Search Results (70)

To learn more about the problem of blast weakening in shallow-buried and extra-thick coal seams, Panjin coal mine was used to provide the engineering background for this study. The influence of blast weakening technology on the vibration of ground buildings was investigated. Based on monitoring the vibration data from the final 400 m of the working face, we established the Sadovsky formula for this coal mine through regression. The maximum safe charge of one blast at different distances was obtained. A numerical model was established and compared with field monitoring data to verify its accuracy. This numerical model was used to analyze the influence of blast weakening vibrations on ground buildings during the final mining stage. Finally, the maximum safe charge for one blast at advancing distances from the working face was derived based on numerical calculation results. It was compared with the maximum safe charge obtained from field measurements. The results show that both exhibit significant consistency, and the maximum safe charge of one blast decreases as the working face advances. In addition, the peak vibration velocity at each monitoring point does not exceed 0.2 cm/s for the remaining 400 m of the measured working face, which is lower than the allowable safety value for blasting vibrations. In the numerical simulation of the final mining stage at 200 m, the ground vibration velocity is largest for the district office, second-largest for the chimney, and smallest for the science and technology building. The maximum vibration velocity and effective stress in the three directions of the three buildings are within the allowable range, indicating that the buildings remained in a safe state. Full article

In order to clarify the pore evolution and coupling characteristics with hydrocarbon charging in the deep-buried ultra-tight sandstone reservoirs of the second member of Xujiahe Formation (hereinafter referred to as the Xu 2 Member) on the eastern slope of the Western Sichuan Depression, this study integrates burial history and thermal history with analytical methods including core observation, cast thin section analysis, scanning electron microscopy, carbon-oxygen isotope analysis, and fluid inclusion homogenization temperature measurements. The Xu 2 Member reservoirs are predominantly composed of lithic sandstones and quartz-rich sandstones, with authigenic quartz and carbonates as the main cementing materials. The reservoir spaces are dominated by intragranular dissolution pores. The timing of reservoir densification varies among different submembers. The upper submember underwent compaction during the Middle-Late Jurassic period due to the high ductility of mudstone clasts and other compaction-resistant components. The middle-lower submembers experienced densification in the Late Jurassic period. Late Cretaceous tectonic uplift induced fracture development, which enhanced dissolution in the middle-lower submembers, increasing reservoir porosity to approximately 5%. Two distinct phases of hydrocarbon charging are identified in the Xu 2 Member. The earlier densification of the upper submember created unfavorable conditions for hydrocarbon accumulation. In contrast, the middle-lower submembers received hydrocarbon charging prior to reservoir densification, providing favorable conditions for natural gas enrichment and reservoir formation. Three sweet-spot reservoir development patterns are recognized: paleo-structural trap + (internal source rock) + source-connected fracture assemblage type, paleo-structural trap + internal source rock + late-stage fracture assemblage type, and paleo-structural trap + (internal source rock) + source-connected fracture + late-stage fracture assemblage type. Full article

Proteins and their surrounding hydration water engage in a dynamic interplay that is critical for maintaining structural stability and functional integrity. However, the intricate coupling between protein dynamics and the structural order of hydration water remains poorly understood. Here, we employ all-atom molecular dynamics simulations to investigate this relationship across four representative proteins. Our results reveal that protein residues with greater flexibility or solvent exposure are surrounded by more disordered hydration water, akin to bulk water, whereas rigid and buried non-polar residues are associated with structurally ordered hydration shells. Due to their strong hydrogen bonding and electrostatic interactions, charged residues exhibit the most disordered hydration water, while non-polar residues are associated with the structurally most ordered hydration water. We further uncovered a positive correlation between the relaxation dynamics of protein residues and their hydration water: slower (faster) protein relaxation is coupled with slower (faster) relaxation of the structural order of hydration water. Notably, this coupling weakens with increasing residue flexibility or solvent exposure, with non-polar residues displaying the strongest coupling, and charged residues the weakest. To further uncover their coupling mechanism, we elucidate residue-specific coupled fluctuations between protein residues and hydration water by generating scatter plots. These findings provide a comprehensive understanding of the mechanisms underlying protein–water interactions, offering valuable insights into the role of hydration water in protein stability, dynamics, and function. Full article

Lead halide perovskite solar cells (PSCs) have shown tremendous progress in the last few years. However, highly toxic Pb and its instability have restricted their further development. On the other hand, antimony-based perovskites such as cesium antimony iodide (Cs₃Sb₂I₉) have shown high stability but low power conversion efficiency (PCE) due to the limited transfer of photocarriers and the poor quality of films. Here, we present a novel method to improve the performance of Cs₃Sb₂I₉ PSCs through a FACl-modified buried interface. FACl acts as a bi-functional additive, and FA incorporation enhances the crystallinity and light absorption of films. Furthermore, treatment with FACl optimizes the level position of Cs₃Sb₂I₉. In addition, transient photovoltage and transient photocurrent were employed to confirm the reduction of charge recombination and superior carrier transportation. By using a planar device structure, we found the PCE of a FACl–Cs₃Sb₂I₉-based device to be 1.66%. The device, stored for 2 months under N₂ conditions, showed a negligible loss in PCE. Overall, this study provides a new strategy to further enhance the performance of Sb-based PSCs. Full article

