Search Results (23)

Dielectric quality tests require a high AC voltage with a frequency range of 0.0001 Hz to 1000 Hz. However, providing a high AC voltage with such a frequency variety is challenging. Providing a high DC voltage and then applying such a voltage to an inverter to adjust the frequency can be an acceptable solution for such a challenge. Notably, a high DC voltage is required for DC tests. This study proposes an improved form of the cascaded boost converter, whose merits are as follows: (i) the high voltage gain providing low duty cycles is possible; (ii) the input current is continuous, which decreases the current ripple of the input filter capacitor; (iii) the current stress of the semiconductors is less than the input current, and most of them have a large difference with it; (iv) the voltage stress of the semiconductors is less than the output voltage with a large difference; (v) only one switch with a simple drive circuit is used; (vi) the common ground of the load and input source decreases the EMI noise; (vii) besides the high voltage gain, the voltage density of the converter based on the number of inductors, capacitors, switches, diodes, and whole components is greater than that of the recently proposed converters; (viii) only two stacked connections of the proposed topology can provide a 2.6 kV voltage for a higher DC voltage test of dielectrics. The functional details of the converter are extracted in ideal and continuous conduction (CCM) modes. Moreover, the converter’s voltage gain and density are compared with the recently proposed converters to show the superiority of the proposed converter. Finally, the experimental results are presented to validate the theoretical relations in a 140 W output power. Full article

In recent decades, wireless sensor networks (WSNs) have become a popular ambient sensing and model-based solution for various applications. WSNs are now achievable due to the developments of micro electro mechanical and semiconductors logic circuits with rising computational power and wireless communication technology. The most difficult issues concerning WSNs are related to their energy consumption. Since communication typically requires a significant amount of energy, there are some techniques/ways to reduce energy consumption during the operation of the sensor’s communication systems. The topology control technique is one such effective method for reducing WSNs’ energy usage. A cluster head (CH) is usually selected using a topology control technique known as clustering to control the entire network. A single factor is inadequate for CH selection. Additionally, with the traditional clustering method, each round exhibits a new batch of head nodes. As a result, when using conventional techniques, nodes decay faster and require more energy. Furthermore, the inceptive energy of nodes, the range between sensor nodes and base stations, the size of data packets, voltage and transmission energy measurements, and other factors linked to sensor nodes are also completely unexpected due to irregular or hazardous natural circumstances. Here, unpredictability represented by Triangular Fuzzy Numbers (TFNs). The associated parameters of nodes were converted into crisp ones via the defuzzification of fuzzy numbers. The fuzzy number has been defuzzified using the well-known signed distance approach. Here, we have employed a multi-criteria decision-making (MCDM) approach to choosing the CHs depending on a bunch of characteristics of each node (i) residual energy, (ii) the number of neighbors, (iii) distance from the sink, (iv) average distance of cluster node, (v) distance ratio, and (vi) reliability. This study used the entropy-weighted Technique for Order Preference by Similarity to the Ideal Solution (TOPSIS) approach to select the CH in WSNs. For experiments, we have used the NSG2.1 simulator, and based on six characteristics comprising residual energy, number of neighbor nodes, distance from the sink or base station (BS), average distance of cluster nodes, distance ratio, and reliability, optimal CHs have been selected. Finally, experimental results have been presented and compared graphically with the existing literature. A statistical hypothesis test has also been conducted to verify the results that have been provided. Full article

