Search Results (10)

The increasing generation of organic and liquid wastes calls for sustainable strategies to convert residues into valuable energy resources. This study investigates waste Oxytree biomass (Paulownia Clon In Vitro 112^®) as a sorbent for producing impregnated solid fuels from selected liquid wastes, including used cooking oil, spent mineral oil, and pyrolysis condensate, targeting industrial energy applications. Oxytree biomass was selected due to its high and predictable yield, uniform composition, and favorable physical properties compared to conventional lignocellulosic residues such as pine sawdust. Biomass and liquid wastes were characterized in terms of fuel properties and elemental composition. Several empirical combinations of sorbent and liquid fractions were tested to optimize homogeneity and fuel quality, resulting in a final composition of sorbent:used cooking oil:used machine oil:pyrolytic condensate equal to 3:1:1:3. The temporal stability of this selected fuel was verified over 24 h, 3 days, and 1 week. The resulting fuels exhibited an energy value of approximately 15 MJ/kg, low ash content (<1%), and minimal concentrations of chlorine and sulfur (<0.08%). Overall, the findings demonstrate that Oxytree waste biomass can serve as an effective sorbent for integrating problematic liquid wastes into solid fuels, providing a practical route for waste valorization and supporting circular economy principles, and establishing a foundation for further research on sustainable energy applications of biomass and industrial residues. Full article

The problem of wastewater discharged from facilities for soilless plant cultivation is a worldwide problem. So, there is a strong need to find a simple, maintenance-free technological solution. Such a solution may be the use of biofilters or constructed wetlands with “active” filling, which will be a source of carbon for denitrifying organisms. The aim of this study was to evaluate four different types of materials—Oxytree wood chips (Paulownia Clon in vitro 112^®), biobased polybutylene succinate derivatives (BioPBS FZ91PB and BioPBS FD92PB), and beech wood chips—as biofilter media and as solid exogenous carbon sources. The highest efficiency of denitrification and dephosphatation (43.11% and 42.48%, respectively) was characterized by the biobased polybutylene succinate FD92PB. The lowest removal efficiency of phosphorus compounds was achieved for beech chips—25.23% and BioPBS FZ91PB—26.42%. The lowest denitrification efficiency—8.8%—was achieved by Oxytree wood chips. The extent of organic matter (COD) repollution in the treated wastewater requires further study. Wood chips were found to release less COD than biobased polybutylene succinate. The research results showed that all tested materials can be a source of carbon in soilless tomato cultivation wastewater treatment. This is a good starting point for further research on selecting appropriate process parameters and creating new solutions for reactor construction. Full article

The aim of the study was to examine the effects of application of plant-growth regulators (PGR) on the growth of paulownia plants and evaluate their usefulness in paulownia nurseries. The experiment was carried out on the paulownia interspecific hybrid (Paulownia elongata × Paulownia fortunei) ‘Oxytree’. Micropropagated plants grown in pots were sprayed with PGR solutions. Gibberellins (GA₃, GA₄+GA₇), 6-benzyladenine (BA), triclopyr (TPA), ethephon (ETH), daminozide (DA), prohexadione-Ca (PH), and trinexapac-ethyl (TE) were used. They were included in commercial products (Florgib 245 mg dm⁻³, Gibb plus 11 SL 5 cm³ dm⁻³, Globaryll 100 SL 1.5 cm³ dm⁻³, Topper 10 ST 200 mg dm⁻³, Agrostym 480 SL 2 cm³ dm⁻³, B-Nine 85 SG 2 g dm⁻³, Regalis plus 10 WG 2.5 g dm⁻³, Moddus 250 EC 1 cm³ dm⁻³, respectively). None of the studied preparations modified positive correlations between the longitudinal vs. transverse growth of stems and growth of leaves. Not only GA₃, GA₄+GA₇, but also BA (cytokinin) and unexpectedly TE (retardant) stimulated stem elongation and thickening. Furthermore, the effect of TE lasted longer than influence of GA_x and BA. Leaves of TE-treated plants were distinguished by a higher chlorophyll a/b ratio, and a lower relative chlorophyll content and efficiency of photosystem II (F_v/F_m, F_v/F₀). TPA strongly deformed the stems and leaves of liners. Other regulators (ETH, DA, PH) retarded the diameter growth of stems and leaf expansion. Some results obtained by GA_x, BA, and especially by TE treatment, might be beneficial for paulownia grown as ornamental and/or timber tree. Full article