Background/Objectives: As with many viral fusion proteins, the native conformation of SARS-CoV-2 Spike is metastable. Most COVID-19 vaccines utilize a stabilized Spike (Spike-2P) containing two proline substitutions, and subsequently, a further stabilized variant with four additional proline substitutions, Spike-6P, has been developed. In an alternative approach, we introduced two aspartic acid residues (2D) in the HR1 region of Spike at positions that are exposed and buried in the pre- and postfusion states, respectively, to destabilize the postfusion conformation. Methods: The recombinant protein constructs were expressed in a mammalian cell culture and characterized for their yield and antigenicity, and the formulations were then used to immunize hamsters. After two immunizations, the hamsters were challenged with live B.1.351 SARS-CoV-2 virus for an evaluation of the protective efficacy. Results: The introduction of the two aspartic acid mutations resulted in an approximately six-fold increase in expression, comparable to that in Spike-2P. When the 2D mutations were combined with the above four proline mutations (Spike-4P-2D), this led to a further three- to four-fold enhancement of protein expression, similar to that seen in Spike-6P. When formulated with the oil-in-water emulsion adjuvant Sepivac SWE, the 2P, 2D, 6P, and 4P-2D Spike variants all protected female hamsters against heterologous challenge with the B.1.351 SARS-CoV-2 virus and elicited high titers of neutralizing antibodies. Conclusions: We suggest that destabilization of the postfusion conformation through the introduction of charged amino acids at sites that are exposed in the pre- and buried in the postfusion conformation offers a general strategy to enhance the yield and stability of the native, prefusion conformation of viral surface proteins. Full article

In this work, we demonstrate that an external pressure of 15–30 kPa can significantly improve metal halide perovskite (MHP) film thermal stability. We demonstrate this through the application of weight on top of an MHP film during thermal aging in preserving the perovskite phase and the mobile ion concentration, an effect which we hypothesize reduces the extent to which volatile species can escape from the MHP lattice. This method is shown to be effective for a more scalable approach by only applying the weight to a cover glass during the lamination of an epoxy-based resin, after which the weight is removed. The amount of pressure applied during lamination is shown to correlate with stability in both 1 sun illumination and damp heat testing. Lastly, the performance of MHP photovoltaic devices is improved using pressure during lamination, an effect which is attributed to improved interfacial contact between the MHP and the adjacent charge transport layers and healing of any voids or defects that may exist at the buried interface after processing. As such, there are implications for tuning the amount of pressure that is applied during lamination to enable the durability of MHP solar modules toward manufacturing-scale deployment. Full article

Field implementations of fully underground sensor networks face many practical challenges that have limited their overall adoption. Power management is a commonly cited issue, as operators are required to either repeatedly excavate batteries for recharging or develop complex underground power infrastructures. Prior works have proposed wireless inductive power transfer (IPT) as a potential solution to these power management issues, but misalignment is a persistent issue in IPT systems, particularly in applications involving moving vehicles or obscured (e.g., underground) coils. This paper presents an automated methodology to sense misalignments and align IPT coils using robotic actuators and sequential Monte Carlo methods. The misalignment of a Class EF inverter-driven IPT system was modeled by tracking changes as its coils move apart laterally and distally. These models were integrated with particle filters to estimate the location of a hidden coil in 3D, given a sequence of sensor measurements. During laboratory tests on a Cartesian robot, these algorithms aligned the IPT system within 1 cm (0.025 coil diameters) of peak lateral alignment. On average, the alignment algorithms required less than four sensor measurements for localization. After laboratory testing, this approach was implemented with an agricultural sensor platform at the Utah Agricultural Experiment Station in Kaysville, Utah. In this implementation, a buried sensor platform was successfully charged using an aboveground, vehicle-mounted transmitter. Overall, this work contributes to the field of underground sensor networks by successfully integrating a self-aligning wireless power delivery system with existing agricultural infrastructure. Furthermore, the alignment strategy presented in this work accomplishes coil misalignment correction without the need for complex sensor or coil architectures. Full article

