Search Results (7)

This comprehensive review examines the transformative role of metal–organic frameworks (MOFs) in advancing battery separator technology to address critical safety challenges in rechargeable lithium metal batteries. MOF-based separators leverage their highly specific surface area, tunable pore structures, and functionalized organic ligands to enable precise ion-sieving effects, uniform lithium-ion flux regulation, and dendrite suppression—significantly mitigating risks of internal short circuits and thermal runaway. We systematically analyze the mechanisms by which classical MOF families (e.g., ZIF, UiO, MIL series) enhance separator performance through physicochemical properties such as electrolyte wettability, thermal stability (>400 °C), and mechanical robustness. Furthermore, we highlight innovative composite strategies integrating MOFs with polymer matrices (e.g., PVDF, PAN) or traditional separators, which synergistically improve ionic conductivity while inhibiting polysulfide shuttling in lithium–sulfur batteries and side reactions in aqueous zinc-ion systems. Case studies demonstrate that functionalized MOF separators achieve exceptional electrochemical outcomes: Li–S batteries maintain >99% Coulombic efficiency over 500 cycles, while solid-state batteries exhibit 2400 h dendrite-free operation. Despite promising results, scalability challenges related to MOF synthesis costs and long-term stability under operational conditions require further research. This review underscores MOFs’ potential as multifunctional separator materials to enable safer, high-energy-density batteries and provides strategic insights for future material design. Full article

In global economic integration and rapid urbanization, the equilibrium between resource utilization efficiency and ecological preservation is confronted with significant challenges. Emerging contaminants have further exacerbated environmental pressures and posed threats to the ecosystem and human health. Metal–organic frameworks (MOFs) have emerged as a prominent area of research in ecological remediation, owing to their distinctive porous configuration, substantial specific surface area, and exceptional chemical stability. The Materials Institute Lavoisier (MIL) series (e.g., MIL-53, MIL-88, MIL-100, MIL-101, and MIL-125) has been shown to effectively promote the separation and migration of photogenerated carriers and significantly enhance the degradation of organic contaminants. This property renders it highly promising for the photocatalytic degradation of emerging contaminants. This paper provides a concise overview of the classification, synthesis methods, modification strategies, and application effects of MIL series MOFs in the removal of emerging contaminants. The advantages and limitations of MIL series MOFs in environmental remediation are further analyzed. Particularly, we offer insights and support for innovative strategies in the treatment of emerging contaminants, including POPs, PPCPs, VOCs, and microplastics, contributing to technological innovation and development in environmental remediation. Future development of MOFs includes the optimization of the performance of the MILs, reducing the high synthesis costs of MILs, applying MILs in real-environment scenarios, and accurate detection of degradation products of environmental pollutants. Full article

The development of efficient antibiotic-releasing materials derived from sustainable and recyclable compounds represents a key area within biomedical materials science, particularly in the treatment of antibacterial infections. Herein, a Fe³⁺/terephthalate-based metal–organic framework (MIL-53) and a novel advanced material made of MIL-53 with biogenic hydroxyapatite (1) were prepared by solvothermal reactions, and these were studied in detail as a Penicillin-G-releasing material. After loading Penicillin G on 1 and MIL-53, the antibiotic percentage release was studied, and the antimicrobial effectiveness of each material was evaluated against two bacterial ATCC strains (E. coli and S. aureus) and various Penicillin-G-resistant uropathogenic strains such as E. coli isolates (HHM 25, ERV 6, and FGI 4). Functional, structural, and morphological characteristics of these materials were thoroughly studied by analytical tools (FTIR, XRD, BET, SEM-EDS, and XPS). The Penicillin G load did not exceed 50% in both materials. The Penicillin G adsorption mechanism involves several types of interactions with the materials. The release of the antibiotic was more efficient from MIL-53, where the load did not exceed 20%. The release was analyzed using mathematical models. They indicated that when Penicillin G is released from MIL-53, the process follows diffusion through a uniform matrix; however, 1 is more porous, which helps with the release by diffusion of Penicillin G, and 1 exhibits more than a 90% inhibition of the growth of bacteria and strains like MIL-53. This suggests a valuable approach to antibiotic activity against resistant pathogens. The use of composite materials derived from the Fe-MOF with a sustainable matrix of hydroxyapatite as antibiotic-releasing materials has been unexplored until now. Full article

