Search Results (724)

Second-generation high-temperature superconducting tapes (2G HTS; SuperPower Inc., Glenville, NY, USA) based on GdBCO (GdBa₂Cu₃O_7−δ, where δ denotes oxygen deficiency) were aged at −26.4 °C, +2 °C, and room temperature (RT) to evaluate the degradation of their superconducting properties. HTS tapes stored at RT exhibited a significantly higher deterioration rate compared to those maintained at lower temperatures. Laser-induced breakdown spectroscopy (LIBS) analysis demonstrated a gradual reduction in the effective chemical depth-profiling length over time, indicating a correlation between the degradation mechanism and the reduction in the effective volumetric density of the GdBCO superconducting layer. These findings imply that oxygen diffusion or redistribution processes substantially contribute to the long-term degradation of GdBCO-based HTS tapes. Full article

A superconducting high-entropy alloy (HEA) Nb_0.67(TiZrHf)_0.33 powder was successfully synthesized via mechanical alloying for the first time. X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectroscopy, magnetic measurements, and specific heat were used to investigate its structural and physical properties. The alloy was crystallized in a single-phase body-centered cubic structure with a small amount of non-magnetic impurities coming from ball milling. Specific heat data confirms the presence of bulk superconductivity in the as-synthesized state, with the broadness of the thermodynamic anomaly reflecting the significant chemical disorder and distribution of critical temperatures typical of HEAs. $T_c$ is in the range 6–7.5 K, and the upper critical field $\mu 0H_{\mathrm{c}2}$ is in the range 6.4–7.6 T. These results demonstrate that mechanical synthesis is a viable route for producing superconducting HEA powders, which are promising candidates for consolidation via sintering and provide a robust platform for investigating superconductivity in highly disordered systems. Full article

High-temperature superconductivity in strongly correlated materials is often accompanied by pseudogap behavior, strange-metal transport, strong phase fluctuations, and reduced superfluid stiffness, particularly in quasi-two-dimensional systems. These features suggest that pairing alone may not determine the onset of global superconductivity. We develop a coordination-based framework in which superconductivity is promoted by the collective organization of internal electronic degrees of freedom coupled to a carrier phase. A minimal lattice model is introduced, combining a U(1) phase sector, an internal coordination field, and an inter-sector coupling. A Landau analysis shows that internal coordination enhances the effective phase stiffness and can destabilize the incoherent state once the coordination amplitude becomes sufficiently large. Monte Carlo simulations of the model confirm that increasing coordination strength enhances phase stiffness and shifts the onset of global coherence to higher temperature. The framework provides a possible organizing interpretation of the separation between pseudogap onset and superconducting coherence, as well as the sensitivity of layered superconductors to reduced dimensionality, competing orders, and vortex-core structure. It is not intended to replace BCS theory, but to extend phase-stiffness-based descriptions to regimes where pairing, local coordination, and global phase coherence are distinct. Full article

The electronic properties of high-temperature superconducting cuprates are encoded in NMR data. Without microscopic theory, reliable NMR phenomenologies are in demand. Here we make use of the extensive literature data to develop a different understanding of the cuprates from the shifts of the ${\mathrm{CuO}}_2$ plane. The Cu shift analysis is based only on the symmetry of the two Cu hyperfine couplings, without assumptions about their size. We use an anisotropic $A_{\alpha }$ and isotropic B, as from atomic Cu orbitals, and find two spin components (A- and B-spins) that explain all the shift data. The components differ in size and temperature dependence according to simple rules. Upon doping the cuprates, metallic B-spin appears above a pseudogap temperature, which is shared with the A-spin. Further doping decreases the pseudogap temperature and increases the B-spin, but less so the A-spin. The apparent linear rate of increase in the density of states of the B-spin with doping is nearly threefold above $x=0.20$, where the pseudogap disappears. The pseudogap temperature is a measure of the coupling between A and B, which suppresses the shifts but not nuclear relaxation. Spin-singlet pairing involves A and B according to three simple condensation rates, which will be discussed. The optimal $T_{\mathrm{c}}$ demands a special match between A and B. However, the shifts do not simply predict the highest $T_{\mathrm{c}}$ of all cuprates, in contrast to nuclear relaxation anisotropy and charge sharing between planar Cu and O. Relations to other probes are discussed. Full article

The solidification process is crucial for preparing high-performance superconductors and is strongly dependent on the characteristics of the starting powder, including particle size, morphology, and phase purity. This review concisely examines the study on four key superconductors: REBCO, Bi-2212, FeSeTe, and MgB₂. In REBCO, additives such as CeO₂, Pt, or BaO₂ powder can refine the RE-211 phase. In Bi-2212, Pb doping stabilizes the high-T_c phase. For FeSeTe, doping with F or Co modifies phase separation and introduces Δκ pinning. Meanwhile, in MgB₂, the incorporation of SiC nanoparticles powder generates effective pinning centers. Concurrently, processing conditions exert a decisive influence on the final microstructure, as demonstrated by the TSMG/TSIG route in REBCO, partial melting parameters for Bi-2212, specific cooling protocols and thermal treatments for FeSeTe, and optimized sintering and post-annealing processes for MgB₂. Future research directions should prioritize fundamental understanding of phase separation mechanisms during powder processing, development of multi-component doping strategies for powder modification, and advancement of scalable powder processing routes for practical conductor architectures. Full article

