Search Results (36)

This study investigated the production of biodiesel from canola oil, the formulation of sustainable ternary fuel blends with diesel and alcohol (ethanol or propanol), and the experimental and machine learning-based modeling of their physical properties, including density and viscosity over a temperature range of 10 °C to 40 °C. Biodiesel was synthesized via alkali-catalyzed transesterification (6:1 methanol-to-oil molar ratio, 0.5 wt % NaOH of oil) and blended with diesel and alcohols (ethanol and propanol) in varying volume ratios. The experimental results revealed that blend density decreased from 0.8622 g/cm³ at 10 °C to 0.8522 g/cm³ at 40 °C for a blend containing ethanol. Similarly, the viscosity showed a significant reduction with temperature, e.g., the blend exhibited a viscosity decline from 8.5 mPa·s at 10 °C to 7.2 mPa·s at 40 °C. Increasing the alcohol or diesel content further reduced density and viscosity due to the lower intrinsic properties of these components. The machine learning models, Gaussian process regression (GPR), support vector regression (SVR), artificial neural networks (ANN), and decision tree regression (DTR), were applied to predict the properties of these blends. GPR demonstrated the best predictive performance for both density and viscosity. These findings confirm the strong potential of GPR for the accurate and reliable prediction of fuel blend properties, supporting the formulation of alternative fuels optimized for diesel engine performance. These aspects contribute new insights into modelling strategies for sustainable fuel formulations. Full article

This study examines the evolving role of canola biofuel in achieving energy security, analyzing its historical significance, current challenges, and prospects. Once a dominant feedstock for biodiesel production in Europe, canola biofuel is facing a decline in relevance due to the emergence of second- and third-generation biofuels, which offer greater economic and environmental advantages. The research highlights key factors influencing this shift, including high production costs, resource-intensive cultivation, and suboptimal life cycle environmental performance. Through correlation and causality analyses, the study finds no definitive relationship between oil prices and the frequency of scientific publications on canola biofuels, suggesting other drivers, such as policy and technological advancements, play a more significant role. Despite its diminishing prominence, canola biofuel retains value in energy diversification and rural agricultural support, due to geographic, policy, and investment constraints. The findings emphasize the need for prioritizing the development of more sustainable and efficient biofuel technologies to address global energy and environmental challenges. Full article

This study investigates the improvement of combustion performance, engine emissions, energy, exergy, and thermodynamic efficiencies by adding oxygenated additives to diesel/biodiesel blends. Five different fuel mixtures (D100, D80B20, D50B50, D30B50S20, and D30B50G20) were tested in a diesel engine. The positive effects of the additives on engine efficiency became evident. In terms of combustion performance, the maximum in-cylinder pressure was observed with D100; however, a decrease of 11.51% was noted with the D50B50 mixture, while an increase of 7.51% was achieved with the addition of butyl diglycol. The addition of butyl diglycol also increased the heat release rate by 34.36%. Regarding exhaust emissions, the D30B50G20 fuel produced the lowest CO emissions (0.02%), while HC emissions decreased by 80% compared to D100. Smoke opacity was also found to be lower with D30B50G20. However, these additives led to a 2.65% decrease in certain performance metrics. On the other hand, the sustainability analysis revealed that the most efficient fuel mixture was D30B50G20. Full article

Biodiesel was produced via transesterification of canola oil in the presence of a silica xerogel catalyst with deposited gold nanoparticles. The silica-gold catalyst was produced in situ, where gold metal was added to a sodium silicate solution; subsequently, gold nanoparticles were synthesised within the solution. The sodium silicate-gold nanoparticles solution was then turned into a silica-gold gel at pH 8.7 and later dried to form silica-gold nanoparticles xerogel. The produced silica-gold nanoparticles xerogel was characterised by X-ray diffraction (XRD), X-ray fluorescence (XRF), transition electron microscopy (TEM), and nitrogen physisorption. The gel had a silica content of 91.6 wt% and a sodium content of 6.4 wt%, with the added gold content being 99.5% retained. The biodiesel produced in the presence of silica-gold nanoparticles xerogel was characterised by gas chromatography-mass spectroscopy (GC-MS) and its physical properties, such as density, kinematic viscosity, flash point, pour point, and cloud point, were also determined. The silica-gold nanoparticles xerogel catalyst remained solid throughout its usage without leaching into the reaction medium. The produced biodiesel contained mostly monounsaturated fatty acid methyl esters and had a yield of 99.2% at optimum reaction conditions. Full article

