Search Results (11)

Chemical mixing of different types of magma, such as basaltic magma and silica-rich, hydrous magma, often triggers volcanic eruptions. However, the kinetics, mechanisms, and rates of sulfide dissolution reactions in hydrous melts are currently unknown, despite the fact that these reactions can influence the sulfur budget in the crust and mantle. I experimentally model dissolution of pyrrhotite minerals in hydrous rhyolite melt at conditions corresponding to the sulfate–sulfide transition field at 1 GPa pressure. The reaction results in the production of FeO, SO₄²⁻, H₂, H₂S and di- and tri-sulfur radical ions, (S₂⁻ or S₃⁻) in fluid/melt. The calculated sulfur diffusion coefficient implies extremely fast sulfur diffusion in the hydrous hybrid melt. The production of S-rich magma is controlled by the fastest-ever-recorded chemical diffusion of sulfur in the form of S₂⁻ or S₃⁻ in hybrid magma under sulfate-sulfide transition conditions. I demonstrate that such dissolution reactions can be responsible for triggering explosive volcanic eruptions (e.g., the 1991 Mount Pinatubo eruption) in volcanic arc settings. The sulfide dissolution reaction can also promote the production of chalcophile metal (sulfur-loving Au, Cu and Pt) ore deposits associated with the formation of volcanic arcs. Full article

Over the past few decades, the oceans have stored the majority of the excess heat in the climate system resulting from anthropogenic emissions. An accurate, long-term sea surface temperature (SST) dataset is essential for monitoring and researching the changes to the global oceans. A variety of SST datasets have been produced by various institutes over the years, and here, we present a new SST data record produced originally within the Copernicus Marine Environment Monitoring Service (which is therefore named CMEMS v2.0) and assess: (1) its accuracy compared to independent observations; (2) how it compares with the previous version (named CMEMS v1.2); and (3) its performance during two major volcanic eruptions. By comparing both versions of the CMEMS datasets using independent in situ observations, we show that both datasets are within the target accuracy of 0.1 K, but that CMEMS v2.0 is closer to the ground truth. The uncertainty fields generated by the two analyses were also compared, and CMEMS v2.0 was found to provide a more accurate estimate of its own uncertainties. Frequency and vector analysis of the SST fields determined that CMEMS v2.0 feature resolution and horizontal gradients were also superior, indicating that it resolved oceanic features with greater clarity. The behavior of the two analyses during two volcanic eruption events (Mt. Pinatubo and El Chichón) was examined. A comparison with the HadSST4 gridded in situ dataset suggested a cool bias in the CMEMS v2.0 dataset versus the v1.2 dataset following the Pinatubo eruption, although a comparison with sparser buoy-only observations yielded less clear results. No clear impact of the El Chichón eruption (which was a smaller event than Mt. Pinatubo) on CMEMS v2.0 was found. Overall, with the exception of a few specific and extreme events early in the time series, CMEMS v2.0 possesses high accuracy, resolution, and stability and is recommended to users. Full article

Adakites are Y- and Yb-depleted, SiO₂- and Sr-enriched rocks with elevated Sr/Y and La/Yb ratios originally thought to represent partial melts of subducted metabasalt, based on their association with the subduction of young (<25 Ma) and hot oceanic crust. Later, adakites were found in arc segments associated with oblique, slow and flat subduction, arc–transform intersections, collision zones and post-collisional extensional environments. New models of adakite petrogenesis include the melting of thickened and delaminated mafic lower crust, basalt underplating of the continental crust and high-pressure fractionation (amphibole ± garnet) of mantle-derived, hydrous mafic melts. In some cases, adakites are associated with Nb-enriched (10 ppm < Nb < 20 ppm) and high-Nb (Nb > 20 ppm) arc basalts in ancient and modern subduction zones (HNBs). Two types of HNBs are recognized on the basis of their geochemistry. Type I HNBs (Kamchatka, Honduras) share N-MORB-like isotopic and OIB-like trace element characteristics and most probably originate from adakite-contaminated mantle sources. Type II HNBs (Sulu arc, Jamaica) display high-field strength element enrichments in respect to island-arc basalts coupled with enriched, OIB-like isotopic signatures, suggesting derivation from asthenospheric mantle sources in arcs. Adakites and, to a lesser extent, HNBs are associated with Cu–Au porphyry and epithermal deposits in Cenozoic magmatic arcs (Kamchatka, Phlippines, Indonesia, Andean margin) and Paleozoic-Mesozoic (Central Asian and Tethyan) collisional orogens. This association is believed to be not just temporal and structural but also genetic due to the hydrous (common presence of amphibole and biotite), highly oxidized (>ΔFMQ > +2) and S-rich (anhydrite in modern Pinatubo and El Chichon adakite eruptions) nature of adakite magmas. Cretaceous adakites from the Stanovoy Suture Zone in Far East Russia contain Cu–Ag–Au and Cu–Zn–Mo–Ag alloys, native Au and Pt, cupriferous Ag in association witn barite and Ag-chloride. Stanovoy adakites also have systematically higher Au contents in comparison with volcanic arc magmas, suggesting that ore-forming hydrothermal fluids responsible for Cu–Au(Mo–Ag) porphyry and epithermal mineralization in upper crustal environments could have been exsolved from metal-saturated, H₂O–S–Cl-rich adakite magmas. The interaction between depleted mantle peridotites and metal-rich adakites appears to be capable of producing (under a certain set of conditions) fertile sources for HNB melts connected with some epithermal Au (Porgera) and porphyry Cu–Au–Mo (Tibet, Iran) mineralized systems in modern and ancient subduction zones. Full article