The often overlooked and annoying aspects of the propensity of no-oxygen semiconductor kesterite, Cu₂ZnSnS₄, to oxidation during manipulation and storage in ambient air prompted the study on the prolonged exposure of kesterite nanopowders to air. Three precursor systems were used to make a large pool of the cubic and tetragonal polytypes of kesterite via a convenient mechanochemical synthesis route. The systems included the starting mixtures of (i) constituent elements (2Cu + Zn + Sn + 4S), (ii) selected metal sulfides and sulfur (Cu₂S + ZnS + SnS + S), and (iii) in situ made copper alloys (from the high-energy ball milling of the metals 2Cu + Zn + Sn) and sulfur. All raw products were shown to be cubic kesterite nanopowders with defunct semiconductor properties. These nanopowders were converted to the tetragonal kesterite semiconductor by annealing at 500 °C under argon. All materials were exposed to the ambient air for 1, 3, and 6 months and were suitably analyzed after each of the stages. The characterization methods included powder XRD, FT-IR/UV-Vis/Raman/NMR spectroscopies, SEM, the determination of BET/BJH specific surface area and helium density (d_He), and direct oxygen and hydrogen-content analyses. The results confirmed the progressive, relatively fast, and pronounced oxidation of all kesterite nanopowders towards, mainly, hydrated copper(II) and zinc(II) sulfates, and tin(IV) oxide. The time-related oxidation changes were reflected in the lowering of the energy band gap E_g of the remaining tetragonal kesterite component. Full article

Titanium-manganites of LaLi₂TiMnO₆ and LaNa₂TiMnO₆ were synthesized by the methods of ceramic technology from the oxides of lanthanum, titanium (IV), manganese (III), and the carbonates of lithium and sodium. The types of their syngony and the parameters of their gratings were determined radiographically. The isobaric heat capacities of titanium-manganites were measured with experimental calorimetry in the range of 298.15–673 K. It was found that on the dependence curve of heat capacity versus temperature of C°_p~f(T), for LaLi₂TiMnO₆ at 348 K and 598 K, and LaNa₂TiMnO₆ at 348 K, there are abnormal jumps in heat capacity, probably related to phase transitions of the second kind. Taking into account the temperatures of the phase transitions, the equations of the temperature dependence of the heat capacity of titanium-manganites were derived. Their standard entropies were calculated by the ion increments method. Temperature dependences of the thermodynamic functions of S°(T), H°(T)-H°(298.15), and Φ^xx(T) were calculated using the experimental data on heat capacities and the calculated values of the standard entropies. The standard heat capacities of the studied compounds were calculated by the independent methods of ion increments and Debye, the values of which were in satisfactory agreement with the experimental data. The standard enthalpy of the formation of LaLi₂TiMnO₆ and LaNa₂TiMnO₆ was calculated according to the methodology developed by the authors. The conducted electrophysical studies determined the nature of the second-order phase transition and the semiconductor features of their conductivity. Thus, all the above-mentioned data on the experimental and calculated studies of the temperature dependence of heat capacity, the thermodynamic functions to determine a standard enthalpy of formation of LaLi₂TiMnO₆ and LaNa₂TiMnO₆, and the investigation of their electrical properties are absolutely new, and they have no analogues. Full article

This review explores the performance and reliability of power semiconductor devices required to enable the electrification of heavy goods vehicles (HGVs). HGV electrification can be implemented using (i) batteries charged with ultra-rapid DC charging (350 kW and above); (ii) road electrification with overhead catenaries supplying power through a pantograph to the HGV powertrain; (iii) hydrogen supplying power to the powertrain through a fuel cell; (iv) any combination of the first three technologies. At the heart of the HGV powertrain is the power converter implemented through power semiconductor devices. Given that the HGV powertrain is rated typically between 500 kW and 1 MW, power devices with voltage ratings between 650 V and 1200 V are required for the off-board/on-board charger’s rectifier and DC-DC converter as well as the powertrain DC-AC traction inverter. The power devices available for HGV electrification at 650 V and 1.2 kV levels are SiC planar MOSFETs, SiC Trench MOSFETs, silicon super-junction MOSFETs, SiC Cascode JFETs, GaN HEMTs, GaN Cascode HEMTs and silicon IGBTs. The MOSFETs can be implemented with anti-parallel SiC Schottky diodes or can rely on their body diodes for third quadrant operation. This review examines the various power semiconductor technologies in terms of losses, electrothermal ruggedness under short circuits, avalanche ruggedness, body diode and conduction performance. Full article

