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Search Results (562)

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19 pages, 32582 KB  
Article
Study on the Characteristics of Cement-Based Magnetoelectric Composites Using COMSOL
by Weixuan Huang, Cuijuan Pang, Jianyu Xu, Kangyang Liang, Cunying Fan, Zeyu Lu and Chuncheng Lu
Materials 2025, 18(21), 5027; https://doi.org/10.3390/ma18215027 - 4 Nov 2025
Viewed by 233
Abstract
A multiphysics-coupled 2–2 cement-based magnetoelectric composite model is established in COMSOL 6.2. This model is used to not only systematically investigate the magnetoelectric-coupling behavior, but also quantify the effects of the magnetic field, frequency, and layer-thickness ratio on the material’s magnetoelectric properties. The [...] Read more.
A multiphysics-coupled 2–2 cement-based magnetoelectric composite model is established in COMSOL 6.2. This model is used to not only systematically investigate the magnetoelectric-coupling behavior, but also quantify the effects of the magnetic field, frequency, and layer-thickness ratio on the material’s magnetoelectric properties. The results demonstrate that the model effectively reproduces the internal stress–strain distribution and voltage evolution. Specifically, the magnetostrictive and piezoelectric layers exhibit mechanical responses with pronounced non-uniformity, which is attributed to boundary effects. The bias magnetic field plays a crucial regulatory role: the output voltage increases linearly from 0 to 2000 Oe and then saturates at higher fields. Under an alternating magnetic field, the composite exhibits pronounced resonance characteristics, whose frequency is jointly governed by structural dimensions and the bias field. The dynamic response was further analyzed using the magnetic flux density modulus, displacement profiles at selected locations, and voltage evolution across the piezoelectric layer. Notably, the thickness of each functional phase exerts a pronounced and distinct influence on the composite’s magnetoelectric coupling, with markedly different trends between phases. Optimization results show that a thin piezoelectric layer combined with a thick magnetostrictive layer yields the highest magnetoelectric performance. Additionally, the longitudinal and transverse magnetoelectric coefficients exhibit markedly different coupling mechanisms—this is owing to the misalignment between the magnetic-field and electric-polarization directions, and this difference further reveals the intrinsic anisotropy of the magnetoelectric response. Overall, this study provides a crucial theoretical foundation for the design and optimization of high-performance cement-based magnetoelectric composites. Full article
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20 pages, 4788 KB  
Article
Vortex Dynamics Effects on the Development of a Confined Turbulent Wake
by Ioannis D. Kalogirou, Alexandros Romeos, Athanasios Giannadakis, Giouli Mihalakakou and Thrassos Panidis
Fluids 2025, 10(11), 283; https://doi.org/10.3390/fluids10110283 - 31 Oct 2025
Viewed by 190
Abstract
In the present work, the turbulent wake of a circular cylinder in a confined flow environment at a blockage ratio of 14% is experimentally investigated in a wind tunnel consisting of a parallel test section followed by a constant-area distorting duct, under subcritical [...] Read more.
