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10 pages, 1763 KiB  
Communication
Multi-Mode Coupling Enabled Broadband Coverage for Terahertz Biosensing Applications
by Dongyu Hu, Mengya Pan, Yanpeng Shi and Yifei Zhang
Biosensors 2025, 15(6), 368; https://doi.org/10.3390/bios15060368 - 7 Jun 2025
Viewed by 560
Abstract
Terahertz (THz) biosensing faces critical challenges in balancing high sensitivity and broadband spectral coverage, particularly under miniaturized device constraints. Conventional quasi-bound states in the continuum (QBIC) metasurfaces achieve high quality factor (Q) but suffer from narrow bandwidth, while angle-scanning strategies for broadband detection [...] Read more.
Terahertz (THz) biosensing faces critical challenges in balancing high sensitivity and broadband spectral coverage, particularly under miniaturized device constraints. Conventional quasi-bound states in the continuum (QBIC) metasurfaces achieve high quality factor (Q) but suffer from narrow bandwidth, while angle-scanning strategies for broadband detection require complex large-angle illumination. Here, we propose a symmetry-engineered, all-dielectric metasurface that leverages multipolar interference coupling to overcome this limitation. By introducing angular perturbation, the metasurface transforms the original magnetic dipole (MD)-dominated QBIC resonance into hybridized, multipolar modes. It arises from the interference coupling between MD, toroidal dipole (TD), and magnetic quadrupole (MQ). This mechanism induces dual counter-directional, frequency-shifted, resonance branches within angular variations below 16°, achieving simultaneous 0.42 THz broadband coverage and high Q of 499. Furthermore, a derived analytical model based on Maxwell equations and mode coupling theory rigorously validates the linear relationship between frequency splitting interval and incident angle with the Relative Root Mean Square Error (RRMSE) of 1.4% and the coefficient of determination (R2) of 0.99. This work establishes a paradigm for miniaturized THz biosensors, advancing applications in practical molecular diagnostics and multi-analyte screening. Full article
(This article belongs to the Special Issue Photonics for Bioapplications: Sensors and Technology—2nd Edition)
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27 pages, 4125 KiB  
Article
Monitoring Gypsiferous Soils by Leveraging Advanced Spaceborne Hyperspectral Imagery via Spectral Indices and a Machine Learning Approach
by Najmeh Rasooli, Saham Mirzaei and Stefano Pignatti
Remote Sens. 2025, 17(11), 1914; https://doi.org/10.3390/rs17111914 - 31 May 2025
Viewed by 744
Abstract
Enhancing the spatial resolution of gypsiferous soil detection, as a valuable baseline information layer, is beneficial for investigating agroecological processes and tackling land degradation in semi-arid environments. This study evaluates the performance of PRISMA (PRecursore IperSpettrale della Missione Applicativa) and EnMAP (Environmental Mapping [...] Read more.
Enhancing the spatial resolution of gypsiferous soil detection, as a valuable baseline information layer, is beneficial for investigating agroecological processes and tackling land degradation in semi-arid environments. This study evaluates the performance of PRISMA (PRecursore IperSpettrale della Missione Applicativa) and EnMAP (Environmental Mapping and Analysis Program) satellites in estimating soil gypsum content and compares models trained on satellite imagery versus lab data. To this end, 242 bare-soil samples were collected from southeast Iran. Gypsum content was measured using acetone precipitation, and spectral reflectance was acquired using the ASD (Analytical Spectral Devices)-Fieldspec 3 spectroradiometer. The gypsum content was retrieved by optical data using three approaches: narrowband indices, spectral absorption features, and machine learning (ML) algorithms. Four machine learning algorithms, including PLSR (Partial Least Squares Regression), RF (Random Forest), SVR (Support Vector Regression), and GPR (Gaussian Process Regression), achieved excellent performance (RPD > 2.5). The results showcased that the difference soil index (DSI) achieved the highest R2 scores of 0.96 (ASD), 0.79 (PRISMA), and 0.84 (EnMAP), slightly outperforming the normalized difference gypsum ratio (NDGI) and ratio soil index (RSI). Comparing the shape indices’, the slope parameter (SLP) index outperformed the half-area parameter (HAP) index. PRISMA, with SVR (R2 ≥ 0.83), and EnMAP, with PLSR (R2 ≥ 0.85), demonstrated that hyperspectral satellites proved reliable in detecting gypsum content, yielding results comparable to ASD with detailed algorithms. Full article
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36 pages, 1587 KiB  
Article
Analysis of MCP-Distributed Jammers and 3D Beam-Width Variations for UAV-Assisted C-V2X Millimeter-Wave Communications
by Mohammad Arif, Wooseong Kim, Adeel Iqbal and Sung Won Kim
Mathematics 2025, 13(10), 1665; https://doi.org/10.3390/math13101665 - 19 May 2025
Cited by 2 | Viewed by 372
Abstract
Jamming devices introduce unwanted signals into the network to disrupt primary communications. The effectiveness of these jamming signals mainly depends on the number and distribution of the jammers. The impact of clustered jamming has not been investigated previously for an unmanned aerial vehicle [...] Read more.