Flexible perovskite solar cells (F-PSCs) have the advantages of high power-per-weight, solution processability, and bending durability and have emerged as a competitive photovoltaic technology for various applications. As the core electron transport layer (ETL) in n-i-p-type device configurations, the solution-processed SnO₂ generally suffers from serious defect stacking on films, compromising the charge transport properties and the performance of resulting devices. Herein, we proposed a media-filling strategy to optimize the contact quality at the buried interface by introducing Al₂O₃ nanoparticles on the SnO₂ surface. Rather than forming a compact insulating layer, the Al₂O₃ can fill the grain boundaries of SnO₂ and smooth the substrate surface. Optimized interfacial contact under careful concentration control can rationally minimize the contact area of the perovskite with the surface imperfections of SnO₂ to mitigate trap-assisted charge recombination. Furthermore, the reduced surface roughness of SnO₂ facilitates the uniform deposition and oriented growth of upper perovskite film. As a result, the target F-PSCs achieved an impressive efficiency of 23.83% and retained 80% of the initial performance after 5000 bending cycles at a radius of four mm. Full article

Flexible perovskite solar cells (F-PSCs) hold great potential for lightweight photovoltaic applications due to their flexibility, bending compatibility, and low manufacturing cost. However, tin oxide (SnO₂), as a common electron transport layer (ETL) used in F-PSCs, typically suffers from high-density surface defects that hinder the charge extraction efficiency and deteriorate the crystallization quality of the upper perovskite film. Additionally, the poor buried interface quality intensifies lattice extrusion and strain residue across the perovskite films, further aggravating the mechanical brittleness in devices. To address the issues, we developed a molecular bridging strategy by introducing the 2,2′-oxybis(ethylenediamine) dihydrochloride (DO) at the perovskite/SnO₂ interface. The diammonium groups of spacer ligands can achieve the bidentate anchoring on the SnO₂ and perovskite films, cooperating with the oxygen atom on the alkyl chain to passivate the charged defects at the buried interface. The tailored interface properties also endow the optimized crystallization quality of perovskite films and significantly alleviate tensile strain to strengthen the perovskite’s pliability. As a result, the F-PSCs achieved a champion efficiency of 23.50%, outperforming the value of 21.87% for the control device. Furthermore, the devices exhibited excellent mechanical robustness, maintaining 90% of the initial PCE after 6000 bending cycles at a radius of 4 mm. This work presents a reliable strategy for the synergistic optimization of the buried contact at the electron extraction interface, contributing to the further development of efficient and stable F-PSCs. Full article

The tight reservoirs in the Sichuan Basin generally contain water and have complex gas–water relationships. The dynamic changes and main controlling factors of natural gas injection are unclear, which has had a serious impact on the exploration and development of tight sandstone gas. This article selects samples from Yongqian and Qiulin gas fields to characterize the reservoir characteristics of the tight sandstone samples in the Xu-3 section. Nuclear magnetic resonance technology is applied to plan gas–water injection simulation experiments, and the dynamic changes in pore water and gas content during the natural gas injection of tight reservoir rock samples are characterized. The main controlling factors are analyzed based on the theory of nuclear magnetic resonance singlet and multifractal models. The results showed that material composition, pore type, structural characteristics, and physical properties cooperatively control the charging characteristics of natural gas. There was no significant difference in mineral content among the tight sandstone samples, and the pore morphology types were mainly parallel plate-like pores and fracture-type pores. There were significant differences in the pore structure characteristics of the samples with varying burial depths. The heterogeneity of gas-bearing pores is negatively related to the buried depth of tight sandstone, is a coupling relationship with quartz and feldspar content, and is negatively correlated with pore permeability. The stronger the sample heterogeneity, the more unfavorable it is for natural gas migration and accumulation. Full article

This theoretical study investigates the high molecular weight (Mw) production in copolymerization of ethylene and 1-octene using heteroatom-substituted constrained geometry catalysts (CGCs). The research explores the correlation between chain termination reactions and polymer molecular weight, revealing that the Gibbs free energy barrier of the chain termination reactions is positively linked to the molecular weight. Quantitative structure–property relationship models were constructed, indicating that molecular descriptors such as atom charge, orbital energy, and buried volume significantly influence the polymer molecular weight. Full article

