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Keywords = aperiodic solid

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15 pages, 4207 KiB  
Review
Beam Steering Technology of Optical Phased Array Based on Silicon Photonic Integrated Chip
by Jinyu Wang, Ruogu Song, Xinyu Li, Wencheng Yue, Yan Cai, Shuxiao Wang and Mingbin Yu
Micromachines 2024, 15(3), 322; https://doi.org/10.3390/mi15030322 - 26 Feb 2024
Cited by 10 | Viewed by 6825
Abstract
Light detection and ranging (LiDAR) is widely used in scenarios such as autonomous driving, imaging, remote sensing surveying, and space communication due to its advantages of high ranging accuracy and large scanning angle. Optical phased array (OPA) has been studied as an important [...] Read more.
Light detection and ranging (LiDAR) is widely used in scenarios such as autonomous driving, imaging, remote sensing surveying, and space communication due to its advantages of high ranging accuracy and large scanning angle. Optical phased array (OPA) has been studied as an important solution for achieving all-solid-state scanning. In this work, the recent research progress in improving the beam steering performance of the OPA based on silicon photonic integrated chips was reviewed. An optimization scheme for aperiodic OPA is proposed. Full article
(This article belongs to the Special Issue Silicon Photonic Devices and Integration)
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17 pages, 1425 KiB  
Article
Study on the Occurrence of Artificial Sweeteners, Parabens, and Other Emerging Contaminants in Hospital Wastewater Using LC-QToF-MS Target Screening Approach
by Olga S. Arvaniti, Georgios Gkotsis, Maria-Christina Nika, Stelios Gyparakis, Thrassyvoulos Manios, Nikolaos S. Thomaidis, Michalis S. Fountoulakis and Athanasios S. Stasinakis
Water 2023, 15(5), 936; https://doi.org/10.3390/w15050936 - 28 Feb 2023
Cited by 6 | Viewed by 3976
Abstract
The presence of 220 emerging contaminants belonging to different classes (artificial sweeteners, personal care products, coffee and tobacco-related compounds, and industrial chemicals) was investigated in hospital wastewater for the first time. Twenty samples were collected within two sampling periods from two points of [...] Read more.
The presence of 220 emerging contaminants belonging to different classes (artificial sweeteners, personal care products, coffee and tobacco-related compounds, and industrial chemicals) was investigated in hospital wastewater for the first time. Twenty samples were collected within two sampling periods from two points of a Greek General Hospital. Target compounds were analyzed using a solid-phase extraction protocol followed by UHPLC-ESI-QToF-MS analysis. Analytical results showed that 23 micropollutants were detected at least once in hospital wastewater samples in Period 1, while 27 compounds were detected at least once in Period 2. The coffee and tobacco-related compounds were the most frequently detected substances, followed by artificial sweeteners, parabens, and industrial chemicals. The highest mean concentrations were recorded for the artificial sweeteners cyclamic acid (377 μg/L) and saccharine (295 μg/L), followed by caffeine (193 μg/L), nicotine (162 μg/L), and the industrial chemical lauryl diethanolamide (153 μg/L). The group of artificial sweeteners contributed up to 55.1% (Point A/Period 1) to the total concentration of studied chemicals. The detection of high concentrations of artificial sweeteners in hospital effluents reveals that hospitals should be considered as important point-sources of these contaminants. Full article
(This article belongs to the Section Wastewater Treatment and Reuse)
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60 pages, 13465 KiB  
Review
Order–Disorder Diversity of the Solid State by NMR: The Role of Electrical Charges
by Luis Sánchez-Muñoz, Pierre Florian, Zhehong Gan and Francisco Muñoz
Minerals 2022, 12(11), 1375; https://doi.org/10.3390/min12111375 - 29 Oct 2022
Cited by 3 | Viewed by 2790
Abstract
The physical explanations and understanding of the order–disorder phenomena in the solid state are commonly inferred from the experimental capabilities of the characterization techniques. Periodicity is recorded according to the averaging procedure of the conventional reciprocal-space techniques (RSTs) in many solids. This approach [...] Read more.