Jamming devices introduce unwanted signals into the network to disrupt primary communications. The effectiveness of these jamming signals mainly depends on the number and distribution of the jammers. The impact of clustered jamming has not been investigated previously for an unmanned aerial vehicle (UAV)-assisted cellular-vehicle-to-everything (C-V2X) communications by considering multiple roads in the given region. Also, exploiting three-dimensional (3D) beam-width variations for a millimeter waveband antenna in the presence of jamming for vehicular node (V-N) links has not been evaluated, which influences the UAV-assisted C-V2X system’s performance. The novelty of this paper resides in analyzing the impact of clustered jamming for UAV-assisted C-V2X networks and quantifying the effects of fluctuating antenna 3D beam width on the V-N performance by exploiting millimeter waves. To this end, we derive the analytical expressions for coverage of a typical V-N linked with a line-of-sight (LOS) UAV, non-LOS UAV, macro base station (MBS), and recipient V-N for UAV-assisted C-V2X networks by exploiting beam-width variations in the presence of jammers. The results show network performance in terms of coverage and spectral efficiencies by setting V-Ns equal to 3 km−2, MBSs equal to 3 km−2, and UAVs equal to 6 km−2. The findings indicate that the performance of millimeter waveband UAV-assisted C-V2X communications is decreased by introducing clustered jamming in the given region. Specifically, the coverage performance of the network decreases by 25.5% at −10 dB SIR threshold in the presence of clustered jammers. The performance further declines by increasing variations in the antenna 3D beam width. Therefore, network designers must focus on considering advanced counter-jamming techniques when jamming signals, along with the beam-width fluctuations, are anticipated in vehicular networks. Full article
(This article belongs to the Section D1: Probability and Statistics)
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19 pages, 5673 KiB  
Article
LoRa Communications Spectrum Sensing Based on Artificial Intelligence: IoT Sensing
by Partemie-Marian Mutescu, Valentin Popa and Alexandru Lavric
Sensors 2025, 25(9), 2748; https://doi.org/10.3390/s25092748 - 26 Apr 2025
Viewed by 891
Abstract
The backbone of the Internet of Things ecosystem relies heavily on wireless sensor networks and low-power wide area network technologies, such as LoRa modulation, to provide the long-range, energy-efficient communications essential for applications as diverse as smart homes, healthcare, agriculture, smart grids, and [...] Read more.