The titanium carbide MXenes currently attract an extreme amount of interest from the material science community due to their promising functional properties arising from the two-dimensionality of these layered structures. In particular, the interaction between MXene and gaseous molecules, even at the physisorption level, yields a substantial shift in electrical parameters, which makes it possible to design gas sensors working at RT as a prerequisite to low-powered detection units. Herein, we consider to review such sensors, primarily based on Ti₃C₂T_x and Ti₂CT_x crystals as the most studied ones to date, delivering a chemiresistive type of signal. We analyze the ways reported in the literature to modify these 2D nanomaterials for (i) detecting various analyte gases, (ii) improving stability and sensitivity, (iii) reducing response/recovery times, and (iv) advancing a sensitivity to atmospheric humidity. The most powerful approach based on designing hetero-layers of MXenes with other crystals is discussed with regard to employing semiconductor metal oxides and chalcogenides, noble metal nanoparticles, carbon materials (graphene and nanotubes), and polymeric components. The current concepts on the detection mechanisms of MXenes and their hetero-composites are considered, and the background reasons for improving gas-sensing functionality in the hetero-composite when compared with pristine MXenes are classified. We formulate state-of-the-art advances and challenges in the field while proposing some possible solutions, in particular via employing a multisensor array paradigm. Full article

Sp²-hybridized monolayer semiconductors (e.g., planar group III-V and IV-IV binary compounds) with inversion symmetry breaking (ISB) display piezoelectricity governed by their σ- and π-bond electrons. Here, we studied their bond-orbital-resolved electronic piezoelectricity (i.e., the σ- and π-piezoelectricity). We formulated a tight-binding piezoelectric model to reveal the different variations of σ- and π-piezoelectricity with the ISB strength ($\Delta$). As $\Delta$ varied from positive to negative, the former decreased continuously, but the latter increased piecewise and jumped at $\Delta =0$ due to the criticality of the π-electrons’ ground-state geometry near this quantum phase-transition point. This led to a piezoelectricity predominated by the π-electrons for a small $|\Delta |$. By constructing an analytical model, we clarified the microscopic mechanisms underlying the anomalous π-piezoelectricity and its subtle relations with the valley Hall effect. The validation of our models was justified by applying them to the typical sp² monolayers including hexagonal silicon carbide, Boron-X (X = N, P, As, Ab), and a BN-doped graphene superlattice. Full article

Using acoustic wave modes propagation in piezoelectric plates loaded with conductive liquids, peculiarities of the mode-liquid acoustoelectric interaction are studied. It is found that (i) in contrast to bulk and surface acoustic waves propagating in piezoelectric semiconductors, the acoustoelectric attenuation of the modes is not symmetric in respect to its maximum, (ii) a large increase in attenuation may be accompanied by a small decrease in phase velocity and vice versa, (iii) the peculiarities are valid for “pure” (without beam steering) and “not pure” (with beam steering) modes, as well as for modes of different orders and polarizations, and (iv) conductivity of test liquid increases electromagnetic leakage between input and output transducers, affecting results of the measurements. To decrease the leakage, the liquid should be localized between transducers, outside the zone over them. If so, the mode sensitivity may be as large as 8.6 dB/(S/m) for amplitude and 107°/(S/m) for phase. However, because of comparable cross-sensitivity towards viscosity and dielectric permittivity, modes with selective detection of liquid conductivity are not found. Full article