In the present work, the turbulent wake of a circular cylinder in a confined flow environment at a blockage ratio of 14% is experimentally investigated in a wind tunnel consisting of a parallel test section followed by a constant-area distorting duct, under subcritical Re inlet conditions. The initial stage of wake development, extending from the bluff body to the end of the parallel section, is analyzed, with the use of hot-wire anemometry and laser-sheet visualization. The near field reveals partial similarity to unbounded wakes, with the principal difference being a modification of the Kármán vortex street topology, attributed to altered vortex dynamics under confinement. Further downstream, the mean and fluctuating velocity distributions of the confined wake gradually evolve toward channel-flow characteristics. To elucidate this transition, wake measurements are systematically compared with channel flow data obtained in the same configuration under identical inlet conditions and with reference channel-flow datasets from the literature. Experimental results show that a vortex-transportation mechanism exists due to confinement effect, resulting in the progressive crossing and realignment of counter-rotating vortices toward the tunnel centerline. Although wake flow characteristics are preserved, suppression of classical periodic shedding is clearly depicted. Furthermore, it is shown that the confined near-wake spectral peak persists up to x1/d~60 as in the free case and then vanishes as the spectra broadens. Coincidentally, the confined wake exhibits a narrower halfwidth than its free wake counterpart, while a centerline shift of the shed vortices is observed. Farfield wake-flow maintains strong anisotropy, while a weaker downstream growth of the streamwise integral scale is observed when compared to channel flow. Together, these findings explain how confinement reforms the nearfield topology and reorganizes momentum transport as the flow evolves to channel-like flow. Full article
(This article belongs to the Special Issue Industrial CFD and Fluid Modelling in Engineering, 3rd Edition)
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20 pages, 1574 KB  
Article
Analysis of Torsional Vibration of Single Pile in Orthotropic Layered Soil
by Zixin Lian, Yanzhi Zhu and Yongzhi Jiu
Buildings 2025, 15(21), 3834; https://doi.org/10.3390/buildings15213834 - 23 Oct 2025
Viewed by 258
Abstract
To address the difficulty in obtaining analytical solutions for the torsional vibration response of pile foundations in orthotropic layered soil foundations subjected to torsional excitation at the pile top, this study investigates a layered recursive algorithm based on the Hankel transform. An integral [...] Read more.
To address the difficulty in obtaining analytical solutions for the torsional vibration response of pile foundations in orthotropic layered soil foundations subjected to torsional excitation at the pile top, this study investigates a layered recursive algorithm based on the Hankel transform. An integral transformation method is employed to reduce the dimensionality of the coupled pile–soil torsional vibration equations, converting the three-dimensional system of partial differential equations into a set of ordinary differential equations. Combining the constitutive properties of transversely anisotropic strata with interlayer contact conditions, a transfer matrix model is established. Employing inverse transformation coupled with the Gauss–Kronrod integration method, an explicit frequency-domain solution for the torsional dynamic impedance at the pile top is derived. The research findings indicate that the anisotropy coefficient of the foundation significantly influences both the real and imaginary parts of the impedance magnitude. The sequence of soil layer distribution and the bonding state at interfaces jointly affect the nonlinear transmission characteristics of torque along the pile shaft. Full article
(This article belongs to the Section Building Structures)
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19 pages, 3386 KB  
Article
Wellbore Stability in Interbedded Weak Formations Utilizing a Shear-Based Method: Numerical Realization and Analysis
by Yuanhong Han, Qian Gao, Deliang Fu, Desheng Zhou, Ahmad Ghassemi, Zhiyu Zhou, Hongyong Guo and Haiyang Wang
Processes 2025, 13(11), 3389; https://doi.org/10.3390/pr13113389 - 23 Oct 2025
Viewed by 208
Abstract
This study employs a finite element approach to investigate wellbore stability in interbedded weak formations, such as unconsolidated layers, with a focus on the failure-tendency method, which is derived according to the principle of Mohr–Coulomb theory. The numerical model is successfully verified through [...] Read more.
