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Search Results (357)

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Keywords = anisotropic strain

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17 pages, 4552 KiB  
Article
Trans-Scale Progressive Failure Analysis Methodology for Composite Materials Incorporating Interfacial Phase Effect
by Zhijie Li, Fei Peng, Jian Zhao, Sujuan Guo, Lefei Hu and Yu Gong
Materials 2025, 18(15), 3667; https://doi.org/10.3390/ma18153667 - 4 Aug 2025
Abstract
Fiber-reinforced resin matrix composites are generally composed of fibers and matrix with significantly different properties, which are non-uniform and anisotropic in nature. Macro-failure criteria generally view composite plies as a uniform whole and do not accurately reflect fiber- and matrix-scale failures. In this [...] Read more.
Fiber-reinforced resin matrix composites are generally composed of fibers and matrix with significantly different properties, which are non-uniform and anisotropic in nature. Macro-failure criteria generally view composite plies as a uniform whole and do not accurately reflect fiber- and matrix-scale failures. In this study, the interface phase effect between fiber and matrix has been introduced into the frame of trans-scale analysis to better model the failure process, and the equivalent mechanical property characterization model of the interface phase has also been established. Combined with the macro–micro-strain transfer method, the trans-scale correlation of the mechanical response of the composite laminates between the macro scale and the fiber, matrix and interface micro scale has been achieved. Based on the micro-scale failure criterion and the stiffness reduction strategy, the trans-scale failure analysis method of composite materials incorporating the interface phase effect has been developed, which can simultaneously predict the failure modes of the matrix, fiber and interface phase. A numerical implementation of the developed trans-scale failure analysis method considering interface phase was carried out using the Python and Abaqus 2020 joint simulation technique. Case studies were carried out for three material systems, and the prediction data of the developed trans-scale failure analysis methodology incorporating interface phase effects for composite materials, the prediction data of the Linde failure criterion and the experimental data were compared. The comparison with experimental data confirms that this method has good prediction accuracy, and compared with the Linde and Hashin failure methods, only it can predict the failure mode of the fiber–matrix interface. The case analysis shows that its prediction accuracy has been improved by about 2–3%. Full article
(This article belongs to the Special Issue Fatigue Damage, Fracture Mechanics of Structures and Materials)
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20 pages, 3657 KiB  
Article
Numerical Study of Chemo–Mechanical Coupling Behavior of Concrete
by Feng Guo, Weijie He, Longlong Tu and Huiming Hou
Buildings 2025, 15(15), 2725; https://doi.org/10.3390/buildings15152725 - 1 Aug 2025
Viewed by 189
Abstract
Subsurface mass concrete infrastructure—including immersed tunnels, dams, and nuclear waste containment systems—frequently faces calcium-leaching risks from prolonged groundwater exposure. An anisotropic stress-leaching damage model incorporating microcrack propagation is developed for underground concrete’s chemo–mechanical coupling. This model investigates stress-induced anisotropy in concrete through the [...] Read more.
Subsurface mass concrete infrastructure—including immersed tunnels, dams, and nuclear waste containment systems—frequently faces calcium-leaching risks from prolonged groundwater exposure. An anisotropic stress-leaching damage model incorporating microcrack propagation is developed for underground concrete’s chemo–mechanical coupling. This model investigates stress-induced anisotropy in concrete through the evolution of oriented microcrack networks. The model incorporates nonlinear anisotropic plastic strain from coupled chemical–mechanical damage. Unlike conventional concrete rheology, this model characterizes chemical creep through stress-chemical coupled damage mechanics. The numerical model is incorporated within COMSOL Multiphysics to perform coupled multiphysics simulations. A close match is observed between the numerical predictions and experimental findings. Under high stress loads, calcium leaching and mechanical stress exhibit significant coupling effects. Regarding concrete durability, chemical degradation has a more pronounced effect on concrete’s stiffness and strength reduction compared with stress-generated microcracking. Full article
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14 pages, 4974 KiB  
Article
Investigation of the Evolution of Anisotropic Full-Field Strain Characteristics of Coal Samples Under Creep Loading Conditions
by Xuguang Li, Yu Wang, Xuefeng Yi and Xinyu Bai
Appl. Sci. 2025, 15(15), 8355; https://doi.org/10.3390/app15158355 - 27 Jul 2025
Viewed by 187
Abstract
This work aims to reveal the full-field strain evolution characteristics and failure mechanisms of anisotropic coal samples under creep loading. A series of compression tests combined with digital image correlation (DIC) monitoring were employed to characterize the strain evolution process of coal specimens [...] Read more.