The backbone of the Internet of Things ecosystem relies heavily on wireless sensor networks and low-power wide area network technologies, such as LoRa modulation, to provide the long-range, energy-efficient communications essential for applications as diverse as smart homes, healthcare, agriculture, smart grids, and transportation. With the number of IoT devices expected to reach approximately 41 billion by 2034, managing radio spectrum resources becomes a critical issue. However, as these devices are deployed at an increasing rate, the limited spectral resources will result in increased interference, packet collisions, and degraded quality of service. Current methods for increasing network capacity have limitations and require advanced solutions. This paper proposes a novel hybrid spectrum sensing framework that combines traditional signal processing and artificial intelligence techniques specifically designed for LoRa spreading factor detection and communication channel analytics. Our proposed framework processes wideband signals directly from IQ samples to identify and classify multiple concurrent LoRa transmissions. The results show that the framework is highly effective, achieving a detection accuracy of 96.2%, a precision of 99.16%, and a recall of 95.4%. The proposed framework’s flexible architecture separates the AI processing pipeline from the channel analytics pipeline, ensuring adaptability to various communication protocols beyond LoRa. Full article
(This article belongs to the Special Issue LoRa Communication Technology for IoT Applications)
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11 pages, 3727 KiB  
Article
Dynamically Tunable Singular States Through Air-Slit Control in Asymmetric Resonant Metamaterials
by Yeong Hwan Ko and Robert Magnusson
Photonics 2025, 12(5), 403; https://doi.org/10.3390/photonics12050403 - 22 Apr 2025
Viewed by 327
Abstract
This study presents a novel method for dynamically tuning singular states in one-dimensional (1D) photonic lattices (PLs) using air-slit-based structural modifications. Singular states, arising from symmetry-breaking-induced resonance radiation, generate diverse spectral features through interactions between resonance modes and background radiation. By strategically incorporating [...] Read more.
This study presents a novel method for dynamically tuning singular states in one-dimensional (1D) photonic lattices (PLs) using air-slit-based structural modifications. Singular states, arising from symmetry-breaking-induced resonance radiation, generate diverse spectral features through interactions between resonance modes and background radiation. By strategically incorporating air slits to break symmetry in 1D PLs, we demonstrated effective control of resonance positions, enabling dual functionalities including narrowband band pass and notch filtering. These singular states originate from asymmetric guided-mode resonances (aGMRs), which can be interpreted by analytical modeling of the equivalent slab waveguide. Moreover, the introduction of multiple air slits significantly enhances spectral tunability by inducing multiple folding behaviors in the resonance bands. This approach allows for effective manipulation of optical properties through simple adjustments of air-slit displacements. This work provides great potential for designing multifunctional photonic devices with advanced metamaterial technologies. Full article
(This article belongs to the Special Issue Optical Metasurfaces: Applications and Trends)
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26 pages, 1158 KiB  
Article
Simultaneously Transmitting and Reflecting Reconfigurable Intelligent Surface-Assisted Non-Orthogonal Multiple Access Wireless Education Network Under Multiple Interference Devices
by Ziyang Zhang
Symmetry 2025, 17(4), 491; https://doi.org/10.3390/sym17040491 - 25 Mar 2025
Viewed by 590
Abstract
Reconfigurable Intelligent Surfaces (RISs) and Non-Orthogonal Multiple Access (NOMA) have emerged as key technologies for next-generation (6G) wireless networks, attracting significant attention from researchers. As an advanced extension of RISs, Simultaneously Transmitting and Reflecting Reconfigurable Intelligent Surfaces (STAR-RISs) offer superior geometric and functional [...] Read more.
Reconfigurable Intelligent Surfaces (RISs) and Non-Orthogonal Multiple Access (NOMA) have emerged as key technologies for next-generation (6G) wireless networks, attracting significant attention from researchers. As an advanced extension of RISs, Simultaneously Transmitting and Reflecting Reconfigurable Intelligent Surfaces (STAR-RISs) offer superior geometric and functional symmetry due to their capability to simultaneously reflect and transmit signals, thereby achieving full 360° spatial coverage. This symmetry not only ensures balanced energy distribution between the Transmission (T) and Reflection (R) regions but also facilitates interference cancellation through phase alignment. Furthermore, in NOMA networks, the symmetric allocation of power coefficients and the tunable transmission and reflection coefficients of STAR-RIS elements aligns with the principle of resource fairness in multi-user systems, which is crucial for maintaining fairness under asymmetric channel conditions. In this study, key factors, such as interference sources and distance effects, are considered in order to conduct a detailed analysis of the performance of STAR-RIS-assisted NOMA wireless education networks under multiple interference devices. Specifically, a comprehensive analysis of the Signal-to-Interference-plus-Noise Ratio (SINR) for both near-end and far-end devices is conducted, considering various scenarios, such as whether or not the direct communication link exists between the base station and the near-end device, and whether or not the near-end device is affected by interference. Based on these analyses, closed-form approximate expressions for the outage probabilities of the near-end and far-end devices, as well as the closed-form approximation for the system’s Spectral Efficiency (SE), are derived. Notably, the Gamma distribution is used to approximate the square of the composite channel amplitude between the base station and the near-end device, effectively reducing computational complexity. Finally, simulation results validate the accuracy of our analytical results. Both numerical and simulation results show that adjusting the base station’s power allocation, and the transmission and reflection coefficients of the STAR-RIS, can effectively mitigate the impact of interference devices on the near-end device and enhance the communication performance of receiving devices. Additionally, increasing the number of STAR-RIS elements can effectively improve the overall performance of the near-end device, far-end device, and the entire system. Full article
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24 pages, 4369 KiB  
Article
RLANet: A Kepler Optimization Algorithm-Optimized Framework for Fluorescence Spectra Analysis with Applications in Oil Spill Detection
by Shubo Zhang, Yafei Yuan and Jing Li
Processes 2025, 13(4), 934; https://doi.org/10.3390/pr13040934 - 21 Mar 2025
Viewed by 399
Abstract
This paper presents a novel deep learning model, RLANet, based on the ResNet-LSTM-Multihead Attention module, designed for processing and classifying one-dimensional spectral data. The model incorporates ResNet, LSTM, and attention mechanisms, omitting the traditional fully connected layer to significantly reduce the parameter count [...] Read more.
