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Keywords = bifacial solar cells

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16 pages, 8073 KB  
Article
Bifaciality Optimization of TBC Silicon Solar Cells Based on Quokka3 Simulation
by Fen Yang, Zhibin Jiang, Yi Xie, Taihong Xie, Jingquan Zhang, Xia Hao, Guanggen Zeng, Zhengguo Yuan and Lili Wu
Materials 2026, 19(2), 405; https://doi.org/10.3390/ma19020405 - 20 Jan 2026
Viewed by 196
Abstract
Tunnel Oxide-Passivated Back Contact solar cells represent a next-generation photovoltaic technology with significant potential for achieving both high efficiency and low cost. This study addresses the challenge of low bifaciality inherent to the rear-side structure of TBC cells. Using the Quokka3 simulation and [...] Read more.
Tunnel Oxide-Passivated Back Contact solar cells represent a next-generation photovoltaic technology with significant potential for achieving both high efficiency and low cost. This study addresses the challenge of low bifaciality inherent to the rear-side structure of TBC cells. Using the Quokka3 simulation and assuming high-quality surface passivation and fine-line printing accuracy, a systematic optimization was conducted. The optimization encompassed surface morphology, optical coatings, bulk material parameters (carrier lifetime and resistivity), and rear-side geometry (emitter fraction, metallization pattern and gap width). Through a multi-parameter co-optimization process aimed at enhancing conversion efficiency, a simulated conversion efficiency of 27.26% and a bifaciality ratio of 92.96% were achieved. The simulation analysis quantified the trade-off relationships between FF, bifaciality, and efficiency under different parameter combinations. This enables accurate prediction of final performance outcomes when prioritizing different metrics, thereby providing scientific decision-making support for addressing the core design challenges in the industrialization of TBC cells. Full article
(This article belongs to the Section Electronic Materials)
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20 pages, 6206 KB  
Article
PV-Scope Test System: Photovoltaic Module Characterization with Maximum Power, Efficiency, and Environmental Sensing
by Christi K. Madsen and Bitian Jiang
Electronics 2025, 14(21), 4305; https://doi.org/10.3390/electronics14214305 - 31 Oct 2025
Viewed by 840
Abstract
An integrated ESP32-based measurement system called PV-Scope is presented for real-time photovoltaic (PV) module efficiency characterization and small off-grid system testing under field conditions. The system includes pyranometer-calibrated irradiance sensors using a solar simulator, maximum power point tracking, and comprehensive environmental monitoring to [...] Read more.
An integrated ESP32-based measurement system called PV-Scope is presented for real-time photovoltaic (PV) module efficiency characterization and small off-grid system testing under field conditions. The system includes pyranometer-calibrated irradiance sensors using a solar simulator, maximum power point tracking, and comprehensive environmental monitoring to enable accurate performance assessment of PV modules across diverse technologies, manufacturers and installation conditions. Unlike standard test condition (STC) measurements at cell temperatures of 25 °C, this system captures the interactions between efficiency and environmental variables that significantly impact real-world efficiency. In particular, measurement of temperature-dependent efficiency under local conditions and validation of temperature-dependent models for extending the results to other environmental conditions are enabled with cell temperature monitoring in addition to ambient temperature, humidity, and wind speed. PV-Scope is designed for integrated sensing versatility, portable outdoor testing, and order-of-magnitude cost savings compared to commercial equipment to meet measurement needs across research, education, and practical PV innovation, including bifacial module testing, assessment of cooling techniques, tandem and multi-junction testing, and agrivoltaics. Full article
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14 pages, 2452 KB  
Article
Energy Yield Analysis of Bifacial Solar Cells in Northeast Mexico: Comparison Between Vertical and Tilted Configurations
by Angel Eduardo Villarreal-Villela, Osvaldo Vigil-Galán, Eugenio Rodríguez González, Jesús Roberto González Castillo, Daniel Jiménez-Olarte, Ana Bertha López-Oyama and Deyanira Del Angel-López
Energies 2025, 18(14), 3784; https://doi.org/10.3390/en18143784 - 17 Jul 2025
Viewed by 831
Abstract
Bifacial photovoltaic technology is made up of solar cells with the ability to generate electrical power on both sides of the cell (front and rear), consequently, they generate more energy in the same area compared to conventional or monofacial solar cells. The present [...] Read more.