This work aims to reveal the full-field strain evolution characteristics and failure mechanisms of anisotropic coal samples under creep loading. A series of compression tests combined with digital image correlation (DIC) monitoring were employed to characterize the strain evolution process of coal specimens with bedding angles of 0°, 30°, 60°, and 90°. Testing results show that the peak strength, peak strain, and the creep loading stage of coal are significantly influenced by the bedding angle. The peak strength initially decreases and then increases as the bedding angle increases. In addition, the creep failure of coal manifests as a process of instantaneous deformation, decelerating creep, steady-state creep, accelerating creep, and failure. Under graded creep loading conditions, coal specimens exhibit distinct creep characteristics at high stress levels. Moreover, the bedding angle significantly influences the strain field evolution of the coal samples. Finally, for coal specimens with bedding angles of 0° and 90°, the final macroscopic fracture pattern upon failure is characterized by longitudinal tensile splitting. In contrast, coal samples with bedding angles of 30° and 60° tend to exhibit failure along the bedding interfaces, forming tensile-shear fractures. The results of this study will provide theoretical guidance for the prevention, early warning, and safety management of coal mine disasters. Full article
(This article belongs to the Topic Failure Characteristics of Deep Rocks, Volume II)
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16 pages, 1420 KiB  
Article
Light-Driven Quantum Dot Dialogues: Oscillatory Photoluminescence in Langmuir–Blodgett Films
by Tefera Entele Tesema
Nanomaterials 2025, 15(14), 1113; https://doi.org/10.3390/nano15141113 - 18 Jul 2025
Viewed by 315
Abstract
This study explores the optical properties of a close-packed monolayer composed of core/shell-alloyed CdSeS/ZnS quantum dots (QDs) of two different sizes and compositions. The monolayers were self-assembled in a stacked configuration at the water/air interface using Langmuir–Blodgett (LB) techniques. Under continuous 532 nm [...] Read more.
This study explores the optical properties of a close-packed monolayer composed of core/shell-alloyed CdSeS/ZnS quantum dots (QDs) of two different sizes and compositions. The monolayers were self-assembled in a stacked configuration at the water/air interface using Langmuir–Blodgett (LB) techniques. Under continuous 532 nm laser illumination on the red absorption edge of the blue-emitting smaller QDs (QD450), the red-emitting larger QDs (QD645) exhibited oscillatory temporal dynamics in their photoluminescence (PL), characterized by a pronounced blueshift in the emission peak wavelength and an abrupt decrease in peak intensity. Conversely, excitation by a 405 nm laser on the blue absorption edge induced a drastic redshift in the emission wavelength over time. These significant shifts in emission spectra are attributed to photon- and anisotropic-strain-assisted interlayer atom transfer. The findings provide new insights into strain-driven atomic rearrangements and their impact on the photophysical behavior of QD systems. Full article
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17 pages, 2783 KiB  
Article
Hydrostatic-Pressure Modulation of Band Structure and Elastic Anisotropy in Wurtzite BN, AlN, GaN and InN: A First-Principles DFT Study
by Ilyass Ez-zejjari, Haddou El Ghazi, Walid Belaid, Redouane En-nadir, Hassan Abboudi and Ahmed Sali
Crystals 2025, 15(7), 648; https://doi.org/10.3390/cryst15070648 - 15 Jul 2025
Viewed by 369
Abstract
III-Nitride semiconductors (BN, AlN, GaN, and InN) exhibit exceptional electronic and mechanical properties that render them indispensable for high-performance optoelectronic, power, and high-frequency device applications. This study implements first-principles Density Functional Theory (DFT) calculations to elucidate the influence of hydrostatic pressure on the [...] Read more.