The physical explanations and understanding of the order–disorder phenomena in the solid state are commonly inferred from the experimental capabilities of the characterization techniques. Periodicity is recorded according to the averaging procedure of the conventional reciprocal-space techniques (RSTs) in many solids. This approach gives rise to a sharp trimodal view including non-crystalline or amorphous compounds, aperiodic crystals and periodic crystals. However, nuclear magnetic resonance (NMR) spectroscopy offers an alternative approach that is derived from the distinct character of the measurements involved at the local scale. Here, we present a sequence of progressive order–disorder states, from amorphous structures up to fully ordered mineral structures, showing the great diversity existing in the solid state using multinuclear NMR spectroscopy. Some examples in glasses and products of their crystallization are used, as well as several minerals (including beryl-group and feldspar-group minerals) at magnetic fields up to 35.2 T, and some examples from literature. This approach suggests that the solid state is a dynamic medium, whose behavior is due to atomic adjustments from local compensation of electrical charges between similar structural states, which explains Ostwald’s step rule of successive reactions. In fully ordered feldspar minerals, we propose that the electronic structure of the elements of the cavity site is involved in bonding, site morphology and feldspar topology. Furthermore, some implications are derived about what is a mineral structure from the point of view of the NMR experiments. They open the possibility for the development of the science of NMR Mineralogy. Full article
(This article belongs to the Special Issue NMR Spectroscopy in Mineralogy and Crystal Structures)
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10 pages, 222 KiB  
Article
Answering Schrödinger’s “What Is Life?”
by Stuart Kauffman
Entropy 2020, 22(8), 815; https://doi.org/10.3390/e22080815 - 25 Jul 2020
Cited by 28 | Viewed by 8706
Abstract
In his “What Is Life?” Schrödinger poses three questions: (1) What is the source of order in organisms? (2) How do organisms remain ordered in the face of the Second Law of Thermodynamics? (3) Are new laws of physics required? He answers his [...] Read more.
In his “What Is Life?” Schrödinger poses three questions: (1) What is the source of order in organisms? (2) How do organisms remain ordered in the face of the Second Law of Thermodynamics? (3) Are new laws of physics required? He answers his first question with his famous “aperiodic solid”. He leaves his second and third questions unanswered. I try to show that his first answer is also the answer to his second question. Aperiodic solids such as protein enzymes are “boundary conditions” that constrain the release of energy into a few degrees of freedom in non-equilibrium processes such that thermodynamic work is done. This work propagates and builds structures and controls processes. These constitute his causally efficacious “code script” controlling development. The constrained release of energy also delays the production of entropy that can be exported from cells as it forms. Therefore, cells remain ordered. This answers his second question. However, “What is life?” must also ask about the diachronic evolution of life. Here, the surprising answer to this extended version of Schrödinger’s third question is that there are no new entailing laws of physics. No laws at all entail the evolution of ours or any biosphere. Full article
(This article belongs to the Special Issue Thermodynamics and Information Theory of Living Systems)
21 pages, 1941 KiB  
Review
Real Space Theory for Electron and Phonon Transport in Aperiodic Lattices via Renormalization
by Vicenta Sánchez and Chumin Wang
Symmetry 2020, 12(3), 430; https://doi.org/10.3390/sym12030430 - 7 Mar 2020
Cited by 8 | Viewed by 4075
Abstract
Structural defects are inherent in solids at a finite temperature, because they diminish free energies by growing entropy. The arrangement of these defects may display long-range orders, as occurring in quasicrystals, whose hidden structural symmetry could greatly modify the transport of excitations. Moreover, [...] Read more.
Structural defects are inherent in solids at a finite temperature, because they diminish free energies by growing entropy. The arrangement of these defects may display long-range orders, as occurring in quasicrystals, whose hidden structural symmetry could greatly modify the transport of excitations. Moreover, the presence of such defects breaks the translational symmetry and collapses the reciprocal lattice, which has been a standard technique in solid-state physics. An alternative to address such a structural disorder is the real space theory. Nonetheless, solving 1023 coupled Schrödinger equations requires unavailable yottabytes (YB) of memory just for recording the atomic positions. In contrast, the real-space renormalization method (RSRM) uses an iterative procedure with a small number of effective sites in each step, and exponentially lessens the degrees of freedom, but keeps their participation in the final results. In this article, we review aperiodic atomic arrangements with hierarchical symmetry investigated by means of RSRM, as well as their consequences in measurable physical properties, such as electrical and thermal conductivities. Full article
(This article belongs to the Special Issue Symmetry and Asymmetry in Quasicrystals or Amorphous Materials)
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9 pages, 784 KiB  
Proceeding Paper
The Quasicrystal Model as a Framework for Order to Disorder Transitions in 2D Systems
by Nadezhda L. Cherkas and Sergey L. Cherkas
Proceedings 2018, 2(14), 1117; https://doi.org/10.3390/IECC_2018-05251 - 21 May 2018
Viewed by 1525
Abstract
Order to disorder transitions are important for 2D objects such as oxide films with a cellular porous structure, honeycomb, graphene, and Bénard cells in liquid and artificial systems consisting of colloid particles on a plane. For instance, solid films of the porous alumina [...] Read more.