Volcanic ash clouds often become multilayered and thin with distance from the vent. We explore one mechanism for the development of this layered structure. We review data on the characteristics of turbulence layering in the free atmosphere, as well as examples of observations of layered clouds both near-vent and distally. We then explore dispersion models that explicitly use the observed layered structure of atmospheric turbulence. The results suggest that the alternation of turbulent and quiescent atmospheric layers provides one mechanism for the development of multilayered ash clouds by modulating vertical particle motion. The largest particles, generally μ$>100 \mathsf{\mu }$m, are little affected by turbulence. For particles in which both settling and turbulent diffusion are important to vertical motion, mostly in the range of 10–100 μ$\mathsf{\mu }$m, the greater turbulence intensity and more rapid turbulent diffusion in some layers causes these particles to spend greater time in the more turbulent layers, leading to a layering of concentration. The results may have important implications for ash cloud forecasting and aviation safety. Full article

The transition to renewable energies is an unavoidable step to guarantee a peaceful and sustainable future for humankind. Although solar radiation is one of the main sources of renewable energy, there are broad regions of the planet where it has not been characterized appropriately to provide the necessary information for regional and local planning and design of the different solar powered systems. The Caribbean, and Cuba in particular, lacked until very recently at least one long-term series of surface solar radiation measurements. Here we present the first long-term records of solar radiation for this region. Solar radiation measurements manually conducted and recorded on paper were rescued, reprocessed and quality controlled to develop the solar radiation climatology at the Actinometrical Station of Camagüey, in Cuba (21.422${}^{°}$N; 77.850${}^{°}$W; 122 m a.s.l.) for the period 1981–2016. The diurnal cycle based on the average hourly values of the global, direct and diffuse horizontal variables for the entire period have been determined and analyzed showing the dependence on solar zenith angle (SZA) and clouds. The annual cycle of global solar component given by the mean monthly daily values presents two maxima, one in April and another one in July with values of 5.06 and 4.91 kWh m${}^{-2}$, respectively (18.23 and 17.67 MJ m${}^{-2}$ per day for insolation), and the minimum in December (3.15 kWh m${}^{-2}$ or 11.33 MJ m${}^{-2}$). The maxima are governed by the direct solar components and are modulated by cloudiness. Both, diurnal and annual cycles of the diffuse solar component show a smoothed bell shaped behavior. In general solar radiation at this station presents a strong influence of clouds, with little seasonal variation but with higher values during the rainy season. Daily global radiation annual averages showed its maximum value in the year 1983, with 17.45 MJ m${}^{-2}$ explained by very low cloudiness this year, and the minimum value was reported in 2009 with a value of 12.43 MJ m${}^{-2}$ that could not explained by the cloud coverage or the aerosols optical depths registered that year. The effects of the 1982 El Chichón and 1991 Mount Pinatubo volcanic eruptions on the solar radiation variables at Camagüey are also shown and discussed. The results achieved in this study shown the characteristics of solar radiation in this area and their potential for solar power applications. Full article