This study employs a finite element approach to investigate wellbore stability in interbedded weak formations, such as unconsolidated layers, with a focus on the failure-tendency method, which is derived according to the principle of Mohr–Coulomb theory. The numerical model is successfully verified through analytical solutions for stress distributions around a borehole. Through finite element modeling, the method captures critical shear failure thresholds, exemplifying how variations in horizontal stress anisotropy, orientation of interbedded weak layers, and mechanical properties of layered geological formations impact wellbore stability in stratified formations. Results indicate that the potential unstable regions, aligned in the direction of minimum principal stress, and the range of unstable regions gradually enlarge as the internal cohesive strength decreases. By modeling heterogeneous rock sequences with explicit representation of interbedded weak layers and stress anisotropy, the analysis reveals that interbedded weak layers are prone to shear-driven borehole breakouts due to stress redistribution and relatively lower internal cohesive strength. As compressive stresses concentrate at interfaces between stiff and compliant layers, breakouts are induced at those weak layers along the interfaces; this type of failure is also manifested through a field borehole breakout observation. Simulation results reveal the significant influences of the mechanical properties of layered formations and in situ stress on the distribution of instability regions around a borehole. The study underscores the necessity of layer-specific geomechanical models to predict shear failure in complex layered geological formations and offers insights for optimizing drilling parameters to enhance wellbore stability in anisotropic, stratified subsurface environments. Full article
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45 pages, 10445 KB  
Review
A Critical Review on Synergistic Integration of Nanomaterials in 3D-Printed Concrete: Rheology to Microstructure and Eco-Functionality
by Siva Jamjala, Manivannan Thulasirangan Lakshmidevi, K. S. K. Karthik Reddy, Bidur Kafle and Riyadh Al-Ameri
Appl. Sci. 2025, 15(20), 11267; https://doi.org/10.3390/app152011267 - 21 Oct 2025
Viewed by 599
Abstract
The use of nanomaterials (NMs) in 3D printing concrete (3DPC) has shown significant advancements in enhancing both fresh and hardened properties. This review finds that their inclusion in printable concrete has altered the rheological properties of the mix by promoting thixotropy, extrudability, and [...] Read more.
The use of nanomaterials (NMs) in 3D printing concrete (3DPC) has shown significant advancements in enhancing both fresh and hardened properties. This review finds that their inclusion in printable concrete has altered the rheological properties of the mix by promoting thixotropy, extrudability, and buildability while simultaneously refining the microstructure to enhance mechanical strength. Studies further highlight that these additives impart functional properties, such as the photocatalytic activity of nano-TiO2, which enables self-cleaning ability and assists pollutant degradation. At the same time, carbon-based materials enhance electrical conductivity, thereby facilitating the development of innovative and multifunctional structures. Such incorporation also mitigates anisotropy by filling voids, creating crack-bridging networks, and reducing pore interconnectivity, thereby improving load distribution and structural cohesion in printed structures. Integrating topology optimisation with 3DPC has the potential to enable efficient material usage. Thus, it enhances both sustainability and cost-effectiveness. However, challenges such as efficient dispersion, agglomeration, energy-intensive production processes, high costs, and ensuring environmental compatibility continue to hinder their widespread adoption in concrete printing. This article emphasises the need for optimised NM dosages, effective dispersion techniques, and standardised testing methods, as well as sustainability considerations, for adapting NMs in concrete printing. Full article
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34 pages, 13918 KB  
Article
Integrated Petrophysics and 3D Modeling to Evaluate the Role of Diagenesis in Permeability of Clastic Reservoirs, Belayim Formation, Gulf of Suez
by Mohamed Fathy, Mahmoud M. Abdelwahab and Haitham M. Ayyad
Minerals 2025, 15(10), 1092; https://doi.org/10.3390/min15101092 - 20 Oct 2025
Viewed by 315
Abstract
Fluid flow prediction in clastic heterogeneous reservoirs is a universal issue, especially when diagenetic development supplants structural and depositional controls. We consider this issue in the Middle Miocene Belayim Formation of the Gulf of Suez, a principal syn-rift reservoir where extreme, diagenetically induced [...] Read more.
