat systems. Full article

Groundwater wells are essential for sustaining biodiversity in arid and hyper-arid regions. Wells are easily affected by external disturbances, particularly in hyper-arid regions like the Siwa Oasis, where the environmental variables influencing groundwater communities remain understudied. This study assessed the quality of several groundwater wells and agricultural drains based on the physical, chemical and hydrochemical parameters. The results classified the wells and drains into three distinct groups: (1) highly mineralized, carbonated systems with high concentrations of potassium, calcium, sodium, magnesium, chloride, and sulfate, and an average electrical conductivity (EC) of 12.01 mS/cm; (2) low-mineralized wells with an average EC of 2.15 mS/cm; and (3) a moderate one averaging 7.77 mS/cm. The major ions were dominated by Na⁺ (59.3%) and Mg²⁺ (26.8%) for cations, and Cl⁻ (79.1%) and SO₄²⁻ (13.4%) for anions in meq/L. Collectively, the evaluation based on total dissolved solids (TDS), sodium percentage (Na%), sodium adsorption ratio (SAR), and the US Salinity Laboratory (USSL) diagram revealed that about 80% of the analyzed wells are unsuitable for irrigation, with only three wells (W03, W12, and W16) deemed suitable for drinking. These findings confirmed a critical vulnerability of the oasis ecosystem. The uncontrolled and extensive use of finite, non-renewable aquifers for agricultural and other purposes is directly exacerbating water salinization and soil sodicity, posing a threat to the future sustainability of the oasis’s water resources. Full article

Shale gas extraction is underway in the Karoo Basin. Previous oil and gas explorers abandoned several wells, and the abandonment statuses of these wells are unknown. Critically, improperly abandoned wells can provide a pathway for the leakage of stray gas into shallow aquifers and degrade water quality. To understand the abandonment integrity risk posed by these wells, a qualitative risk model was developed to assess the likelihood of well-barrier failure leading to a potential leak. The potential leak paths identified include zones with cement losses during grouting, casing corrosion, cement channels, failure to case and cement risk zones, uncased and uncemented sources, uncemented annuli, and unplugged wells. To confirm whether these wells are leaking, geochemical tracing of stray gas was integrated. Eleven of the fifty samples collected had dissolved hydrocarbon gas concentrations that were high enough to use isotopic analysis to determine the source. The results revealed microbial gas via fermentation and carbon dioxide reduction, thermogenic gas, and geothermal gas, as evidenced by larger δ¹³C₁ values and isotopic reversals associated with dolerite intrusions. The thermogenic-type gas detected in legacy abandoned wells and <1 km water boreholes adjacent to these wells serves as evidence that the downhole plugs did not maintain their integrity or were improperly plugged, whereas the thermogenic gas detected in >1 km water boreholes indicates leakage contamination due to natural fracture pathways. The presence of thermogenic gas in legacy wells and in groundwater boreholes <1 km from legacy wells implies that shale gas extraction using hydraulic fracturing cannot be supported in these situations. However, using safety buffer zones greater than 1 km from the legacy wells for shale gas drilling could be supported. Full article

The Tarim Basin is currently the largest petroliferous basin in China, with hydrocarbons primarily hosted in Ordovician marine carbonate paleokarst fracture–vug reservoirs—a typical example being the Tahe Oilfield located in the northern structural uplift of the basin. The principle of “the present is the key to the past” serves as a core method for studying paleokarst fracture–vug reservoirs in the Tahe Oilfield. The deep and ultra-deep carbonate fracture–vug reservoirs in the Tahe Oilfield formed under humid tropical to subtropical paleoclimates during the Paleozoic Era, belonging to a humid tropical–subtropical paleoepikarst dynamic system. Modern karst types in China are diverse, providing abundant modern karst analogs for paleokarst research in the Tarim Basin. Carbonate regions in Eastern China can be divided into two major zones from north to south: the arid to semiarid north karst and the humid tropical–subtropical south karst. Karst in Northern China is characterized by large karst spring systems, with fissure–conduit networks as the primary aquifers; in contrast, karst in Southern China features underground river networks dominated by conduits and caves. From the perspective of karst hydrodynamic conditions, the paleokarst environment of deep fracture–vug reservoirs in the Tarim Basin exhibits high similarity to the modern karst environment in Southern China. The development patterns of karst underground rivers and caves in Southern China can be applied to comparative studies of carbonate fracture–vug reservoir structures in the Tarim Basin. Research on modern and paleokarst systems complements and advances each other, jointly promoting the development of karstology from different perspectives. Full article

This study evaluates the technical, design, and economic feasibility of large-scale hydrogen storage in deep water-bearing geological formations (aquifers), presenting it as a scalable solution for seasonal energy storage within the European Union’s decarbonization framework. A techno-economic model was developed for a 1 BCM facility, integrating geomechanical, microbial, and thermodynamic criteria. The results indicate a recoverable hydrogen fraction of 70–85%, with dissolution and microbial conversion losses limited to below 10% under optimized operational regimes. Geochemical and microbiological modelling demonstrated that sulfate-reducing and methanogenic bacterial activity can be reduced by 80–90% through controlled salinity and pH management. The proposed design, incorporating high-permeability sandstone reservoirs (100–300 mD), hydrogen-resistant materials, and fibre-optic monitoring ensures stable containment at 60–100 bar pressure and enables multi-cycle operation with minimal leakage (<0.05% per year). Economically, the baseline Levelized Cost of Hydrogen Storage (LCOHS) for aquifers was found to be ~0.29 EUR/kWh, with potential reductions to ~0.18 EUR/kWh through optimized drilling, modularized compression systems, and microbial mitigation. The lifecycle carbon footprint (0.20–0.36 kg CO₂-eq/kg H₂) is competitive with other geological storage methods, while offering superior scalability and strategic flexibility. Full article