Search Results (473)

In this paper, an Artificial Neural Network (ANN) is built to predict the performance of intumescent coatings subjected to the ISO 384 fire curve. The performance metric is called the Retention Loss Onset Time (RLOT) in the structural steel. The network receives the steel and coating thicknesses as input and provides RLOT as the performance of any intumescent coating in a fire accident with substantial accuracy. The required data for obtaining the model is provided by revisiting the recent attempts in this field, which include hybrid numerical and experimental methods. It is found that the trapped gas fraction parameter and empirical expansion ratio substantially affect the accuracy of predictive modelling. Therefore, a new, comprehensive dynamic model that numerically simulates the bubble expansion process has been developed. This novel method directly determines the expansion ratio of the thermal conductivity model. The Eurocode is then used with multi-layer models to predict the steel temperature profile for a 1 h duration ISO fire. The accuracy is improved by modelling the temperatures and thermal resistances at the centre of each divided layer. The effects of different coatings and steel thicknesses are also investigated to provide the required data. The results are verified and validated by comparing them with the recent numerical and empirical results available in the literature. Full article

This study explores the use of bentonite to enhance biological biogas upgrading in a bubble reactor (BR) operated under mesophilic conditions (39 ± 1 °C). The experimental setup consisted of a 2 L vertically oriented BR (height-to-diameter ratio 16:1) fed with a synthetic gas mixture (60% H₂, 15% CO₂, 25% CH₄, v/v) at a gas recirculation rate of 4 L L_R⁻¹ h⁻¹. The aim was to overcome hydrogen’s low gas–liquid mass transfer rate while avoiding the operational challenges typically associated with trickle-bed reactors (TBR). Bentonite increases the density and hydrostatic pressure of the liquid medium and likely alters its rheology, thereby extending the gas–liquid contact time without requiring elevated pressures or intensive gas recirculation. Additionally, bentonite is expected to provide microstructural support that promotes the formation of biofilm-like communities, creating favorable microenvironments for hydrogenotrophic methanogens. As a clay-based additive, bentonite may also contribute to improved process stability through adsorption of inhibitory compounds, enhanced biomass retention, and pH buffering. Under mesophilic conditions, the bentonite-modified BR achieved a methane production rate of 2.17 ± 0.06 LCH₄ L_R⁻¹ d⁻¹ at a gas retention time of 1.49 h, with methane purity reaching 96.25%. In comparison, a previously reported mesophilic BR operated under an identical reactor configuration and operating conditions but without bentonite exhibited substantially lower methane production rates, supporting the beneficial role of bentonite in biological methanation. The findings highlight bentonite’s potential dual role (physical and biological) in improving process efficiency and stability in biological methanation. Full article

This study employs a Computational Fluid Dynamics (CFD) approach based on the Two-Fluid Model (TFM) to investigate the CO₂ capture characteristics in a bubbling fluidized bed reactor using potassium carbonate (K₂CO₃) as the sorbent. The simulations are conducted at five superficial gas velocities ranging from 1.5 to 3.5 times the minimum bubbling velocity (u_mb = 0.26 m/s), with a particle diameter of 0.4 mm, particle density of 2300 kg/m³, and an initial solid volume fraction of 0.55. The gas mixture consists of CO₂, H₂O, and N₂ at a molar ratio of 0.1:0.1:0.8 and a temperature of 343 K. First, the numerical simulation was validated against experimental data reported in the literature, confirming its accuracy in quantitatively describing the adsorption process. Subsequently, the distributions of CO₂ concentration and adsorption reaction rate in both the bubble phase and the emulsion phase were analyzed under different superficial gas velocities. The simulation results indicate that CO₂ concentration and adsorption reaction rate in both phases decrease along the bed height. Compared to the emulsion phase, the bubble phase exhibits higher CO₂ concentration and gas temperature but a lower adsorption reaction rate. As the gas velocity increases, CO₂ concentration rises in both the bubble and emulsion phases, accompanied by an increase in the proportion of the bubble phase, and a higher CO₂ concentration at the reactor outlet. Further comparison of CO₂ concentrations in the bubble and emulsion phases at the upper part of the bed with the outlet concentration reveals that the outlet CO₂ primarily originates from the unadsorbed portion within the bubble phase, while the contribution from unadsorbed CO₂ in the emulsion phase is almost negligible. Full article

