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19 pages, 3874 KiB  
Article
The Formation Age and Geological Setting of the Huoqiu Group in the Southern Margin of North China Craton: Implication for BIF-Type Iron Prospecting Potentiality
by Lizhi Xue, Rongzhen Tang, Xinkai Chen, Jiashuo Cao and Yanjing Chen
Minerals 2025, 15(7), 695; https://doi.org/10.3390/min15070695 - 29 Jun 2025
Viewed by 305
Abstract
The Huoqiu Group is located in the southern margin of the North China Craton and is considered an Archean geologic body. Its supracrustal rocks are divided into the Huayuan, Wuji, and Zhouji formations in ascending order. The Wuji and Zhouji formations contain large [...] Read more.
The Huoqiu Group is located in the southern margin of the North China Craton and is considered an Archean geologic body. Its supracrustal rocks are divided into the Huayuan, Wuji, and Zhouji formations in ascending order. The Wuji and Zhouji formations contain large BIF-type iron deposits. The BIFs show geological and geochemical features of Paleoproterozoic Lake Superior-type rather than Archean Algoma-type. The study of the formation ages and evolutionary history of the Huoqiu Terrane will provide significant guidance for the mineralization and exploration of the Huoqiu iron deposits. In this paper, we collected all available isotopic ages and Hf isotopic compositions obtained from the Huoqiu Terrane and reassessed their accuracy and geological meanings. We conclude that the Wuji and Zhouji formations were not older than 2343 Ma. Therefore, the BIFs hosted in the Wuji and Zhouji formations must be of Paleoproterozoic age. The magmatic zircons from the TTG gneisses and granite yield U-Pb ages of Neoarchean Era, indicating that the Wuji and Zhouji formations of the Huoqiu Group were deposited on an Archean granitic basement that mainly comprises the trondhjemite-tonalite-granodiorite (TTG) gneisses and granites of the “Huayuan Formation”. The Early Precambrian crystalline basement in the Huoqiu area can be divided into the Huayuan Gneiss Complex and the Huoqiu Group, comprising the Wuji and Zhouji formations. The tectonic scenario of granitic complexes overlain by supracrustal rocks in the Huoqiu Terrane has been recognized in the Songshan, Zhongtiao, Xiaoshan, and Lushan Early Precambrian terranes in the southern margin of the North China Craton. As indicated by the zircon U-Pb ages and εHf(t) data, the crustal growth of the Huoqiu Terrane occurred mainly at ~2.9 Ga and ~2.7 Ga. Based on the sedimentary age, environment, and rhythm, the BIFs in the Huoqiu region are considered to be of Lake Superior type and of great potential for Fe ore exploration. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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25 pages, 5462 KiB  
Article
Late Carboniferous Slab Rollback in the Southern Altaids: Evidence from a Slab-Derived Adakitic Granodiorite in the South Tianshan
by Nijiati Abuduxun, Wenjiao Xiao, Wanghu Zhang, He Yang, Abidan Alimujiang, Peng Huang and Jingmin Gan
Minerals 2025, 15(7), 674; https://doi.org/10.3390/min15070674 - 24 Jun 2025
Viewed by 354
Abstract
The South Tianshan records the latest accretionary and collisional events in the southwestern Altaids, but the internal subduction-related processes are controversial. This study provides an integrative analysis of a newly identified Late Carboniferous adakitic granodiorite from the South Tianshan, incorporating geochronological, zircon U-Pb [...] Read more.
The South Tianshan records the latest accretionary and collisional events in the southwestern Altaids, but the internal subduction-related processes are controversial. This study provides an integrative analysis of a newly identified Late Carboniferous adakitic granodiorite from the South Tianshan, incorporating geochronological, zircon U-Pb and Lu-Hf isotopic, whole-rock geochemical, and Sr-Nd isotopic data. Zircon U-Pb analysis indicates that the granite was emplaced at 310 ± 2.5 Ma. Based on major element compositions, the granodiorite belongs to medium-K calc-alkaline weakly peraluminous series (A/CNK = 0.95–1.09). The samples exhibit typical high-silica adakitic affinity, as evidenced by the elevated contents of SiO2 (67.75–69.27 wt.%), Al2O3 (15.29–15.90 wt.%), Sr (479–530 ppm), and Ba (860–910 ppm); low concentrations of Yb (0.43–0.47 ppm) and Y (7.12–7.44 ppm); high Sr/Y ratios (67–72); and slight Eu anomalies (δEu = 0.89–1.03). The sodium-rich composition (K2O/Na2O = 0.48–0.71) is comparable to adakitic rocks from slab-derived melts. Elevated concentrations of Ni (22.12–24.25 ppm), Cr (33.20–37.86 ppm), Co (6.32–6.75 ppm), and V (30.33–32.48 ppm), along with high Mg# values (55–57), suggest melt–mantle interaction during magma ascent. The slightly enriched isotopic signatures, characterized by higher initial 87Sr/86Sr ratios (0.706086–0.706205) and lower εNd(t) (−3.09 to –2.47) and εHf(t) (−3.11 to +7.66) values, point to notable sedimentary contributions, potentially through source contamination and/or shallow-level crustal contamination. By integrating the new results with previously published data, we consider that the adakitic granodiorite was generated by partial melting of the subducted oceanic crust, triggered by asthenospheric upwelling associated with the southward rollback of the north-dipping South Tianshan oceanic lithosphere. Our data provide new insights into Late Carboniferous retreating subduction along the southern active margin of the Yili-Central Tianshan and the accretionary architecture of the southern Altaids. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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34 pages, 12770 KiB  
Article
Immiscibility in Magma Conduits: Evidence from Granitic Enclaves
by Ya Tian, Guanglai Li, Yongle Yang, Chao Huang, Yinqiu Hu, Kai Xu and Ji Zhang
Minerals 2025, 15(7), 664; https://doi.org/10.3390/min15070664 - 20 Jun 2025
Viewed by 303
Abstract
Many granitic enclaves are developed in the volcanic channel of the Xiangshan volcanic basin. To explore their genesis, this study examined the petrography, geochemistry, LA-ICP-MS zircon U–Pb chronology, and zircon Hf isotopes of the granitic enclaves and compared them with the porphyroclastic lavas. [...] Read more.