III-Nitride semiconductors (BN, AlN, GaN, and InN) exhibit exceptional electronic and mechanical properties that render them indispensable for high-performance optoelectronic, power, and high-frequency device applications. This study implements first-principles Density Functional Theory (DFT) calculations to elucidate the influence of hydrostatic pressure on the electronic, elastic, and mechanical properties of these materials in the wurtzite crystallographic configuration. Our computational analysis demonstrates that the bandgap energy exhibits a positive pressure coefficient for GaN, AlN, and InN, while BN manifests a negative pressure coefficient consistent with its indirect-bandgap characteristics. The elastic constants and derived mechanical properties reveal material-specific responses to applied pressure, with BN maintaining superior stiffness across the pressure range investigated, while InN exhibits the highest ductility among the studied compounds. GaN and AlN demonstrate intermediate mechanical robustness, positioning them as optimal candidates for pressure-sensitive applications. Furthermore, the observed nonlinear trends in elastic moduli under pressure reveal anisotropic mechanical responses during compression, a phenomenon critical for the rational design of strain-engineered devices. The computational results provide quantitative insights into the pressure-dependent behavior of III-N semiconductors, facilitating their strategic implementation and optimization for high-performance applications in extreme environmental conditions, including high-power electronics, deep-space exploration systems, and high-pressure optoelectronic devices. Full article
(This article belongs to the Section Materials for Energy Applications)
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25 pages, 3458 KiB  
Article
Comparative Analysis and Performance Evaluation of SSC, n-SAC, and Creep-SCLAY1S Soil Creep Models in Predicting Soil Settlement
by Tulasi Ram Bhattarai, Netra Prakash Bhandary and Gustav Grimstad
Geotechnics 2025, 5(3), 47; https://doi.org/10.3390/geotechnics5030047 - 9 Jul 2025
Viewed by 221
Abstract
The precise prediction of soil settlement under applied loads is of paramount importance in the field of geotechnical engineering. Conventional analytical approaches often lack the capacity to accurately represent the rate-dependent deformations exhibited by soft soils. Creep affects the integrity of geotechnical structures [...] Read more.
The precise prediction of soil settlement under applied loads is of paramount importance in the field of geotechnical engineering. Conventional analytical approaches often lack the capacity to accurately represent the rate-dependent deformations exhibited by soft soils. Creep affects the integrity of geotechnical structures and can lead to loss of serviceability or even system failure. Over time, they deform, the soil structure can be weakened, and consequently, the risk of collapse increases. Despite extensive research, regarding the creep characteristics of soft soils, the prediction of creep deformation remains a substantial challenge. This study explores soil consolidation settlement by employing three different material models: the Soft Soil Creep (SSC) model implemented in PLAXIS 2D, alongside two user-defined elasto-viscoplastic models, specifically Creep-SCLAY1S and the non-associated creep model for Structured Anisotropic Clay (n-SAC). Through the simulation of laboratory experiments and the Lilla Mellösa test embankment situated in Sweden, the investigation evaluates the strengths and weaknesses of these models. The results demonstrate that the predictions produced by the SSC, n-SAC, and Creep-SCLAY1S models are in close correspondence with the field observations, in contrast to the more simplistic elastoplastic model. The n-SAC and Creep-SCLAY1S models adeptly represent the stress–strain response in CRS test simulations; however, they tend to over-predict horizontal deformations in field assessments. Further investigation is advisable to enhance the ease of use and relevance of these sophisticated models. Full article
(This article belongs to the Special Issue Recent Advances in Geotechnical Engineering (2nd Edition))
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14 pages, 5151 KiB  
Article
Scale-Model Experiment on the Delayed Failure Mechanism of Deep Tunnels in Brittle Rock
by Ning Zhang and Ziwei Chen
Appl. Sci. 2025, 15(13), 7496; https://doi.org/10.3390/app15137496 - 3 Jul 2025
Viewed by 276
Abstract
Rock bursts usually happen during the hours or days after tunnel excavation, even in an unsupported opening where no collapses occur. To investigate the mechanism of those delayed failures in brittle rock tunnels, this paper showcases the performed scale-model test based upon the [...] Read more.