Bifacial photovoltaic technology is made up of solar cells with the ability to generate electrical power on both sides of the cell (front and rear), consequently, they generate more energy in the same area compared to conventional or monofacial solar cells. The present work deals with the calculation of the energy yield using bifacial solar cells under the specific environmental conditions of Tampico, Tamaulipas, Mexico. Two configurations were compared: (1) tilted, optimized in height and angle, oriented to the south, and (2) vertically optimized in height, oriented east–west. The results were also compared with a standard monofacial solar cell optimally tilted and oriented south. The experimental data were acquired using a current–voltage (I-V) curve tracer designed for this purpose. This study shows that the vertically optimized bifacial solar cell produces similar electrical power to the conventional monofacial solar cell, with the benefit of maximum production in peak hours (8:30 and 16:30). In contrast, in the case of the inclined bifacial solar cell, about 26% more in the production of electrical power was reached. These results guide similar studies in other places of the Mexican Republic and regions with similar latitudes and climate. Full article
(This article belongs to the Section A2: Solar Energy and Photovoltaic Systems)
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15 pages, 3886 KB  
Article
Optimization of the Boron Back Surface Field Produced with Reduced Thermal Steps in Bifacial PERT Solar Cell
by Thais Crestani, Izete Zanesco, Adriano Moehlecke, Lucas Teixeira Caçapietra Pires da Silva and João Victor Zanatta Britto
Energies 2025, 18(9), 2347; https://doi.org/10.3390/en18092347 - 3 May 2025
Viewed by 1051
Abstract
Bifacial solar cells are the leading technology, and the number of steps in the manufacturing process influences the processing time and production cost. The goal of this paper is to optimize the boron back surface field (B-BSF) produced with reduced thermal steps and [...] Read more.
Bifacial solar cells are the leading technology, and the number of steps in the manufacturing process influences the processing time and production cost. The goal of this paper is to optimize the boron back surface field (B-BSF) produced with reduced thermal steps and to analyze its influence on the electrical parameters and bifaciality coefficients of p-type bifacial PERT solar cells. The boron diffusion and a silicon oxide layer grown as a phosphorus diffusion barrier were carried out in a single thermal step, according to the patent granted BR102012030606-9. The sheet resistance of the emitter and B-BSF were not affected by the reduced thermal steps, demonstrating the effectiveness of the silicon oxide layer as a barrier to phosphorus diffusion in the boron-doped side. The short-circuit current density with incident irradiance on the boron-doped side was impacted by the B-BSF sheet resistance, affecting the efficiency and the maximum power bifaciality coefficient. The high recombination in the pp+ region limited the maximum power bifaciality coefficient to approximately 0.7, which is typical in p-type solar cells. Considering the achieved results, the boron and phosphorus diffusion performed with reduced thermal steps produces bifacial p-PERT solar cells with typical bifaciality, avoiding two thermal steps for silicon oxide growth and chemical etching and cleaning. Full article
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20 pages, 6429 KB  
Article
Asymmetric Four-Terminal Solar Concentrator Improving Power Collection in Bifacial Solar Cells
by Floriana Morabito, Daniela Fontani, Paola Sansoni, Salvatore Lombardo, Andrea Farina and Silvia Maria Pietralunga
Energies 2025, 18(8), 2044; https://doi.org/10.3390/en18082044 - 16 Apr 2025
Viewed by 1007
Abstract
The exploitation of bifacial solar cells in photovoltaics aims to provide cost-effective solutions to maximize solar power collection on specific surfaces. A prerequisite for this is the effective collection of backscattered diffuse light from albedo, to which self-shading is an obstacle. We discuss [...] Read more.
