Search Results (228)

This paper introduced a simple, efficient method to prepare mechanically strong lignin-based foams (lignofoams) with open-cell structures using a facile baking technique. The self-expansion of lignin occurred without any additional chemical blowing agents, foaming agents, plasticizers, or lubricants. During heating, kraft lignin softened, and the internal water, either initially adsorbed or generated in situ through the dehydration of hydroxyl groups, acted as a natural blowing agent for foaming a porous foam structure. Incorporating a small amount of polypropylene (PP) enhanced mechanical properties by coating the inner walls of open cells. The porous, softened composite was then cooled to room temperature and solidified into the self-expanded lignofoam. The resulting lignofoams exhibited tunable densities ranging from 0.21 to 0.49 g/cm³ and a maximum compressive strength of 3.6 MPa. The lignofoam also showed excellent thermal insulation properties with low thermal conductive coefficients (0.057–0.098 W/mK). These features highlight the great potential of lignofoam for a bio-based thermal insulation material for construction applications. Full article

This paper aims to investigate the effects of the co-pyrolytic product produced from the co-pyrolysis of waste cooking oil (WCO) and polypropylene (PP) on pure bitumen by using some physical and rheological tests. To reach this goal, the product was obtained by producing from the co-pyrolysis of WCO and PP at distinct conditions. Different pyrolytic products with different structural properties can be obtained from the co-pyrolysis of various materials at different pyrolysis conditions. It was not found any study in which bitumen was modified with the co-pyrolytic product produced from the co-pyrolysis of WCO and PP materials at specified blending ratios and conditions, as described in this paper. For this reason, this paper investigates the effects of this co-pyrolytic product as an additive on bitumen in order to improve some of the rheological and physical properties of bitumen and to overcome some problems for the first time. The mixture ratio was determined as 1:2 (WCO:PP). PG 64-22 neat bitumen was modified with this co-pyrolytic product, and some features of the bituminous binders were detected by using differential scanning calorimetry (DSC), Fourier transform infrared spectroscopy (FTIR), penetration, softening point, dynamic shear rheometer (DSR), rotational viscometer (RV), a rolling thin film oven test (RTFOT), a pressurized aging vessel (PAV), a bending beam rheometer (BBR), storage stability, and scanning electron microscopy (SEM) tests. From the FTIR results of the modified binders, it was found that the intensity of the peak around 2357.69 cm⁻¹ increased with the addition of this pyrolytic product. This pyrolytic additive hardened the pure bitumen’s consistency, increased its viscosity, improved its resistance against rutting deformations, and enhanced its high-temperature performance. It can be said that PG 64-22 pure bitumen can easily be modified with this pyrolytic product at the conditions described in this study. Additionally, this co-pyrolytic product improved the high-temperature performance grade (PG) of pure bitumen from PG 64 to PG 76 when it was used at 5% of the weight of neat bitumen. The findings demonstrated that the modified bituminous binders containing 3% and 5% co-pyrolytic product had suitable storage stabilities. Full article

Anion exchange membrane water electrolysis (AEMWE) is promising for low-cost hydrogen production, but its progress is limited by the weak mechanical strength and structural instability of polymer membranes. Here, a PPS-PBP/PVA composite membrane was developed using a polyphenylene sulfide (PPS) mesh as the mechanical scaffold, poly(biphenyl piperidinium) (PBP) as the ion-conducting polymer, and poly(vinyl alcohol) (PVA) as an interfacial binder. The membrane shows significantly enhanced tensile strength and puncture resistance, reduced swelling, and improved interfacial integrity. The optimized PPS-PBP/PVA (10 wt%) membrane delivers 6 A cm⁻² at 2.16 V in 1 M KOH at 80 °C and maintains stable operation for 500 h at 1 A cm⁻² with only a slight voltage increase. The results demonstrate that reinforcement coupled with interface regulation is an effective approach to constructing robust and durable composite membranes for AEMWE. Full article