This article describes the characteristics of th Oxytree (Paulownia) plant, both in terms of its impact on GHG emissions and its potential use to produce biofuel, i.e., biogas. The described research involved the physico-chemical and elemental analysis of the Oxytree leaf composition and its biogas efficiency depending on the harvesting method. Three different scenarios were considered: the freshest possible leaves—processed immediately after stripping from the living tree; after the first day of collection from pruned or harvested wood; after the first week of collection from pruned or harvested wood. The best results were achieved for the harvest of the freshest leaves—on average 430 m³/Mg (biogas) and 223 m³/Mg (methane) per dry organic mass. The highest yield of biogas in terms of fresh mass (FM) was obtained for leaves fallen and collected after 1 day—123 m³/Mg FM, and 59 m³/Mg FM (methane). Processing Oxytree leaves through anaerobic digestion will contribute to reducing the carbon footprint of wood biomass production and is an additional source of renewable energy and fertilizer product. Full article

It is not easy to find data in the scientific literature on the quantitative content of individual phytochemicals. It is possible to find groups of compounds and even individual compounds rather easily, but it is not known what their concentration is in cultivated or wild plants. Therefore, the subject of this study was to determine the content of individual compounds in the new Paulownia species, Oxytree, developed in a biotechnology laboratory in 2008 at La Mancha University in Spain. Six secondary metabolites were isolated, and their chemical structure was confirmed by spectral methods. An analytical method was developed, which was then used to determine the content of individual compounds in leaves, twigs, flowers and fruits of Paulownia Clon in Vitro 112^®. No flavonoids were found in twigs and fruits of Oxytree, while the highest phenylethanoid glycosides were found in twigs. In this study, we also focused on biological properties (anticoagulant or procoagulant) of extract and four fractions (A–D) of different chemical composition from Paulownia Clon in Vitro 112 leaves using whole human blood. These properties were determined based on the thrombus-formation analysis system (T-TAS), which imitates in vivo conditions to assess whole blood thrombogenecity. We observed that three fractions (A, C and D) from leaves decrease AUC₁₀ measured by T-TAS. In addition, fraction D rich in triterpenoids showed the strongest anticoagulant activity. However, in order to clarify the exact mechanism of action of the active substances present in this plant, studies closer to physiological conditions, i.e., in vivo studies, should be performed, which will also allow to determine the effects of their long-term effects. Full article

The potential of the Paulownia hybrid for the uptake and transport of 67 elements along with the physiological response of plants cultivated in highly contaminated post-industrial wastes (flotation tailings—FT, and mining sludge—MS) was investigated. Biochar (BR) was added to substrates to limit metal mobility and facilitate plant survival. Paulownia could effectively uptake and translocate B, Ca, K, P, Rb, Re and Ta. Despite severe growth retardation, chlorophyll biosynthesis was not depleted, while an increased carotenoid content was noted for plants cultivated in waste materials. In Paulownia leaves and roots hydroxybenzoic acids (C6-C1) were dominant phenolics, and hydroxycinnamic acids/phenylpropanoids (C6-C3) and flavonoids (C6-C3-C6) were also detected. Plant cultivation in wastes resulted in quantitative changes in the phenolic fraction, and a significant drop or total inhibition of particular phenolics. Cultivation in waste materials resulted in increased biosynthesis of malic and succinic acids in the roots of FT-cultivated plants, and malic and acetic acids in the case of MS/BR substrate. The obtained results indicate that the addition of biochar can support the adaptation of Paulownia seedlings growing on MS, however, in order to limit unfavorable changes in the plant, an optimal addition of waste is necessary. Full article