Fluid flow prediction in clastic heterogeneous reservoirs is a universal issue, especially when diagenetic development supplants structural and depositional controls. We consider this issue in the Middle Miocene Belayim Formation of the Gulf of Suez, a principal syn-rift reservoir where extreme, diagenetically induced pore system heterogeneity thwarts production. Although fault compartmentalization is understood as creating first-order traps, sub-seismic diagenetic controls on permeability anisotropy and reservoir within these traps are not restricted. This study uses a comprehensive set of petrophysical logs (ray gamma, resistivity, density, neutrons, sonic) of four key wells in the western field of Tawila (Tw-1, Tw-3, TW-4, TN-1). We apply an integrated workflow that explicitly derives permeability from petrophysical logs and populates it within a seismically defined structural framework. This study assesses diagenetic controls over reservoir permeability and fluid flow. It has the following primary objectives: (1) to characterize complicated diagenetic assemblage utilizing sophisticated petrophysical crossplots; (2) to quantify the role of shale distribution morphologies in affecting porosity effectiveness utilizing the Thomas–Stieber model; (3) to define hydraulic flow units (HFUs) based on pore throat geometry; and (4) to synthesize these observations within a predictive 3D reservoir model. This multiparadigm methodology, involving M-N crossplotting, Thomas–Stieber modeling, and saturation analysis, deconstructs Tawila West field reservoir complexity. Diagenesis that has the potential to destroy or create reservoir quality, namely the general occlusion of pore throats by dispersed, authigenic clays (e.g., illite) and anhydrite cement filling pores, is discovered to be the dominant control of fluid flow, defining seven unique hydraulic flow units (HFUs) bisecting the individual stratigraphic units. We show that reservoir units with comparable depositional porosity display order-of-magnitude permeability variation (e.g., >100 mD versus <1 mD) because of this diagenetic alteration, primarily via pore throat clogging resulting from widespread authigenic illite and pore occupation anhydrite cement, as quantitatively exemplified by our HFU characterization. A 3D model depicts a definitive NW-SE trend towards greater shale volume and degrading reservoir quality, explaining mysterious dry holes on structurally valid highs. Critically, these diagenetic superimpressions can replace the influence of structural geometry on reservoir performance. Therefore, we determine that a paradigm shift from a highly structured control model to an integrated petrophysical and mineralogical approach is needed. Sweet spot prediction relies upon predicting diagenetic facies distribution as a control over permeability anisotropy. Full article
(This article belongs to the Section Mineral Exploration Methods and Applications)
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28 pages, 5501 KB  
Article
Electrospun Fabrication of 1–3-Type PVP/SbSI and PVP/SbSeI Nanocomposites with Excellent Piezoelectric Properties for Nanogenerators and Sensors
by Bartłomiej Toroń, Wiktor Matysiak, Anna Starczewska, Jan Dec, Piotr Szperlich and Marian Nowak
Energies 2025, 18(20), 5506; https://doi.org/10.3390/en18205506 - 18 Oct 2025
Viewed by 423
Abstract
Electrospun one-dimensional nanocomposites composed of polyvinylpyrrolidone (PVP) matrices reinforced with antimony sulphoiodide (SbSI) or antimony selenoiodide (SbSeI) nanowires were fabricated for the first time. Their properties were investigated for applications in piezoelectric sensors and nanogenerators. Precise control of the electrospinning parameters produced nanofibres [...] Read more.
Electrospun one-dimensional nanocomposites composed of polyvinylpyrrolidone (PVP) matrices reinforced with antimony sulphoiodide (SbSI) or antimony selenoiodide (SbSeI) nanowires were fabricated for the first time. Their properties were investigated for applications in piezoelectric sensors and nanogenerators. Precise control of the electrospinning parameters produced nanofibres with diameters comparable to the lateral dimensions of the nanowires, ensuring parallel alignment and a 1–3 composite structure. Structural analysis confirmed uniform nanowire distribution and stoichiometry retention. In both nanocomposites, the alignment of the nanowires enables clear observation of the anisotropy of their piezoelectric properties. PVP/SbSI nanocomposites exhibited a ferroelectric–paraelectric transition near 290 K. Under air-pressure excitation of 17.03 bar, they generated a maximum piezoelectric voltage of 2.09 V, with a sensitivity of 229 mV/bar and a surface power density of 12.0 µW/cm2 for sandwich-type samples with nanowires aligned perpendicularly to the electrodes. PVP/SbSeI composites demonstrated stable semiconducting behaviour with a maximum piezoelectric voltage of 1.56 V, sensitivity of 130 mV/bar, and surface power density of 2.3 µW/cm2 for the same type of sample and excitation. The high piezoelectric coefficients d33 of 98 pC/N and 64 pC/N for PVP/SbSI and PVP/SbSeI, respectively, combined with mechanical flexibility, confirm the effectiveness of these nanocomposites as a practical solution for mechanical energy harvesting and pressure sensing in nanogenerators and sensors. Full article
(This article belongs to the Section D3: Nanoenergy)
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19 pages, 809 KB  
Article
The Mass Profile of NGC 3268 from Its Stellar Kinematics
by Juan Pablo Caso, Bruno Javier De Bórtoli and Tom Richtler
Universe 2025, 11(10), 344; https://doi.org/10.3390/universe11100344 - 16 Oct 2025
Viewed by 208
Abstract
The mass profile of the central galaxy of the Antlia cluster, NGC 3268, is studied through a spherical Jeans analysis, combined with a Bayesian approach. The prior distributions are derived from dark matter simulations. The observational dataset consists of Gemini/GMOS multi-object spectra observed [...] Read more.
