Search Results (35)

As part of a fundamental and comprehensive monitoring and conservation of the tomb of Emperor Otto the Great in the cathedral of Magdeburg, the question of the provenance of the marble cover slab of the sarcophagus was investigated. Within the restoration activities, two samples of the slab were taken for scientific provenance analyses, one sample of the white marble and another of the irregular grey bands. The following investigations were used for this purpose: analysis of the stable isotopes of O and C, and chemical analysis of a large number of trace elements, resulting in a large number of variables. For the simultaneous evaluation of these numerical results, statistical multivariate analysis was used for comparing the results with our database of approximately 7000 samples from ancient marble quarries and the data being referenced in this investigation are published and listed here. The results obtained clearly identify the quarries of Prokonnesos in the Sea of Marmara as the most probable source of the examined slab. This is in perfect agreement with petrographic analyses carried out on these samples. Full article

This paper presents an outline of a historical stone: the Marble of Campiglia, from Tuscany (Italy). A comprehensive review of the literature and archival documents, combined with a new detailed field survey, allowed us to revise the geological setting and exploitation history of this cultural heritage marble, which has been sporadically utilized from Etruscan times to the present day. The Campiglia Marittima Marble (CMM) has a thermal-metamorphic origin associated with the intrusion of a granitic pluton dated to approximately 5.4 Ma. This process gave rise to a marble with peculiar textural, grain size, and fracturing characteristics that influenced extraction techniques and methodologies. The primary exploitation periods of the CMM as an ornamental stone were the Etruscan-Roman era, the Renaissance, and the nineteenth century; currently, it is used exclusively for industrial purposes. A significant number of ancient quarries are located on the western slope of Monte Rombolo, likely attributable to the high variety of commercial marble types available in the area and its strategic location, which facilitated transport routes to the Tyrrhenian Sea. This research aims to bring attention to this historical marble and may support, alongside the potential reopening of selected quarries for restoration purposes, the preservation of the authenticity of the historical artefacts in which it was employed. Full article

This study examines the marble resources of the Mani peninsula, southern Greece, a region that has long been known for its white, gray-black (bigio antico), green (cipollino verde Tenario), and particularly red (rosso antico or lapis Taenarium) and dark (nero antico) marbles. Based on extensive fieldwork, more than 90 quarrying sites were documented, several of which were recorded for the first time. This study provides a systematic characterization of these stones through combined mineralogical, petrographic, and stable isotopic (δ¹⁸O, δ¹³C) analyses of 27 representative samples. The results confirm the presence of calcitic marbles, which vary in color due to hematite in the red varieties, graphite and organic matter in the gray-black and black types, and chlorite in the green marbles. The isotopic results demonstrate a generally high degree of homogeneity, although the red marbles display greater variability, complicating their distinction from analogous stones in Asia Minor, such as those from Iasos and Milas. Quarrying of Mani marbles began in the Bronze Age and reached its peak during Roman times. It continued into the Byzantine period, with renewed exploitation in the 19th and 20th centuries. This study highlights the significant role of Mani in the ancient marble trade and contributes to ongoing debates about the provenance of famous red, white, and black marbles across the Mediterranean. Furthermore, it establishes a strong reference framework, integrating new analytical results with the existing literature, providing an updated mineralogical, petrographic, and isotopic database for provenance studies of marble artifacts. Full article

This study presents the results of an archaeometric investigation of white marble votive reliefs from the Roman city of Pautalia (modern Kyustendil, Bulgaria), with the aim of clarifying patterns of material selection, production, and connectivity within the eastern provinces of the Roman Empire. Although these votive monuments, primarily dated to the 2nd and 3rd centuries AD, have long been examined from stylistic, iconographic, and epigraphic perspectives, the provenance of the marble used in their manufacture has remained largely unexplored. A total of 27 votive reliefs from urban and extra-urban sanctuary contexts were analysed using a multi-method approach combining petrographic analysis, stable isotope ratios (δ¹³C and δ¹⁸O), and trace element analysis by ICP-MS, and compared against an extensive geological reference database of ancient marble quarries. The results indicate a clear predominance of local and regional marble sources, alongside a limited but meaningful presence of imported material. This distribution pattern supports the existence of local workshops operating in or near Pautalia, which relied primarily on nearby quarry sources while selectively incorporating imported marble, likely through the reuse of pre-existing blocks or workshop offcuts rather than through systematic long-distance supply. These findings underscore Pautalia’s role as a regional production centre and as a nodal point within wider networks connecting the Aegean world and the Balkan hinterland. Full article