Background: The Paulownia Clone in Vitro 112, known as oxytree or oxygen tree, is a hybrid clone of the species Paulownia elongata and Paulownia fortunei (Paulowniaceae). The oxytree is a fast-growing hybrid cultivar that can adapt to wide variations in edaphic and climate conditions. In this work, Paulownia Clone in Vitro 112 leaves were separated into an extract and four fractions (A–D) differing in chemical content in order to investigate their chemical content using LC-MS analysis. The extract and fractions were also evaluated for their anticoagulant and antioxidant properties in a human plasma in vitro. Results: The Paulownia leaf extract contained mainly phenolic compounds (e.g., verbascoside), small amounts of iridoids (e.g., aucubin or 7-hydroxytometoside) and triterpenoids (e.g., maslinic acid) were also detected. Our results indicate that the extract and fractions have different effects on oxidative stress in human plasma treated with H₂O₂/Fe in vitro, which could be attributed to differences in their chemical content. For example, the extract and all the fractions, at the two highest concentrations of 10 and 50 µg/mL, significantly inhibited the plasma lipid peroxidation induced by H₂O₂/Fe. Fractions C and D, at all tested concentrations (1–50 µg/mL) were also found to protect plasma proteins against H₂O₂/Fe-induced carbonylation. The positive effects of fraction C and D were dependent on the dose. Conclusions: The extract and all four fractions, but particularly fractions C and D, which are rich in phenolic compounds, are novel sources of antioxidants, with an inhibitory effect on oxidative stress in human plasma in vitro. Additionally, the antioxidant potential of fraction D may be associated with triterpenoids. Full article

Oxytree is a fast-growing energy crop with C4 photosynthesis. In this research, for the first time, the torrefaction kinetic parameters of pruned Oxytree biomass (Paulownia clon in Vitro 112) were determined. The influence of the Oxytree cultivation method and soil class on the kinetic parameters of the torrefaction was also investigated. Oxytree pruned biomass from a first-year plantation was subjected to torrefaction within temperature range from 200 to 300 °C and under anaerobic conditions in the laboratory-scale batch reactor. The mass loss was measured continuously during the process. The relative mass loss increased from 1.22% to 19.56% with the increase of the process temperature. The first-order constant rate reaction (k) values increased from 1.26 × 10⁻⁵ s⁻¹ to 7.69 × 10⁻⁵ s⁻¹ with the increase in temperature. The average activation energy for the pruned biomass of Oxytree torrefaction was 36.5 kJ∙mol⁻¹. Statistical analysis showed no significant (p < 0.05) effect of the Oxytree cultivation method and soil class on the k value. The results of this research could be useful for the valorization of energy crops such as Oxytree and optimization of waste-to-carbon and waste-to-energy processes. Full article

Biowaste generated in the process of Oxytree cultivation and logging represents a potential source of energy. Torrefaction (a.k.a. low-temperature pyrolysis) is one of the methods proposed for the valorization of woody biomass. Still, energy is required for the torrefaction process during which the raw biomass becomes torrefied biomass with fuel properties similar to those of lignite coal. In this work, models describing the influence of torrefaction temperature and residence time on the resulting fuel properties (mass and energy yields, energy densification ratio, organic matter and ash content, combustible parts, lower and higher heating values, CHONS content, H:C and O:C ratios) were proposed according to the Akaike criterion. The degree of the models’ parameters matching the raw data expressed as the determination coefficient (R²) ranged from 0.52 to 0.92. Each model parameter was statistically significant (p < 0.05). Estimations of the value and quantity of the produced torrefied biomass from 1 Mg of biomass residues were made based on two models and a set of simple assumptions. The value of torrefied biomass (€123.4·Mg⁻¹) was estimated based on the price of commercially available coal fuel and its lower heating value (LHV) for biomass moisture content of 50%, torrefaction for 20 min at 200 °C. This research could be useful to inform techno-economic analyses and decision-making process pertaining to the valorization of pruned biomass residues. Full article

The very fast growing Oxytree (Paulownia Clon in Vitro 112) is marketed as a promising new energy crop. The tree has characteristically large leaves, thrives in warmer climates, and requires initial pruning for enhanced biomass production in later years. We explored valorizing the waste biomass of initial (first year) pruning via thermal treatment. Specifically, we used torrefaction (‘roasting’) to produce biochar with improved fuel properties. Here for the first time, we examined and summarized the fuel properties data of raw biomass of Oxytree pruning and biochars generated via torrefaction. The effects of torrefaction temperature (200~300 °C), process time (20~60 min), soil type, and agro-technical cultivation practices (geotextile and drip irrigation) on fuel properties of the resulting biochars were summarized. The dataset contains results of thermogravimetric analysis (TGA) as well as proximate and ultimate analyses of Oxytree biomass and generated biochars. The presented data are useful in determining Oxytree torrefaction reaction kinetics and further techno-economical modeling of the feasibility of Oxytree valorization via torrefaction. Oxytree torrefaction could be exploited as part of valorization resulting from a synergy between a high yield crop with the efficient production of high-quality renewable fuel. Full article