Search Results (24,972)

With global climate change, urbanization, and agricultural resource limitations, precision agriculture and crop monitoring are crucial worldwide. Integrating multi-source remote sensing data with deep learning enables accurate crop mapping, but selecting optimal network architectures remains challenging. To improve remote sensing-based fruit planting classification and support orchard management and rural revitalization, this study explored feature selection and network optimization. We proposed an improved CF-EfficientNet model (incorporating FGMF and CGAR modules) for fruit planting classification. Multi-source remote sensing data (Sentinel-1, Sentinel-2, and SRTM) were used to extract spectral, vegetation, polarization, terrain, and texture features, thereby constructing a high-dimensional feature space. Feature selection identified 13 highly discriminative bands, forming an optimal dataset, namely the preferred bands (PBs). At the same time, two classification datasets—multi-spectral bands (MS) and preferred bands (PBs)—were constructed, and five typical deep learning models were introduced to compare performance: (1) EfficientNetB0, (2) AlexNet, (3) VGG16, (4) ResNet18, (5) RepVGG. The experimental results showed that the EfficientNetB0 model based on the preferred band performed best in terms of overall accuracy (87.1%) and Kappa coefficient (0.677). Furthermore, a Fine-Grained Multi-scale Fusion (FGMF) and a Condition-Guided Attention Refinement (CGAR) were incorporated into EfficientNetB0, and the traditional SGD optimizer was replaced with Adam to construct the CF-EfficientNet architecture. The results indicated that the improved CF-EfficientNet model achieved high performance in crop classification, with an overall accuracy of 92.6% and a Kappa coefficient of 0.830. These represent improvements of 5.5 percentage points and 0.153, compared with the baseline model, demonstrating superiority in both classification accuracy and stability. Full article

Biopharmaceutical medicines represent one of the most dynamic sectors of the pharmaceutical industry, with therapeutic proteins forming the largest and most important group. Their structural complexity and inherent sensitivity to chemical and physical stressors, however, continue to pose major challenges for formulation development and long-term stability. Short peptides have emerged as a promising yet underutilized class of excipients for protein-based drug products. Their modular architecture allows for precise tuning of physicochemical properties such as polarity, charge distribution, and hydrogen-bonding potential, thereby offering advantages over single amino acids. Experimental studies indicate that short peptides can serve multiple functions: stabilizers, antioxidants, viscosity-lowering agents, and as lyo/cryoprotectants or bulking agents in lyophilized formulations. Notably, the relatively small and chemically defined space of short peptides—approximately 400 possible dipeptides and 8000 tripeptides—makes them particularly amenable to systematic screening and computational modeling. This enables rational identification of candidates with tailored excipient functions. This review summarizes current knowledge on the use of short peptides as excipients in parenteral protein formulations, with a focus on their functional versatility and potential for rational design in future development. Full article

This study aims to understand the effects of wildfires in sagebrush ecosystem on soil properties by examining connections between Soil Water Repellency (SWR), reflectance, and chemistry. Ash and burned soil samples were collected after performing laboratory burns of three common sagebrush plants: sagebrush, rabbitbrush, and bitterbrush. The collected samples were analyzed for their physical properties, including SWR measured by Water Drop Penetration Time (WDPT) and Apparent Contact Angle (ACA), and solar spectral reflectance in the wavelength range of 350 to 2500 nm. Chemical functional groups of the samples were analyzed using Fourier-Transform Infrared (FTIR) spectroscopy. WDPT and ACA values were in the range of 1 to 600 s and ~10° to 88°, respectively, for all three tested fuels. The FTIR analysis showed a decrease (~2 to 4 times) in the ratio of COO⁻/C=C signals for the burned soil samples compared to the unburned soil samples. Overall, increase in temperature and ACA levels for the samples of burned and burned soil from a 2 cm depth led to increased formation of non-polar compounds with C=C functional groups, and decarboxylation. Full article

Multi-channel optical systems can provide more feature information compared to single-channel systems, making them valuable for optical remote sensing, target identification, and other applications. The division of aperture polarization imaging modality allows for the simultaneous imaging of targets in the same field of view with a single detector. To overcome the limitations of conventional refractive aperture-divided systems for miniaturization, this work proposes an off-axis catadioptric aperture-divided technique for polarization imaging. First, the design method of the off-axis reflective telescope structure is discussed. The relationship between optical parameters such as magnification, surface coefficient, and primary aberration is studied. Second, by establishing the division of the aperture optical model, the method of maximizing the field of view and aperture is determined. Finally, an off-axis catadioptric cooled aperture-divided infrared optical system with a single aperture focal length of 60 mm is shown as a specific design example. Each channel can achieve 100% cold shield efficiency, and the overall length of the telescope module can be decreased significantly. The image quality of each imaging channel is close to the diffraction limit, verifying the effectiveness and feasibility of the method. The proposed off-axis catadioptric aperture-divided design method holds potential applications in simultaneous infrared polarization imaging. Full article