Many granitic enclaves are developed in the volcanic channel of the Xiangshan volcanic basin. To explore their genesis, this study examined the petrography, geochemistry, LA-ICP-MS zircon U–Pb chronology, and zircon Hf isotopes of the granitic enclaves and compared them with the porphyroclastic lavas. In general, the granitic enclaves and porphyroclastic lavas have similar structures, and the rock-forming minerals and accessory minerals have relatively close compositions. In terms of rock geochemical characteristics, the granitic enclaves are richer in silicon and alkalis but have lower abundances of aluminum, magnesium, iron, and calcium than the porphyroclastic lavas. Rb, Th, K, Sm, and other elements are more enriched, whereas Ba, Ti, Nb, P, and other elements are more depleted. The granitic enclaves have lower rare earth contents (195.53 × 10−6–271.06 × 10−6) than the porphyroclastic lavas (246.67 × 10−6–314.27 × 10−6). The rare earth element distribution curves of the two are generally consistent, both right-leaning, and enriched with light rare earth patterns. The weighted average zircon U–Pb ages of two granitic enclave samples were 135.45 ± 0.54 Ma (MSWD = 0.62, n = 17) and 135.81 ± 0.60 Ma (MSWD = 0.40, n = 20), respectively, which are consistent with the weighted average age of a single porphyroclastic lava sample of 134.01 ± 0.53 Ma (MSWD = 2.0, n = 20). The zircons of the two kinds of rocks crystallize at almost the same temperature. The consistent trend of the rare earth element distribution curve of zircons in the granitic enclaves and the porphyroclastic lava samples indicates that the zircons of the two samples were formed in the same stage. The formation process of granitic enclaves may be that the lower crustal melt is induced to rise, and the crystallization differentiation occurs in the magma reservoir and is stored in the form of crystal mush, forming a shallow crystal mush reservoir. The crystal mush reservoir is composed of a large number of rock-forming minerals such as quartz, feldspar, and biotite, as well as accessory mineral crystals such as zircon and flowable intergranular melt. In the later stage of magma high evolution, a small and short-time magmatic activity caused a large amount of crystalline granitic crystal mush to pour into the volcanic pipeline. In the closed system of volcanic pipeline, the pressure and temperature decreased rapidly, and the supercooling degree increased, and the immiscibility finally formed pale granitic enclaves. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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25 pages, 9142 KiB  
Article
Petrogenesis and Tectonic Significance of Middle Jurassic Mafic–Ultramafic Cumulate Rocks in Weiyuanpu, Northern Liaoning, China: Insights from Zircon Geochronology and Isotope Geochemistry
by Yifan Zhang, Xu Ma, Jiafu Chen, Yuqi Liu, Yi Zhang and Yongwei Ma
Minerals 2025, 15(6), 651; https://doi.org/10.3390/min15060651 - 17 Jun 2025
Viewed by 413
Abstract
The tectonic evolution of the Paleo-Pacific Ocean and the destruction mechanism of the North China Craton (NCC) are still controversial. In this study, we conducted zircon U-Pb dating, whole-rock geochemistry, and Sr-Nd-Hf isotope analyses on the Weiyuanpu mafic–ultramafic intrusions in the eastern segment [...] Read more.