Jerusalem’s prominent building material of limestone and dolostone, which is commonly known as “Jerusalem stone”, characterizes the city’s architecture and built environment. The distinctive stone was quarried from the Jerusalem landscape, prepared as building stone, and transported to building sites, a process referred to in this paper as the “lithic journey”. While these ancient quarries have been identified in previous studies, new evidence identifies the characteristics and the spatial distribution of these quarries and the connections between them. This study examined over one hundred archeological reports resulting from mainly salvage excavations conducted in the last decade (2012–2024), which has enabled the creation of updated mapping. Data collected from the Hadashot Arkheologiyot: Excavations and Surveys in Israel (HA-ESI), are included in a database that classifies quarry types, building material provenance, and specific characteristics of the ancient quarries that supplied Jerusalem’s building stones. The resulting expanded dataset of this open-access, online resource broadens our understanding of the quarry landscape and the continuous use of stone in the city’s building culture, while also offering an understanding of Jerusalem’s urban development and the design of Jerusalem’s cityscape from antiquity to the present day, as well as contribute to the city’s heritage management. Full article

This paper presents the results of a research project on the use of stone in Roman architecture in Oderzo and Concordia Sagittaria, located between the Tagliamento and the Piave rivers (Italy). The study involved a documental survey, material sampling and analysis, provenance identification, and interpretation of results to reconstruct ancient stone trade routes. During sampling, 33 carbonate rock specimens were collected from archaeological sites and architectural elements in Oderzo, and 52 from Concordia Sagittaria. In both cities, these rocks were primarily used for architectural elements such as columns and capitals, whereas these lithotypes were less frequently employed in structures and infrastructures. The analysis revealed a significant reliance on regional limestones. Petrographic examinations (PLM-TL) identified six main limestone groups, many of which were linked to quarries located in the Aurisina and in the Triestine Karst region, as well as in the Prealps and Berici Hills. The study encountered several challenges: many analysed samples displayed petrographic characteristics consistent with multiple sources, complicating the precise identification of their extraction site. Despite a detailed understanding of the region’s geology, reference geological datasets often overlook outcrops that may have been exploited in antiquity. Consequently, when samples lacked distinctive features, tracing them to a particular quarrying basin proved difficult. In conclusion, the research underscores the extensive use of local limestones while acknowledging the challenges posed by limited petrographic reference data, which hinder the precise identification of the source basins of the materials used in Roman construction. Full article

This study explores the provenance of white marble architectural elements from Roman Philippopolis, with a particular focus on the Eastern Gate complex. By determining the origin of the marble, we aim to elucidate economic, social, and urban dynamics related to material selection and trade networks. The investigation examines the symbolic significance of prestigious marble in elite representation and highlights the role of quarry exploitation in the region’s economic and technological development. The Eastern Gate, a monumental ensemble integrated into the city’s urban fabric, was primarily constructed with local Rhodope marble, alongside imported materials such as Prokonnesian marble. Analytical methods included petrographic examination, chemical analysis of trace elements (Mn, Mg, Fe, Sr, Y, V, Cd, La, Ce, Yb, and U), and stable isotope analysis (δ¹⁸O, δ¹³C). Statistical evaluations were performed for each sample (37 in total) and compared with a comprehensive database of ancient quarry sources. The results underscore the dominance of local materials while also indicating selective use of imports, potentially linked to symbolic or functional criteria. The findings support the hypothesis of local workshop activity in the Asenovgrad/Philippopolis area and shed light on regional and long-distance marble trade during the Roman Imperial period, reflecting broader economic and cultural interconnections. Full article

La Vispesa is an archaeological settlement occupied from the First Iron Age to the Imperial Roman Period. The objectives of this study were to (i) perform a geomorphological characterization of the site; (ii) place it in its regional context; (iii) obtain values of uniaxial compressive strength (UCS) to characterize the construction materials; (iv) assess the chronological data obtained; (v) establish the origin of the sandstones used; and (vi) assess the application of these techniques at archaeological sites. UCS estimations were produced for the preserved walls using a Schmidt hammer, and two groups of samples were identified. In these samples, stones from the Iberian Epoch walls were considerably weathered, while the Roman ashlars were well preserved as they were built from better-quality material that produced high UCS values. In addition, measurements of various sandstone outcrops probably used as quarries were made to compare values. Only one sandstone outcrop had estimations that could relate to the provision of raw material for the Roman period, while other estimations are compatible with Iberian walls. The application of this methodology proves to be highly beneficial for the analysis and comprehension of ancient constructions. Full article

Serpentinite is a common lithology in Greece with significant geotectonic and petrogenetic implications, yet its archaeometric study remains limited. This also applies to the Ras serpentinite outcrop on Tinos Island—an enigmatic ancient quarry with no prior documentation of its exploitation. This study aims to provide a holistic provenance analysis and full material characterization to establish a unique fingerprint for future comparative research. A multidisciplinary methodology was applied, including petrography, XRD, FTIR, BET, LA-ICP-MS, electron microprobe analyses, and lichenometry—the latter used to estimate the quarry’s period of activity. The Ras serpentinite consists of a dark-green, brecciated lizardite matrix cut by a pale-green chrysotile network, and notably hosts the first recorded occurrence of minnesotaite in Greece. Relict antigorite within the matrix indicates high-pressure, high-temperature metamorphism preceding a greenschist facies overprint. Geochemical data classify the Ras occurrence as a subduction-related serpentinite derived from a depleted ultrabasic protolith. The aforementioned traits distinguish it from other Greek examples. Lichenometric analysis suggests the quarry was active in the 13th century A.D., with evidence of deliberate extraction techniques. These findings offer valuable insights into archaeometric studies and the provenance of serpentinites in the Aegean. Full article

A Miocene carbonatic clay quarried in Transylvania (Romania) has been used for more than 100 years for the production of traditional ceramic ware, bricks, and tiles. To investigate the mineralogical and microstructural changes of this clay when heated between 700 °C and 1200 °C, a combination of polarized light optical microscopy, X-ray powder diffraction, scanning electron microscopy coupled with energy dispersive X-ray spectrometry, and Fourier transform infrared spectroscopy was applied. Primary mineral phases such as illite, muscovite, feldspar, carbonate, Fe oxyhydroxides, and quartz undergo a gradual thermal alteration and form, besides a glassy phase, a wide range of minerals such as gehlenite, clinopyroxene, feldspar, maghemite, hematite, mullite, and α-cristobalite. These firing phases can be regarded as ‘ceramic markers’. A comparison between the data obtained by several methods is discussed. The combination of the optical appearance and the microstructure on one side, and the specific associations of primary phases and ceramic markers on the other side, can be used as a ‘ceramic thermometer’ in estimating the firing temperature for ancient ceramics. Full article

This study presents a systematic analysis of stable isotopes (δ¹³C and δ¹⁸O) in Pentelic marble from the ancient quarries of Mount Pentelikon, Greece. A total of 610 samples were collected from 83 quarry pits, including all identified ancient extraction sites, to build a comprehensive reference database. Of those, stable isotope ratios of carbon and oxygen were measured for 384 samples. The results reveal significant variability in stable isotope values across different quarry regions, challenging the assumption of isotopic homogeneity in Pentelic marble. Notably, distinct δ¹³C and δ¹⁸O patterns allow differentiation between quarry areas and specific extraction zones. These findings provide a more refined isotopic framework for provenance studies of ancient artifacts. Application of the new database suggests that marble for the Parthenon’s West Pediment was sourced from the northern upslope quarries in Aspra Marmara, whereas structural elements of the Parthenon were extracted from the lower Spilia Divail quarry, as well as other pits across the ancient quarry zone. The results demonstrate that multiple quarry pits from both the lower slope and upper slope quarries were exploited for the construction of the Parthenon. This research highlights the benefits of extensive sampling and stable isotope analysis in identifying quarry sources, emphasizing the value of undertaking detailed and thorough field surveys and sampling programs to gain new perspectives into ancient resource use. Full article