Rock bursts usually happen during the hours or days after tunnel excavation, even in an unsupported opening where no collapses occur. To investigate the mechanism of those delayed failures in brittle rock tunnels, this paper showcases the performed scale-model test based upon the Jinping II headrace tunnelling project. The model test was conducted in a particularly designed loading apparatus; the scale-model is composed of a similar material for the deep brittle rock. The tunnel in the scale-model is excavated by a specially made drilling tool. The failure mode of the deep circle tunnel under isotropic and anisotropic geostress were obtained; the delay failure time was recorded, and the accompanying stresses and strains changing were monitored. Under isotropic geostress the failure shape has a smooth circle boundary, failure process totally costs 56 h. While under anisotropic geostress a dog-eared breakdown was found, the failure process amounted to 72 h. The time-to-failure was evaluated by delay failure theory, and the evaluation equation was implemented into in FEM code. Numerical simulations have been performed to simulate the failure time and failure mode. The numerical results of failure time and failure mode mainly match the scale-model testing results. Full article
(This article belongs to the Section Civil Engineering)
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13 pages, 3840 KiB  
Article
Second Harmonic Generation Imaging of Strain-Induced Domain Evolution Across Grain Boundaries in SrTiO3 Bicrystals
by Yuhang Ren and Piyali Maity
Surfaces 2025, 8(3), 47; https://doi.org/10.3390/surfaces8030047 - 1 Jul 2025
Viewed by 371
Abstract
Understanding strain behavior near grain boundaries is critical for controlling structural distortions and oxygen vacancy migration in perovskite oxides. However, conventional techniques often lack the spatial resolution needed to analyze phase and domain evolution at the nanoscale. In this paper, polarization-dependent second-harmonic generation [...] Read more.
Understanding strain behavior near grain boundaries is critical for controlling structural distortions and oxygen vacancy migration in perovskite oxides. However, conventional techniques often lack the spatial resolution needed to analyze phase and domain evolution at the nanoscale. In this paper, polarization-dependent second-harmonic generation (SHG) imaging is employed as a tool to probe local symmetry breaking and complex domain structures in the vicinity of a low-angle grain boundary of SrTiO3 (STO) bicrystals. We show that the anisotropic strain introduced by a tilted grain boundary produces strong local distortions, leading to the coexistence of tetragonal and rhombohedral domains. By analyzing SHG intensity and variations in the second-order nonlinear optical susceptibility, we map the distribution of strain fields and domain configurations near the boundary. In pristine samples, the grain boundary acts as a localized source of strain accumulation and symmetry breaking, while in samples subjected to intentional electrical stressing, the SHG response becomes broader and more uniform, suggesting strain relaxation. This work highlights SHG imaging as a powerful technique for visualizing grain-boundary-driven structural changes, with broad implications for the design of strain-engineered functional oxide devices. Full article
(This article belongs to the Collection Featured Articles for Surfaces)
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18 pages, 3549 KiB  
Article
Dynamic Statistical Mechanics Modeling of Percolation Networks in Conductive Polymer Composites for Smart Sensor Applications
by Sang-Un Kim and Joo-Yong Kim
Materials 2025, 18(13), 3097; https://doi.org/10.3390/ma18133097 - 30 Jun 2025
Viewed by 345
Abstract
Conductive polymer composites (CPCs) are widely used in flexible electronics due to their tunable electrical properties and mechanical deformability. However, accurately predicting the evolution of conductive networks, particularly under compressive strain, remains a significant challenge. In this study, we developed a statistical mechanics [...] Read more.