Hydrogen-mediated microbial electrosynthesis (MES) of chemicals from CO₂ relies on effective gas–liquid transfer at the cathode interface, yet the extent to which cathode surface area regulates acetate productivity remains insufficiently quantified. In this study, three identical MES reactors equipped with stainless-steel cathodes of different geometric areas (8 × 1, 8 × 4, and 8 × 16 cm²) were operated at a constant electric current of 0.3 A. The largest cathode significantly accelerated hydrogen mass transfer (k_La = 0.592 h⁻¹), reaching dissolution equilibrium within 3 min, which was nearly twice as fast as the smallest electrode. Upon inoculation with enriched acetate-producing microbial consortia, the 8 × 16 cm²_cathode reactor fed with CO₂ achieved the highest steady-state acetate concentration of 32 g·L⁻¹ produced at a rate of 2.12 g·L⁻¹·d⁻¹, with 94% hydrogen utilization, and 59% coulombic efficiency. In contrast, smaller electrodes exhibited rapid bubble detachment and reduced residence time, thereby limiting microbial gas uptake, and resulting in low acetate productivity. These findings demonstrate that cathode surface area is a key engineering lever controlling both hydrogen availability and electron recovery efficiency in H₂-driven MES. The results provide practical guidance for electrode design and scale-up of CO₂-to-acetate bioconversion via the MES process. Full article

The rising demand for sustainable and functional ingredients necessitates the development of novel replacers for traditional food components, such as eggs, which are critical for structure and aeration in baked goods. This study investigated hydrocolloids derived from cassava (Manihot esculenta) as a partial egg substitute in sponge cakes, evaluating their effect on rheological, physicochemical, nutritional, and sensory properties. The resulting cake batter exhibited characteristic non-Newtonian, pseudoplastic, and viscoelastic fluid behavior. A microstructural analysis confirmed that the stabilized, higher-viscosity doughs successfully facilitated the formation of larger, more stable air bubbles, effectively mimicking the structural role of the egg. Physicochemical assessments demonstrated a high product equivalence; the fat content showed no significant difference (p < 0.05) compared to the control, while pH and carbohydrate levels decreased. Crucially, the optimized formula, CK-S50-H2.5 (50% egg and 2.5% hydrocolloids substitutions), exhibited a minimal color difference (ΔE) consistent with the control, preserving product appearance. Sensory evaluation confirmed that hydrocolloid substitution did not compromise consumer acceptance. Panelists preferred cakes utilizing lower egg substitution levels for their enhanced flavor and texture. These findings establish that cassava hydrocolloids serve as an effective and functional partial egg replacer, yielding a high-quality and well-accepted product and offering a valuable, sustainable solution for the food industry. Full article

Foaming technology can effectively reduce the viscosity of polymer-modified asphalt and significantly decrease energy consumption during pavement construction, making it an effective approach for achieving low-carbon pavement construction and maintenance. However, mechanically foamed asphalt relies on specialized equipment and requires strict parameter control. Although water-based foaming methods using zeolites or ethanol can alleviate these issues to some extent, they still present disadvantages such as significant variability in foaming performance and potential risks during transportation and construction. Therefore, this study investigates the feasibility of using crystalline hydrates with high water of crystallization for micro-foamed asphalt. Three types of micro-foamed SBS-modified asphalt (MFPA) were prepared using hydrates with different contents of water of crystallization. Physical property tests, foaming characteristic parameters, viscosity–temperature analysis, Fourier transform infrared spectroscopy (FTIR), adhesion tensile tests, scanning electron microscopy (SEM), and fluorescence microscopy were conducted to evaluate their effects on the physical and chemical properties, viscosity reduction performance, adhesion, and compatibility of SBS-modified asphalt. Furthermore, dynamic shear rheometer (DSR) tests, bending beam rheometer (BBR) tests, fatigue life modeling, and morphological analysis were employed to investigate the rheological properties, fatigue life, and bubble evolution behavior of the MFPA system. The results indicate that utilizing the thermal decomposition characteristics of crystalline hydrates with high water of crystallization (Na₂SO₄·10H₂O, Na₂HPO₄·12H₂O, and Na₂CO₃·10H₂O) to release H₂O and CO₂ in SBS-modified asphalt for micro-foaming is a short-term reversible physical viscosity reduction process. The maximum expansion ratio (ERmax) of MFPA reaches 8–10, the half-life (HL) remains stable at approximately 180 s, and the foaming index (FI) peak is about 1160. The construction temperature can be reduced by 10–15%, and the viscosity reduction effect remains stable within 60 min. Compared with unfoamed SBS-modified asphalt, the compatibility, rutting resistance, and fatigue life of MFPA increase by approximately 65%, 32%, and 30%, respectively, while the low-temperature performance decreases by 18%. Under the same short-term and long-term aging conditions, MFPA exhibits better aging resistance. Specifically, its rutting resistance increases by 37%, and fatigue resistance improves by 30% compared with aged SBS-modified asphalt, while the low-temperature performance remains essentially unchanged. Full article