The largest explosive volcanic eruptions produce umbrella clouds that drive ash radially outward, enlarging the area that impacts aviation and ground-based communities. Models must consider the effects of umbrella spreading when forecasting hazards from these eruptions. In this paper we test a version of the advection–dispersion model Ash3d that considers umbrella spreading by comparing its simulations with observations from three well-documented umbrella-forming eruptions: (1) the 15 June 1991 eruption of Pinatubo (Philippines); (2) the 13 February 2014 eruption of Kelud (Indonesia); and (3) phase 2 of the 22–23 April 2015 eruption of Calbuco (Chile). In volume, these eruptions ranged from several cubic kilometers dense-rock equivalent (DRE) for Pinatubo to about one tenth for Calbuco. In mass eruption rate (MER), they ranged from 10⁸–10⁹ kg s⁻¹ at Pinatubo to 9–16 × 10⁶ kg s⁻¹ at Calbuco. For each case we ran simulations that considered umbrella growth and ones that did not. All umbrella-cloud simulations produced a cloud whose area was within ~25% of the observed cloud by the end of the eruption. By the eruption end, the simulated areas of the Pinatubo, Kelud, and Calbuco clouds were 851, 53.2, and 100 × 10³ km² respectively. These areas were 2.2, 2.2, and 1.5 times the areas calculated in simulations that ignored umbrella growth. For Pinatubo and Kelud, the umbrella simulations provided better agreement with the observed cloud area than the non-umbrella simulations. Each of these simulations extended 24 h from the eruption start. After the eruption ended, the difference in cloud area (umbrella minus non-umbrella) at Pinatubo persisted for many hours; at Kelud it diminished and became negative after 14 h and at Calbuco it became negative after ~23 h. The negative differences were inferred to result from the fact that non-umbrella simulations distributed ash over a wider vertical extent in the plume, and that wind shear spread the cloud out in multiple directions. Thus, for some smaller eruptions, wind shear can produce a larger cloud than might be produced by umbrella spreading alone. Full article

Using the two-box energy balance model (EBM), we explore the climate system response to radiative forcing generated by variations in the concentrations of stratospheric aerosols and estimate the effect of uncertainties in radiative feedbacks on changes in global mean surface temperature anomaly used as an indicator of the response of the climate system to external radiative perturbations. Radiative forcing generated by stratospheric sulfate aerosols from the second-largest volcanic eruption in the 20th century, the Mount Pinatubo eruption in June 1991, was chosen for this research. The global mean surface temperature response to a specified change in radiative forcing is estimated as a convolution of the derived impulse response function corresponding to EBM with a function that describes the temporal change in radiative forcing. The influence of radiative feedback uncertainties on changes in the global mean surface temperature is estimated using several “versions” of the EBM. The parameters for different “versions” were identified by applying a specific procedure for calibrating the two-box EBM parameters using the results of climate change simulations conducted with coupled atmosphere–ocean general circulation models from the Coupled Model Intercomparison Project phase 5 (CMIP5). Changes in the global mean surface temperature caused by stratospheric aerosol forcing are found to be highly sensitive not only to radiative feedbacks but also to climate system inertia defined by the effective heat capacity of the atmosphere–land–ocean mixed layer system, as well as to deep-ocean heat uptake. The results obtained have direct implications for a better understanding of how uncertainties in climate feedbacks, climate system inertia and deep-ocean heat uptake affect climate change modelling. Full article

Large explosive eruptions can result in the formation of an umbrella cloud which rapidly expands, spreading ash out radially from the volcano. The lateral spread by the intrusive gravity current dominates the transport of the ash cloud. Hence, to accurately forecast the transport of ash from large eruptions, lateral spread of umbrella clouds needs to be represented within volcanic ash transport and dispersion models. Here, we describe an umbrella cloud parameterisation which has been implemented into an operational Lagrangian model and consider how it may be used during an eruption when information concerning the eruption is limited and model runtime is key. We examine different relations for the volume flow rate into the umbrella, and the rate of spreading within the cloud. The scheme is validated against historic eruptions of differing scales (Pinatubo 1991, Kelud 2014, Calbuco 2015 and Eyjafjallajökull 2010) by comparing model predictions with satellite observations. Reasonable predictions of umbrella cloud spread are achieved using an estimated volume flow rate from the empirical equation by Bursik et al. and the observed eruption height. We show how model predictions can be refined during an ongoing eruption as further information and observations become available. Full article