The tectonic evolution of the Paleo-Pacific Ocean and the destruction mechanism of the North China Craton (NCC) are still controversial. In this study, we conducted zircon U-Pb dating, whole-rock geochemistry, and Sr-Nd-Hf isotope analyses on the Weiyuanpu mafic–ultramafic intrusions in the eastern segment of the northern margin of the NCC to discuss their petrogenesis and tectonic implications. The Weiyuanpu mafic–ultramafic intrusions consist of troctolite, hornblendite, hornblende gabbro, gabbro, and minor diorite, anorthosite, characterized by cumulate structure. The main crystallization sequence of minerals is olivine → pyroxene → magnetite → hornblende. The zircon U-Pb ages of hornblendite, hornblende grabbro, and diorite are ~170Ma. Geochemical characteristics exhibit low-K tholeiitic to calc-alkaline series, enriched in light rare-earth elements (LREE) and significant large-ion lithophile elements (LILE), and depleted in high-field-strength elements (HFSE). Sr-Nd isotopic compositions are ISr = 0.7043–0.7055, εNd(t) = −0.7 to +0.9, and zircon εHf (t) values range from +3.4 to +8.7. These results suggest that the source region was a phlogopite-bearing garnet lherzolite mantle metasomatized by subduction fluids. The study reveals that the northeastern margin of the NCC was in a back-arc extensional setting due to the subduction of the Paleo-Pacific Ocean during the Middle Jurassic, which caused lithosphere thinning and mantle melting in this region. Full article
(This article belongs to the Special Issue Selected Papers from the 7th National Youth Geological Congress)
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18 pages, 6412 KiB  
Article
Geochemistry and Zircon U-Pb Chronology of West Kendewula Late Paleozoic A-Type Granites in the East Kunlun Orogenic Belt: Implications for Post-Collision Extension
by Bang-Shi Dong, Wen-Qin Wang, Gen-Hou Wang, Pei-Lie Zhang, Peng-Sheng Li, Zhao-Lei Ding, Ze-Jun He, Pu Zhao, Jing-Qi Zhang and Chao Bo
Appl. Sci. 2025, 15(12), 6661; https://doi.org/10.3390/app15126661 - 13 Jun 2025
Viewed by 488
Abstract
The Late Paleozoic granitoids widely distributed in the central section of the East Kunlun Orogenic Belt (EKOB) are responsible for the constraints on its post-collisional extensional processes. We report the whole-rock geochemical compositions, zircon U-Pb ages, and zircon Hf isotope data of granites [...] Read more.
The Late Paleozoic granitoids widely distributed in the central section of the East Kunlun Orogenic Belt (EKOB) are responsible for the constraints on its post-collisional extensional processes. We report the whole-rock geochemical compositions, zircon U-Pb ages, and zircon Hf isotope data of granites in the western Kendewula area. The granites, dated between 413.7 Ma and 417.7 Ma, indicate emplacement during the Early Devonian period. The granite is characterized by high silicon content (72.45–78.96 wt%), high and alkali content (7.59–9.35 wt%), high 10,000 × Ga/Al values, and low Al2O3 (11.29–13.32 wt%), CaO (0.07–0.31 wt%), and MgO contents (0.16–0.94 wt%). The rocks exhibit enrichment in large-ion lithophile element (LILE) content and high-field-strength element (HFSE) content, in addition to strong losses, showing significant depletion in Ba, Sr, P and Eu. These geochemical characteristics correspond to A2-type granites. The values of Rb/N and Ba/La and the higher zircon saturation temperature (800~900 °C) indicate that the magma source is mainly crustal, with the participation of mantle materials, although limited. In addition, the zircon εHf(t) values (−4.3–3.69) also support this view. In summary, the A2-type granite exposed in the western Kendewula region formed against a post-collisional extensional setting background, suggesting that the Southern Kunlun Terrane (SKT) entered a post-orogenic extensional phase in the evolution stage since the Early Devonian. The upwelling of the asthenospheric mantle of the crust, triggered by crustal detachment and partial melting, likely contributed to the flare-up of A2-type granite during this period. By studying the nature of granite produced during orogeny, the evolution process of the formation of orogenic belts is discussed, and our understanding of orogenic is enhanced. Full article
(This article belongs to the Special Issue Technologies and Methods for Exploitation of Geological Resources)
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19 pages, 3459 KiB  
Article
Triassic Retrograde Metamorphism and Anatexis in the Sulu Orogenic Zone, Central China: Constraints from U–Pb Ages, Trace Elements, and Hf Isotopic Compositions of Zircon
by Yongkang Ye, Hengcong Lei, Fei Xia, Hui Zhang and Congjun Yu
Appl. Sci. 2025, 15(11), 6145; https://doi.org/10.3390/app15116145 - 29 May 2025
Viewed by 347
Abstract
We report information on the protolith, the Triassic retrograde metamorphism, and anatexis recorded in zircons extracted from granitic gneiss and biotite schist in the Sulu orogenic zone, central China. The schist is enclosed within the granitic gneiss in the form of a lens. [...] Read more.