The mass profile of the central galaxy of the Antlia cluster, NGC 3268, is studied through a spherical Jeans analysis, combined with a Bayesian approach. The prior distributions are derived from dark matter simulations. The observational dataset consists of Gemini/GMOS multi-object spectra observed from several programmes, supplemented with the kinematics of a small sample of globular clusters from the literature. An NFW mass profile and several options of constant anisotropy are considered. The analysis indicates a moderately massive halo, with a virial mass of (1.4 – 4.3) × 1013M, depending on the assumed anisotropy. A comparison with the kinematics of the galaxy population from the Antlia cluster suggests that a fraction of galaxies is not yet virialised and may currently be infalling into the cluster. Full article
(This article belongs to the Section Galaxies and Clusters)
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25 pages, 15326 KB  
Article
Macro–Micro Quantitative Model for Deformation Prediction of Artificial Structural Loess
by Yao Zhang, Chuhong Zhou, Heng Zhang, Zufeng Li, Xinyu Fan and Peixi Guo
Buildings 2025, 15(20), 3714; https://doi.org/10.3390/buildings15203714 - 15 Oct 2025
Viewed by 380
Abstract
To overcome the limitations imposed by the anisotropy and heterogeneity of natural loess, this study establishes a novel quantitative macro–micro correlation framework for investigating the deformation mechanisms of artificial structural loess (ASL). ASL samples were prepared by mixing remolded loess with cement (0–4%) [...] Read more.
To overcome the limitations imposed by the anisotropy and heterogeneity of natural loess, this study establishes a novel quantitative macro–micro correlation framework for investigating the deformation mechanisms of artificial structural loess (ASL). ASL samples were prepared by mixing remolded loess with cement (0–4%) and NaCl (0–16%), followed by static compaction (95% degree) and 28-day curing (20 ± 2 °C, >90% RH) to replicate the structural properties of natural loess under controlled conditions. An integrated experimental methodology was employed, incorporating consolidation/collapsibility tests, particle size analysis, X-ray diffraction (XRD), and mercury intrusion porosimetry (MIP). A three-dimensional nonlinear model was proposed. The findings show that intergranular cementation, particle size distribution, and pore architecture are the main factors influencing loess’s compressibility and collapsibility. A critical transition from medium to low compressibility was observed at cement content ≥1% and moisture content ≤16%. A strong correlation (Pearson |r| > 0.96) was identified between the mesopore volume ratio and the collapsibility coefficient. The innovation of this study lies in the establishment of a three-dimensional nonlinear model that quantitatively correlates key microstructural parameters (fractal dimension value (D), clay mineral ratio (C), and large and medium porosity (n)) with macroscopic deformation indicators (porosity ratio (e) and collapsibility coefficient (δs)). The measured data and the model’s output agree quite well, with a determination coefficient (R2) of 0.893 for porosity and 0.746 for collapsibility, verifying the reliability of the model. This study provides a novel quantitative tool for loess deformation prediction, offering significant value for engineering settlement assessment in controlled cementation and moisture conditions, though its application to natural loess requires further validation. Full article
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30 pages, 7521 KB  
Review
Probing the Sources of Ultra-High-Energy Cosmic Rays—Constraints from Cosmic-Ray Measurements
by Teresa Bister
Universe 2025, 11(10), 331; https://doi.org/10.3390/universe11100331 - 3 Oct 2025
Viewed by 423
Abstract
Ultra-high-energy cosmic rays (UHECRs) are the most energetic particles known—and yet their origin is still an open question. However, with the precision and accumulated statistics of the Pierre Auger Observatory and the Telescope Array, in combination with advancements in theory and modeling—e.g., of [...] Read more.