To ensure adequate skill development, but also competitive advantage as a software engineering organization, initiatives in cybersecurity training is one of several important investment decisions to make for management. This study builds upon three case organizations in Sweden and Greece, where managers’ and software developers’ perceptions on trialability and observability effects are analyzed, grounded in the theory of innovation diffusion. Using interviews and a developer-centric survey, both quantitative and qualitative data are collected, and used in combination to support the development of a pre-investment framework for management. The analysis includes thematic analysis, cosine similarity comparison, and, to some extent, sentiment polarity scoring. A pre-investment framework consisting of a process of seven concrete steps is proposed, based on the empirical findings in the study. Full article

The aim of the study is to investigate the influence of the physicochemical characteristics of the molecular and supramolecular structure of polymers on electroadhesive interactions and their change under the action of a constant electric field. Currently, this effect is modeled in electroadhesion studies, but the range of variable parameters is limited and includes permittivity, moisture content, and surface roughness. It is important to consider other physicochemical parameters, such as material crystallinity and surface characteristics, changes in which can affect the magnitude of electroadhesive forces. In this study, the electric field strength was varied by altering the constant voltage in the range of 3–8 kV. Polyethylene, ethylene-vinyl acetate copolymers, and polyvinyl acetate were used as substrates for adhesive systems. The influence of the concentration of vinyl acetate groups, which determine the energy characteristics of the surface, and the degree of crystallinity on electroadhesive interactions under conditions of an external constant electric field and without it was traced. The degree of crystallinity was varied both by the cooling rate and the orientation during drawing. It was shown that by changing the polar component of the surface energy and the proportion of the crystalline phase in the substrate, electroadhesive interactions can be increased by 4 times to 120 Pa compared to polyethylene. The obtained laws are explained by the local dipoles induced by polar functional groups, which enhance the polymer’s surface interactions with other materials and external fields. At the same time, the fixation of macromolecules in crystalline regions complicates polarization under the influence of an electric field. Full article

Tourist reviews provide essential insights into travellers experiences and public perceptions of destinations. In Kazakhstan, however, sentiment analysis, particularly using ensemble learning, remains underexplored for evaluating such reviews. This study proposes a hybrid stacking ensemble for sentiment analysis of English-language tourist reviews about Kazakhstan, integrating four complementary approaches: VADER, TextBlob, Stanza, and Local Context Focus Mechanism with Bidirectional Encoder Representations from Transformers (LCF-BERT). Each model contributes distinct analytical capabilities, including lexicon-based polarity detection, rule-based subjectivity evaluation, generalised star-rating estimation, and contextual aspect-oriented sentiment classification. The evaluation utilised a cleaned dataset of 11,454 TripAdvisor reviews collected between February 2022 and June 2025. The ensemble aggregates model outputs through majority and weighted voting strategies to enhance robustness. Experimental results (accuracy 0.891, precision 0.838, recall 0.891, and F1-score 0.852) demonstrate that the proposed method KazSATR outperforms individual models in overall classification accuracy and exhibits superior capacity for aspect-level sentiment detection. These findings underscore the potential of the hybrid ensemble as a practical and scalable tool for the tourism sector in Kazakhstan. By leveraging multiple analytical paradigms, the model enables tourism professionals and policymakers to better understand traveller preferences, identify service strengths and weaknesses, and inform strategic decision-making. The proposed approach contributes to advancing sentiment analysis applications in tourism research, particularly in underrepresented geographic contexts. Full article