We report information on the protolith, the Triassic retrograde metamorphism, and anatexis recorded in zircons extracted from granitic gneiss and biotite schist in the Sulu orogenic zone, central China. The schist is enclosed within the granitic gneiss in the form of a lens. Zircon grains from the schist sample indicate anatexis occurred at 214.6 ± 3.6 Ma (MSWD = 5.1), with εHf (t) values ranging from −22.6 to −18.3, corresponding to TDMC(Hf) ages between 2675 Ma and 2407 Ma. The granitic gneiss originated from magmatic rock formed at 774 ± 32 Ma (MSWD = 5.7) and subsequently underwent metamorphism at ~211 Ma. Three zircon cores from the granitic gneiss exhibit εHf (t) values ranging from −13.6 to −6.3, with TDM C(Hf) ages spanning 2487–2075 Ma. Six zircon rims from the gneiss yield εHf (t) values of −14.7 to −13.3, and TDM C(Hf) ages ranging from 2176 to 2092 Ma. We believe that the protolith of granitic gneiss is the Neoproterozoic magmatic rock, whose tectonic affinity is the northern margin of the Yangtze craton. The granitic gneiss experienced Triassic collisional orogeny-related metamorphism and subsequent retrograde metamorphism, with the timing of retrograde overprinting consistent with zircon-recorded anatexis in the schist. In addition, the protoliths of both the gneiss and schist exhibit close affinity to Archean-Paleoproterozoic crustal sources. Full article
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12 pages, 1341 KiB  
Article
Zircon Systematics of the Shionomisaki Volcano–Plutonic Complex (Kii Peninsula, Japan): A Potential Tool for the Study of the Source Region of Silicic Magmas
by Ulrich Knittel, Monika Walia and Shigeyuki Suzuki
Minerals 2025, 15(5), 537; https://doi.org/10.3390/min15050537 - 18 May 2025
Viewed by 353
Abstract
The Shionomisaki Igneous Complex is part of the Mid Miocene igneous province developed within the Shimanto Accretionary Complex in front of the volcanic front in SW Japan. The igneous rocks in this province mostly have silicic compositions. New U-Pb ages obtained for two [...] Read more.
The Shionomisaki Igneous Complex is part of the Mid Miocene igneous province developed within the Shimanto Accretionary Complex in front of the volcanic front in SW Japan. The igneous rocks in this province mostly have silicic compositions. New U-Pb ages obtained for two samples from the Shionomisaki Complex at the southern tip of the Kii Peninsula (14.6 ± 0.4 Ma and 14.9 ± 0.4 Ma) fall into the range of previous age determinations (14.6 ± 0.2 to 15.4 ± 0.3 Ma). Hf isotopic compositions obtained for co-magmatic zircon (εHf(t) = −0.7 to +4.8) lie between typical values obtained for mantle-derived magmas and values obtained for old crustal rocks. They are thus consistent with previous interpretations that the magmas are mixtures of mantle and crustally derived magmas. In the modelling of the isotopic characteristics of the magmas, the sediments of the Shimanto belt are taken as the protolith of the silicic magmas. Xenocrystal zircon (i.e., zircon picked up during ascent and emplacement of the magma) found in the silicic igneous rocks exhibits a similar age pattern as detrital zircon of the Shimanto sediments. However, the age pattern obtained in this study for zircon cores, which are considered to be restitic zircon (i.e., zircon derived from the source of the anatectic melt), shows little semblance with the age pattern of Shimanto sediments. It is, therefore, tentatively suggested that the source area of the silicic magmas may not be identical with the sediments of the Shimanto Accretionary Complex. Full article
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21 pages, 8878 KiB  
Article
Significance of Adakitic Plutons for Mineralization in Wubaduolai Copper Deposit, Xizang: Evidence from Zircon U-Pb Age, Hf Isotope, and Geochemistry
by Ke Gao, Zhi Zhang, Linkui Zhang, Peiyan Xu, Yi Yang, Jianyang Wu, Yingxu Li, Miao Sun and Wenpeng Su
Minerals 2025, 15(5), 500; https://doi.org/10.3390/min15050500 - 8 May 2025
Viewed by 454
Abstract
The Wubaduolai copper deposit, a newly discovered porphyry-type deposit located in the western section of the Gangdese metallogenic belt, shows great potential for mineralization. Investigating the ore-bearing potentiality of the adakitic granite in this area is crucial for identifying concealed ore bodies and [...] Read more.