Conductive polymer composites (CPCs) are widely used in flexible electronics due to their tunable electrical properties and mechanical deformability. However, accurately predicting the evolution of conductive networks, particularly under compressive strain, remains a significant challenge. In this study, we developed a statistical mechanics model and an extended dynamic statistical mechanics model to quantitatively describe percolation behavior in CPCs. The static model incorporates filler geometry, aspect ratio (AR), and surface-to-volume ratio, and was validated using Monte Carlo simulations. Results show that the percolation threshold for spherical fillers was 0.11965, while significantly lower values of 0.00669 and 0.00203 were observed for plate- and rod-shaped fillers, respectively, confirming the enhanced connectivity of anisotropic particles. To capture strain-dependent behavior, a dynamic model was constructed using a Smoluchowski-type gain–loss framework. This model separates conductive network formation (gain) from network disconnection (loss) caused by filler alignment and Poisson-induced expansion. At high Poisson’s ratios (0.3 and 0.5), the model accurately predicted the reduction in connectivity, particularly for anisotropic fillers. Across all tested conditions, the model exhibited strong agreement with simulation data, with RMSE values ranging from 0.0004 to 0.0449. The results confirm that high AR fillers enhance conductivity under compression, while large Poisson’s ratios suppress network formation. These findings provide a reliable, physically grounded modeling framework for designing strain-sensitive devices such as flexible pressure sensors. Full article
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18 pages, 8142 KiB  
Article
Influence of Principal Stress Orientation on Cyclic Degradation of Soft Clay Under Storm Wave Loading
by Chengcong Hu, Feng Gao, Biao Huang, Peipei Li, Zheng Hu and Kun Pan
J. Mar. Sci. Eng. 2025, 13(7), 1227; https://doi.org/10.3390/jmse13071227 - 26 Jun 2025
Viewed by 298
Abstract
Coastal marine soft clays subjected to long-term storm wave loading often exhibit inclined initial principal stress orientation (α0) and subsequent cyclic principal stress rotation (PSR). These stress states critically influence soil mechanical behavior and failure mechanisms, threatening offshore structural stability. [...] Read more.
Coastal marine soft clays subjected to long-term storm wave loading often exhibit inclined initial principal stress orientation (α0) and subsequent cyclic principal stress rotation (PSR). These stress states critically influence soil mechanical behavior and failure mechanisms, threatening offshore structural stability. This study employs hollow cylinder apparatus testing to investigate the undrained cyclic loading behavior of reconstituted soft clay under controlled α0 and PSR conditions, simulating storm wave-induced stress paths. Results demonstrate that α0 governs permanent pore pressure and vertical strain accumulation with distinct mechanisms, e.g., a tension-dominated response with gradual pore pressure rise at α0 < 45° transitions to a compression-driven rapid strain accumulation at α0 > 45°. Rotational loading with PSR significantly intensifies permanent strain accumulation and stiffness degradation rates, exacerbating soil’s anisotropic behavior. Furthermore, the stiffness degradation index tends to uniquely correlate with the permanent axial or shear strain, which can be quantified by an exponential relationship that is independent of α0 and PSR, providing a unified framework for normalizing stiffness evolution across diverse loading paths. These findings advance the understanding of storm wave-induced degradation behavior of soft clay and establish predictive tools for optimizing marine foundation design under cyclic loading. Full article
(This article belongs to the Section Coastal Engineering)
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16 pages, 1205 KiB  
Article
Theoretical Prediction of the Impact of Phosphorus Doping on the Elastic Constants of Silicon
by Azadeh Jafari and Behraad Bahreyni
Micromachines 2025, 16(7), 748; https://doi.org/10.3390/mi16070748 - 25 Jun 2025
Viewed by 1200
Abstract
Accurately controlling the mechanical properties of silicon is essential for developing high-performance micro-devices and systems. In this study, we investigate the influence of phosphorus doping on the elastic constants of silicon across a wide temperature range using a combination of tight-binding simulations and [...] Read more.