This paper presents a novel deep learning model, RLANet, based on the ResNet-LSTM-Multihead Attention module, designed for processing and classifying one-dimensional spectral data. The model incorporates ResNet, LSTM, and attention mechanisms, omitting the traditional fully connected layer to significantly reduce the parameter count while maintaining global spectral feature extraction. This design enables RLANet to be lightweight and computationally efficient, making it suitable for real-time applications, especially in resource-constrained environments. Furthermore, this study introduces the Kepler Optimization Algorithm (KOA) for hyperparameter tuning in deep learning, demonstrating its superiority over the traditional Bayesian optimization (BO) in achieving optimal hyperparameter configurations for complex models. Experimental results indicate that the RLANet model successfully achieves accurate identification of three types of engine oil products and their mixtures, with classification accuracy approaching one. Compared to conventional deep learning models, it features a significantly reduced parameter count of only 0.09 M, enabling the deployment of compact devices for rapid on-site classification of oil spill types. Furthermore, relative to traditional machine learning models, RLANet demonstrates a lower sensitivity to preprocessing methods, with the standard deviation of classification accuracy maintained within approximately 0.001, thereby underscoring its excellent end-to-end analytical capabilities. Moreover, even under a strong noise interference at a signal-to-noise ratio of 15 dB, its classification performance declines by only 19% relative to the baseline, attesting to its robust resilience. These results highlight the model’s potential for practical deployment in end-to-end online spectral analysis, particularly in resource-constrained hardware environments. Full article
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38 pages, 9980 KiB  
Review
Metasurfaces with Multipolar Resonances and Enhanced Light–Matter Interaction
by Evan Modak Arup, Li Liu, Haben Mekonnen, Dominic Bosomtwi and Viktoriia E. Babicheva
Nanomaterials 2025, 15(7), 477; https://doi.org/10.3390/nano15070477 - 21 Mar 2025
Cited by 3 | Viewed by 2537
Abstract
Metasurfaces, composed of engineered nanoantennas, enable unprecedented control over electromagnetic waves by leveraging multipolar resonances to tailor light–matter interactions. This review explores key physical mechanisms that govern their optical properties, including the role of multipolar resonances in shaping metasurface responses, the emergence of [...] Read more.