The exploitation of bifacial solar cells in photovoltaics aims to provide cost-effective solutions to maximize solar power collection on specific surfaces. A prerequisite for this is the effective collection of backscattered diffuse light from albedo, to which self-shading is an obstacle. We discuss the benefits of bifaciality for an asymmetric low-concentrating and spectral-splitting photovoltaic optics system that features a wedged right-prism geometry to address self-shading. The performance of the conceptual design is analyzed, using commercial ray-tracing software, for four different latitudes of installation, by assuming a standard solar AM1.5G spectrum as input. The daily Relative Optical Power Increase (ROPI) is evaluated with respect to standard flat bifacial configurations, reaching ROPI = 293% at a latitude of 25° north at winter solstice. The photocurrent and total Power Conversion Efficiency (PCE) in a four-terminal (4T) configuration are estimated, assuming the operation of a commercial Si HJT bifacial cell and a commercial single-junction GaAs cell. A global increase in PCE of up to 23% is obtained with respect to the best-performing trackless standard bifacial configuration. From this perspective, the use of high-performance, high-bandgap solar cells in 4T configurations might further leverage the advantages of the optics proposed here. Full article
(This article belongs to the Section A2: Solar Energy and Photovoltaic Systems)
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25 pages, 10597 KB  
Article
Optimizing Bifacial Solar Modules with Trackers: Advanced Temperature Prediction Through Symbolic Regression
by Fabian Alonso Lara-Vargas, Carlos Vargas-Salgado, Jesus Águila-León and Dácil Díaz-Bello
Energies 2025, 18(8), 2019; https://doi.org/10.3390/en18082019 - 15 Apr 2025
Cited by 2 | Viewed by 2287
Abstract
Accurate temperature prediction in bifacial photovoltaic (PV) modules is critical for optimizing solar energy systems. Conventional models face challenges to balance accuracy, interpretability, and computational efficiency. This study addresses these limitations by introducing a symbolic regression (SR) framework based on genetic algorithms to [...] Read more.
Accurate temperature prediction in bifacial photovoltaic (PV) modules is critical for optimizing solar energy systems. Conventional models face challenges to balance accuracy, interpretability, and computational efficiency. This study addresses these limitations by introducing a symbolic regression (SR) framework based on genetic algorithms to model nonlinear relationships between environmental variables and module temperature without predefined structures. High-resolution data, including solar radiation, ambient temperature, wind speed, and PV module temperature, were collected at 5 min intervals over a year from a 19.9 MW bifacial PV plant with trackers in San Marcos, Colombia. The SR model performance was compared with multiple linear regression, normal operating cell temperature (NOCT), and empirical regression models. The SR model outperformed others by achieving a root mean squared error (RMSE) of 4.05 °C, coefficient of determination (R2) of 0.91, Spearman’s rank correlation coefficient of 0.95, and mean absolute error (MAE) of 2.25 °C. Its hybrid structure combines linear ambient temperature dependencies with nonlinear trigonometric terms capturing solar radiation dynamics. The SR model effectively balances accuracy and interpretability, providing information for modeling bifacial PV systems. Full article
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11 pages, 9659 KB  
Article
Fabrication of Bifacial-Modified Perovskites for Efficient Semitransparent Solar Cells with High Average Visible Transmittance
by Dazheng Chen, Wenjing Shi, Yan Gao, Sai Wang, Baichuan Tian, Zhizhe Wang, Weidong Zhu, Long Zhou, He Xi, Hang Dong, Wenming Chai, Chunfu Zhang, Jincheng Zhang and Yue Hao
Molecules 2025, 30(6), 1237; https://doi.org/10.3390/molecules30061237 - 10 Mar 2025
Viewed by 1517
Abstract
Semitransparent perovskite solar cells (PSCs) that possess a high-power conversion efficiency (PCE) and high average visible light transmittance (AVT) can be employed in applications such as photovoltaic windows. In this study, a bifacial modification comprising a buried layer of [4-(3,6-Dimethyl-9H-carbazol-9-yl) butyl] phosphonic acid [...] Read more.
Semitransparent perovskite solar cells (PSCs) that possess a high-power conversion efficiency (PCE) and high average visible light transmittance (AVT) can be employed in applications such as photovoltaic windows. In this study, a bifacial modification comprising a buried layer of [4-(3,6-Dimethyl-9H-carbazol-9-yl) butyl] phosphonic acid (Me-4PACz) and a surface passivator of 2-(2-Thienyl) ethylamine hydroiodide (2-TEAI) was proposed to enhance device performance. When the concentrations of Me-4PACz and 2-TEAI were 0.3 mg/mL and 3 mg/mL, opaque PSCs with a 1.57 eV perovskite absorber achieved a PCE of 22.62% (with a VOC of 1.18 V) and retained 88% of their original value after being stored in air for 1000 h. By substituting a metal electrode with an indium zinc oxide electrode, the resulting semitransparent PSCs showed a PCE of over 20% and an AVT of 9.45%. It was, therefore, suggested that the synergistic effect of Me-4PACz and 2-TEAI improved the crystal quality of perovskites and the carrier transport in devices. When employing an absorber with a wider bandgap (1.67 eV), the corresponding PSC obtained a higher AVT of 20.71% and maintained a PCE of 18.73%; these values show that a superior overall performance is observed compared to that in similar studies. This work is conductive to the future application of semitransparent PSCs. Full article
(This article belongs to the Special Issue Recent Advancements in Semiconductor Materials)
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25 pages, 5650 KB  
Article
Efficiency and Sustainability in Solar Photovoltaic Systems: A Review of Key Factors and Innovative Technologies
by Luis Angel Iturralde Carrera, Margarita G. Garcia-Barajas, Carlos D. Constantino-Robles, José M. Álvarez-Alvarado, Yoisdel Castillo-Alvarez and Juvenal Rodríguez-Reséndiz
Eng 2025, 6(3), 50; https://doi.org/10.3390/eng6030050 - 6 Mar 2025
Cited by 11 | Viewed by 11324
Abstract
PSS (Photovoltaic Solar Systems) are a key technology in energy transition, and their efficiency depends on multiple interrelated factors. This study uses a systematic review based on the PRISMA methodology to identify four main categories affecting performance: technological, environmental, design and installation, and [...] Read more.