Edible oils are one of the renewable sources that enable the possibility of producing biodiesel sustainably. The transesterification of canola oil with methanol using cesium-modified phosphotungstic acid (Cs_2.5H_0.5PW₁₂O₄₀) as a heterogeneous catalyst was studied. Reaction conditions, specifically reaction time, catalyst loading, and the ratio of methanol to canola oil, were systematically explored. The canola oil conversion reached 55% at room temperature after 24 h. The reusability tests showed that the conversion of canola oil to biodiesel was maintained. Full article

Environmental pollution caused by marine engines fueled with fossil fuels is a matter of growing significance. The search for renewable and clean energy sources and improvements in the way fossil fuels are burnt aims to reduce the environmental impact of these engines. For this purpose, fatty acid methyl esters were produced from pure canola oil using KOH-assisted methanol-based transesterification with a maximum yield of 90.68 ± 1.6%. The marine engine’s model was created with CONVERGE software, followed by experimental verification. This paper examines the blended fuel characteristics of a diesel engine with biodiesel blends (0%, 5%, 10%, and 15%) at different loads of engines (50%, 75%, and 100%). It also explores the variation in these characteristics of B10 (10% biodiesel–diesel blends) at three different load conditions and four different EGR rates (0%, 5%, 10%, and 15%). The results indicate that the addition of biodiesel to diesel fuel reduces CO, HC, and soot emissions, while increasing NO_x emissions. Additionally, the EGR rate decreases NO_x emissions but results in higher levels of soot, CO, and HC emissions. Finally, response surface methodology was used to elicit the engine’s characteristics. It was determined that the optimum experimental operating conditions were 100% engine load, 6.9% biodiesel addition, and 7.7% EGR. The corresponding BTE, BSFC, NO_x, and HC emissions were 38.15%, 282.62 g/(kW-h), 274.38 ppm, and 410.37 ppm, respectively. Full article

Diesel exhaust particles (DEPs) contribute to air pollution exposure-related adverse health impacts. Here, we examined in vitro, and in vivo toxicities of DEPs from a Caterpillar C11 heavy-duty diesel engine emissions using ultra-low-sulfur diesel (ULSD) and biodiesel blends (20% v/v) of canola (B20C), soy (B20S), or tallow–waste fry oil (B20T) in ULSD. The in vitro effects of DEPs (DEP_ULSD, DEP_B20C, DEP_B20S, and DEP_B20T) in exposed mouse monocyte/macrophage cells (J774A.1) were examined by analyzing the cellular cytotoxicity endpoints (CTB, LDH, and ATP) and secreted proteins. The in vivo effects were assessed in BALB/c mice (n = 6/group) exposed to DEPs (250 µg), carbon black (CB), or saline via intratracheal instillation 24 h post-exposure. Bronchoalveolar lavage fluid (BALF) cell counts, cytokines, lung/heart mRNA, and plasma markers were examined. In vitro cytotoxic potencies (e.g., ATP) and secreted TNF-α were positively correlated (p < 0.05) with in vivo inflammatory potency (BALF cytokines, lung/heart mRNA, and plasma markers). Overall, DEP_ULSD and DEP_B20C appeared to be more potent compared to DEP_B20S and DEP_B20T. These findings suggested that biodiesel blend-derived DEP potencies can be influenced by biodiesel sources, and inflammatory process- was one of the potential underlying toxicity mechanisms. These observations were consistent across in vitro and in vivo exposures, and this work adds value to the health risk analysis of cleaner fuel alternatives. Full article