The conventional synthesis of the Metal–Organic Framework (MOF) MIL-101(Cr)-SO₃H employs hydrofluoric acid as the modulator, posing handling challenges due to its irritating, corrosive, and toxic nature, as well as its reactivity with glass and metals. This study aims to find a new hydrofluoric acid-free synthesis route for MIL-101(Cr)-SO₃H, proposing acetic acid and nitric acid as modulator alternatives. Four MIL-101(Cr)-SO₃H samples were prepared: one without any modulator and the other three using a similar volume of either hydrofluoric acid, acetic acid, or nitric acid as the modulator. The so-obtained mass yield ranked as follows: without any modulator (32.6%) > acetic acid (29.6%) > nitric acid (25.2%) >> hydrofluoric acid (2.2%), whereas the total pore volume and BET surface area followed the order: hydrofluoric acid (0.87 cm³ g⁻¹, 1862 m² g⁻¹) > nitric acid (0.81 cm³ g⁻¹, 1554 m² g⁻¹) > acetic acid (0.72 cm³ g⁻¹, 1374 m² g⁻¹) > without any modulator (0.69 cm³ g⁻¹, 1342 m² g⁻¹). Despite the superior texture parameters obtained using hydrofluoric acid, the low synthesis yield and associated risks make this route non-viable. Acetic or nitric acid-based synthesis offers a promising alternative with a drastically higher yield, safer handling, and reduced environmental impact. In an attempt to improve the textural properties of the hydrofluoric acid-free MOFs, a series of samples were produced with increasing amounts of acetic acid, achieving BET surface areas of up to 1504 m² g⁻¹ and pore volumes of up to 0.81 cm³ g⁻¹. Full article

The release of organic contaminants has grown to be a major environmental concern and a threat to the ecology of water bodies. Persulfate-based Advanced Oxidation Technology (PAOT) is effective at eliminating hazardous pollutants and has an extensive spectrum of applications. Iron-based metal–organic frameworks (Fe-MOFs) and their derivatives have exhibited great advantages in activating persulfate for wastewater treatment. In this article, we provide a comprehensive review of recent research progress on the significant potential of Fe-MOFs for removing antibiotics, organic dyes, phenols, and other contaminants from aqueous environments. Firstly, multiple approaches for preparing Fe-MOFs, including the MIL and ZIF series were introduced. Subsequently, removal performance of pollutants such as antibiotics of sulfonamides and tetracyclines (TC), organic dyes of rhodamine B (RhB) and acid orange 7 (AO7), phenols of phenol and bisphenol A (BPA) by various Fe-MOFs was compared. Finally, different degradation mechanisms, encompassing free radical degradation pathways and non-free radical degradation pathways were elucidated. This review explores the synthesis methods of Fe-MOFs and their application in removing organic pollutants from water bodies, providing insights for further refining the preparation of Fe-MOFs. Full article

A series of titanium-based, metal–organic framework (MOF) materials, xM@NH₂-MIL125(Ti) (x is the alkali metal loading percentage during the synthesis; M = Li, Na, K), have been synthesized solvothermally. Alkali metal doping in the NH₂–MIL125(Ti) in situ solvothermal process demonstrated a vital modification of the material structure and surface morphology for the CO₂ adsorption capacity at ambient conditions. By changing the reactants’ precursor, including different kinds of alkali metal, the morphology of xM@NH₂–MIL125(Ti) can be adjusted from a tetragonal plate through a circular plate to a truncated octahedron. The variation of the alkali metal loading results in substantial differences in the CO₂ adsorption. The properties of xM@NH₂–MIL125(Ti) were evaluated via functional group coordination using FT-IR, phase identification based on X-ray diffraction (XRD), surface morphology through scanning electron microscopy (SEM), as well as N₂ and CO₂ adsorption by physical gas adsorption analysis. This work reveals a new pathway to the modification of MOF materials for high-efficiency CO₂ adsorption. Full article

A series of aluminum-based coordination polymers or metal–organic frameworks (Al–MOFs), i.e., DUT-4, DUT-5, MIL-53, NH₂-MIL-53, and MIL-100, have been facile prepared by microwave (MW)-assisted reactions and used as catalysts for selective sulfoxidation reactions. The MW-assisted synthesis drastically reduced the reaction time from few days to hours. The prepared MOFs have smaller and uniform particle sizes and better yield compared to conventional hydrothermal method. Furthermore, the Al–MOFs have been successfully demonstrated as catalysts in oxidation reaction of methyl phenyl sulfide with H₂O₂ as oxidant, even under mild conditions, with more than 95% conversion. Full article