Metasurfaces, composed of engineered nanoantennas, enable unprecedented control over electromagnetic waves by leveraging multipolar resonances to tailor light–matter interactions. This review explores key physical mechanisms that govern their optical properties, including the role of multipolar resonances in shaping metasurface responses, the emergence of bound states in the continuum (BICs) that support high-quality factor modes, and the Purcell effect, which enhances spontaneous emission rates at the nanoscale. These effects collectively underpin the design of advanced photonic devices with tailored spectral, angular, and polarization-dependent properties. This review discusses recent advances in metasurfaces and applications based on them, highlighting research that employs full-wave numerical simulations, analytical and semi-analytic techniques, multipolar decomposition, nanofabrication, and experimental characterization to explore the interplay of multipolar resonances, bound and quasi-bound states, and enhanced light–matter interactions. A particular focus is given to metasurface-enhanced photodetectors, where structured nanoantennas improve light absorption, spectral selectivity, and quantum efficiency. By integrating metasurfaces with conventional photodetector architectures, it is possible to enhance responsivity, engineer photocarrier generation rates, and even enable functionalities such as polarization-sensitive detection. The interplay between multipolar resonances, BICs, and emission control mechanisms provides a unified framework for designing next-generation optoelectronic devices. This review consolidates recent progress in these areas, emphasizing the potential of metasurface-based approaches for high-performance sensing, imaging, and energy-harvesting applications. Full article
(This article belongs to the Section Nanophotonics Materials and Devices)
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32 pages, 5714 KiB  
Article
Polynomial Modeling of Noise Figure in Erbium-Doped Fiber Amplifiers
by Rocco D’Ingillo, Alberto Castronovo, Stefano Straullu and Vittorio Curri
Fibers 2025, 13(3), 34; https://doi.org/10.3390/fib13030034 - 14 Mar 2025
Viewed by 866
Abstract
Erbium-Doped Fiber Amplifiers (EDFAs) are fundamental to optical communication networks, providing signal amplification while introducing noise that affects system performance. Accurate noise figure estimation is critical for optimizing link budgets, monitoring optical Signal-to-Noise Ratio (OSNR), and enabling real-time network optimization. Traditional analytical models, [...] Read more.
Erbium-Doped Fiber Amplifiers (EDFAs) are fundamental to optical communication networks, providing signal amplification while introducing noise that affects system performance. Accurate noise figure estimation is critical for optimizing link budgets, monitoring optical Signal-to-Noise Ratio (OSNR), and enabling real-time network optimization. Traditional analytical models, while computationally efficient, often fail to capture device-specific variations, whereas machine-learning-based approaches require large training datasets and introduce high computational overhead. This paper proposes a polynomial regression model for real-time EDFA noise figure estimation, striking a balance between accuracy and computational efficiency. The model leverages Generalized Least Squares (GLS) regression to fit a multivariate polynomial function to measured EDFA noise figure data, ensuring robustness against measurement noise and dataset variations. The proposed method is benchmarked against experimental measurements from multiple EDFAs, achieving prediction errors that are within the measurement uncertainty of Optical Spectrum Analyzers (OSAs). Furthermore, the model demonstrates strong generalization across different EDFA architectures, outperforming analytical models while requiring significantly less data than deep-learning approaches. Computational efficiency is also analyzed, showing that inference time is below 0.2 ms per evaluation, making the model suitable for real-time digital-twin applications in optical networks. Future work will explore hybrid modeling approaches, integrating physics-based regression with Machine Learning (ML) to enhance performance in high-variance spectral regions. These results highlight the potential of lightweight polynomial regression models as an alternative to complex ML-based solutions, enabling scalable and efficient EDFA performance prediction for next-generation optical networks. Full article
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14 pages, 5093 KiB  
Article
In Situ Classification of Original Rocks by Portable Multi-Directional Laser-Induced Breakdown Spectroscopy Device
by Mengyang Zhang, Hongbo Fu, Huadong Wang, Feifan Shi, Saifullah Jamali, Zongling Ding, Bian Wu and Zhirong Zhang
Chemosensors 2025, 13(1), 18; https://doi.org/10.3390/chemosensors13010018 - 15 Jan 2025
Cited by 1 | Viewed by 1044
Abstract
In situ rapid classification of rock lithology is crucial in various fields, including geological exploration and petroleum logging. Laser-induced breakdown spectroscopy (LIBS) is particularly well-suited for in situ online analysis due to its rapid response time and minimal sample preparation requirements. To facilitate [...] Read more.