Accurately controlling the mechanical properties of silicon is essential for developing high-performance micro-devices and systems. In this study, we investigate the influence of phosphorus doping on the elastic constants of silicon across a wide temperature range using a combination of tight-binding simulations and deformation potential theory. The mechanical properties were derived using Keyes’s framework integrated with Fermi–Dirac statistics. The Goodwin–Skinner–Pettifor functional form was applied to estimate dopant-induced stress potentials and their effect on lattice stiffness. In particular, we investigated the change in elastic constants and their temperature dependence under ultra-high doping concentrations. The results show a monotonic decrease in c11 and a non-monotonic increase in c12 with both temperature and doping, while c44 remains relatively unaffected, consistent with experimental and theoretical studies. These changes are attributed to anisotropic carrier redistribution among conduction band valleys and strain-modulated interactions between valleys. The novelty of this work lies in the explicit, atomistically informed calculation of deformation potential constants using tight-binding parameters specific to phosphorus doping in silicon, enabling the accurate prediction of temperature-dependent elastic constants and anisotropic mechanical behaviour in emerging microsystem applications. Full article
(This article belongs to the Collection Women in Micromachines)
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17 pages, 4562 KiB  
Article
Study on Anisotropic Mechanical Properties of Single-Crystal Silicon at Different Strain Rates
by Zhongwang Tian, Wei Xue, Wenzhong Lou, Min Liu, Hengzhen Feng, Xiaoxia Wang, Shiteng Li and Shaokuan Wu
Micromachines 2025, 16(7), 744; https://doi.org/10.3390/mi16070744 - 25 Jun 2025
Viewed by 429
Abstract
To examine the impact of the strain rate on the anisotropic mechanical characteristics of single-crystal silicon, nanoindentation and micro-tensile–compression tests were performed. This study analyzed the effects of varying crystal orientations at different strain rates on load–displacement behavior, elastic modulus, hardness, fracture toughness, [...] Read more.
To examine the impact of the strain rate on the anisotropic mechanical characteristics of single-crystal silicon, nanoindentation and micro-tensile–compression tests were performed. This study analyzed the effects of varying crystal orientations at different strain rates on load–displacement behavior, elastic modulus, hardness, fracture toughness, and true stress–strain responses. The nanoindentation results showed that at room temperature, single-crystal silicon exhibited an elastic recovery rate of approximately 42%. Notably, the elastic modulus remained unaffected by strain rate variations, whereas hardness increased with higher strain rates. Fracture toughness at room temperature displayed marked anisotropy, with the <100> orientation exhibiting the lowest value at 0.691 MPa·m1/2 and the <110> orientation showing the highest one at 0.797 MPa·m1/2. Additionally, tensile and compression experiments revealed that the fracture strength of <100>-oriented silicon increased from 117 MPa at a strain rate of 0.001 s−1 to 550 MPa at a strain rate of 0.01 s−1. Full article
(This article belongs to the Special Issue Recent Advances in Silicon-Based MEMS Sensors and Actuators)
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18 pages, 6693 KiB  
Article
Tensile Resistance and Fracture Mechanisms of Silica Aerogels Reinforced by Nanotube–Graphene Hybrid Networks
by Lin Guo, Mu Du, Jiaqian Li, Wei Li, Mingyang Yang and Gongming Xin
Gels 2025, 11(6), 471; https://doi.org/10.3390/gels11060471 - 19 Jun 2025
Viewed by 370
Abstract
Despite their outstanding thermal insulation and ultralight structure, silica aerogels suffer from inherent mechanical fragility, making the investigation of their mechanical behavior crucial for expanding their practical utility in advanced applications. To enhance their mechanical performance, this study introduces a dual-phase reinforcement strategy [...] Read more.