Ultra-high-energy cosmic rays (UHECRs) are the most energetic particles known—and yet their origin is still an open question. However, with the precision and accumulated statistics of the Pierre Auger Observatory and the Telescope Array, in combination with advancements in theory and modeling—e.g., of the Galactic magnetic field—it is now possible to set solid constraints on the sources of UHECRs. The spectrum and composition measurements above the ankle can be well described by a population of extragalactic, homogeneously distributed sources emitting mostly intermediate-mass nuclei. Additionally, using the observed anisotropy in the arrival directions, namely the large-scale dipole > 8 EeV, as well as smaller-scale warm spots at higher energies, even more powerful constraints on the density and distribution of sources can be placed. Yet, open questions remain—like the striking similarity of the sources that is necessary to describe the rather pure mass composition above the ankle, or the origin of the highest energy events whose tracked back directions point toward voids. The current findings and possible interpretation of UHECR data will be presented in this review. Full article
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23 pages, 4556 KB  
Article
Radiomics-Based Detection of Germ Cell Neoplasia In Situ Using Volumetric ADC and FA Histogram Features: A Retrospective Study
by Maria-Veatriki Christodoulou, Ourania Pappa, Loukas Astrakas, Evangeli Lampri, Thanos Paliouras, Nikolaos Sofikitis, Maria I. Argyropoulou and Athina C. Tsili
Cancers 2025, 17(19), 3220; https://doi.org/10.3390/cancers17193220 - 2 Oct 2025
Viewed by 486
Abstract
Background/Objectives: Germ Cell Neoplasia In Situ (GCNIS) is considered the precursor lesion for the majority of testicular germ cell tumors (TGCTs). The aim of this study was to evaluate whether first-order radiomics features derived from volumetric diffusion tensor imaging (DTI) metrics—specifically apparent diffusion [...] Read more.
Background/Objectives: Germ Cell Neoplasia In Situ (GCNIS) is considered the precursor lesion for the majority of testicular germ cell tumors (TGCTs). The aim of this study was to evaluate whether first-order radiomics features derived from volumetric diffusion tensor imaging (DTI) metrics—specifically apparent diffusion coefficient (ADC) and fractional anisotropy (FA) histogram parameters—can detect GCNIS. Methods: This study included 15 men with TGCTs and 10 controls. All participants underwent scrotal MRI, including DTI. Volumetric ADC and FA histogram metrics were calculated for the following tissues: group 1, TGCT; group 2: testicular parenchyma adjacent to tumor, histologically positive for GCNIS; and group 3, normal testis. Non-parametric statistics were used to assess differences in ADC and FA histogram parameters among the three groups. Pearson’s correlation analysis was followed by ordinal regression analysis to identify key predictive histogram parameters. Results: Widespread distributional differences (p < 0.05) were observed for many ADC and FA variables, with both TGCTs and GCNIS showing significant divergence from normal testes. Among the ADC statistics, the 10th percentile and skewness (p = 0.042), range (p = 0.023), interquartile range (p = 0.021), total energy (p = 0.033), entropy and kurtosis (p = 0.027) proved the most significant predictors for tissue classification. FA_energy (p = 0.039) was the most significant fingerprint of the carcinogenesis among the FA metrics. These parameters correctly characterized 88.8% of TGCTs, 87.5% of GCNIS tissues and 100% of normal testes. Conclusion: Radiomics features derived from volumetric ADC and FA histograms have promising potential to differentiate TGCTs, GCNIS, and normal testicular tissue, aiding early detection and characterization of pre-cancerous lesions. Full article
(This article belongs to the Special Issue Updates on Imaging of Common Urogenital Neoplasms 2nd Edition)
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17 pages, 5033 KB  
Article
The Influence Mechanism of a Scanning Strategy on the Fatigue Life of SLM 316L Stainless Steel Forming Parts
by Huijun Ma, Xiaoling Yan and Huiwen Fu
Materials 2025, 18(19), 4571; https://doi.org/10.3390/ma18194571 - 1 Oct 2025
Viewed by 521
Abstract
The quality of SLM formed parts is one of the key factors of the promotion and application of additive manufacturing technology. The scanning strategy fundamentally affects the fatigue life of SLM 316L stainless steel parts by regulating residual stress, defect distribution, and microstructure. [...] Read more.