The range-dependence on polarization distortion of spaceborne polarimetric synthetic aperture radar (SAR) affects the accuracy of wide-swath polarization applications, such as environmental monitoring, sea ice classification and ocean wave inversion. Traditional calibration methods, assessing the distortion mainly based on ground experiments, suffer from tedious active calibrator deployment work, which are time-consuming and cost-intensive. This paper proposes a novel polarimetric assessment and calibration method for the quad-polarized wide-swath ScanSAR imaging mode. Firstly, by using distributed target data that satisfy the system reciprocity requirement, we assess the polarization distortion matrices for a single beam in the mode. Secondly, we transfer the matrix results from one beam to another by analyzing data from the overlapping region between beams. Thirdly, we calibrate the quad-polarized data and achieve an overall assessment and calibration results. Compared to traditional calibration methods, the presented method focuses on using cross-beam (overlapping area) data to reduce the dependence on active calibrators and avoid conducting calibration work beam-by-beam. The assessment and calibration experiment is conducted on Gaofen-3 quad-polarized ScanSAR experiment mode data. The calibrated images and polarization decomposition results are compared with those from well-calibrated quad-polarized Stripmap mode data located in the same region. The results of the comparison revealed the effectiveness and accuracy of the proposed method. Full article

During China’s 41st Antarctic research expedition, samples were collected from wildlife on the Fildes Peninsula, South Shetland Islands, Antarctica. Real-time RT-PCR screening confirmed H5N1 positivity, representing the first identification of the virus in brown skuas on the Fildes Peninsula. Whole-genome sequences obtained from positive samples via next-generation sequencing were subjected to phylogenetic and phylogeographic analyses. The results revealed that these Antarctic strains are most closely related to H5N1 viruses circulating in South America, particularly from Peru and Chile, suggesting a likely introduction via avian migration routes. Furthermore, a unique 17-amino-acid deletion was identified in the stalk region of the neuraminidase (NA) gene, which is uncommon among globally sampled clade 2.3.4.4b variants. This study confirms the arrival of HPAI H5N1 in the Antarctic continent and underscores the necessity for enhanced surveillance to understand the viral ecology and potential risks within this unique ecosystem. Full article

To address the issue of reduced image contrast and visibility caused by turbid media, such as dense fog, this paper proposes a novel polarization-based single-image dehazing model. The model introduces a first-of-its-kind nonlinear joint polarization model for airlight and target light. This model is established within a Cartesian coordinate system, abstracted as an analytical geometric model. Leveraging the structural similarity principle in images, boundary constraints are applied to enhance the accuracy of target light estimation. Finally, image dehazing and enhancement are achieved using the atmospheric scattering model. Experimental results demonstrate that the proposed algorithm does not rely on dataset training, maintains the highest structural consistency, and achieves superior image restoration across various scenarios, producing results that most closely resemble natural observation. Full article

This study reports the synthesis and comprehensive spectroscopic characterization of 4-indolylcyanamide (4ICA), a novel indole-derived infrared (IR) probe designed for assessing local microenvironments in biological systems. 4ICA was synthesized via a two-step procedure with an overall yield of 43%, and its structure was confirmed using high-resolution mass spectrometry and ¹HNMR. Fourier Transform Infrared (FTIR) spectroscopy revealed that the cyanamide group stretching vibration of 4ICA exhibits exceptional solvent-dependent frequency shifts, significantly greater than those of conventional cyanoindole probes. A strong linear correlation was observed between the vibrational frequency and the combined Kamlet–Taft parameter, underscoring the dominant role of solvent polarizability and hydrogen bond acceptance in modulating its spectroscopic behavior. Quantum chemical calculations employing density functional theory (DFT) with a conductor-like polarizable continuum model (CPCM) provided further insight into the solvatochromic shifts and suppression of Fermi resonance in high-polarity solvents such as DMSO. Additionally, IR pump–probe measurements revealed short vibrational lifetimes (~1.35 ps in DMSO and ~1.13 ps in ethanol), indicative of efficient energy relaxation. With a transition dipole moment nearly twice that of traditional nitrile-based probes, 4ICA demonstrates enhanced sensitivity and signal intensity, establishing its potential as a powerful tool for site-specific environmental mapping in proteins and complex biological assemblies using nonlinear IR techniques. Full article

To address the flood risks driven by climate change and urbanization, this study proposes the DRIRA model (Driving Force, Resistance, Influence, Recoverability, Adaptability). Distinct from BRIC (Baseline Resilience Indicators for Communities) and PEOPLES (Population, Environmental/Ecosystem, Organized Governmental Services, Physical Infrastructure, Lifestyle, Economic Development, Social–Cultural Capital), the model emphasizes dynamic interactions across the entire disaster lifecycle, introduces the “Influence” dimension, and integrates SNA (Social Network Analysis) with a modified gravity model to reveal cascading effects and resilience linkages among cities. Based on an empirical study of 30 cities in the Central Plains Urban Agglomeration, and using a combination of entropy weighting, a modified spatial gravity model, and social network analysis, the study finds that: (1) Urban flood resilience increased by 35.5% from 2012 to 2021, but spatial polarization intensified, with Zhengzhou emerging as the dominant core and peripheral cities falling behind; (2) Economic development, infrastructure investment, and intersectoral governance coordination are the primary factors driving resilience differentiation; (3) Intercity resilience connectivity has strengthened, yet administrative fragmentation continues to undermine collaborative effectiveness. In response, three strategic pathways are proposed: coordinated development of sponge and resilient infrastructure, activation of flood insurance market mechanisms, and intelligent cross-regional dispatch of emergency resources. These strategies offer a scientifically grounded framework for balancing physical flood defenses with institutional resilience in high-risk urban regions. Full article