The Wubaduolai copper deposit, a newly discovered porphyry-type deposit located in the western section of the Gangdese metallogenic belt, shows great potential for mineralization. Investigating the ore-bearing potentiality of the adakitic granite in this area is crucial for identifying concealed ore bodies and assessing the metallogenic potential. This paper presents the zircon U-Pb dating, Hf isotope analysis, and whole-rock major and trace geochemical analysis of the plutons in the Wubaduolai mining area. The results indicate that the zircon U-Pb concordia age of the monzogranite is 15.7 ± 0.1 Ma, while the granodiorite porphyry has a concordia age of 15.9 ± 0.2 Ma, both corresponding to a Miocene diagenesis. The geochemical data show that both plutons belong to the high-K calc-alkaline series, characterized by a relative enrichment of large-ion lithophile elements (K, Rb, Ba, and Sr) and a depletion of high-field-strength elements (Nb, Ta, and Ti). Both plutons are characterized by low Y, low Yb, and high Sr/Y values, displaying the typical geochemical characteristics of adakites. Their mineral composition is similar to that of adakite. The εHf(t) values of the monzogranite and granodiorite porphyry range from −5.34 to −2.3 and −5.2 to −3.43, respectively, with two-stage model ages (TDM2) of 1246–1441 Ma and 1318–1432 Ma. Based on the regional data and this study, the plutons in the Wubaduolai mining area formed in a post-collision setting following the India–Asia continental collision. The magma source is identified as the partial melting of a thickened, newly formed lower crust. The above characteristics are consistent with the diagenetic and metallogenic ages, magma source, and dynamic backgrounds of the typical regional deposits. Full article
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23 pages, 15341 KiB  
Article
Petrogenesis of Middle Jurassic Syenite-Granite Suites and Early Cretaceous Granites with Associated Enclaves in Southwestern Zhejiang, SE China: Implications for Subduction-Related Tectonic Evolution Beneath Northeastern Cathaysia Block
by Yu Wang, Haoyuan Lan, Chong Jin and Yuhuang Zhang
Minerals 2025, 15(5), 474; https://doi.org/10.3390/min15050474 - 30 Apr 2025
Viewed by 453
Abstract
Late Mesozoic magmatism in Southeast China extensively reworked the Cathaysia Block’s crust, linked to the Paleo-Pacific Plate subduction beneath East Asia. The northeastern Cathaysia Block, largely covered by Cretaceous volcanic-sedimentary basins, has limited Jurassic exposure to Early Cretaceous intrusions, which provides critical insights [...] Read more.
Late Mesozoic magmatism in Southeast China extensively reworked the Cathaysia Block’s crust, linked to the Paleo-Pacific Plate subduction beneath East Asia. The northeastern Cathaysia Block, largely covered by Cretaceous volcanic-sedimentary basins, has limited Jurassic exposure to Early Cretaceous intrusions, which provides critical insights into deep crust-mantle processes. In this study, we present zircon U-Pb geochronology and Hf isotope, whole-rock geochemistry, and Sr-Nd isotopes of the Middle Jurassic syenite-granite suites and Early Cretaceous granites with enclaves in the Qingyuan area (SW Zhejiang Province) to constrain their petrogenesis and tectonic significance. Middle Jurassic syenites and alkali-feldspar granites (169–167 Ma) exhibit calc-alkaline to shoshonitic affinities and weakly peraluminous compositions. Early Cretaceous granites (134 Ma) and their enclaves (136 Ma) are high-K calc-alkaline and weakly peraluminous to metaluminous. All samples show LILE and LREE enrichment, HFSE depletion, and negative Eu and Sr anomalies, with only syenites displaying negative Ce anomalies. We suggest that the Middle Jurassic syenites originated from the partial melting of an enriched lithospheric mantle influenced by subduction-related metasomatism. Alkali-feldspar granites derived from partial melting of the basement of the Cathaysia Block. Early Cretaceous granites formed by partial melting of lower crustal mafic rocks, with enclaves representing earlier crystallization products, which were then mechanically mixed with granites. We propose the NE Cathaysia Block underwent significant reworking from the Middle Jurassic to the Early Cretaceous. Middle Jurassic syenites formed in a compressional setting linked to Paleo-Pacific Plate subduction, while Early Cretaceous magmatism reflects lithospheric extension and crust-mantle interaction triggered by slab rollback. Full article
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30 pages, 15713 KiB  
Article
Magma Mixing Origin for the Menyuan Granodioritic Pluton in the North Qilian Orogenic Belt, China
by Shugang Xia, Yu Qi, Shengyao Yu, Xiaocong Jiang, Xiangyu Gao, Yue Wang, Chuanzhi Li, Qian Wang, Lintao Wang and Yinbiao Peng
Minerals 2025, 15(4), 391; https://doi.org/10.3390/min15040391 - 8 Apr 2025
Viewed by 621
Abstract
Magma mixing or mingling is not just a geological phenomenon that widely occurs in granitoid magmatism, but a complex dynamic process that influences the formation of mafic microgranular enclaves (MMEs) and the diversity of granitic rocks. Herein, we carried out a comprehensive study [...] Read more.
Magma mixing or mingling is not just a geological phenomenon that widely occurs in granitoid magmatism, but a complex dynamic process that influences the formation of mafic microgranular enclaves (MMEs) and the diversity of granitic rocks. Herein, we carried out a comprehensive study that encompassed the petrology, mineral chemistry, zircon U-Pb ages, Lu-Hf isotopes, whole-rock elements, and Sr-Nd isotope compositions of the Menyuan Granodioritic Pluton in the northern margin of the Qilian Block, to elucidate the petrogenesis and physical and chemical processes occurring during magma mixing. The Menyuan Granodioritic Pluton is mainly composed of granodiorites accompanied by numerous mafic microgranular enclaves (MMEs) and is intruded by minor gabbro dikes. LA-ICP-MS zircon U-Pb dating reveals that these rocks possess a similar crystallization age of ca. 456 Ma. The Menyuan host granodiorites, characterized as metaluminous to weakly peraluminous, belong to subduction-related I-type calc-alkaline granites. The MMEs and gabbroic dikes have relatively low SiO2 contents and high Mg# values, probably reflecting a mantle-derived origin. They are enriched in large ion lithophile elements (LILEs) and light, rare earth elements (LREEs) but are depleted in high field strength elements (HFSEs), indicating continental arc-like geochemical affinities. The host granodiorites yield relatively enriched whole-rock Sr-Nd and zircon Hf isotopic compositions (87Sr/86Sri = 0.7072–0.7158; εNd(t) = −9.21 to −4.23; εHf(t) = −8.8 to −1.2), implying a derivation from the anatexis of the ancient mafic lower continental crust beneath the Qilian Block. The MMEs have similar initial Sr isotopes but distinct whole-rock Nd and zircon Hf isotopic compositions compared with the host granodiorites (87Sr/86Sri = 0.7078–0.7089; εNd(t) = −3.88 to −1.68; εHf(t) = −0.1 to +4.1). Field observation, microtextural and mineral chemical evidence, geochemical characteristics, and whole-rock Nd and zircon Hf isotopic differences between the host granodiorites and MMEs suggest insufficient magma mixing of lithospheric mantle mafic magma and lower continental crust felsic melt. In combination with evidence from regional geology, we propose that the anatexis of the ancient mafic lower continental crust and subsequent magma mixing formed in an active continental arc setting, which was triggered by the subducted slab rollback and mantle upwelling during the southward subduction of the Qilian Proto-Tethys Ocean during the Middle-Late Ordovician. Full article
(This article belongs to the Special Issue Tectonic Evolution of the Tethys Ocean in the Qinghai–Tibet Plateau)
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16 pages, 7909 KiB  
Article
Zircon U-Pb Geochronology and Hf Isotopes of the Granitoids from Cahanwusu Cu Deposit in Awulale Mountain, Western Tianshan: Implication for Regional Mineralization
by Wei Zhang, Mao-Xue Chen, Mei-Li Yang, Wen-Hui Yang and Xing-Chun Zhang
Minerals 2025, 15(4), 380; https://doi.org/10.3390/min15040380 - 4 Apr 2025
Cited by 1 | Viewed by 436
Abstract
Awulale Mountain is one of the most important Fe-Cu concentration areas situated in the eastern part of Western Tianshan. The Cu deposits in the belt are genetically associated with the Permian intermediate and felsic intrusions. However, the precise age and magma source of [...] Read more.
Awulale Mountain is one of the most important Fe-Cu concentration areas situated in the eastern part of Western Tianshan. The Cu deposits in the belt are genetically associated with the Permian intermediate and felsic intrusions. However, the precise age and magma source of the causative intrusions are currently not confirmed, constraining our understanding of regional mineralization. The Cahanwusu porphyry Cu deposit is located in the western part of Awulale Mountain. Field investigations have shown that the mineralization in the deposit is genetically associated with granitic porphyry and diorite porphyry. In this paper, we provide detailed zircon U-Pb ages and in-situ Hf isotopic compositions of the granitic porphyry and diorite porphyry. The granitic porphyry and diorite porphyry have zircon U-Pb ages of 328.6 ± 2.6 Ma (MSWD = 0.52; n = 23) and 331 ± 2.8 Ma (MSWD = 0.95; n = 21), respectively. This indicates that the Cahanwusu deposit was formed in the Carboniferous in a subduction setting. This is distinguishable from other porphyry Cu deposits in the belt, which were generally formed in the Permian in the post-collision extensional setting. The granitic porphyry and diorite porphyry exhibit positive εHf(t) values varying from +2.8 to +5.4 (average of +4.1) and +2.0 to +5.1 (average of +4.1), respectively. The magmas of these causative intrusions were interpreted to be derived from the partial melting of the juvenile lower crust which originated from cooling of mantle-derived magmas related to the subduction process. Our new results highlight that the Cahanwusu deposit represents a new episode of Cu mineralization in the belt and the Carboniferous granitoids in Awulale Mountain are potential candidates for Cu exploration. Full article
(This article belongs to the Special Issue Igneous Rocks and Related Mineral Deposits)
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21 pages, 6656 KiB  
Article
A Geochemical and Sr–Nd–Hf–O Isotopic Study of the Early Silurian Shandan Adakites in the Longshoushan Area: Implications for the Collisional Setting of the Proto–Tethyan North Qilian Orogen, Northwest China
by Zhihan Bai, Yang Yang, Xijun Liu, Pengde Liu, Gang Chen, Xiao Liu, Rongguo Hu, Hao Tian, Yande Liu, Wenmin Huang and Yao Xiao
Minerals 2025, 15(4), 352; https://doi.org/10.3390/min15040352 - 27 Mar 2025
Viewed by 440
Abstract
The North Qilian Orogen experienced a series of late Neoproterozoic to early Paleozoic tectonic events, including the opening and closure of the Proto-Tethyan Qilian Ocean, as well as post-subduction processes. This study investigated the Shandan adakites in the Longshoushan area of the North [...] Read more.