Due to its unique physical, chemical, and mechanical properties, such as a low specific density, large specific surface area, excellent thermal stability, oxidation resistance, low friction, good dispersion stability, enhanced adsorbing capacity, large interlayer shear force, and wide bandgap, hexagonal boron nitride (h-BN) nanostructures are of great interest in many fields. These include, but are not limited to, (i) heterogeneous catalysts, (ii) promising nanocarriers for targeted drug delivery to tumor cells and nanoparticles containing therapeutic agents to fight bacterial and fungal infections, (iii) reinforcing phases in metal, ceramics, and polymer matrix composites, (iv) additives to liquid lubricants, (v) substrates for surface enhanced Raman spectroscopy, (vi) agents for boron neutron capture therapy, (vii) water purifiers, (viii) gas and biological sensors, and (ix) quantum dots, single photon emitters, and heterostructures for electronic, plasmonic, optical, optoelectronic, semiconductor, and magnetic devices. All of these areas are developing rapidly. Thus, the goal of this review is to analyze the critical mass of knowledge and the current state-of-the-art in the field of BN-based nanomaterial fabrication and application based on their amazing properties. Full article

Ni thin films with different thicknesses were grown on a GaAs substrate using the magnetron sputtering technique followed by in situ X-ray diffraction (XRD) annealing in order to study the solid-state reaction between Ni and GaAs substrate. The thickness dependence on the formation of the intermetallic phases was investigated using in situ and ex situ XRD, pole figures, and atom probe tomography (APT). The results indicate that the 20 nm-thick Ni film exhibits an epitaxial relation with the GaAs substrate, which is (001) Ni//(001) GaAs and [111] Ni//[110] GaAs after deposition. Increasing the film’s thickness results in a change of the Ni film’s texture. This difference has an impact on the formation temperature of Ni₃GaAs. This temperature decreases simultaneously with the thickness increase. This is due to the coherent/incoherent nature of the initial Ni/GaAs interface. The Ni₃GaAs phase decomposes into the binary and ternary compounds xNiAs and Ni_3−xGaAs_1−x at about 400 °C. Similarly to Ni₃GaAs, the decomposition temperature of the second phase also depends on the initial thickness of the Ni layer. Full article

Tracking fluctuations in the Cu²⁺ level in sweat is meaningful for non-invasive and real-time assessment of Cu²⁺-abnormality-related diseases and provides important diagnostic information. However, the user-unfriendly ways to obtain sweat and sweat biofouling have limited the development of this field. Herein, we exploit a highly sensitive photoelectrochemical (PEC) sensor as a detection method, a powerful laser engraving technique for the large-scale fabrication of laser-induced graphene and In-doped CdS (LIG-In-CdS) photoelectrodes, and a hydrophilic porous polyvinyl alcohol (PVA) hydrogel for natural sweat collection for fingertip touch sweat Cu²⁺ monitoring. The proposed sensor has several very attractive features: (i) the LIG-In-CdS photoelectrode with high photoelectric conversion efficiency can be produced by a cheap 450 nm semiconductor laser system; (ii) the sensor performs Cu²⁺ detection with a wide linear range of 1.28 ng/mL~5.12 μg/mL and good selectivity; (iii) the PVA hydrogel possesses an excellent antifouling effect ability and a rapid natural sweat collection ability; and (iv) the sensor exhibits feasibility and good reliability for PEC sensing of sweat Cu²⁺. Thus, these advantages endow the proposed method with a great deal of potential for smart monitoring of heavy metals in sweat in the future. Full article

Splitting of water with the help of photocatalysts has gained a strong interest in the scientific community for producing clean energy, thus requiring novel semiconductor materials to achieve high-yield hydrogen production. The emergence of 2D nanoscale materials with remarkable electronic and optical properties has received much attention in this field. Owing to the recent developments in high-end computation and advanced electronic structure theories, first principles studies offer powerful tools to screen photocatalytic systems reliably and efficiently. This review is organized to highlight the essential properties of 2D photocatalysts and the recent advances in the theoretical engineering of 2D materials for the improvement in photocatalytic overall water-splitting. The advancement in the strategies including (i) single-atom catalysts, (ii) defect engineering, (iii) strain engineering, (iv) Janus structures, (v) type-II heterostructures (vi) Z-scheme heterostructures (vii) multilayer configurations (viii) edge-modification in nanoribbons and (ix) the effect of pH in overall water-splitting are summarized to improve the existing problems for a photocatalytic catalytic reaction such as overcoming large overpotential to trigger the water-splitting reactions without using cocatalysts. This review could serve as a bridge between theoretical and experimental research on next-generation 2D photocatalysts. Full article