In this work a study about the behavior of nanomaterial-based innovative transparent electrodes is presented, with a special focus on graphene, for space photovoltaic applications, in particular their transparency and the efficiency of the final device. The efficiency of a solar cell is characterized by referring to Power Conversion Efficiency and External/Internal Quantum Efficiency. Starting from the literature results, it is possible to observe that solar cells realized by innovative nanomaterial-based transparent electrodes show promising results in terms of efficiency in the Earth environment. It is known that the space environment is characterized by extreme conditions including high-energy radiation, strong temperature variations and high vacuum, which can damage materials and, consequentially, influence their performances. Among all the properties like transmittance and sheet resistance, which are the main requirements for a good transparent electrode, could change their value and, therefore, influence the efficiency of the solar cell adopting this kind of electrode. In this paper, a theoretical analysis on the effects of high-energy radiation on the transmittance of graphene layers is given, leading to the observation that in the UV frequency range, it shows a sharp fall. Moreover, the effect of temperature varying is studied by an theoretical analysis on the resistivity of the twisted graphene bilayer. It is possible to observe that, in this configuration, the system moves from a superconductor to a metal, according to temperature and twist angle. This represents a starting point to have good efficiency of solar devices in a space environment by keeping high the transparency of their electrodes. Full article

The transport experiments reveal that the low-temperature resistivity in the normal state of cuprate superconductors is quadratic in temperature (T-quadratic) in the underdoped pseudogap phase, while it is linear in temperature (T-linear) in the overdoped strange-metal phase; however, the full understanding of these different behaviors is still a challenging issue. Here starting from the microscopic electronic structure of cuprate superconductors, the low-temperature resistivity in the normal state is investigated from the underdoped pseudogap phase to the overdoped strange-metal phase. It is shown that the mechanism requires both the impurity scattering and the umklapp scattering: the impurity scattering is needed to restrict the modification of the distribution function to at and around the antinodal region, while the impurity-scattering assisted umklapp scattering from a spin excitation is at the heart of the behavior in the low-temperature resistivity, where the doping dependence of the temperature scale exists, and presents a similar behavior of the antinodal spin pseudogap crossover temperature. In the low-temperature region above the temperature scale in the overdoped strange-metal phase, the resistivity is T-linear; however, in the low-temperature region below the temperature scale in the underdoped pseudogap phase, the opening of the spin pseudogap lowers the spin excitation density of states at and around the antinodal region, which reduces the strength of the electron umklapp scattering from a spin excitation associated with the antinode, and thus leads to a T-quadratic behavior of the resistivity. Full article

FeSe-based superconductors have become a hot topic with regard to high-temperature superconductor mechanisms and applications due to their broadly adjustable critical temperatures and the underlying rich physics. This has led to the emergence of numerous experimental approaches for regulating important critical parameters, particularly superconducting transition temperature, T_c. Owing to its powerful and effective control, electrochemical intercalation has become a widely adopted technique for tailoring the chemical and physical properties of layered materials in recent years. This short review concisely introduces FeSe-based superconductors and an electrochemical intercalation method and summarizes the research progress that has been made in utilizing this method to modulate the structure and superconductivity of FeSe-based materials. Full article

We suggest Josephson interferometry as a quantitative probe of spin–orbit-driven phenomena in superconducting heterostructures. Two distinct mechanisms are analyzed: (i) intrinsic helical superconductivity, producing asymmetric Fraunhofer patterns with lobe deformations and field-reversal asymmetry, and (ii) emergent interfacial magnetism in ferromagnet–superconductor hybrids, where Rashba spin–orbit coupling generates spontaneous fields that rigidly shift the interference fringes. The predicted signatures—flux-shifted interference minima, anisotropic critical current suppression, and angle-dependent pattern distortions—provide direct experimental access to finite-momentum pairing and interface-localized fields via standard Josephson current measurements. Full article

Recently, CuBa₂Ca₃Cu₄O_10+δ (Cu1234) has garnered significant interest owing to its distinctive triple-high superconducting properties (118K high T_c, combined with high J_c and high H_irr at liquid nitrogen temperature at ambient pressure) and potential for practical applications. The Cu1234 is initially synthesized at high pressures and is stable at a room temperature range but tends to decompose upon heating above 300 °C at ambient. In this study, we investigate the thermal stability of Cu1234 through annealing at various temperatures and oxygen pressures. It is found that Cu1234 starts to decompose at approximately 350 °C, 550 °C, and 600 °C when annealed at 1 bar, 100 bar, and 150 bar oxygen pressure, respectively. Prior to decomposition, however, the superconducting properties remain largely unchanged. The decrease in oxygen occupancy within the BaO layer of the BaCuO_3−δ charge reservoir block is proposed to be the primary cause of the structural instability of Cu1234, while higher oxygen pressures retard oxygen loss from this block. Our result suggests that the decomposition temperature of Cu1234 will further increase with higher oxygen pressure, e.g., possibly to 800 °C at 260 bar if a linear extrapolation is adopted. This study offers important insights for fabricating Cu1234 tapes via the powder-in-tube method. