Search Results (48)

Laser-driven ion acceleration in dense, hydrogen-rich media can be significantly enhanced by embedding metallic nanoantennas that support localized surface plasmon (LSP) resonances. Using large-scale particle-in-cell (PIC) simulations with the EPOCH code, we investigate how nanoantenna geometry and laser pulse parameters influence proton acceleration in gold-doped polymer targets. The study covers dipole, crossed, and advanced 3D-cross antenna configurations under laser intensities of 10¹⁷–10¹⁹ W/cm² and pulse durations from 2.5 to 500 fs, corresponding to experimental conditions at the ELI laser facility. Results show that the dipole antennas exhibit resonance-limited proton energies of ~0.12 MeV, with optimal acceleration at the intensities 4 × 10¹⁷–1 × 10¹⁸ W/cm² and pulse durations around 100–150 fs. This energy is higher by roughly three orders of magnitude than the proton energy for the same field and same polymer without dopes: ~1–2 × 10⁻⁴ MeV. Crossed antennas achieve higher energies (~0.2 MeV) due to dual-mode plasmonic coupling that sustains local fields longer. Advanced 3D and Yagi-like geometries further enhance field localization, yielding proton energies up to 0.4 MeV and larger high-energy proton populations. For dipole antennas, experimental data from ELI exists and our results agree with it. We find that moderate pulses preserve plasmonic resonance for longer and improve energy transfer efficiency, while overly intense pulses disrupt the resonance early. These findings reveal that plasmonic field enhancement and its lifetime govern energy transfer efficiency in laser–matter interaction. Crossed and 3D geometries with optimized spacing enable multimode resonance and sequential proton acceleration, overcoming the saturation limitations of simple dipoles. The results establish clear design principles for tailoring nanoantenna geometry and pulse characteristics to optimize compact, high-energy proton sources for inertial confinement fusion and high-energy-density applications. Full article

Surface-enhanced Raman scattering (SERS) is a highly sensitive analytical technique capable of single-molecule detection, yet its performance strongly depends on the underlying plasmonic architecture. In this study, we developed a robust SERS platform based on long-range–ordered bullseye plasmonic nano-gratings with tunable period and filling fraction, fabricated via electron beam lithography and reactive ion etching and uniformly coated with a thin gold film. These concentric nanostructures support efficient surface plasmon resonance and radial SPP focusing, enabling intense electromagnetic field enhancement across the substrate. Using this platform, we achieved quantitative detection of Rhodamine 6G with enhancement factors of ${10}^5$. Notably, our results reveal a previously unrecognized mechanistic insight: the geometric configuration producing the strongest local electric fields does not yield the highest SERS enhancement, due to misalignment between the dominant field orientation and the molecular polarizability tensor. This finding explains the non-monotonic dependence of SERS performance on grating geometry and introduces a new design principle in which both field strength and field–molecule alignment must be co-optimized. Overall, this work provides a mechanistic framework for rationally engineering plasmonic substrates for sensitive and quantitative molecular detection. Full article

We investigated the influence of gold deposition on the magnetic behavior, biocompatibility, and bioactivity of CoFe₂O₄ (MCF) nanomaterials (NMs) functionalized with sodium citrate (Cit) or glycine (Gly). The resulting multifunctional plasmonic nanostructured materials (MCF-Au-L, where L is Cit, Gly) exhibit superparamagnetic behavior with magnetic saturation of 59 emu/g, 55 emu/g, and 60 emu/g, and blocking temperatures of 259 K, 311 K, and 322 K for pristine MCF, MCF-Au-Gly, and MCF-Au-Cit, respectively. The MCF NMs exhibit a small uniform size (with a mean size of 7.1 nm) and an atomic ratio of Fe:Co (2:1). The gold nanoparticles (AuNPs) show high heterogeneity as determined by high-resolution transmission electron microscopy (HR-TEM) and energy-dispersive X-ray spectroscopy (EDX). The UV-Vis spectroscopy of the composites reveals two localized surface plasmons (LSPs) at 530 nm and 705 nm, while Fourier Transformed-Infrared spectroscopy (FTIR) and thermogravimetric analysis (TGA) confirm the presence of Cit and Gly on their surface. Subsequent biocompatibility tests confirm that MCF-Au-L NMs do not exert hemolytic activity (hemolysis < 5%). In addition, the CCK-8 viability assay tests indicate the higher sensitivity of cancerous cells (A549) to the photoactivity of MCF-Au compared to healthy Detroit 548 (D548) cell lines. We use advanced microscopy techniques, namely atomic force, fluorescence, and holotomography microscopies (AFM, FM, and HTM, respectively) to provide further insights into the nature of the observed photoactivity of MCF-Au-L NMs. In addition, in situ radiation, using a modified HTM microscope with an IR laser accessory, demonstrates the photoactivity of the MCF-Au NMs and their suitability for destroying cancerous cells through photodynamic therapy. The combined imaging capabilities demonstrate clear morphological changes, NMs internalization, and oxidative damage. Our results confirm that the fabricated multifunctional NMs exhibit high stability in aqueous solution, chemical solidity, superparamagnetic behavior, and effective IR responses, making them promising precursors for hybrid cancer therapy. Full article

