Search Results (5)

Syndiotactic polystyrene (sPS) is an important class of engineering plastics, primarily produced through metal-catalyzed highly stereoselective polymerization of styrene monomer. This paper summarizes the advances in metal catalysts for syndiospecific polymerization of styrene and its derivatives including mono-cyclopentadienyl titanium and rare-earth metal catalysts. The effects of the cyclopentadienyl, the metal center, and the ancillary ligand on styrene polymerization are emphasized. It provides a practical reference for polymer and organometallic chemists who are interested in developing and designing highly efficient mono-cyclopentadienyl metal catalysts for the synthesis of sPS and functionalized sPS. Full article

Surface subsidence is a serious threat to human life, buildings and traffic in Beijing. Surface subsidence is closely related to human activities, and human activities in Beijing area showed a decreasing trend during the Corona Virus Disease 2019 (COVID-19). To study surface subsidence in Beijing before and after the COVID-19 outbreak and its causes, a total of 51 Sentinel-1A SAR images covering Beijing from January 2018 to April 2022 were selected to derive subsidence information by Time Series Interferometry Synthetic Aperture Radar (TS-InSAR). The results of surface subsidence in Beijing demonstrate that Changping, Chaoyang, Tongzhou and Daxing Districts exhibited the most serious subsidence phenomenon before the COVID-19 outbreak. The four main subsidence areas form an anti-Beijing Bay that surrounds other important urban areas. The maximum subsidence rate reached −57.0 mm/year. After the COVID-19 outbreak, the main subsidence area was separated into three giant subsidence funnels and several small subsidence funnels. During this period, the maximum subsidence rate was reduced to −43.0 mm/year. Human activity decrease with the COVID-19 outbreak. This study effectively analysed the influence of natural factors on surface subsidence after excluding most of the human factors. The following conclusions are obtained from the analysis: (1) Groundwater level changes, Beijing’s geological structure and infrastructure construction are the main reasons for surface subsidence in Beijing. (2) Seasonal changes in rainfall and temperature indirectly affect groundwater level changes, thereby affecting surface subsidence in the area. (3) The COVID-19 outbreak in early 2020 reduced the payload of Beijing’s transportation facilities. It also slowed down the progress of various infrastructure construction projects in Beijing. These scenarios affected the pressure on the soft land base in Beijing and reduced the surface subsidence trend to some extent. Full article

Due to the growing demand for land resources, many coastal reclamation projects have been implemented around the world in recent decades. Although coastal zone reclamation provides economic benefits, it produces a series of threats to coastal environments and ecosystems. Hence, the ecological costs and economic benefits of reclamation projects must be balanced. In this study, we select Tongzhou Bay, a key development area of the marine industry in the Jiangsu Province, as the research region to study the limits of reclamation control of the port operation area based on regional ecological security. First, we determine the standard limit values of the tidal catchment water line and the water dividing line, the change rate of the tidal flux ±5%, and water area of sandbars above the 0 m line based on key factors and evaluation indices for the ecological impact of reclamation in this region. Then, eight reclamation cases are investigated in Tongzhou Bay, which include the undeveloped natural state, development status, construction projects to be built, and possible construction scale based on the results of tidal current numerical simulation calculations. Although case 3 has impacts on Section 2 (DM2) tidal flux of less than 5% and on Section 1 (DM1) tidal flux of less than 10%, it causes a northward shift of the flood catchment water line in the middle of Yaosha. Finally, case 8 meets the requirements of the standard limit values of evaluation indicators, e.g., 1455 hectares of reclamation is the limit value to maintain the natural state of the Sanshahong channel and the stability of the tidal creek system and Yaosha. Therefore, the results suggest optimizing the structure and layout of breakwaters, controlling the restriction of reclamation, and further maintaining and protecting the ecological function of Tongzhou Bay. Full article

Coastal zones, and in particular offshore areas, are coming under ever-increasing pressure from human development. Therefore, the evaluation of habitat quality is of vital importance for management of coastal zones. The InVEST model adopts a multi-module and multi-level design form, which has the advantages of strong visualization and fast calculation. As a result, this study used the InVEST-Habitat quality (HQ) model to assess the habitat quality of the Tongzhou Bay offshore area. Development activities were included in the classification of habitat types and the benthic habitat suitability index was used to describe the spatial variation in habitat quality of the offshore area. The results showed that the methodological approach mentioned above achieved a more detailed assessment of the spatial variation in habitat quality. The empirical model constructed based on the relationship between the Shannon–Weiner index and environmental factors performed well in revealing the suitability of habitat, with the regression equation showing an R² of 0.57 and R² of 0.5 significant at level of p < 0.05. The habitat suitability of Tongzhou Bay water was mainly influenced by aquaculture and industrial sea use. The habitat quality of Tongzhou Bay was relatively low due to disturbance by coastal development and a low water habitat suitability. The distribution of habitat quality in Tongzhou Bay was uneven and improved with the increase of the distance from the coast. Improvement of the habitat quality of Tongzhou Bay requires strict control of sea reclamation, optimization of the structure of offshore aquaculture, improvements to water quality and habitat suitability, and strengthening of the protection of areas of high habitat quality. This study provides a novel method for evaluating habitat quality of offshore areas. Full article

The fast economic development of the People’s Republic of China has created an increasing demand for usable land, resulting in large-scale land reclamations along the coastal zone. One of these regions is Tongzhou Bay (Jiangsu coast), a region characterized by large intertidal mudflats and deep tidal channels with potential for the development of agri-aquaculture and the construction of a deep-sea port. However, these intertidal mudflats also provide vital ecosystem services and support many wildlife species, including several endangered migratory shorebirds within the East Asian–Australasian Flyway. With increasing realization of the importance of maintaining such ecological values, a more integrated coastal development strategy is needed. This study aims to develop a sustainable integrated design for the Tongzhou Bay port, following a “Building with Nature” approach. We use a morphodynamic model to compute habitat suitability for two shorebird species (Great Knot Calidris tenuirostris and Bar-tailed Godwit Limosa lapponica). Several port configurations were developed on the basis of three design criteria: (1) create area for future port development, whilst (2) preserving existing high-value ecotopes for shorebirds and (3) enhance the natural accretion rate of such ecotopes. Simulation results showed a clear difference in siltation patterns, preservation and enhancement of preferred ecotopes. This work therefore demonstrates the potential and importance of morphological and habitat suitability modelling when designing large-scale reclamations and port constructions, especially in dynamic areas such as Tongzhou Bay. Full article