Progressive and increasingly noticeable climate change is forcing the search for new energy sources to reduce greenhouse gas emissions, especially carbon dioxide. One way to reduce greenhouse gas emissions is by gradually replacing fossil fuels with biofuels. The authors of this work addressed the production of second-generation biofuel. The purpose of this study was to produce second-generation biodiesel from babassu palm oil (BBuE) and first-generation biodiesel from rapeseed oil (RME), to study their properties, and to determine the effect of the addition of these biodiesels to diesel fuel on selected properties of “B” fuels that affect the fuel–air mixture formation process and the combustion process. Biodiesel from babassu oil was produced because it is non-edible and has a different composition than canola oil. Then, fuels were prepared that were mixtures of diesel oil and biodiesel containing from 10 to 40% (v/v) BBuE or RME (B10, B20, B30, and B40).Tests were conducted on selected physicochemical properties of the obtained fuels. “B” fuels prepared with BBuE and DF were shown to have more favorable fuel properties than those obtained from RME and DF. Fuels that are blends of BBuE and DF have slightly higher heating values, higher cetane number values, a more favorable distillation curve, lower dynamic viscosity values as a function of temperature, and marginally lower flash point values compared to the corresponding blends of RME and DF. Esters with shorter molecules have been shown to have more favorable fuel properties. Full article

The environmentally sustainable production of biodiesel is important for providing both a renewable alternative transportation fuel as well as a fuel for power generation using diesel engines. This research evaluates the use of inexpensive catalysts derived from waste materials for converting triglycerides in seed oils into biodiesel composed of fatty acid methyl esters. The performance of CaO catalysts derived from the shells of oysters, mussels, lobsters, and chicken eggs was investigated. The shell-derived powders were calcined with and without the addition of zinc nitrate at 700–1000 °C for 4 h to yield CaO whereas the CaO-ZnO mixed catalyst were prepared by wet impregnation followed by calcination at 700 °C. The catalysts were characterized by XRF, XRD, TGA, SEM, FTIR and GC-MS. The CaO-ZnO catalysts showed slightly better conversion efficiency compared to CaO catalysts for the transesterification of canola oil. The mixed CaO-ZnO catalysts derived mainly from oyster shells showed the highest catalytic activity with >90% biodiesel yield at a 9:1 methanol-to-oil mole ratio within 10 min of ultrasonication. The reduction of toxicant emission from the generator is 43% and 60% for SO₂, 11% and 26% for CO, were observed for the biodiesel blending levels of B20 and B40, respectively. Full article

Biodiesel, which can be made from a variety of natural oils, is currently promoted as a sustainable, healthier replacement for commercial mineral diesel despite little experimental data supporting this. The aim of our research was to investigate the health impacts of exposure to exhaust generated by the combustion of diesel and two different biodiesels. Male BALB/c mice (n = 24 per group) were exposed for 2 h/day for 8 days to diluted exhaust from a diesel engine running on ultra-low sulfur diesel (ULSD) or Tallow or Canola biodiesel, with room air exposures used as control. A variety of respiratory-related end-point measurements were assessed, including lung function, responsiveness to methacholine, airway inflammation and cytokine response, and airway morphometry. Exposure to Tallow biodiesel exhaust resulted in the most significant health impacts compared to Air controls, including increased airway hyperresponsiveness and airway inflammation. In contrast, exposure to Canola biodiesel exhaust resulted in fewer negative health effects. Exposure to ULSD resulted in health impacts between those of the two biodiesels. The health effects of biodiesel exhaust exposure vary depending on the feedstock used to make the fuel. Full article