Conventional all-optical modulators based on surface plasmon polaritons (SPPs) primarily utilize the nonlinear effect of a given material for modulation. Their performance is heavily dependent on the optical properties of the dielectric materials used and requires high pumping power. However, manipulating SPPs by controlling electron concentrations offers a material-independent approach suitable for all-optical modulators. In this paper, we propose a hybrid gold–ITO–silver block structure integrated within a Mach–Zehnder interferometer configuration to address this problem. The gold–ITO interface effectively localizes propagating SPPs. The pump light excites localized surface plasmons (LSPs) in the silver block, generating surface electric fields that modulate the electron concentration in the adjacent ITO layer. The extinction ratio is 50.8 dB when the electron concentration changes by 3.3 × 10²⁰ cm⁻³, indicating that this structure is an all-optical modulator with a high extinction ratio. This approach shows significant promise for reducing pump power and enhancing the performance of all-optical modulators. Full article

We present in this study a theoretical investigation of the near-field enhancement phenomenon within nanostructures, which have garnered recent attention due to their potential applications in sensing, imaging, and energy harvesting. The analysis reveals a significant intensification of electromagnetic fields proximal to periodically arranged arrays of gold nanoparticles sustaining a highly lossy mode. In addition to the existence of a localized surface plasmon (LSP) mode exhibiting suboptimal quality, our investigation unveils intricate aspects of near-field enhancement closely correlated to the dynamics of lasing mechanisms. Notably, our investigation is focused on elucidating the augmentation’s behavior across varying pumping energies. The achieved enhancement surpasses two orders of magnitude compared to the passive counterparts. We introduce a description of the energy conversion rate specific to the SPASER configuration. The conceptualized SPASER reveals a significant promise. It showcases energy conversion efficiency up to 80%, emphasizing the SPASER’s potential as a highly effective nano-scale energy source. Full article

Gold nanoparticles have been a central topic in the last few decades due to their excellent optical properties that can be exploited in many applications, including food analysis, materials science, and biomedicine. The basis of these unique optical properties is the phenomenon known as localized surface plasmon (LSP), which relays in the collective oscillation of the conduction band electrons in the nanoparticle when excited by electromagnetic radiation. The optical properties of the nanoparticles are critical for selecting the best nanomaterials for each application, a key factor for optimum performance, and can be tuned due to their dependence on the geometry and size of the nanoparticles, as well as the polarization of the light beam. Here, we conducted simulations to study the tunable optical properties and local electric field distribution of three types of gold nanoparticles, cubes (AuNC), boxes (AuNB), and triangular prisms (AuNT), which have relatively simple synthetic routes. Finally, we compared these results with experimental data and described possible synthetic routes to discuss the positive and negative aspects of using each type of nanoparticle for potential applications. Full article

We investigated hybrid functional transparent conductive electrodes (HFTCEs) composed of indium-tin-oxide (ITO) and silver nanowires (AgNWs) for the enhancement of output efficiency in GaN-based ultraviolet light-emitting diodes (UVLEDs). The HFTCEs demonstrated an optical transmittance of 69.5% at a wavelength of 380 nm and a sheet resistance of 16.4 Ω/sq, while the reference ITO TCE exhibited a transmittance of 76.4% and a sheet resistance of 18.7 Ω/sq. Despite the 8.9% lower optical transmittance, the UVLEDs fabricated with HFTCEs achieved a 25% increase in output efficiency compared to reference UVLEDs. This improvement is attributed to the HFTCE’s twofold longer current spreading length under operating forward voltages, and more significantly, the enhanced out-coupling of localized surface plasmon (LSP) resonance with the trapped wave-guided light modes. Full article