This paper introduces a novel topology of the proposed converter that has these merits: (i) the topology of the converter is based on conventional boost and buck-boost converters, which has caused its simplicity; (ii) the voltage gain of the converter has provided higher values by the lower value of the duty cycle; (iii) due to the use of high-efficiency conventional topologies in its structure, the efficiency of the converter keeps its high value for a great interval of duty cycle; (iv) besides the increase of the voltage gain, the current/voltage stresses of the semiconductors have been kept low; (v) the continuous input current of this converter reduces the current stress of the capacitor in the input filter. It is worth noting that the proposed converter has been discussed in both ideal and non-ideal modes. Moreover, the operation of the converter has been discussed in both continuous/discontinuous current modes. The advantages of the converter have been compared with recently suggested converters. In addition, the different features of the converter have been discussed for different conditions. In the small-signal analysis, the appropriate compensator has been designed. Finally, the simulation and experimental results have been reported for 90 W output power, 90 V output voltage, 3-times voltage gain, and 100 kHz switching frequency. Full article

Heterogeneous photocatalysis has emerged as a promising alternative for both micropollutant removal and bacterial inactivation under solar irradiation. Among a variety of photocatalysts explored in the literature, graphite carbon nitride (g-C₃N₄) is a metal-free semiconductor with acceptable chemical stability, low toxicity, and excellent cost-effectiveness. To minimize its high charge recombination rate and increase the photocatalyst adsorption capacity whilst keeping the metal-free photocatalyst system idea, we proposed the heterojunction formation of g-C₃N₄ with diamond nanocrystals (DNCs), also known as nanodiamonds. Samples containing different amounts of DNCs were assessed as photocatalysts for pollutant removal from water and as light-activated antibacterial agents against Staphylococcus sureus. The sample containing 28.3 wt.% of DNCs presented the best photocatalytic efficiency against methylene blue, removing 71% of the initial dye concentration after 120 min, with a pseudo-first-order kinetic and a constant rate of 0.0104 min⁻¹, which is nearly twice the value of pure g-C₃N₄ (0.0059 min⁻¹). The best metal-free photocatalyst was able to promote an enhanced reduction in bacterial growth under illumination, demonstrating its capability of photocatalytic inactivation of Staphylococcus aureus. The enhanced photocatalytic activity was discussed and attributed to (i) the increased adsorption capacity promoted by the presence of DNCs; (ii) the reduced charge recombination rate due to a type-II heterojunction formation; (iii) the enhanced light absorption effectiveness; and (iv) the better charge transfer resistance. These results show that g-C₃N₄/DNC are low-cost and metal-free photoactive catalysts for wastewater treatment and inactivation of bacteria. Full article

Diamond cubic silicon is widely used for electronic applications, integrated circuits, and photovoltaics, due to its high abundance, nontoxicity, and outstanding physicochemical properties. However, it is a semiconductor with an indirect band gap, depriving its further development. Fortunately, other polymorphs of silicon have been discovered successfully, and new functional allotropes are continuing to emerge, some of which are even stable in ambient conditions and could form the basis for the next revolution in electronics, stored energy, and optoelectronics. Such structures can lead to some excellent features, including a wide range of direct or quasi-direct band gaps allowed efficient for photoelectric conversion (examples include Si-III and Si-IV), as well as a smaller volume expansion as lithium-battery anode material (such as Si₂₄, Si₄₆, and Si₁₃₆). This review aims to give a detailed overview of these exciting new properties and routes for the synthesis of novel Si allotropes. Lastly, the key problems and the developmental trends are put forward at the end of this article. Full article