Despite their outstanding thermal insulation and ultralight structure, silica aerogels suffer from inherent mechanical fragility, making the investigation of their mechanical behavior crucial for expanding their practical utility in advanced applications. To enhance their mechanical performance, this study introduces a dual-phase reinforcement strategy by anisotropically incorporating carbon nanotubes (CNTs) and graphene oxide (GO) sheets into the aerogel matrix. Using molecular dynamic simulations, we systematically investigate the tensile behavior and pore structure evolution of these hetero-structured composites. The results reveal a non-monotonic dependence of tensile strength on loading ratio, distinguishing three strain-dependent reinforcement regimes. High loading content (11.1%) significantly improves strength under low strain (0–26%), whereas low loading levels (1.8%) are more effective at preserving structural integrity under large strain (44–50%). Moderate loading (5.1%) yields balanced performance in intermediate regimes. While increasing carbon content reduces initial pore size by partially filling the framework, tensile deformation leads to interfacial debonding and the formation of larger pores due to CNT–GO hybrid structure interactions. This work elucidates a dual reinforcement mechanism—physical pore confinement and interfacial coupling—highlighting the critical role of nanostructure geometry in tuning strain-specific mechanical responses. The findings provide mechanistic insights into anisotropic nanocomposite behavior and offer guidance for designing robust porous materials for structural and functional applications. Full article
(This article belongs to the Special Issue Aerogels: Synthesis and Applications)
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17 pages, 2559 KiB  
Article
Thermal Strain and Microstrain in a Polymorphic Schiff Base: Routes to Thermosalience
by Teodoro Klaser, Marko Jaklin, Jasminka Popović, Ivan Grgičević and Željko Skoko
Molecules 2025, 30(12), 2567; https://doi.org/10.3390/molecules30122567 - 12 Jun 2025
Viewed by 369
Abstract
We present a comprehensive structural and thermomechanical investigation of N-salicylideneaniline, a Schiff base derivative that exhibits remarkable thermosalient phase transition behavior. By combining variable-temperature X-ray powder diffraction (VT-XRPD), differential scanning calorimetry (DSC), hot-stage microscopy, and Hirshfeld surface analysis, we reveal two distinct [...] Read more.
We present a comprehensive structural and thermomechanical investigation of N-salicylideneaniline, a Schiff base derivative that exhibits remarkable thermosalient phase transition behavior. By combining variable-temperature X-ray powder diffraction (VT-XRPD), differential scanning calorimetry (DSC), hot-stage microscopy, and Hirshfeld surface analysis, we reveal two distinct thermosalient mechanisms operating in different polymorphic forms. Form I displays pronounced anisotropic thermal expansion with negative strain along a principal axis, culminating in a sudden and explosive phase transition into Form IV. In contrast, Form III transforms more gradually through a microstrain accumulation mechanism. Fingerprint plots and contact evolution from Hirshfeld surface analysis further support this dual-mechanism model. These insights highlight the importance of integrating macro- and microscale structural descriptors to fully capture the mechanical behavior of responsive molecular solids. The findings not only enhance the fundamental understanding of thermosalience but also inform the rational design of functional materials for actuating and sensing applications. Full article
(This article belongs to the Section Materials Chemistry)
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17 pages, 1899 KiB  
Article
Structural Mechanics of the Flight Feather Rachis: The Role of Cortical Keratin Asymmetry
by Hao Wu, Ju-Cheng Hsiao, Wan-Chi Liao, You-Sian Wang, Xiang-Ning Xie and Wen-Tau Juan
Symmetry 2025, 17(6), 880; https://doi.org/10.3390/sym17060880 - 5 Jun 2025
Viewed by 470
Abstract
The flight feather rachis is a lightweight, anisotropic structure that must withstand asymmetric aerodynamic loads generated during flapping flight—particularly under unidirectional compression during the wing downstroke. To accommodate this spatiotemporal loading regime, the rachis exhibits refined internal organization, especially along the dorsoventral axis. [...] Read more.
The flight feather rachis is a lightweight, anisotropic structure that must withstand asymmetric aerodynamic loads generated during flapping flight—particularly under unidirectional compression during the wing downstroke. To accommodate this spatiotemporal loading regime, the rachis exhibits refined internal organization, especially along the dorsoventral axis. In this study, we used finite element modeling (FEM) to investigate how dorsoventral polarization in cortical keratin allocation modulates the mechanical performance of shaft-like structures under bending. All models were constructed with conserved second moments of area and identical material properties to isolate the effects of spatial material placement. We found that dorsal-biased reinforcement delays yield onset, enhances strain dispersion, and promotes elastic recovery, while ventral polarization leads to premature strain localization and plastic deformation. These outcomes align with the dorsally thickened rachises observed in flight-specialized birds and reflect their adaptation to asymmetric aerodynamic forces. In addition, we conducted a conceptual exploration of radial (cortex–medulla) redistribution, suggesting that even inner–outer asymmetry may contribute to directional stiffness tuning. Together, our findings highlight how the flight feather rachis integrates cortical material asymmetry to meet directional mechanical demands, offering a symmetry-informed framework for understanding biological shaft performance. Full article
(This article belongs to the Section Life Sciences)
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