Background: Perforator flaps improved the reconstruction paradigm in the lower extremity, increasing coverage possibilities. This study aims to quantify how added perforators could enhance standard geometrical patterns (compared to random flaps). Methods: A total of 29 cases of lower limb soft tissue reconstruction (STR)—52% trauma, 21% osteomyelitis with skin fistulas, 21% healing disorders with unstable scarring and 6% cancer-related surgery—were performed in our institution between 2012 to 2023 with geometric random (GR) local flaps (34%), geometric perforator-enhanced (GP) flaps (32%) or pure propeller perforator (PP) flaps (34%), were retrospectively analysed. Patients with proximal thigh defects, a follow up of less than 3 months and those who received an axial, muscle or free flap were excluded. Geometric patterns (as length:width ratio (L:W)) were compared among groups, analysing healing outcomes and complications. Results: Leg defects were categorized into 62% distal, 14% middle, 14% proximal third and 10% distal thigh. No significant difference in defect size was detected among groups. Mean flap size was significantly larger for GP (70.5 cm², (p < 0.05)) and PP (74.4 cm², (p < 0.01)) than GR (53.7 cm²). The L:W ratio was significantly higher in GP (L:W 2.2:1, (p < 0.05)) and PP (L:W 2.8:1, (p < 0.01)) than in GR (1.5:1), but no significant difference was found between GP and PP. A reduced complications rate (partial flap loss, infection, healing, revision surgery, etc.) was observed in the GP group, when compared to GR. Conclusions: Flap geometric design can be significantly improved by the inclusion of perforators, maintaining spatial advantages with larger ductility and improved vascular solidity. Full article

Background/Objectives: The effect of a high-volume, lower-body resistance exercise session on repeat power ability (RPA), defined as the ability to reach peak power (PP) or near PP during a high-volume resistance training session, remains unclear. The purpose of this study was to analyze the effects of recovery time and sex on loss of power within and across sets during a high-volume, low-load squat session. Methods: Twenty-five resistance-trained males and females (age = 25.5 ± 7.2 years; ht = 169.8 ± 8.9 cm; wt = 75.9 ± 16.9 kg) completed the study. Mean power output across five sets was measured during two sessions (one-minute rest vs. two-minute rest) using a linear position transducer in random order. Five sets at 45% of the participant’s 1RM were completed until power output decreased below 80% of the participant’s within-set PP for two consecutive repetitions or until volitional exhaustion occurred. The data were analyzed with a three-way ANOVA (recovery time by set by sex). Results: The males demonstrated a significant loss across sets for both the one-minute (194 watts) and two-minute recovery period (104 watts), while no change occurred for females in either condition. The males produced greater mean power across both recovery times and sets (p = 0.017). Further, a significant recovery time-by-set interaction was observed (p = 0.015). Mean power decreased an average of 111.3 watts during the one-minute recovery period compared to a loss of 54.0 watts during the two-minute recovery period. Lastly, within-set fatigue occurred during repetitions 9–11 and 11–14 during the one- and two-minute recovery periods, respectively. Conclusions: The data indicate that greater RPA occurs within and across sets with two minutes of rest. In addition, sex must also be considered when implementing a high-volume resistance training session with the goal of training repeat power ability. Full article

Near-infrared (NIR) spectroscopy is a rapid, non-destructive analytical tool widely used in the food and agricultural sectors. In this study, two NIR instruments were compared for classifying the addition of microplastics (MPs) to high-moisture-content samples such as vegetables and fruit. Polyethylene (PE), polypropylene (PP), and a mix of polymers (PE + PP) MP were added to mixtures of spinach and banana and scanned using benchtop (Bruker Tango) and portable (MicroNIR) instruments. Both principal component analysis (PCA) and partial least squares (PLS) were used to analyze and interpret the spectra of the samples. Quantitative models were developed to predict the addition of Mix, PP, or PE to spinach and banana samples using PLS regression. The R² _CV and the SECV obtained were 0.88 and 0.44 for the benchtop samples, and 0.54 and 0.67 for the portable instruments, respectively. Two wavenumber regions were also evaluated: 11,520–7500 cm⁻¹ (short to medium wavelengths), and 7500–4200 cm⁻¹ (long wavelengths). The R² _CV and the SECV obtained were 0.88 and 0.46, 0.86 and 0.49, respectively, for the prediction of addition in samples analyzed on the benchtop instrument using short and long wavenumbers, respectively. This study provides new insights into the comparison of two instruments for detecting the addition of MPs in high-moisture samples. The results of this study will ensure that NIR can be utilized not only to measure the quality of these samples but also to monitor MPs. Full article