The North Qilian Orogen experienced a series of late Neoproterozoic to early Paleozoic tectonic events, including the opening and closure of the Proto-Tethyan Qilian Ocean, as well as post-subduction processes. This study investigated the Shandan adakites in the Longshoushan area of the North Qilian Orogen, focusing on zircon U–Pb geochronology, whole-rock geochemistry, and Sr–Nd–Hf–O isotopic compositions. The Shandan adakites yield ages of ca. 446–440 Ma, suggesting they crystallized during the collision between the Alxa and Qilian blocks following the closure of the Proto-Tethyan North Qilian Ocean. High Sr/Y (40.9–117) ratios and enrichments in light rare earth elements indicate that the Shandan adakites were formed by partial melting of thickened magnesian lower crust. They have relatively rich εNd (t) (−7.66 to −6.32), εHf(t) (3.30 to −12.4), and δ18O (5.34‰–7.52‰). Zircon Hf–O and whole-rock Sr–Nd isotopes confirm significant contributions from the ancient crust and mantle-derived melts, suggesting complex crust–mantle interactions in their magma sources. We propose that the Shandan adakites formed during the (early) post-collisional stage of orogenesis. Based on regional geological evidence and previous studies, we suggest the Alxa and Central Qilian blocks collided during ca. 446–440 Ma, leading to the thickening of the lower crust. After ca. 440 Ma, the tectonic setting of the Northern Qilian Orogen transitioned from a collisional to a post-collisional stage. Full article
(This article belongs to the Special Issue Tectonic Evolution of the Tethys Ocean in the Qinghai–Tibet Plateau)
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19 pages, 4764 KiB  
Article
Tectonic Evolution of the Hainan Island, South China: Geochronological and Geochemical Constraints from Late Permian to Early Triassic Basalts
by Jieting Ouyang, Guoyu Chen, Liya Yang, Wenqian Lu and Yun Zhou
Minerals 2025, 15(3), 293; https://doi.org/10.3390/min15030293 - 13 Mar 2025
Cited by 1 | Viewed by 631
Abstract
The tectonic evolution of Hainan Island during the Late Permian–Early Triassic period is still unclear. This study identified two types of basalts on the island and presented detailed geochronology, whole-rock geochemistry, and Hf isotope data of the Late Permian–Early Triassic basalts. U-Pb dating [...] Read more.
The tectonic evolution of Hainan Island during the Late Permian–Early Triassic period is still unclear. This study identified two types of basalts on the island and presented detailed geochronology, whole-rock geochemistry, and Hf isotope data of the Late Permian–Early Triassic basalts. U-Pb dating results indicated that baddeleyites and zircons of one sample from Group 1 basalts had formation ages of 256 ± 3 Ma and 255 ± 3 Ma, respectively, and two samples from Group 2 gave formation ages of 241 ± 2 Ma and 240 ± 3 Ma, respectively. Both groups are characterized by negative anomalies of Nb, Ta, and Ti, and enrichment in Ba, Th, U, and K. Group 1 belongs to sub-alkaline basalt and exhibited SiO2 contents ranging from 50.50% to 51.05%, with ΣREE concentration of 136–148 ppm. Hf isotope analysis showed that the εHf(t) values of baddeleyites and zircons were −10.56 to −4.70 and −14.94 to −6.95, respectively. Group 2 belongs to alkaline basalt and had a higher SiO2 content of 52.48%–55.49% and ΣREE concentration of 168–298 ppm. They showed more depleted Hf isotopic composition with εHf(t) values ranging from −2.82 to +4.74. These data indicate that the source area of Group 1 was an enriched mantle, likely derived from partial melting of spinel lherzolite mantle, and was modified by subduction-derived fluids. Group 2 was derived from depleted mantle, most likely originating from partial melting of garnet + spinel lherzolite mantle. They were contaminated by crustal materials and metasomatized by subduction-derived fluids with a certain degree of fractional crystallization. Comprehensive analysis suggests that Group 1 samples likely formed in an island arc tectonic setting, while Group 2 formed in a continental intraplate extensional (or initial rift) tectonic setting. Their formation was mainly controlled by the Paleo-Tethys tectonic domain. Group 1 basalts implied that subduction of the Paleo-Tethys oceanic crust lasted at least in the late Permian (ca. 255 Ma). Group 2 basalts revealed that the intra-plate extensional (or initial rift) stage occurred in the middle Triassic (ca. 240 Ma). Full article
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22 pages, 28128 KiB  
Article
Mafic Intrusions in the Cuona Area, Eastern Tethyan Himalaya: Early Kerguelen Mantle Plume Activity and East Gondwana Rifting
by Chunxi Shan, Zhiqiang Kang, Feng Yang, Chengyou Ma, Zedong Qiao, Zonghao Liu, Jizhong Mu, Lingling Wu and Lu Zhou
Minerals 2025, 15(3), 281; https://doi.org/10.3390/min15030281 - 10 Mar 2025
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Abstract
The widespread occurrence of Mesozoic ocean island basalt (OIB)-like igneous rocks in the Southern Tibetan Himalayan Belt provides important constraints on the rifting of East Gondwana. This study undertook a petrological, geochronological, and geochemical investigation of mafic intrusive rocks in the Cuona area [...] Read more.