Against the backdrop of increasingly scarce global arable land resources, the remediation and resource utilization of saline–alkali soils have become a critical issue in circular agriculture. This study proposes micro-nano bubble (MNB) irrigation technology as a green, low-carbon strategy for saline–alkali soil remediation, highlighting its multi-level driving mechanism through pot experiments at different aeration frequencies. Results indicated that MNB irrigation significantly enhanced salt leaching and acid-base neutralization by reducing the soil pH (11.75%) and electrical conductivity (53.41%). Meanwhile, soil organic matter, cation exchange capacity, and available nitrogen, phosphorus, and potassium increased to normal soil levels. MNBs also strongly activated native enzymes (urease and alkaline phosphatase), raising the total enzyme activity by 68.54%, which is linked to carbon, nitrogen, and phosphorus metabolism. These results were also validated by microbial analysis, which indicated that MNBs shifted the community structure from one dominated by salt-tolerant taxa (i.e., Pseudomonadota) to a more functionally beneficial composition (i.e., Bacillota). Through these changes, the microbial diversity and network connectivity were enhanced, with Qipengyuania and Psychrophilus identified as critical nodes. This study reveals the multi-level driving mechanism of MNB technology, providing new technical pathways and theoretical support for the remediation, resource recovery, and circular utilization of agricultural waste soils. Full article

Ozonation is widely applied for refractory wastewater treatment, but its practical engineering is often limited by poor ozone mass transfer and low ozone utilization. In this study, micro-nano bubbles (MNBs) technology was employed to improve ozone delivery, and the performance of an O₃-MNBs system for treating coking reverse osmosis concentrate (ROC) was systematically compared with the conventional millimeter-sized ozone bubbles (O₃-MBs) system. To further promote oxidation, hydrogen peroxide (H₂O₂) was introduced, forming an O₃-MNBs/H₂O₂ system. Results showed that O₃-MNBs (D₅₀ = 36 μm) achieved a volumetric mass transfer coefficient 2.5 times higher than O₃-MBs. Under optimized conditions (pH: 7–9, ozone dosage: 10 mg/(L·min), temperature: 20–30 °C), COD removal in the O₃-MNBs system reached 34.9 ± 1.2%, nearly twice that of the O₃-MBs system, while the O/C ratio decreased by approximately 50% (4.7 ± 0.2), indicating enhanced ozone utilization efficiency. The addition of H₂O₂ further increased COD removal to 52.1 ± 2.9% and reduced the O/C ratio to 2.9 ± 0.2, reflecting strong synergistic effects. Moreover, the integration of MNBs and H₂O₂ effectively reduced energy consumption per unit of pollutant removed. Overall, the O₃-MNBs-based technology enhances organic pollutant degradation, ozone utilization and energy efficiency, offering a promising strategy for high-salinity refractory wastewater treatment. Full article

Shale oil reservoirs are characterized by ultra-low matrix permeability. After large-scale hydraulic fracturing is applied to horizontal wells, fluid transport becomes highly complex, posing major challenges for accurately predicting production performance. In this study, a coupled multi-mechanism numerical model is developed for shale oil reservoirs with complex fracture networks. Using the Embedded Discrete Fracture Model (EDFM), the mass transport between the fracture and matrix and within the hydraulic fracture network can be accurately quantified. Based on core analysis and fluid experimental data, the dynamic evolution of rock and fluid properties is characterized by incorporating nanopore confinement effects, stress sensitivity, and threshold pressure gradient behavior. Numerical simulations are then conducted to investigate the impacts of multiple mechanisms, including nanopore confinement effects, stress sensitivity, and threshold pressure gradient, as well as their coupling effects on shale oil production. A field application is carried out using Well H1 in the Qingcheng shale oil reservoir. Simulation results indicate that nanopore confinement reduces bubble-point pressure, leading to a 3.60% increase in cumulative oil production and a noticeable reduction in the producing gas–oil ratio. Stress sensitivity causes a 2.68% decrease in cumulative oil production and suppresses gas production. The threshold pressure gradient exerts the strongest negative impact, resulting in an 8.01% reduction in cumulative oil production and a slight decrease in gas–oil ratio. When all mechanisms are simultaneously considered, strong nonlinear interactions emerge, yielding a 7.09% reduction in cumulative oil production—significantly different from the linear superposition of individual effects. These results demonstrate the necessity of accounting for multi-mechanism coupling to achieve reliable production forecasting in fractured shale oil reservoirs. Full article