Overhead transmission lines have long relied on cross-linked polyethylene (XLPE) insulation. The production of XLPE insulation requires silane cross-linking, which generates by-products, consumes high energy, and results in poor recyclability-retired XLPE insulation can only be disposed of through incineration or landfilling. Additionally, its high density leads to increased cable weight and sag, reducing the service life of the cables. Therefore, there is an urgent need to develop recyclable and lightweight insulation materials. In this study, recyclable polypropylene (PP) was used as a substitute for XLPE. Hollow glass microspheres (HGM) were incorporated to reduce weight, and hydrogenated styrene-ethylene-butylene-styrene block copolymer (SEBS) was added for toughening, thereby constructing a PP/HGM/SEBS ternary composite system. The results show that the introduction of HGM into the PP matrix effectively reduces the material density, decreasing from 0.890 g/cm³ (pure PP) to 0.757 g/cm³—a reduction of 15%. With the addition of SEBS, the mechanical properties of the composite are significantly improved: the tensile strength increases from 14.94 MPa (PP/HGM) to 32.40 MPa, and the elongation at break jumps sharply from 72.02% to 671.22%, achieving the synergistic optimization of “weight reduction” and “strengthening-toughening”. Electrical performance tests indicate that the PP/HGM/SEBS composite exhibits a volume resistivity of 1.66 × 10¹² Ω·m, a characteristic breakdown strength of 108.6 kV/mm, a low dielectric loss tangent of 2.76 × 10⁻⁴, and a dielectric constant of 2.24. It achieves density reduction while maintaining low dielectric loss and high insulation strength, verifying its feasibility for application in lightweight insulation scenarios of overhead transmission lines. Full article

Background: Although brachial–ankle pulse wave velocity (baPWV) has been used to predict cardiovascular events, studies comparing it with brachial pulse pressure (brPP) for predictive value have been lacking. We investigated how brPP and baPWV differ in their ability to predict future cardiovascular events. Methods: We retrospectively reviewed the clinical data of 11,703 consecutive patients where brPP and baPWV measurements had been made. The primary endpoint was differences in the incidence of major adverse cardiovascular and cerebrovascular events (MACCE). Results: Participants had a median age of 61 years, and men accounted for 57.7% of the cohort. During a median follow-up duration of 3.64 years, 347 (3.0%) MACCE occurred. Using established reference values of baPWV > 1800 cm/s and brPP > 60 mmHg, we, respectively, stratified patients by these values. Kaplan–Meier survival curve analysis revealed that both high baPWV and brPP groups displayed elevated MACCE incidence, all-cause mortality, and cardiovascular mortality. After controlling for potential confounders, multivariate Cox regression analysis showed that individuals with elevated baPWV had higher rates of MACCE, overall mortality, and cardiovascular death, whereas brPP was not significantly associated with these outcomes. Subgroup analysis showed a consistent difference in MACCE incidence across all subgroups when stratified by baPWV; however, the significance disappeared in several subgroups when stratified by brPP. Conclusions: baPWV exhibited a stronger association with MACCE incidence than brPP. Thus, baPWV may be a more effective factor than brPP for cardiovascular risk stratification. Full article

Background: Oral health (OH) seems to be relevant for the number of sick and injured days (NSID), missing matches (MM) and secondarily for the physical performance (PP). Aim: The objective was to clarify possible associations between OH, NSID, and PP for elite soccer players. Methods: Thirty-nine male athletes (age: 24.6 ± 4.2 years, age range: 17–34 years) from a third league professional soccer team were examined concerning several dental parameters (decayed, missing, and filled teeth, DMFT; periodontal screening index, PSI; approximal plaque index, API; papillary bleeding index, PBI) and PP parameters. The PP diagnostic contains grip strength, posturography, jump and sprint tests, and an endurance test on treadmill. Furthermore, the number of sick and injured days and missing matches was collected and assessed over four seasons. Results: We could not find any relevant (r > 0.7) correlations between sick and injured days or missing matches and variables of different dimensions (OH, PP). The soccer players showed a remarkable level of oral health (missing teeth, MT: 0.18 ± 0.56), jumping performance (44.5 ± 5.42 cm), and grip strength (53.7 ± 7.02 kg). The endurance capacity (velocity at 4 mmol/L lactate threshold, v4: 14.9 ± 1.11 km/h) was on an average level, whereas the levels of postural stability (stability indicator, ST: 20.0 ± 4.55) and sprinting performance (10 m sprint: 1.79 ± 0.09 s) were comparatively low. Only five players (13%) reported that oral health had ever had a negative impact on his physical performance. Two players (5%) reported currently tooth pain and six players (15%) bleeding gums or grinding teeth. Conclusions: Based on the high level of dental health, it was difficult to prove any relationships between OH and the NSID/MM or PP. Nevertheless, it seems that young soccer players benefit particularly from improved oral health programs. The excellent dental care appears to have a positive effect on general health and physical performance in soccer. Full article