The widespread occurrence of Mesozoic ocean island basalt (OIB)-like igneous rocks in the Southern Tibetan Himalayan Belt provides important constraints on the rifting of East Gondwana. This study undertook a petrological, geochronological, and geochemical investigation of mafic intrusive rocks in the Cuona area of the eastern Tethyan Himalayan Belt. The mafic intrusions have OIB-type geochemical signatures, including diabase porphyrite, gabbro, and diabase. Zircon U–Pb dating indicates that the diabase porphyrite formed at 135.0 ± 1.6 Ma. The diabase porphyrite and gabbro are enriched in high-field-strength elements (Nb and Ti) and large-ion lithophile elements (Sr and Pb) and experienced negligible lithospheric mantle or crustal contamination. The diabase is enriched in large-ion lithophile elements (LILEs, e.g., La and Ce) and depleted in high-field-strength elements (HFSEs, e.g., Ru, Zr and Ti). In general, the mafic intrusions exhibit significant light REE enrichment and heavy REE depletion and have no Eu anomalies. Whole-rock neodymium (εNd(t) = 1.55) and zircon Hf (εHf(t) = 0.60–3.73) isotopic compositions indicate derivation of the magma from enriched type I mantle. We propose that the diabase porphyrite and diabase formed in a continental margin rift setting, influenced by the Kerguelen mantle plume, and represent magmatism related to the breakup of East Gondwana. However, the gabbro formed in a relatively stable continental intraplate environment, likely derived from deep magmatic processes associated with the Kerguelen mantle plume. Our results provide new constraints on the early activity of the Kerguelen mantle plume and offer insights into the breakup and tectonic evolution of East Gondwana. Full article
(This article belongs to the Special Issue Tectonic Evolution of the Tethys Ocean in the Qinghai–Tibet Plateau)
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17 pages, 15255 KiB  
Article
The Genesis of Cs-Rich Geyserite in the Chabu Geothermal Field in Southern Tibet
by Ruo-Ming Li, Yu-Bin Li, Chang-Jin Yang, Jin-Shu Zhang, Cong Shen, Lin Yuan, Can Yang, Guo-Miao Xu, Duo Liu, Lin-Chao Yang, Ze-Lin Zhang and Zhe-Wei Sun
Minerals 2025, 15(1), 36; https://doi.org/10.3390/min15010036 - 30 Dec 2024
Cited by 1 | Viewed by 844
Abstract
Recent studies have shown that the geothermal systems in Tibet are rich in rare metal elements such as lithium (Li), boron (B), rubidium (Rb), and cesium (Cs). However, the understanding of the origin of Cs-rich geyserite formed by hot springs remains unclear. In [...] Read more.
Recent studies have shown that the geothermal systems in Tibet are rich in rare metal elements such as lithium (Li), boron (B), rubidium (Rb), and cesium (Cs). However, the understanding of the origin of Cs-rich geyserite formed by hot springs remains unclear. In this study, a detailed petrological, elemental geochemical, and strontium–neodymium (Sr–Nd) isotopic investigation on Cs-rich geyserite in the Chabu region revealed that opal was the main mineral component of Chabu geyserite; here, some samples were rich in terrigenous clastic material, and well-developed diatom fossils were also present. Chabu geyserite had high contents of SiO2 (78.95%–94.72%) and Al2O3 (3.02%–8.14%) and low contents of Fe2O3 (0.21%–1.94%), TiO2 (0.01%–0.20%), MnO (0.01%–0.15%); additionally, the Fe/Ti ratio, the Al/(Al + Fe) ratio, and the Al/(Al + Fe + Mn) ratio showed large variations. These results indicated different degrees of participation by the terrigenous materials, hydrothermal deposition, and biogenic processes. Chabu geyserite was depleted in transition metal elements (e.g., Sc, V, and Cr) and high field strength elements (e.g., Nb, Zr, and Hf), relatively enriched in large-ion lithophile elements (e.g., Li, Rb, Sr, and Ba), and strongly enriched in Cs, (by up to 100 times the Cs content in the upper crust); in addition, it had low V/Y (1.30–2.00) and U/Th ratios. Chabu geyserite exhibited a right-dipping rare earth element (REE) distribution pattern and had significant negative Eu anomalies (0.26–0.72) and no or weak positive Ce anomalies (0.97–1.36). These results further indicated the influence of terrigenous clastic materials and nonhydrothermal sedimentation factors. The Sr–Nd isotopic composition of Chabu geyserite was significantly different from that of the mantle, with relatively high 87Sr/86Sr ratios (0.7070–0.7076) and low 143Nd/144Nd ratios (0.512223–0.512314). These ratios were similar to those of the crust. Combined with previous studies, the results from this study indicated that Chabu geyserite was a Cs-rich geyserite and was formed in an intracontinental post-collisional orogenic environment, mainly from crustal material, with the participation of biological and hydrothermal processes. Full article
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