The study of localized surface plasmons (LSPs) in nanoscale structures is an essential step towards identifying optimal plasmonic modes that can facilitate robust optomechanical coupling and deepen our understanding of light–matter interactions at the nanoscale. This paper investigates, numerically, using the finite element method, LSP modes in a design comprising two coupled nano-ridges deposited on a gold layer with an interposing polymer spacer layer. Such a structure, usually referred to as a particle-on-mirror structure, shows exquisite optical properties at the nanoscale. We first examine the LSP modes of a single nano-ridge through the analysis of its scattering cross-section in the visible and infrared ranges. To enhance the plasmonic response, a thin polymer layer is placed at the middle of the ridge, which introduces additional LSP modes confined within the former. Then, we extend the analysis to the dimer configuration, which exhibits more complex and enhanced plasmonic behavior compared to a single nano-ridge. In particular, the dimer configuration yields LSP resonances with a quality factor enhancement of approximately threefold relative to a single nano-ridge. Furthermore, the presence of the polymer layer within the ridges significantly improves plasmon field localization and the quality factor. These findings underscore the potential of nano-ridge-based structures in advancing optomechanical coupling and offering valuable insights for the development of high-performance acousto-plasmonic devices. In particular, the proposed device could help significantly improve the design of nano-acousto-optic modulators, operating in the visible or in the near-infrared ranges, that require an enhanced light–phonon coupling rate. Full article

As the driving source, highly efficient silicon-based light emission is urgently needed for the realization of optoelectronic integrated chips. Here, we report that enhanced green electroluminescence (EL) can be obtained from oxygen-doped silicon nitride (SiN_x:O) films based on an ordered and tunable Ag nanocavity array with a high density by nanosphere lithography and laser irradiation. Compared with that of a pure SiN_xO device, the green electroluminescence (EL) from the SiN_x:O/Ag nanocavity array device can be increased by 7.1-fold. Moreover, the external quantum efficiency of the green electroluminescence (EL) is enhanced 3-fold for SiN_x:O/Ag nanocavity arrays with diameters of 300 nm. The analysis of absorption spectra and the FDTD calculation reveal that the localized surface plasmon (LSP) resonance of size-controllable Ag nanocavity arrays and SiN_x:O films play a key role in the strong green EL. Our discovery demonstrates that SiN_x:O films coupled with tunable Ag nanocavity arrays are promising for silicon-based light-emitting diode devices of the AI period in the future. Full article

The Localized Surface Plasmon (LSP) effect of 5 nm mean size Au particles deposited on TiO₂ P25 was investigated during the photo-thermal water gas shift reaction (WGSR). The effects of CO concentration, excitation light flux and energy, and molecular oxygen addition during the reaction were investigated. The photocatalytic WGSR rate under light excitation with wavelengths extending from 320 to 1100 nm was found to be higher than the thermal reaction alone at the same temperature (85 °C). A H₂/CO₂ ratio of near unity was found at high concentrations of CO. The addition of molecular oxygen during the reaction resulted in a slight decrease in molecular hydrogen production, while the rates of CO₂ formation and CO consumption changed by one order of magnitude. More importantly, it was found that the WGSR rates were still high under only visible light excitation (600–700 nm). The results prove that Au LSP alone triggers this chemical reaction without requiring the excitation of the semiconductor on which they are deposited. Full article

Optical imaging and photolithography hold the promise of extensive applications in the branch of nano-electronics, metrology, and the intricate domain of single-molecule biology. Nonetheless, the phenomenon of light diffraction imposes a foundational constraint upon optical resolution, thus presenting a significant barrier to the downscaling aspirations of nanoscale fabrication. The strategic utilization of surface plasmons has emerged as an avenue to overcome this diffraction-limit problem, leveraging their inherent wavelengths. In this study, we designed a pioneering and two-staged resolution, by adeptly compressing optical energy at profound sub-wavelength dimensions, achieved through the combination of propagating surface plasmons (PSPs) and localized surface plasmons (LSPs). By synergistically combining this plasmonic lens with parallel patterning technology, this economic framework not only improves the throughput capabilities of prevalent photolithography but also serves as an innovative pathway towards the next generation of semiconductor fabrication. Full article