The Ddw1 dwarfing gene is pivotal for reducing plant height and improving lodging resistance in triticale, but its pleiotropic effects on yield components and heading date pose significant challenges for breeders. This study identifies the Growth-Regulating Factor 9-6A (GRF9-6A) gene that compensates for these drawbacks. Field trials across locations (Moscow, Krasnodar) and years (2018, 2019) confirmed the effect of Ddw1, reducing plant height by 26.1–30.1 cm (31.8–32.5%) and thousand-kernel weight (TKW) by 6.0–6.3 g (11.8–15.7%) while increasing the harvest index by up to 4.8 percentage points in three out of four environments, with its effect nullified under the heat stress of Krasnodar 2019. In a Ddw1 background, the GRF9-6Ab allele distinguished by a 12 bp deletion in its promoter compensated for yield losses by increasing grain weight per main spike by up to 0.34 g (19.2%) via boosts in grain number per spike (up to 11.6%) and TKW (up to 11.5%). This combination also elevated the harvest index by up to 4.0 pp and, critically, provided a key agronomic advantage by accelerating heading by 6.3–6.5 days (10.0–10.2%), thereby mitigating the Ddw1-associated developmental delay. Our results demonstrate that pyramiding Ddw1 with the GRF9-6Ab allele the development of semi-dwarf, high-yielding, and early-maturing triticale cultivars for food and forage. This breeding strategy, facilitated by a newly developed diagnostic marker for GRF9-6Ab, is particularly advantageous for cultivation in environments similar to the Central Non-Chernozem region. Full article

This study investigated the effects of lightweight wearable resistance on the kinetics and kinematics of squat jumps (SJ) and countermovement jumps (CMJ) with 2%, 4%, and 6% body mass (BM). Twenty male athletes (age: 18.05 ± 0.6 years; weight: 76.4 ± 7.6 kg; height: 182.4 ± 5 cm) were assessed on a force plate. Key variables included jump height (JH), concentric (ConT) and eccentric (EccT) phase durations, concentric impulse (CI), mean force (CMF), mean velocity (CMV), mean power (CMP), and relative metrics. Elastic utilization ratios (EUR) were calculated to quantify stretch-shortening cycle enhancement. Load led to decrements in both jumps but with varying sensitivity. With 2% BM the CMJ significantly reduced JH (−8.6%), EccT (−7%), CMV (−4.1%), rCI (−4.1%), rPP (−4.4%), and velocity at PP (−4.8%), whereas variables in the SJ were non-significant until 4–6% BM. EURs observed the greatest differences with 2% BM with JH, CMV, rCMP, and VPP all significantly decreasing (p < 0.05). The varying sensitivity to load across variables observed in the two jumps supports the hypothesis that SJ and CMJ offer distinct diagnostic insights due to varying MTU contraction dynamics and neural factors. This has implications for WR use in training. Further, absolute metrics showed limited load sensitivity. However, when accounting for body mass, relative metrics revealed substantial declines. This indicates absolute values can misrepresent the effects of WR loading. Full article

Gelatin has been widely used as a raw material for packaging development in the food industry. Edible films made from biopolymers such as gelatin can incorporate functional ingredients from natural sources like peel powder and fresh pulp from Opuntia guerrana (tuna fruit). The formulations GFP, GPP, GM, and the control GF, were developed and characterized. The physicochemical composition of PP and FP (protein, fat, ash, fiber, and carbohydrates) was evaluated. Antioxidant activity showed 98.19 ± 0.21% ABTS radical inhibition for PP. FTIR analysis showed a characteristic peak at 3294–3284 cm⁻¹, associated with the interaction between gelatin and hydroxyl (OH) groups from Opuntia guerrana phenolic compounds. The color and barrier properties of the films were affected by the addition of prickly pear peel and pulp. Mechanical properties such as Young’s modulus and tensile strength showed significant differences (p ≤ 0.05) when pulp was added to the films. The film with PP exhibited the highest concentration of bioactive compounds (phenols, flavonoids, and betalains) and inhibited the ABTS radical 98.24 ± 0.08% and 38.50 ± 2.11% DPPH radical. All films reached biodegradation levels of approximately 90% after 15 days of incubation. The use of prickly pear residues to obtain value-added compounds can significantly modify the physicochemical and functional properties of gelatin films. Full article

The problem of marine plastic pollution is multifaceted and poses a serious threat to the ecosystem and human health. This work is the first investigation of mesoplastics (MEPs, 5 mm–2.5 cm) along the most representative beaches of the whole Mediterranean coast of Morocco. Surface sediment samples (0–5 cm), with 3 replicates each, were collected from thirty-three beaches to identify mesoplastic item characteristics (concentration, weight, type, size, color, and nature). The samples were collected between October and November 2021 and a total of 1998 mesoplastics (59.99 g kg⁻¹) were collected from the thirty-three beaches studied. The average concentrations ranged from 20.18 ± 13.93 MEP kg⁻¹ to 0.61 ± 0.61 g kg⁻¹, showing a great variability within each beach and between the beaches investigated. Mesoplastic fragments accounted for 43.92% of the total mesoplastic items, showed sizes from 5 to 10 mm (56.64%) and were predominantly white/transparent (43.36%). Fourier Transform Infrared Spectroscopy (FTIR) analysis revealed that Polyethylene (PE), Polypropylene (PP), Polystyrene (PS), and Polyvinyl chloride (PVC) were the most common polymers. The present results revealed a moderate level of mesoplastics pollution along the beaches investigated. Fishing, coastal activities, and wastewater discharges were probably the main sources. Furthermore, this study is likely to serve as a scientific baseline for monitoring and tracking mesoplastic pollution on Moroccan beaches. Full article

Biomass pellets are widely used for combustion but can also serve as sustainable feedstocks for pyrolysis. This study examined wood (WP), palm-pruning (PP), reed (RD), and daphne (DP) pellets. We present a compact framework linking composition (proximate/ultimate and lignocellulosic fractions) with TG/DTG, FTIR, TGA-derived indices (CPI, D_dev, R_w), T_pmax and R_av to predict product selectivity and temperature ranges. TG/DTG showed the following sequence: hemicellulose (≈200–315 °C) first, cellulose (≈315–400 °C) with a sharp maximum, and lignin ≈200–600 °C. Low-ash WP and DP had sharper, higher peaks, favoring concentrated devolatilization and condensables. Mineral-rich PP and RD began earlier and showed depressed peaks from AAEM catalysis, shifting toward gases and ash-richer chars. Composition shaped these patterns: higher cellulose increased R_av and CPI; links to T_pmax were moderated by ash. Lignin strengthened a high-T shoulder, while hemicellulose promoted early deacetylation (RD’s 1730 cm⁻¹ acetyl C=O) and release of CO₂ and acids. Correlations (|r| ≥ 0.70) supported these links: VM with total (m_∞) and second stage mass loss; cellulose with R_av and CPI (T_pmax moderated by ash); lignin and O/C with T_f and last stage mass loss; ash negatively with T_i, T_pmax, and m_∞. The obtained results guide the sustainable valorization of biomass pellets by selecting temperatures for liquids, H₂/CO-rich gases or low-ash aromatic chars. Full article

Accurate identification of plastic polymers is essential for effective recycling, quality control, and environmental monitoring. This study assesses how spectral derivative preprocessing affects the classification of six common plastic polymers: Polyethylene Terephthalate (PET), Polyvinyl Chloride (PVC), Polypropylene (PP), Polystyrene (PS), and both High- and Low-Density Polyethylene (HDPE and LDPE), based on Fourier Transform Infrared (FTIR) spectroscopy data acquired at a resolution of 8 ${cm}^{-1}$. Using Savitzky–Golay derivatives (orders 0, 1, and 2), five machine learning algorithms, namely Multilayer Perceptron (MLP), Extremely Randomized Trees (ET), Linear Discriminant Analysis (LDA), Support Vector Classifier (SVC), and Random Forest (RF), were tested within a strict framework involving stratified repeated cross-validation and a final hold-out test set to evaluate generalization. The first spectral derivative notably improved the model performance, especially for MLP and SVC, and increased the stability of the ET, LDA, and RF classifiers. The combination of the first derivative with the ET model provided the best results, achieving a mean F1-score of 0.99995 (±0.00033) in cross-validation and perfect classification (1.0 in Accuracy, F1-score, Cohen’s Kappa, and Matthews Correlation Coefficient) on the independent test set. LDA also performed very well, underscoring the near-linear separability of spectral data after derivative transformation. These results demonstrate the value of derivative-based preprocessing and confirm a robust method for creating high-precision, interpretable, and transferable machine learning models for automated plastic polymer identification. Full article