The biodiesel industry is expanding rapidly in accordance with the high energy demand and environmental deterioration related to the combustion of fossil fuel. However, poor physicochemical properties and the malperformance of biodiesel fuel still concern the researchers. In this flow, polymers were introduced in biodiesel industry to overcome such drawbacks. This paper reviewed the current utilizations of polymers in biodiesel industry. Hence, four utilizing approaches were discussed, namely polymeric biodiesel, polymeric catalysts, cold-flow improvers (CFIs), and stabilized exposure materials. Hydroxyalkanoates methyl ester (HAME) and hydroxybutyrate methyl ester (HBME) are known as polymeric biodiesel sourced from carbon-enriched polymers with the help of microbial activity. Based on the literature, the highest HBME yield was 70.7% obtained at 10% H₂SO₄ ratio in methanol, 67 °C, and 50 h. With increasing time to 60 h, HAME highest yield was reported as 68%. In addition, polymers offer wide range of esterification/transesterification catalysts. Based on the source, this review classified polymeric catalysts as chemically, naturally, and waste derived polymeric catalysts. Those catalysts proved efficiency, non-toxicity, economic feasibility, and reusability till the 10th cycle for some polymeric composites. Besides catalysis, polymers proved efficiency to enhance the biodiesel flow-properties. The best effect reported in this review was an 11 °C reduction for the pour point (PP) of canola biodiesel at 1 wt% of ethylene/vinyl acetate copolymers and cold filter plugging point (CFPP) of B20 waste oil biodiesel at 0.08 wt% of EVA copolymer. Polymeric CFIs have the capability to modify biodiesel agglomeration and facilitate flowing. Lastly, polymers are utilized for storage tanks and auto parts products in direct contact with biodiesel. This approach is completely exclusive for polymers that showed stability toward biodiesel exposure, such as polyoxymethylene (POM) that showed insignificant change during static immersion test for 98 days at 55 °C. Indeed, the introduction of polymers has expanded in the biodiesel industry to promote green chemistry. Full article

In this study, three solid acid catalysts, namely mesoporous aluminophosphate-supported 12-tungstophosphoric heteropoly acid (HPW/MAP), mesoporous aluminosilicate-supported 12-tungstophosphoric heteropoly acid (HPW/MAS), and gamma alumina-supported 12-tungstophosphoric heteropoly acid (HPW/γ-Al₂O₃) were prepared and characterized. Mesoporous aluminophosphate (MAP) and mesoporous aluminosilicate (MAS) were synthesized via sol-gel and hydrothermal methods, respectively, and 25 wt.% of 12-tungstophosphoric heteropoly acid (HPW) was immobilized on the support materials using the wet impregnation method. The features of the fabricated catalysts were comprehensively investigated using various techniques such as BET, XRD, NH₃-TPD, TGA, and TEM. The surface area of the supported catalysts decreased after HPW impregnation according to BET results, which indicates that HPW loaded on the supports and inside of their pores successfully. The density and strengths of the acid sites of the support materials and the catalysts before reaction and after regeneration were determined by the NH₃-TPD technique. Accordingly, an increase in acidity was observed after HPW immobilization on all the support materials. The catalytic performance of the catalysts was studied through alcoholysis reaction using unrefined green seed canola oil as the feedstock. The maximum biodiesel yield of 82.3% was obtained using 3 wt.% of HPW/MAS, with a methanol to oil molar ratio of 20:1, at 200 °C and 4 MPa over 7 h. The reusability study of HPW/MAS showed that it can maintain 80% of its initial activity after five runs. Full article

In this study we report the effect of fuel type (biodiesel vs. methane), flame structure and flame height (inner-cone vs. outer-cone), and the percent of oxygen content in the oxidizer stream for the formation of hydrophobic carbon layers using co-flow diffusion flames. It was found that a flame formed using a gaseous fuel (methane) over a vaporized liquid fuel, Canola Methyl Ester (CME), has significant structural differences that enable vastly different deposition behavior of soot layers on the surface of solid substrates. Due to its larger pyrolysis zone (taller inner-cone), the CH₄/air flame has a smaller region that supports uniform soot deposition of hydrophobic carbon layers (C-layers) compared to the CME/air flame. When a solid substrate is placed within the pyrolysis zone (inner-cone) of a flame the resulting layer is non-uniform, hydrophilic, and consists of undeveloped soot. However, when outside the pyrolysis zone, the deposited soot tends to be uniform and mature, ultimately creating a hydrophobic C-layer consisting of the typical microscale interconnected weblike structures formed of spherical soot nanoparticles. The effect of oxygen content (35% and 50% O₂) in the oxidizer stream for the formation of hydrophobic C-layers was also studied in this work. It was found that oxygen enrichment within the CME flame alters the structure of the flame, hence affecting the morphology of the formed C-layer. Under oxygen enrichment the central region of the deposited C-layer is composed of a weblike structure similar to those seen in the air flames; however, this central region is bordered by a region of densely compacted soot that shows signs of significant thermal stress. At 35% O₂ the thermal stress is expressed as multiple microscale cracks while at 50% O₂ this border region shows much larger cracks and macroscale layer peeling. The formed C-layers under the different flame conditions were tested for hydrophobicity by measuring the contact angle of a water droplet. The morphology of the C-layers was analyzed using scanning electron microscopy. Full article