In situ rapid classification of rock lithology is crucial in various fields, including geological exploration and petroleum logging. Laser-induced breakdown spectroscopy (LIBS) is particularly well-suited for in situ online analysis due to its rapid response time and minimal sample preparation requirements. To facilitate in situ raw rock discrimination analysis, a portable LIBS device was developed specifically for outdoor use. This device built upon a previous multi-directional optimization scheme and integrated machine learning to classify seven types of original rock samples: mudstone, basalt, dolomite, sandstone, conglomerate, gypsolyte, and shale from oil logging sites. Initially, spectral data were collected from random areas of each rock sample, and a series of pre-processing steps and data dimensionality reduction were performed to enhance the accuracy and efficiency of the LIBS device. Subsequently, four classification algorithms—linear discriminant analysis (LDA), K-nearest neighbor (KNN), support vector machine (SVM), and extreme gradient boosting (XGBoost)—were employed for classification discrimination. The results were evaluated using a confusion matrix. The final average classification accuracies achieved were 95.71%, 93.57%, 92.14%, and 98.57%, respectively. This work not only demonstrates the effectiveness of the portable LIBS device in classifying various original rock types, but it also highlights the potential of the XGBoost algorithm in improving LIBS analytical performance in field scenarios and geological applications, such as oil logging sites. Full article
(This article belongs to the Special Issue Application of Laser-Induced Breakdown Spectroscopy, 2nd Edition)
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20 pages, 7798 KiB  
Article
Soil Burn Severity Assessment Using Sentinel-2 and Radiometric Measurements
by Rafael Llorens, José Antonio Sobrino, Cristina Fernández, José M. Fernández-Alonso and José Antonio Vega
Fire 2024, 7(12), 487; https://doi.org/10.3390/fire7120487 - 23 Dec 2024
Cited by 2 | Viewed by 1248
Abstract
The objective of this article is to create soil burn severity maps to serve as field support for erosion tasks after forest fire occurrence in Spain (2017–2022). The Analytical Spectral Device (ASD) FieldSpec and the CIMEL CE-312 radiometers (optical and thermal, respectively) were [...] Read more.
The objective of this article is to create soil burn severity maps to serve as field support for erosion tasks after forest fire occurrence in Spain (2017–2022). The Analytical Spectral Device (ASD) FieldSpec and the CIMEL CE-312 radiometers (optical and thermal, respectively) were used as input data to establish relationships between soil burn severity and reflectance or emissivity, respectively. Spectral indices related to popular forest fire studies and soil assessment were calculated by Sentinel-2 convolved reflectance. All the spectral indices that achieve the separability index algorithm (SI) were validated using specificity, sensitivity, accuracy (ACC), balanced accuracy (BACC), F1-score (F1), and Cohen’s kappa index (k), with 503 field plots. The results displayed the highest overall accuracy results using the Iron Oxide ratio (IOR) index: ACC = 0.71, BACC = 0.76, F1 = 0.63 and k = 0.50, respectively. In addition, IOR was the only spectral index with an acceptable k value (k = 0.50). It is demonstrated that, together with NIR and SWIR spectral bands, the use of blue spectral band reduces atmospheric interferences and improves the accuracy of soil burn severity mapping. The maps obtained in this study could be highly valuable to forest agents for soil erosion restoration tasks. Full article
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25 pages, 6453 KiB  
Article
Comparison of Multiple NIR Instruments for the Quantitative Evaluation of Grape Seed and Other Polyphenolic Extracts with High Chemical Similarities
by Matyas Lukacs, Flora Vitalis, Adrienn Bardos, Judit Tormási, Krzysztof B. Bec, Justyna Grabska, Zoltan Gillay, Rita A. Tömösközi-Farkas, László Abrankó, Donatella Albanese, Francesca Malvano, Christian W. Huck and Zoltan Kovacs
Foods 2024, 13(24), 4164; https://doi.org/10.3390/foods13244164 - 23 Dec 2024
Cited by 1 | Viewed by 4888
Abstract
Grape seed extract (GSE), one of the world’s bestselling dietary supplements, is prone to frequent adulteration with chemically similar compounds. These frauds can go unnoticed within the supply chain due to the use of unspecific standard analytical methods for quality control. This research [...] Read more.