PSS (Photovoltaic Solar Systems) are a key technology in energy transition, and their efficiency depends on multiple interrelated factors. This study uses a systematic review based on the PRISMA methodology to identify four main categories affecting performance: technological, environmental, design and installation, and operational factors. Notably, technological advances in materials such as perovskites and emerging technologies like tandem and bifacial cells significantly enhance conversion efficiency, fostering optimism in the field. Environmental factors, including solar radiation, temperature, and contaminants, also substantially impact system performance. Design and installation play a crucial role, particularly in panel orientation, solar tracking systems, and the optimization of electrical configurations. Maintenance, material degradation, and advanced monitoring systems are essential for sustaining efficiency over time. This study provides a comprehensive understanding of the field by reviewing 113 articles and analyzing three key areas—materials, application of sizing technologies, and optimization—from 2018 to 2025. The paper also explores emerging trends, such as the development of energy storage systems and the integration of smart grids, which hold promise for enhancing photovoltaic module (PM) performance. The findings highlight the importance of integrating technological innovation, design strategies, and effective operational management to maximize the potential of PM systems, providing a solid foundation for future research and applications across residential, industrial, and large-scale contexts. Full article
(This article belongs to the Special Issue Interdisciplinary Insights in Engineering Research)
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15 pages, 4153 KB  
Article
Optimizing Light Management in Bifacial Perovskite Solar Cells Using Silica-Based Anti-Dust and Anti-Reflection Coatings for Harsh Environments
by Kevin Thomas, Ahasanur Rahman, Amith Khandakar, Puvaneswaran Chelvanathan, Brahim Aissa and Mohammad Istiaque Hossain
Processes 2025, 13(2), 578; https://doi.org/10.3390/pr13020578 - 18 Feb 2025
Cited by 12 | Viewed by 1631
Abstract
In this work, we demonstrate an advanced light management strategy for bifacial perovskite solar cells incorporating a silica-based anti-dust and anti-reflection (AR) coating. The silica layer provides dual functionality, enhancing optical efficiency through effective reflection suppression and protecting the solar cell surface from [...] Read more.
In this work, we demonstrate an advanced light management strategy for bifacial perovskite solar cells incorporating a silica-based anti-dust and anti-reflection (AR) coating. The silica layer provides dual functionality, enhancing optical efficiency through effective reflection suppression and protecting the solar cell surface from environmental contaminants, especially dust. The hydrophobic nature of the silica coating further prevents accumulation of dust and particulate matter, supporting a self-cleaning mechanism that maintains cell transparency and performance over extended periods. The simulation results indicated that transitioning from a monofacial to a bifacial design with a silica layer on top had a considerable impact on the PSC performance. The optimized bifacial structure demonstrated high-performance metrics, achieving a voltage of 1.35 V, a fill factor of 84.24%, a current density (JSC) of 29.10 mA/cm2, and a power conversion efficiency of 31.00% when illuminated from the electron transport layer side. When illuminated from the hole transport layer side, the structure attained an efficiency of 22.00% with a calculated bifaciality factor (BF) of 72.12%, highlighting the potential of bifacial PSC design. Our findings reveal that the addition of the silica layer led to a notable improvement in light harvesting efficiency. Full article
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12 pages, 2997 KB  
Article
Improved Performance of Bifacial Photovoltaic Modules with Low-Temperature Processed Textured Rear Reflector
by Hyung-Jun Song, Deukgwang Lee, Chungil Kim and Jun-Hee Na
Appl. Sci. 2024, 14(19), 8718; https://doi.org/10.3390/app14198718 - 27 Sep 2024
Cited by 4 | Viewed by 3199
Abstract
Bifacial photovoltaic (PV) modules can capture both front and rear incident light simultaneously, thereby enhancing their power output. Achieving uniformity in rear incident light is crucial for an efficient and a stable operation. In this study, we present a simple, yet effective textured [...] Read more.