A suite of peridotite xenoliths were collected from lahar flow deposits located close to the summit of Mt. Pinatubo. Spinel harzburgite is the most dominant lithology among dunites, pyroxenites and websterites. A rare spinel lherzolite xenolith (P12-7) is also present in this suite. The spinel lherzolite has well-preserved protogranular texture with very minimal presence of secondary amphibole, low Cr# in the chromian spinel, and depleted and hump shaped patterns of chondrite-normalized rare earth element (REE) patterns for the clinopyroxenes. In contrast, the spinel harzburgites contain abundant secondary amphiboles and orthopyroxenes, higher Cr# in the spinel, and slightly elevated patterns for the chondrite-normalized REE patterns for the amphiboles. The spinel lherzolite also exhibits higher olivine Fo content for a given spinel Cr# compared to the spinel harzburgites. The spinel lherzolite is interpreted as a typical residue from partial melting of abyssal peridotites whereas the spinel harzburgites may have formed via partial melting with subsequent modification during the influx of fluids in the mantle wedge. Our results suggest that fragments of MOR-derived lithosphere exist in the mantle wedge beneath the Philippine island arc. This work provides evidence for the conversion of abyssal to arc peridotites in the mantle wedge. Full article

The radiative perturbation associated to stratospheric aerosols from major explosive volcanic eruptions may induce significant changes in stratospheric dynamics. The aerosol heating rates warm up the lower stratosphere and cause a westerly wind anomaly, with additional tropical upwelling. Large scale transport of stratospheric trace species may be perturbed as a consequence of this intensified Brewer–Dobson circulation. The radiatively forced changes of the stratospheric circulation during the first two years after the eruption of Mt. Pinatubo (June 1991) may help explain the observed trend decline of long-lived greenhouse gases at surface stations (approximately −8 and −0.4 ppbv/year for CH₄ and N₂O, respectively). This decline is partly driven by the increased mid- to high-latitude downward flux at the tropopause and also by an increased isolation of the tropical pipe in the vertical layer near the tropopause, with reduced horizontal eddy mixing. Results from a climate-chemistry coupled model are shown for both long-lived trace species and the stratospheric age-of-air. The latter results to be younger by approximately 0.5 year at 30 hPa for 3–4 years after the June 1991 Pinatubo eruption, as a result of the volcanic aerosols radiative perturbation and is consistent with independent estimates based on long time series of in situ profile measurements of SF₆ and CO₂. Younger age of air is also calculated after Agung, El Chichón and Ruiz eruptions, as well as negative anomalies of the N₂O growth rate at the extratropical tropopause layer. This type of analysis is made comparing the results of two ensembles of model simulations (1960–2005), one including stratospheric volcanic aerosols and their radiative interactions and a reference case where the volcanic aerosols do not interact with solar and planetary radiation. Full article

Large explosive volcanic eruptions are capable of injecting considerable amounts of particles and sulfur gases above the tropopause, causing large increases in stratospheric aerosols. Five major volcanic eruptions after 1960 (i.e., Agung, St. Helens, El Chichón, Nevado del Ruiz and Pinatubo) have been considered in a numerical study conducted with a composition-climate coupled model including an aerosol microphysics code for aerosol formation and growth. Model results are compared between an ensemble of numerical simulations including volcanic aerosols and their radiative effects (VE) and a reference simulations ensemble (REF) with no radiative impact of the volcanic aerosols. Differences of VE-REF show enhanced diabatic heating rates; increased stratospheric temperatures and mean zonal westerly winds; increased planetary wave amplitude; and tropical upwelling. The impact on stratospheric upwelling is found to be larger when the volcanically perturbed stratospheric aerosol is confined to the tropics, as tends to be the case for eruptions which were followed by several months with easterly shear of the quasi-biennial oscillation (QBO), e.g., the Pinatubo case. Compared to an eruption followed by a period of westerly QBO, such easterly QBO eruptions are quite different, with meridional transport to mid- and high-latitudes occurring later, and at higher altitude, with a consequent decrease in cross-tropopause removal from the stratosphere, and therefore longer decay timescale. Comparing the model-calculated e-folding time of the volcanic aerosol mass during the first year after the eruptions, an increase is found from 8.1 and 10.3 months for El Chichón and Agung (QBO westerly shear), to 14.6 and 30.7 months for Pinatubo and Ruiz (QBO easterly shear). The corresponding e-folding time of the global-mean radiative flux changes goes from 9.1 and 8.0 months for El Chichón and Agung, to 28.7 and 24.5 months for Pinatubo and Ruiz. Full article