Donor–π–acceptor (D–π–A) dyes have garnered significant attention due to their unique optical properties and potential applications in various fields, including optoelectronics, chemical sensing and bioimaging. This study presents the design, synthesis, and comprehensive photophysical investigation of a series of ionic dyes incorporating five- and six-membered heterocyclic rings as electron-donating and electron-withdrawing units, respectively. The influence of the dye structure, i.e., (a) the systematically varied heteroatom (NMe, S and O) in donor moiety, (b) benzannulation of the acceptor part and (c) position of the donor vs. acceptor, on the photophysical properties was evaluated by steady-state and time-resolved spectroscopy across solvents of varying polarity. To probe solvatochromic behavior, the Reichardt parameters and the Catalán four-parameter scale, including polarizability (SP), dipolarity (SdP), acidity (SA) and basicity (SB) parameters, were applied. Emission dynamics were further analyzed through time-resolved fluorescence spectroscopy employing multi-exponential decay models to accurately describe fluorescence lifetimes. Time-dependent density functional theory (TDDFT) calculations supported the experimental findings by elucidating electronic structures, charge-transfer character, and dipole moments in the ground and excited states. The experimental results show the introduction of O or S instead of NMe causes substantial hypsochromic shifts in the absorption and emission bands. Benzannulation enhances the photoinduced charge transfer and causes red-shifted absorption spectra to be obtained without deteriorating the emission properties. Hence, by introducing an appropriate modification, it is possible to design materials with tunable photophysical properties for practical applications, e.g., in opto-electronics or sensing. Full article

Corbicula fluminea protein (CFP) and cyanidin-3-O-glucoside (C3G) are natural nutrient fortifiers. During consumption or processing, they may interact with each other, inducing alternations in their structural and functional properties. However, nothing was known about the mechanism of their interaction and their synergistic antioxidant effect. In this research, C3G was physically mixed with CFP to simulate practical scenarios. The impact of the presence of C3G on the multispectral characteristics, antioxidant activity, and particle properties of CFP was examined and compared to chemically fabricated C3G-CFP covalent conjugates. The results indicate that C3G tended to spontaneously bind to CFP and formed compact non-covalent complex, with hydrophobic forces predominantly governing the interaction. This binding resulted in the statically quenched intrinsic fluorescence of CFP, accompanied by a dynamic model. Moreover, C3G preferentially induced Trp residue in CFP exposed to a more polar microenvironment, yet it exerted nearly no effects on CFP when analyzed using ultraviolet–visible (UV-Vis) spectroscopy and synchronous fluorescence spectroscopy (SFS). Additionally, although the formed non-covalent complex demonstrated strengthened antioxidant capacity, C3G displayed an antagonistic effect with CFP, whereas lower C3G concentrations led to synergistic effects in covalent conjugates. These findings provide new insights into the effective application of C3G and CFP as nutritional antioxidants. Full article

Accurate measurement of the Goos–Hänchen (GH) shift serves as a crucial foundation for the deepening of its theories and the expansion of its applications. To meet the requirements for GH shift measurement, this study constructed a complete experimental system. Composed of a stable laser light source, a high-precision optical path control unit with adjustable incident angles, a high sensitivity detection scheme, and an integrated control and data processing module, this system possesses the capability of full-process measurement covering optical signal generation, adjustment, detection, and data analysis. To effectively obtain the GH shift, this research adopted the TE/TM polarization differential method for measurement experiments and discussed the performance indicators of the system. Experimental verification shows that the system can accomplish the GH shift measurement task accurately and reliably. The experimental platform established in this study provides a practical tool for in-depth theoretical research and application exploration of the GH shift. Furthermore, its high-precision measurement capability not only lays a foundation for the research and development of optical sensing technologies based on the GH shift phenomenon but also offers important support for further revealing the physical essence of the beam shift effect and exploring its potential technical application value. Full article