The quality of SLM formed parts is one of the key factors of the promotion and application of additive manufacturing technology. The scanning strategy fundamentally affects the fatigue life of SLM 316L stainless steel parts by regulating residual stress, defect distribution, and microstructure. Three different scanning strategies (meander scanning, stripe scanning, and chessboard scanning) were adopted to prepare the specimens. High cycle fatigue loading was applied to SLM 316L stainless steel specimens prepared by different scanning strategies. The thermal conductivity characteristics during the SLM part forming process were analyzed based on scanning electron microscopy observations of microstructure of SLM specimens, and the mechanism of residual stress and internal defect generation were revealed. The scanning direction determines the growth direction of the grains, thereby affecting the anisotropy and overall fatigue performance of SLM 316L stainless steel parts. The scanning path determines the overlap and lap joint of the melt pool, directly affecting the number, size, and location of pores and incomplete fusion defects. The scanning strategy affects the distribution and magnitude of residual stresses by changing the path of heat source movement. Theoretical analysis and experimental verification results indicate that the selection of a scanning strategy is an effective method for optimizing the fatigue performance of SLM parts. Full article
(This article belongs to the Section Metals and Alloys)
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25 pages, 11327 KB  
Article
Synthesis-Dependent Magnetic Modifications in Starch-Coated CoFe2O4 Monodomain Nanoparticles: Structural, Magnetic and Spectroscopic Study
by Zorica Ž. Lazarević, Valentin N. Ivanovski, Aleksandra Milutinović, Marija Šuljagić, Ana Umićević, Jelena Belošević-Čavor and Ljubica Andjelković
Nanomaterials 2025, 15(19), 1504; https://doi.org/10.3390/nano15191504 - 1 Oct 2025
Viewed by 449
Abstract
This study investigates the structural and magnetic properties of CoFe2O4 nanoparticles prepared by five different synthesis methods: coprecipitation, ultrasound-assisted coprecipitation, coprecipitation coupled with mechanochemical treatment, microemulsion and microwave-assisted hydrothermal synthesis. The produced powders were additionally functionalized with starch to improve [...] Read more.