In this study we investigate the optical properties of a 2D-gap surface plasmon metasurface composed of gold nanoblocks (nanoantennas) arranged in a metal–dielectric configuration. This novel structure demonstrates the capability of generating simultaneous multi-plasmonic resonances and offers tunability within the near-infrared domain. Through finite difference time domain (FDTD) simulations, we analyze the metasurface’s reflectance spectra for various lattice periods and identify two distinct dips with near-zero reflectance, indicative of resonant modes. Notably, the broader dip at 1150 nm exhibits consistent behavior across all lattice periodicities, attributed to a Fano-type hybridization mechanism originating from the overlap between localized surface plasmons (LSPs) of metallic nanoblocks and surface plasmon polaritons (SPPs) of the underlying metal layer. Additionally, we investigate the influence of dielectric gap thickness on the gap surface plasmon resonance and observe a blue shift for smaller gaps and a spectral red shift for gaps larger than 100 nm. The dispersion analysis of resonance wavelengths reveals an anticrossing region, indicating the hybridization of localized and propagating modes at wavelengths around 1080 nm with similar periodicities. The simplicity and tunability of our metasurface design hold promise for compact optical platforms based on reflection mode operation. Potential applications include multi-channel biosensors, second-harmonic generation, and multi-wavelength surface-enhanced spectroscopy. Full article

Controllable surface plasmonic bending beams (SPBs) with propagating along bending curves have a wide range of applications in the fields of fiber sensors, optical trapping, and micro-nano manipulations. In terms of designing and optimizing controllable SPB generators, there is great significance in realizing conversion between multiple SPBs and single SPB without rebuilding metasurface structures. In this study, a SPB generator, composed of an X-shaped nanohole array, is proposed to realize conversion between multiple SPBs and a single one by changing the incident light wavelength. The Fabry–Pérot (F–P) resonance effect of SPPs in nanoholes and localized surface plasmonic (LSP) resonance of the nanohole are utilized to explain this conversion. It turns out that the relationship between the electric field intensities of SPBs and the polarization angle of incident light satisfies the sine distribution, which is consistent with dipole radiation theory. In addition, we also find that the electric field intensities of SPBs rely on the width, length, and angle of the X-shaped nanohole. These findings could help in designing and optimizing controllable and multi-functions SPBs converters. Full article

Improving the performance of upconversion systems based on triplet–triplet annihilation (TTA-UC) can have far-reaching implications for various fields, including solar devices, nano-bioimaging, and nanotherapy. This review focuses on the use of localized surface plasmon (LSP) resonance of metal nanostructures to enhance the performance of TTA-UC systems and explores their potential applications. After introducing the basic driving mechanism of TTA-UC and typical sensitizers used in these systems, we discuss recent studies that have utilized new sensitizers with distinct characteristics. Furthermore, we confirm that the enhancement in upconverted emission can be explained, at least in part, by the mechanism of “metal-enhanced fluorescence”, which is attributed to LSP resonance-induced fluorescence enhancement. Next, we describe selected experiments that demonstrate the enhancement in upconverted emission in plasmonic TTA-UC systems, as well as the emerging trends in their application. We present specific examples of studies in which the enhancement in upconverted emission has significantly improved the performance of photocatalysts under both sunlight and indoor lighting. Additionally, we discuss the potential for future developments in plasmonic TTA-UC systems. Full article

Although the fabrication of controllable three-dimensional (3D) microstructures on substrates has been proposed as an effective solution for SERS, there remains a gap in the detection and manufacturability of 3D substrates with high performance. In this study, photolithography is adopted to obtain a pyramid-like array on a patterned sapphire substrate (PSS), with Al₂O₃ as the dielectric layer. In addition, silver nanoparticles (AgNPs) are used to decorate Au films to obtain mass-producible 3D SRES substrates. In the case of low fluorescence, the substrate realizes the coupling of localized surface plasmon polaritons (LSPs) and surface plasmon polaritons (SPPs), which is consistent with the simulation results obtained using the finite element method. The performance of the SERS substrate is evaluated using rhodamine 6G (R6G) and toluidine blue (TB) as probe molecules with detection limits of 10⁻¹¹ M and 10⁻⁹ M, respectively. The substrate exhibits high hydrophobicity and excellent light-capturing capability. Moreover, it shows self-cleaning ability and long-term stability in practical applications. Allowing for the consistency of the composite substrate in the preparation process and the high reproducibility of the test results, it is considered to be promising for mass production. Full article