The Central Anticline Belt of the Xihu Sag is one of the structural units with the most abundant natural gas in the East China Sea Shelf Basin. However, there are significant differences among the anticline units in terms of the scale of natural gas enrichment, occurrence horizons, types of gas reservoirs, accumulation processes, and gas-bearing properties of different strata, which influence the optimization of exploration zones and the orientation of exploration in deep-buried areas. This study conducted a comprehensive analysis in terms of the structural evolution, fault activity, hydrocarbon charging stages, and process of hydrocarbon accumulation. It clarifies that (1) the preservation condition is one of the core factors for the differential enrichment of natural gas in the Central Anticline Belt. Under the background of differential compression of the Longjing Movement, late-stage and E-W-trending faults are commonly developed in the anticline cores of the strong compression area in the south, which damage the effectiveness of traps, resulting in a large amount of natural gas escaping and being locally adjusted and accumulated in shallow effective traps. The gas reservoirs show the characteristics of multiple accumulation horizons and a small scale. In the moderately strong compression area in the north, the E-W-trending faults have weak activities and shallow incision horizons. The original gas reservoirs are not damaged, and the structures are fully filled. (2) The coupling between faults and sand bodies determines the degree of oil and gas enrichment. In the weakly compressed area in the west, late-stage E-W-trending faults are not developed, and the preservation conditions are good. The main controlled faults on the flanks of the anticline are highly active, and the coupling degree between faults and sand bodies is good, resulting in a high gas saturation. However, the transport capacity in the anticline cores is relatively poor, with a low gas saturation. (3) The differences in the paleo-structural characteristics affect the degree of oil and gas enrichment. The paleo-structures formed before the Longjing Movement provided favorable conditions for the early convergence of oil and gas. Natural gas has the characteristics of multi-stage charging, and the deep gas reservoirs have higher gas saturation than the shallow ones. On this basis, this study proposed two natural gas accumulation processes developed in the Central Anticline Belt of the Xihu Sag under the background of differential compression. One is where the hydrocarbon convergence occurs first and then oil and gas transport and accumulate into the reservoirs; the other one is where the hydrocarbon convergence and accumulation occur simultaneously, followed by gas adjustment. This paper also concludes three differential accumulation models: the local enrichment and accumulation model of gas in the strongly compressed zone, the integrated enrichment and accumulation model in the medium-strongly compressed zone, and the fault–sand coupling accumulation model in the weakly compressed zone. The results of this research have great significance for the subsequent exploration, hydrocarbon enrichment style analysis, and further strategy in the deep-buried, tight to low-permeable reservoirs in ocean exploration areas. Full article

In this paper, the degradation mechanism of the RF performance of 22 nm fully depleted (FD) silicon-on-insulator nMOSFETs at different total ionizing dose levels has been investigated. The RF figures of merit (the cut-off frequency f_T, maximum oscillation frequency f_max) show significant degradation of approximately 14.1% and 6.8%, respectively. The variation of the small-signal parameters (output conductance (g_ds), transconductance (g_m), reflection coefficient (|Γ_in|), and capacitance (C_gg)) at different TID levels has been discussed. TID-induced trapped charges in the gate oxide and buried oxide increase the vertical channel field, which leads to more complex degradation of small-signal parameters across a wide frequency range. Full article

This study leverages the efficacy of Voronoi diagram theory within a mixed-methods approach to thoroughly examine the spatial distribution, service coverage, and optimal locations for expanding electric vehicle (EV) charging infrastructure in Bangkok. Drawing on data from field surveys and public data providers, our analysis unfolds in four key stages. Firstly, we delve into the spatial distribution of charging stations, scrutinizing density, proximity to various road types, and land use through the lens of Voronoi diagrams. Secondly, the application of Voronoi diagrams informs the evaluation of service boundaries. Thirdly, utilizing this effective tool, we assess population density per parking slot or charging head to anticipate future EV adoption. Finally, the study introduces an approach to identify suitable locations for new charging stations through the application of overlapping Voronoi circles. Findings reveal a clustered distribution of charging stations along roads, particularly in the central business district, showcasing the efficiency of Voronoi diagrams in spatial analysis. Residential areas and urban commercial zones also host significant charging station concentrations. Notably, service coverage in inner Bangkok surpasses that of middle and outer areas, highlighting underserved regions. Prospective areas for new charging stations, identified through Voronoi analysis, include Bang Khae, Phra Khanong, Min Buri, and Huai Khwang. This research, rooted in the application of Voronoi diagram theory, offers vital insights for various stakeholders involved in urban infrastructure planning. By employing Voronoi diagrams within Geographic Information Systems (GIS), the study contributes to strategically placing charging stations, optimizing spatial understanding, and enhancing resource allocation. This GIS-based approach not only supports the rise of electric vehicles but also promotes sustainable urban development practices through the efficient utilization of spatial data and analysis techniques. Full article

Batteries with an energy storage capacity of 280 Ah play a crucial role in promoting the development of smart grids. However, the inhomogeneity of their internal temperature cannot be accurately measured at different constant charge and discharge power, affecting the efficiency and safety of the battery. This work adopts finite element analysis to determine the typical internal temperature of a single-cell model, which can guide the measuring position of the battery. Before the manufacturing process, a slim pre-buried sensor is utilized to reduce the negative impacts of different constant charge and discharge powers. The maximum internal temperature of the battery is up to 77 °C at a constant charge and discharge power of 896 W. The temperature difference between the two poles and the battery surface is as high as 26.2 °C, which is beyond the safety temperature (55 °C). This phenomenon will result in the degradation of the positive electrode through dQ/dV curves. These measurements of battery internal temperature can improve battery heat control and facilitate the development of energy storage technology. Full article