This study investigates the structural and magnetic properties of CoFe2O4 nanoparticles prepared by five different synthesis methods: coprecipitation, ultrasound-assisted coprecipitation, coprecipitation coupled with mechanochemical treatment, microemulsion and microwave-assisted hydrothermal synthesis. The produced powders were additionally functionalized with starch to improve biocompatibility and colloidal stability. The starch-coating procedure itself by sonication in starch solution, as well as its result, affects the structural and magnetic properties of functionalized nanoparticles. The resulting changes of properties in the process of ligand addition depend significantly on the starting nanoparticles, or rather, on the method of their synthesis. The structural, magnetic and spectroscopic properties of the resulting materials were systematically investigated using X-ray diffraction (XRD), Raman spectroscopy, Mössbauer spectroscopy and magnetic measurements. Taken together, XRD, Raman and Mössbauer spectroscopy show that starch deposition reduces structural disorder and internal stress, resulting in nanoparticles with a more uniform size distribution. These changes, in turn, affect all magnetic properties—magnetization, coercivity and magnetic anisotropy. Magnetic responses are preserved what is desirable for future biomedical applications. This work emphasizes the importance of surface modification for tailoring the properties of magnetic nanoparticles while maintaining their desired functionality. Full article
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21 pages, 1453 KB  
Article
First and Second Moments of Spherical Distributions That Are Relevant for Biological Applications
by Alexandra Shyntar and Thomas Hillen
Axioms 2025, 14(10), 743; https://doi.org/10.3390/axioms14100743 - 30 Sep 2025
Viewed by 424
Abstract
Spherical distributions, in particular, the von Mises–Fisher distribution, are often used to analyze directional data. The first and second moments of these distributions are of central interest, as they describe mean orientations as well as anisotropic diffusion tensors. Finding these moments often requires [...] Read more.
Spherical distributions, in particular, the von Mises–Fisher distribution, are often used to analyze directional data. The first and second moments of these distributions are of central interest, as they describe mean orientations as well as anisotropic diffusion tensors. Finding these moments often requires a numerical approximation of complex trigonometric integrals. Instead, we apply the divergence theorem on suitable domains to derive explicit forms of the first and second moments for n-dimensional von Mises–Fisher and peanut distributions. Based on these new formulas, we characterize some meaningful characteristics of these distributions: fractional anisotropy and the anisotropy ratio. We find, surprisingly, that the peanut distribution has an upper bound on anisotropy, while the von-Mises Fisher distribution has no such bound. As a side benefit, we find different forms of some identities for Bessel functions. Full article
(This article belongs to the Special Issue Advances in Mathematical Modeling and Related Topics)
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12 pages, 7003 KB  
Article
The Comparison of Microstructure, Phase Composition and Mechanical Properties of Inconel 625 Alloys Obtained by Wire Arc and Wire Electron Beam Additive Manufacturing
by Denis Gurianov, Sergey Fortuna, Sergei Tarasov, Vyacheslav Semenchuk, Nikolay Shamarin, Andrey Chumaevskii, Valery Rubtsov, Alexander M. Korsunsky and Evgeny Kolubaev
Crystals 2025, 15(10), 848; https://doi.org/10.3390/cryst15100848 - 29 Sep 2025
Viewed by 528
Abstract
The present paper compares the microstructure and mechanical properties of Inconel 625 alloy samples produced by using wire-arc additive manufacturing (WAAM) and wire electron beam additive manufacturing (WEBAM). The obtained wall-shaped samples did not contain any macroscopic defects in the form of cracks, [...] Read more.
The present paper compares the microstructure and mechanical properties of Inconel 625 alloy samples produced by using wire-arc additive manufacturing (WAAM) and wire electron beam additive manufacturing (WEBAM). The obtained wall-shaped samples did not contain any macroscopic defects in the form of cracks, delaminations and geometry distortions. The WAAM-built “wall” exhibits finer dendritic structures (WAAM—10–16 μm; WEBAM—20–25 μm). Also, the WAAM-built one is characterized by the more homogeneous-sized distribution of microstructure components. In both cases, the material is represented by the γ-phase, with large precipitates of MC-type carbides in the interdendritic spaces. Additionally, the sample obtained using the WAAM contained aluminum oxide. It was found that the intrinsic periodic heat treatment is not sufficient for the formation of the γ″-phase, and it is necessary to perform a subsequent long-term aging. However, the overall mechanical properties of both samples show similar levels of yield stress and ultimate tensile strength, and demonstrate the same degree of anisotropy. Full article
(This article belongs to the Section Crystalline Metals and Alloys)
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