Bifacial photovoltaic (PV) modules can capture both front and rear incident light simultaneously, thereby enhancing their power output. Achieving uniformity in rear incident light is crucial for an efficient and a stable operation. In this study, we present a simple, yet effective textured rear reflector, designed to optimize the performance and stability of bifacial PV modules. The three-dimensional textured surface was created using an ethylene vinyl acetate sheet (EVA) through a hot-press method at 150 °C. Subsequently, the textured EVA surface was coated with solution-processed silver ink, increasing the reflectance of the textured reflector through a low-temperature process. The integration of the developed textured rear reflector into bifacial crystalline silicon (c-Si) PV modules resulted in an additional 6.9% improvement in power conversion efficiency compared to bifacial PV modules without a rear reflector, particularly when the rear reflector is close to the PV module. Furthermore, the textured rear reflector may mitigate current mismatch among cells by randomizing incident light and uniformly redistributing the reflected light to the PV cells. Consequently, the proposed textured reflector contributes to the enhanced performance and stability of bifacial PV modules. Full article
(This article belongs to the Section Optics and Lasers)
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31 pages, 2446 KB  
Review
Advance of Sustainable Energy Materials: Technology Trends for Silicon-Based Photovoltaic Cells
by Mladen Bošnjaković
Sustainability 2024, 16(18), 7962; https://doi.org/10.3390/su16187962 - 12 Sep 2024
Cited by 28 | Viewed by 6732
Abstract
Modules based on c-Si cells account for more than 90% of the photovoltaic capacity installed worldwide, which is why the analysis in this paper focusses on this cell type. This study provides an overview of the current state of silicon-based photovoltaic technology, the [...] Read more.
Modules based on c-Si cells account for more than 90% of the photovoltaic capacity installed worldwide, which is why the analysis in this paper focusses on this cell type. This study provides an overview of the current state of silicon-based photovoltaic technology, the direction of further development and some market trends to help interested stakeholders make decisions about investing in PV technologies, and it can be an excellent incentive for young scientists interested in this field to find a narrower field of research. This analysis covers all process steps, from the production of metallurgical silicon from raw material quartz to the production of cells and modules, and it includes technical, economic and environmental aspects. The economic aspect calls for more economical production. The ecological aspect looks for ways to minimise the negative impact of cell production on the environment by reducing emissions and using environmentally friendly materials. The technical aspect refers to the state of development of production technologies that contribute to achieving the goals of the economic, environmental and sustainability-related aspects. This involves ways to reduce energy consumption in all process steps, cutting ingots into wafers with the smallest possible cutting width (less material waste), producing thin cells with the greatest possible dimensional accuracy, using cheaper materials and more efficient production. An extremely important goal is to achieve the highest possible efficiency of PV cells, which is achieved by reducing cell losses (optical, electrical, degradation). New technologies in this context are Tunnel Oxide Passivated Contact (TOPcon), Interdigitated Back Contact Cells (IBCs), Heterojunction Cells (HJTs), Passivated Emitter Rear Totally Diffused cells (PERTs), silicon heterojunction cells (SHJs), Multi-Bush, High-Density Cell Interconnection, Shingled Cells, Split Cells, Bifacial Cells and others. The trend is also to increase the cell size and thus increase the output power of the module but also to reduce the weight of the module per kW of power. Research is also focused to maximise the service life of PV cells and minimise the degradation of their operating properties over time. The influence of shade and the increase in cell temperature on the operating properties should preferably be minimised. In this context, half-cut and third-cut cell technology, covering the cell surface with a layer that reduces soiling and doping with gallium instead of boron are newer technologies that are being applied. All of this leads to greater sustainability in PV technology, and solar energy becomes more affordable and necessary in the transition to a “green” economy. Full article
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22 pages, 4543 KB  
Article
An Assessment of a Photovoltaic System’s Performance Based on the Measurements of Electric Parameters under Changing External Conditions
by Agata Zdyb and Dariusz Sobczyński
Energies 2024, 17(9), 2197; https://doi.org/10.3390/en17092197 - 3 May 2024
Cited by 9 | Viewed by 2506
Abstract
This article presents an analysis of the performance of a 14.04 kWp grid-connected photovoltaic (PV) installation consisting of monocrystalline silicon, polycrystalline silicon and bifacial glass–glass monocrystalline silicon modules. The photovoltaic system was mounted in Poland, a location characterized by temperate climate conditions. On [...] Read more.