Grape seed extract (GSE), one of the world’s bestselling dietary supplements, is prone to frequent adulteration with chemically similar compounds. These frauds can go unnoticed within the supply chain due to the use of unspecific standard analytical methods for quality control. This research aims to develop a near-infrared spectroscopy (NIRS) method for the rapid and non-destructive quantitative evaluation of GSE powder in the presence of multiple additives. Samples were prepared by mixing GSE with pine bark extract (PBE) and green tea extract (GTE) on different levels between 0.5 and 13% in singular and dual combinations. Measurements were performed with a desktop and three different handheld devices for performance comparison. Following spectral pretreatment, partial least squares regression (PLSR) and support vector regression (SVR)-based quantitative models were built to predict extract concentrations and various chemical parameters. Cross- and external-validated models could reach a minimum R2p value of 0.99 and maximum RMSEP of 0.27% for the prediction of extract concentrations using benchtop data, while models based on handheld data could reach comparably good results, especially for GTE, caffeic acid and procyanidin content prediction. This research shows the potential applicability of NIRS coupled with chemometrics as an alternate, rapid and accurate quality evaluation tool for GSE-based supplement mixtures. Full article
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18 pages, 5691 KiB  
Article
The Inversion of Rice Leaf Pigment Content: Using the Absorption Spectrum to Optimize the Vegetation Index
by Longfei Ma, Yuanjin Li, Ningge Yuan, Xiaojuan Liu, Yuyan Yan, Chaoran Zhang, Shenghui Fang and Yan Gong
Agriculture 2024, 14(12), 2265; https://doi.org/10.3390/agriculture14122265 - 11 Dec 2024
Viewed by 1226
Abstract
The pigment content of rice leaves plays an important role in the growth and development of rice. The accurate and rapid assessment of the pigment content of leaves is of great significance for monitoring the growth status of rice. This study used the [...] Read more.
The pigment content of rice leaves plays an important role in the growth and development of rice. The accurate and rapid assessment of the pigment content of leaves is of great significance for monitoring the growth status of rice. This study used the Analytical Spectra Device (ASD) FieldSpec 4 spectrometer to measure the leaf reflectance spectra of 4 rice varieties during the entire growth period under 4 nitrogen application rates and simultaneously measured the leaf pigment content. The leaf’s absorption spectra were calculated based on the physical process of spectral transmission. An examination was conducted on the variations in pigment composition among distinct rice cultivars, alongside a thorough dissection of the interrelations and distinctions between leaf reflectance spectra and absorption spectra. Based on the vegetation index proposed by previous researchers in order to invert pigment content, the absorption spectrum was used to replace the original reflectance data to optimize the vegetation index. The results showed that the chlorophyll and carotenoid contents of different rice varieties showed regular changes during the whole growth period, and that the leaf absorption spectra of different rice varieties showed more obvious differences than reflectance spectra. After replacing the reflectance of pigment absorptivity-sensitive bands (400 nm, 550 nm, 680 nm, and red-edge bands) with absorptivities that would optimize the vegetation index, the correlation between the vegetation index, which combines absorptivity and reflectivity, and the chlorophyll and carotenoid contents of 4 rice varieties during the whole growth period was significantly improved. The model’s validation results indicate that the pigment inversion model, based on the improved vegetation index using absorption spectra, outperforms the traditional vegetation index-based pigment inversion model. The results of this study demonstrate the potential application of absorption spectroscopy in the quantitative inversion of crop phenotypes. Full article
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11 pages, 3516 KiB  
Article
High-Sensitivity, High-Resolution Miniaturized Spectrometers for Ultraviolet to Near-Infrared Using Guided-Mode Resonance Filters
by Jingjun Wu, Cong Wei, Hanxiao Cui, Fujia Chen, Kang Hu, Ang Li, Shilong Pan, Yihao Yang, Jun Ma, Zongyin Yang, Wanguo Zheng and Rihong Zhu
Molecules 2024, 29(23), 5580; https://doi.org/10.3390/molecules29235580 - 26 Nov 2024
Viewed by 1316
Abstract
Miniaturized spectrometers have significantly advanced real-time analytical capabilities in fields such as environmental monitoring, healthcare diagnostics, and industrial quality control by enabling precise on-site spectral analysis. However, achieving high sensitivity and spectral resolution within compact devices remains a significant challenge, particularly when detecting [...] Read more.