This research investigates wettability-induced, preferential, pressure-driven bubble nucleation of gases from a multi-gas dissolved liquid system in hydrophilic and hydrophobic glass vials. The hydrophobic glass surfaces were prepared using (heptadecafluoro-1,1,2,2-tetrahydrodecyl)triethoxysilane (HT). Degassed deionized water in a vial, placed inside a pressure cell, was saturated with a precisely controlled mixture of CO₂ and CH₄ gases at either 6000 mbar or 3000 mbar for 24 h. To initiate the pressure-driven bubble nucleation process, a 500 mbar step-down pressure was applied to the pressure cell every 15 min until bubble nucleation was observed. CH₄ and CO₂ volume fractions were measured using micro-gas chromatography (Micro-GC), while a digital microscope was employed to observe the bubble nucleation process. No bubble nucleation was observed in the case of the hydrophilic vial even when the system pressure was brought to atmospheric pressure. In the case of the hydrophobic vial, the average onset bubble nucleation pressures were 4800 mbar and 2000 mbar for 6000 mbar and 3000 mbar saturation pressures, respectively. The average feed gas concentrations during saturation were 84.44 ± 0.14% and 15.44 ± 0.2% of CH₄ and CO₂, respectively, while at the onset pressure for bubble nucleation, the concentrations shifted to 85.24 ± 0.48% and 13.12 ± 0.52% of CH₄ and CO₂, respectively, when the saturation pressure was 6000 mbar. The average feed gas concentrations during saturation were 85.12 ± 0.28% and 14.67 ± 0.1% of CH₄ and CO₂, respectively, and the average concentrations of CH₄ and CO₂ gases at onset pressure for bubble nucleation were 86.06 ± 1.21% and 12.03 ± 1.03%, respectively, when the saturation pressure was 3000 mbar. The increase in CH₄ concentration is attributed to its preferential separation during the bubble nucleation process. Full article

Laminar separation bubbles (LSBs) on low-Reynolds-number airfoils are sustained by intrinsic unsteadiness driven by Kelvin–Helmholtz (K-H) growth in the separated shear layer. Using incompressible 2D URANS with the SA-$\gamma$ transition model for a NACA 0012 airfoil at $Re=5.3\times {10}^4$, we reveal that numerical dissipation behaves as a critical bifurcation parameter. Validated against the recent Jardin (2025) experimental benchmark, the physical state correctly resolves the LSB-induced pressure plateau ($C_p$) and local negative skin friction ($C_f<0$). However, when numerical dissipation exceeds the K-H instability growth rate, the physical limit-cycle oscillation collapses into a spurious fixed-point attractor—a phenomenon defined as numerical quenching. This pseudo-convergence triggers a catastrophic ∼30% deficit in mean lift ($C_l$). Furthermore, at $\alpha =6^{\circ }$, a drag-mechanism inversion is identified: while the physical branch is dominated by LSB-induced pressure (form) drag, the quenched branch exhibits a non-physical drag surge that exceeds the fully turbulent baseline. Phase portraits and power spectral densities ($St\approx 0.2$) provide objective diagnostics, demonstrating that standard residual convergence is a deceptive indicator of physical fidelity in transitional separated aerodynamics. Full article

Copper(II) oxide (CuO) nanoparticles are of growing interest due to their versatility in catalysis, energy storage, and environmental remediation. In this work, a novel air-assisted polyol–thermal decomposition method was developed to synthesize crystalline CuO nanoparticles with a controlled size. The reaction used copper(II) acetate in 1,4-butanediol at 140 °C under varying airflow conditions and reaction times, followed by calcination at 400 °C in air. Continuous air bubbling minimized the formation of Cu₂O and metallic Cu, while maximizing the CuO yield with shortened reaction times. The optimal conditions involved a 4 h polyol reaction while purging air at 1800 cm³/min, followed by 4 h of calcination. This method resulted in polycrystalline monoclinic CuO nanoparticles with a size of 73 ± 32 nm, as observed by TEM and XRD. FT-IR and Raman spectroscopy verified the compositional purity of the nanoparticles. To enhance colloidal stability, a citrate coating reaction of CuO was optimized using sodium citrate dihydrate or citric acid in either water or 1,4-butanediol. The optimal coating conditions employed sodium citrate in water with bath sonication and overhead stirring, yielding a zeta potential of −40.6 ± 0.4 mV at pH 7. This work provides a practical and tunable method for producing high-quality CuO nanoparticles suitable for diverse applications. Full article