This article presents an analysis of the performance of a 14.04 kWp grid-connected photovoltaic (PV) installation consisting of monocrystalline silicon, polycrystalline silicon and bifacial glass–glass monocrystalline silicon modules. The photovoltaic system was mounted in Poland, a location characterized by temperate climate conditions. On the basis of the obtained results, the photovoltaic parameters were determined in accordance with the international standard. The annual energy yield of the entire system was 1033 kWh/kWp, and the performance ratio achieved was 83%. The highest average daily final yield was in the range of 4.0–4.5 kWh/kWp for each photovoltaic technology under investigation. In the cold part of the year, the efficiency of the photovoltaic modules was estimated to be 15%, and it was estimated to be 7% during the warm part of the year. Array capture losses accounted for around 0.75 kWh/kWp of energy loss per day, whereas the inverter efficiency was over 95% during the months that are beneficial for energy production. Full article
(This article belongs to the Section A2: Solar Energy and Photovoltaic Systems)
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29 pages, 10047 KB  
Article
A Building-Integrated Bifacial and Transparent PV Generator Operated by an “Under-Glass” Single Axis Solar Tracker
by Rosario Carbone and Cosimo Borrello
Energies 2023, 16(17), 6350; https://doi.org/10.3390/en16176350 - 1 Sep 2023
Cited by 6 | Viewed by 2667
Abstract
Nearly Zero Energy Buildings (NZEBs) play a key role in the world energy transition. This is motivating the scientific community to develop innovative electrical and thermal systems characterized by very high efficiency to specifically address the energy needs of modern buildings. Naturally, the [...] Read more.
Nearly Zero Energy Buildings (NZEBs) play a key role in the world energy transition. This is motivating the scientific community to develop innovative electrical and thermal systems characterized by very high efficiency to specifically address the energy needs of modern buildings. Naturally, the integration of the latest generation photovoltaic (PV) systems into buildings helps to satisfy this need, and, with this objective in mind, an innovative and highly efficient building-integrated photovoltaic (BIPV) system is presented and discussed in this paper. The proposed PV system is purpose-built to be fully integrated into a variety of buildings (preferably into their rooftops) and assumes the form of a PV skylight. It is based on a certain number of innovative rotating bifacial PV modules, which are specifically made to be installed “under-glass” within a custom-made transparent casing. Thanks to their properties, the PV modules can be rotated using a very low-power, reliable, and efficient mono-axial solar tracking system, fully protected against adverse atmospheric agents. Once the proposed PV skylight is fully integrated into a building, it generates electricity and, additionally, helps to improve both the energy performance and the aesthetic appearance of the building. The electricity generation and illuminance performances of the proposed PV skylight are experimentally tested using a low-power homemade prototype driven by different solar tracking logics and under different operating conditions; the most relevant results are summarized and extensively discussed. The main outcome of the experimental study is that the most effective performance of the PV skylight is obtained by installing, in its available surface, the maximum possible number of rotating bifacial PV modules, side by side and with no empty spaces between them. Full article
(This article belongs to the Special Issue Advanced PV Solutions for Achieving the NZEB Goal)
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31 pages, 16267 KB  
Article
Exploring Ln(III)-Ion-Based Luminescent Species as Down-Shifters for Photovoltaic Solar Cells
by Gabriela Brito-Santos, Cecilio Hernández-Rodríguez, Beatriz Gil-Hernández, Joaquín Sanchiz, Inocencio R. Martín, Benjamín González-Díaz and Ricardo Guerrero-Lemus
Materials 2023, 16(14), 5068; https://doi.org/10.3390/ma16145068 - 18 Jul 2023
Cited by 6 | Viewed by 2333
Abstract
In this work, we have compiled our research on lanthanide-based luminescent materials for use as down-shifter layers in photovoltaic (PV) mini-modules. The complexes we have prepared (C1–17), with formulas [Eu2(phen)2(bz)6] (C1), [Eu2(bphen)2(bz)6 [...] Read more.