Miniaturized spectrometers have significantly advanced real-time analytical capabilities in fields such as environmental monitoring, healthcare diagnostics, and industrial quality control by enabling precise on-site spectral analysis. However, achieving high sensitivity and spectral resolution within compact devices remains a significant challenge, particularly when detecting low-concentration analytes or subtle spectral variations critical for chemical and molecular analysis. This study introduces an innovative approach employing guided-mode resonance filters (GMRFs) to address these limitations. Functioning similarly to notch filters, GMRFs selectively block specific spectral bands while allowing others to pass, maximizing energy extraction from incident light and enhancing spectral encoding. Our design incorporates narrow band-stop filters, which are essential for accurate spectrum reconstruction, resulting in improved resolution and sensitivity. Our spectrometer delivers a spectral resolution of 0.8 nm over a range of 370–810 nm. It achieves sensitivity values that are more than ten times greater than those of conventional grating spectrometers during fluorescence spectroscopy of mouse jejunum. This enhanced sensitivity and resolution are particularly beneficial for chemical and biological applications, facilitating the detection of trace analytes in complex matrices. Furthermore, the spectrometer’s compatibility with complementary metal oxide semiconductor (CMOS) technology enables scalable and cost-effective production, fostering broader adoption in chemical analysis, materials science, and biomedical research. This study underscores the transformative potential of the GMRF-based spectrometer as an innovative tool for advancing chemical and interdisciplinary analytical applications. Full article
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18 pages, 3617 KiB  
Article
Hyperspectral Remote Sensing Combined with Ground Vegetation Surveys for the Study of the Age of Rodent Mounds
by Hao Qi, Xiaoni Liu, Tong Ji, Chenglong Ma, Yafei Shi, Guoxing He, Rong Huang, Yunjun Wang, Zhuoli Yang and Dong Lin
Agriculture 2024, 14(12), 2142; https://doi.org/10.3390/agriculture14122142 - 26 Nov 2024
Viewed by 880
Abstract
Background: Rodents severely damage the ecological environment of grasslands, and rodent mounds of different ages require distinct management strategies. Understanding the age of these mounds aids in formulating targeted restoration measures, which can enhance grassland productivity and biodiversity. Current surveys of rodent mounds [...] Read more.
Background: Rodents severely damage the ecological environment of grasslands, and rodent mounds of different ages require distinct management strategies. Understanding the age of these mounds aids in formulating targeted restoration measures, which can enhance grassland productivity and biodiversity. Current surveys of rodent mounds rely on ground exposure and mound height to determine their age, which is time-consuming and labor-intensive. Remote sensing methods can quickly and easily identify the distribution of rodent mounds. Existing remote sensing images use ground exposure and mound height for identification but do not distinguish between mounds of different ages, such as one-year-old and two-year-old mounds. According to the existing literature, rodent mounds of different ages exhibit significant differences in vegetation structure, soil background, and plant diversity. Utilizing a combination of vegetation indices and hyperspectral data to determine the age of rodent mounds aims to provide a better method for extracting rodent hazard information. This experiment investigates and analyzes the age, distribution, and vegetation characteristics of rodent mounds, including total coverage, height, biomass, and diversity indices such as Patrick, Shannon–Wiener, and Pielou. Spectral data of rodent mounds of different ages were collected using an Analytical Spectral Devices field spectrometer. Correlation analysis was conducted between vegetation characteristics and spectral vegetation indices to select key indices, including NDVI670, NDVI705, EVI, TCARI, Ant, and SR. Multiple stepwise regression and Random Forest (RF) inversion models were established using vegetation indices, and the most suitable model was selected through comparison. Random Forest modeling was conducted to classify plateau zokor rat mounds of different ages, using both vegetation characteristic indicators and vegetation indices for comparison. The rodent mound classification models established using vegetation characteristic indicators and vegetation indices through Random Forest could distinguish rodent mounds of different ages, with out-of-bag error rates of 36.96% and 21.74%, respectively. The model using vegetation indices performed better. Conclusions: (1) Rodent mounds play a crucial ecological role in alpine meadow ecosystems by enhancing plant diversity, biomass, and the stability and vitality of the ecosystem. (2) The vegetation indices SR and TCARI are the most influential in classifying rodent mounds. (3) Incorporating vegetation indices into Random Forest modeling facilitates a precise and robust remote sensing interpretation of rodent mound ages, which is instrumental for devising targeted restoration strategies. Full article
(This article belongs to the Section Artificial Intelligence and Digital Agriculture)
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