Order to disorder transitions are important for 2D objects such as oxide films with a cellular porous structure, honeycomb, graphene, and Bénard cells in liquid and artificial systems consisting of colloid particles on a plane. For instance, solid films of the porous alumina represent an almost regular quasicrystal structure (perfect aperiodic quasicrystals discovered in 1991 is not implied here). We show that, in this case, the radial distribution function is well described by the quasicrystal model, i.e., the smeared hexagonal lattice of the two-dimensional ideal crystal by inserting a certain amount of defects into the lattice. Another example is a system of hard disks in a plane, which illustrates the order to disorder transitions. It is shown that the coincidence with the distribution function, obtained by the solution of the Percus-Yevick equation, is achieved by the smoothing of the square lattice and injecting the defects of the vacancy type into it. However, a better approximation is reached when the lattice is a result of a mixture of the smoothened square and hexagonal lattices. Impurity of the hexagonal lattice is considerable at short distances. Dependences of the lattices constants, smoothing widths, and impurity on the filling parameter are found. Transition to the order occurs upon an increasing of the hexagonal lattice contribution and decreasing of smearing. Full article
(This article belongs to the Proceedings of The 1st International Electronic Conference on Crystals)
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20 pages, 34674 KiB  
Article
Entropy Analysis of the Interaction between the Corner Separation and Wakes in a Compressor Cascade
by Hao Wang, Dun Lin, Xinrong Su and Xin Yuan
Entropy 2017, 19(7), 324; https://doi.org/10.3390/e19070324 - 30 Jun 2017
Cited by 32 | Viewed by 6020
Abstract
The corner separation in the high-loaded compressors deteriorates the aerodynamics and reduces the stable operating range. The flow pattern is further complicated with the interaction between the aperiodic corner separation and the periodically wake-shedding vortices. Accurate prediction of the corner separation is a [...] Read more.
The corner separation in the high-loaded compressors deteriorates the aerodynamics and reduces the stable operating range. The flow pattern is further complicated with the interaction between the aperiodic corner separation and the periodically wake-shedding vortices. Accurate prediction of the corner separation is a challenge for the Reynolds-Averaged Navier–Stokes (RANS) method, which is based on the linear eddy-viscosity formulation. In the current work, the corner separation is investigated with the Delayed Detached Eddy Simulation (DDES) approach. DDES results agree well with the experiment and are systematically better than the RANS results, especially in the corner region where massive separation occurs. The accurate results from DDES provide a solid foundation for mechanism study. The flow structures and the distribution of Reynolds stress help reveal the process of corner separation and its interaction with the wake vortices. Before massive corner separation occurs, the hairpin-like vortex develops. The appearance of the hairpin-like vortex could be a signal of large-scale corner separation. The strong interaction between corner separation and wake vortices significantly enhances the turbulence intensity. Based on these analyses, entropy analysis is conducted from two aspects to study the losses. One aspect is the time-averaged entropy analysis, and the other is the instantaneous entropy analysis. It is found that the interaction between the passage vortex and wake vortex yields remarkable viscous losses over the 0–12% span when the corner separation has not yet been triggered; however, when the corner separation occurs, an enlarged region covering the 0–30% span is affected, and it is due to the interaction between the corner separation and wake vortices. The detailed coherent structures, local losses information and turbulence characteristics presented can provide guidance for the corner separation control and better design. Full article
(This article belongs to the Special Issue Entropy in Computational Fluid Dynamics)
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