The use of renewable biodiesel fuel in diesel engines can reduce the demand for depleting fossil fuels and reduce harmful emissions to the environment. In this research, an engine simulation is conducted using ANSYS Forte software, which allows for visualization of the spray inside the combustion chamber. The results show that biodiesel has higher liquid and vapor penetration lengths, higher droplet mass and diameter, and a longer breakup length. Molecular images of fuel molecules show that the temperature of biodiesel molecules is 141 °C lower than diesel molecules at 709 degree crank angle (°CA). These characteristics result in an extended evaporation time for biodiesel, consequently leading to poorer performance. Additionally, increased penetration length can lead to carbon deposits inside the combustion chamber. Therefore, such inefficiencies of biodiesel spray properties lead to lower combustive performance than diesel. In terms of performance, on average, biodiesel produces 16.9% lower power and 19.9% higher brake specific fuel consumption. On average, the emissions of CO, CO₂, and HC of biodiesel are 17.8%, 3.41%, and 23.5% lower and NOx is 14.39% higher than the corresponding values obtained for pure diesel, respectively. In-cylinder combustion analyses show that the peak pressure of biodiesel is 0.5 MPa lower, the peak cycle temperature is 36 °C lower, the ignition delay is 4 °CA longer, the peak heat release rate is 16.5 J/deg. higher, and the combustion duration is 5.96 °CA longer compared to diesel combustion. Full article

The oxidation stability (OX) of the biodiesel is an essential parameter mainly during storage, which reduces the quality of the biodiesel, thus affecting the engine performance. Moreover, many factors affect oxidation stability. Therefore, determining the most significant parameter is essential for achieving accurate predictions. In this paper, an empirical equation (Poisson Regression Model (PRM)), machine learning models (Multilayer Feed-Forward Neural Network (MFFNN), Cascade Feed-forward Neural Network (CFNN), Radial Basis Neural Network (RBFNN), and Elman neural network (ENN)) with various combinations of input parameters are utilized and employed to identify the most relevant parameters for prediction of the oxidation stability of biodiesel. This study measured the physicochemical properties of 39 samples of waste frying methyl ester and their blends with various percentages of palm biodiesel and refined canola biodiesel. To this aim, 14 parameters including concentration amount of WFME (X1), PME (X2), and RCME (X3) in the mixture, kinematic viscosity (KV) at 40 °C, density at 15 °C (D), cloud point (CP), pour point (PP), the estimation value of the sum of the saturated ($\sum SFAMs$), monounsaturated (${\displaystyle \sum }MUFAMs$), polyunsaturated (${\displaystyle \sum }PUFAMs$), degree of unsaturation ($DU$), long-chain saturated factor ($LCSF$), very-long-chain fatty acid ($VLCFA$), and ratio ($\frac{{\displaystyle \sum }MUFAMs+{\displaystyle \sum }PUFAMs}{{\displaystyle \sum }SFAMs}$) fatty acid composition were considered. The results demonstrated that the RBFNN model with the combination of X1, X2, X3, ${\displaystyle \sum }SFAMs$, ${\displaystyle \sum }MUFAMs$, ${\displaystyle \sum }PUFAMs$. VLCFA, DU, LCSF, $\frac{{\displaystyle \sum }MUFAMs+{\displaystyle \sum }PUFAMs}{{\displaystyle \sum }SFAMs}$, KV, and D has the lowest value of root mean squared error and mean absolute error. In the end, the results demonstrated that the RBFNN model performed well and presented high accuracy in estimating the value of OX for the biodiesel samples compared to PRM, MFFNN, CFNN, and ENN. Full article