In this work, we have compiled our research on lanthanide-based luminescent materials for use as down-shifter layers in photovoltaic (PV) mini-modules. The complexes we have prepared (C1–17), with formulas [Eu2(phen)2(bz)6] (C1), [Eu2(bphen)2(bz)6] (C2), [Eu(tta)3bphen] (C3), [Eu(bta)3pyz-phen] (C4), [Eu(tta)3pyz-phen] (C5), [Eu(bta)3me-phen] (C6), [Er(bta)3me-phen] (C7), [Yb(bta)3me-phen] (C8), [Gd(bta)3me-phen] (C9), [Yb(bta)3pyz-phen] (C10), [Er(tta)3pyz-phen] (C11), [Eu2(bz)4(tta)2(phen)2] (C12), [Gd2(bz)4(tta)2(phen)2] (C13), [EuTb(bz)4(tta)2(phen)2] (C14), [EuGd(bz)4(tta)2(phen)2] (C15), [Eu1.2Gd0.8(bz)4(tta)2(phen)2] (C16), and [Eu1.6Gd0.4(bz)4(tta)2(phen)2] (C17), can be grouped into three families based on their composition: Complexes C1–6 were synthesized using Eu3+ ions and phenanthroline derivatives as the neutral ligands and fluorinated β-diketonates as the anionic ligands. Complexes C7–11 were prepared with ligands similar to those of complexes C1–6 but were synthesized with Er3+, Yb3+, or Gd3+ ions. Complexes C12–17 have the general formula [M1M2(bz)4(tta)2(phen)2], where M1 and M2 can be Eu3+, Gd3+, or Tb3+ ions, and the ligands were benzoate (bz), 2-thenoyltrifluoroacetone (tta), and 1,10–phenanthroline (phen). Most of the complexes were characterized using X-ray techniques, and their photoluminescent properties were studied. We then assessed the impact of complexes in the C1–6 and C12–17 series on the EQE of PV mini-modules and examined the durability of one of the complexes (C6) in a climate chamber when embedded in PMMA and EVA films. This study emphasizes the methodology employed and the key findings, including enhanced mini-module efficiency. Additionally, we present promising results on the application of complex C6 in a bifacial solar cell. Full article
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19 pages, 5462 KB  
Review
A Review of Different Types of Solar Cell Materials Employed in Bifacial Solar Photovoltaic Panel
by Muthu Vimala, Geetha Ramadas, Muthaiya Perarasi, Athikesavan Muthu Manokar and Ravishankar Sathyamurthy
Energies 2023, 16(8), 3605; https://doi.org/10.3390/en16083605 - 21 Apr 2023
Cited by 29 | Viewed by 8379
Abstract
Conventionally accessible silicon solar cells experience two major drawbacks, such as reduced efficiency and increased fabrication costs. The prospects for the reduction in the cost of the photovoltaic form of energy conversion are bifacial solar cells. Bifacial solar cells show potential opportunity in [...] Read more.
Conventionally accessible silicon solar cells experience two major drawbacks, such as reduced efficiency and increased fabrication costs. The prospects for the reduction in the cost of the photovoltaic form of energy conversion are bifacial solar cells. Bifacial solar cells show potential opportunity in reducing the cost of solar energy conversion when analyzed with respect to monofacial cells. The bifacial solar cells exploit sunlight occurrence on both sides of the cell more efficiently. Bifacial-based solar photovoltaic (PV) is a technology that increases the generation of electrical energy per square meter of PV module through the utilization of light absorption from the albedo. This technology can generally be categorized based on the type of solar cell material and the fabrication technique. PV devices are classified as a silicon-based, thin film, organic, and advanced nano PV. This paper takes a second look at some recent initiatives and significant issues in enhancing the efficiency of bifacial solar cells from material sciences and chemical composition aspects. From this review, it is concluded that screen-printed solar cells have produced a maximum efficiency of 22%. Additionally, triode structure single-crystalline cells produced a maximum front side efficiency of 21.3% and rear side efficiency of 19.8%. Considering the recycling of solar panels, organic solar panels can be developed. Full article
(This article belongs to the Special Issue Review Papers in Energy and Buildings)
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