The 12 November 2025 G4 geomagnetic storm—the third most intense of solar cycle 25—was triggered by a complex shock-ICME (interplanetary coronal mass ejection) structure as a result of three ICMEs and driven shocks that arrived on 11–12 November. The main enhancement in the interplanetary magnetic field occurred in the sheath region behind the shock driven by the second ICME. The Dst index reached −217 nT (the SYM-H index reached −254 nT) and the maximum Kp index was 9-. To comprehensively analyze the causes of the storm and its complex effects on near-Earth space, we used a multi-instrumental data set, involving data from satellite missions (ACE, SDO, PROBA2), GNSS networks, ionosondes, optical instruments, high-frequency radars (SuperDARN-like), and cosmic ray monitors. The auroral oval expanded equatorward (down to ~35° N in America). We recorded a super equatorial plasma bubble that almost reached the auroral oval boundary. The equatorial anomaly crests intensified, exceeding 175 TECU, and shifted poleward (8–10°). At mid-latitudes, the F2 layer critical frequency exhibited a strong negative disturbance (−50%) during the main phase, followed by an unusually prolonged and intense positive phase (+100%). GPS Precise Point Positioning errors increased to 2–3 m at high latitudes and in regions affected by the equatorial bubble. The event also featured a Forbush decrease and ground-level enhancement (GLE 77 according to the database hosted by the University of Oulu) associated with the X5.1 solar flare. The results underscore the complex chain of processes from solar storm to geomagnetic and ionospheric responses, highlighting the risks to satellite-based navigation and communication systems. Full article

The development of smart coatings with active protection is a promising approach to prolonging the service life in extreme environments. Herein, the corrosion inhibitors 2-mercaptobenzimidazole (MBI) and CeO₂ were in situ loaded onto the surface of graphene oxide (GO) by dopamine (DA) polymerization, and we ultimately obtained the multifunctional composite MBI@CeO₂@PDA@GO (MCPG). The electrochemical impedance spectroscopy (EIS) results revealed that after 30 days of immersion in the corrosive media, the |Z|_0.01 Hz value of MCPG/WEP coating remained at 3.7 × 10⁹ Ω/cm², which displayed four orders of magnitude higher than that of pure WEP coating (1.4 × 10⁵ Ω/cm²). In a 200 h salt spray test, the MCPG/WEP coating also demonstrated minimal corrosion products and bubbles, affirming the exceptional corrosion-inhibiting effect and excellent self-healing performance. Consequently, the synergistic combination of pH-sensitive properties and outstanding barrier effect imparted dual active/passive anti-corrosion capabilities to the coating, resulting in long-lasting metal protection. Full article

Objectives: We aimed to visualize the interaction of intravitreal gas with the adjacent vitreomacular interface by using prone position (PP) SD-OCT and suggest possible mechanisms of action behind gas-induced posterior vitreous detachment (PVD) in pneumatic vitreolysis (PV). Methods: This was a descriptive–interpretative morphological study. Spectral domain OCT imaging in PP was carried out using a flexible scanning module (SD-OCT-Flex, Heidelberg Engineering) originally designed for bedside imaging. Routine imaging in sitting position was carried out using a regular SD-OCT-device (Heidelberg Engineering). Patients with symptomatic vitreomacular traction (VMT) scheduled for PV with perfluoropropane (C3F8, 0.3 mL) received both sitting and PP imaging immediately before and at regular follow-up visits during the first 3 post-procedural weeks, beginning 3 h after PV. Imaging was reviewed for positional changes of the gas bubble, posterior hyaloid membrane (PHM), VMT configuration, and retrohyaloidal fluid (RHF). Results: Three consecutive patients with VMT were included (age: 79, 80, 82 years). Before the procedure, no positional alterations were detected. After the intravitreal injection of gas, PP allowed for the precise discrimination of the PHM and the posterior border of the gas bubble. In contrast to regular SD-OCT in sitting position, PP imaging showed a flattened VMT by the gas bubble with consecutive displacement of RHF from the macular region to the midperiphery. Conclusions: This exploratory study describes PP imaging as a tool for the assessment of the morphologic dynamics between the posterior hyaloid membrane, retina, and gas bubble in pneumatic vitreolysis. PP in pneumatic vitreolysis causes the gas bubble to flatten the VMT and to push retrohyaloidal fluid to the midperiphery, possibly allowing for the release of persistent vitreoretinal adhesions and consequent PVD induction. Full article