Underground monument preservation is tightly linked to geological risk. The geological risk management of underground structures typically relies on a preliminary site investigation phase. Engineering geological mapping—as a key site investigation element—is largely based on manual in situ work, often in harsh and dangerous environments. However, although new technologies can, in many cases, decrease the on-field time as well as eliminate inaccessibility issues, the example presented in this study demonstrates a special challenge that had to be addressed. The ancient underground marble quarries of Paros Island in Greece constitute a gallery complex of a total length of 7 km and only two portals, resulting in total darkness throughout almost the full length of the unsurveyed galleries. As such, the entire survey and engineering geological mapping solely relied on a virtual reality application that was developed based on a digital replica of the quarries using laser scanning. The study identifies several critical locations with potentially unstable geologic structures and computes their geometrical properties. Further numerical analyses based on data extracted directly from the digital replica of the rock mass led to the definition of appropriate risk mitigation measures along the underground marble quarries. Full article

This paper presents the results of the analyses conducted on 46 stone samples collected from Roman buildings in Oderzo, a small town located in the heart of the eastern Venetian plain (29 samples), and from architectural artifacts preserved at the local archeological museum “Eno Bellis” (17 samples). The aim of this study is to identify the types and provenance of the stones used for architectural purposes in Roman times in the city of Oderzo (ancient Opitergium). All the materials were petrographically characterized using a multi-analytical approach, including polarized light optical microscopy (PLM). Moreover, volcanic rock samples were analyzed via X-ray fluorescence (XRF) and quantitative phase analysis via X-Ray powder diffraction (QPA-XRPD) to obtain more detailed mineralogical and geochemical characterizations. These methods proved valuable for better determining the provenance of the materials. The results allowed us to determine the quarrying areas that Opitergium mostly relied upon in antiquity for sourcing building materials, as well as the stone trade networks in which the city was integrated. Preliminary findings indicate a higher frequency of stones sourced from outcrops along the Prealpine Arc of north-eastern Italy and Istria, including Aurisina limestone (Trieste Karst), and micritic limestones possibly quarried in the Istrian peninsula for architectural artifacts. Conversely, lithotypes from north-western Prealps appear to have been used less frequently. The volcanic rock samples were entirely sourced from various quarry sites in the Euganean Volcanic District in the Veneto region. Full article

In 44 BC, Julius Caesar established Colonia Laus Iulia Corinthiensis, strategically reviving Corinth to dominate Isthmian trade routes and extend Rome’s commercial influence eastwards. At the centre of the colony lies Temple E, an enigmatic structure with an unidentified associated cult. This study investigates the architectural characteristics of Temple E, focusing on the use of marble as the primary building material. Petrographic analysis, elemental chemical profiling (Mn, Mg, Fe, Sr, Y, V, Cd, La, Ce, Yb, U), and isotopic measurements (δ¹⁸O ‰, δ¹³C ‰) are employed to analyse marble samples from the surrounding region, exploring sourcing and construction practices. Statistical comparisons with ancient quarry databases indicate a strong reliance on locally sourced Doliana marble, underscoring the economic significance of regional quarries and suggesting the existence of a local workshop dedicated to architectural production in Roman Corinth. By integrating geological and archaeometric approaches, this study highlights Corinth’s pivotal role in the regional marble trade and its broader economic importance during the Roman Imperial period. The findings emphasise the use of local resources, illustrating a flourishing marble-working industry and enhancing our understanding of the relationship between local materials and Roman architectural practices. Full article

Limestone has always been widely used in various sectors, thus having significant economic and environmental impacts. The quarrying process is, on the one hand, essential, but on the other, harmful to the environment and people’s health, therefore, the challenge is finding a balance. This review explores the multifaceted nature of limestone, a sedimentary rock predominantly composed of calcium carbonate. The formation of limestone, along with its various types and global occurrence, is discussed to provide a basic understanding. The diverse applications of limestone range from historical uses in ancient monuments to contemporary roles in cement production, plasticized polyvinyl chloride (PVC), and soda–lime glass. The discussion extends to post-mining solutions, showcasing successful rehabilitation and innovative repurposing of former quarries into useful infrastructures, wildlife habitats, and cultural spaces. This article draws attention to the importance of sustainable practices and technological developments to balance resource use with environmental conservation. Ultimately, it emphasizes the need for responsible limestone quarrying and proactive rehabilitation strategies to ensure that no permanent ecological problems will occur. Full article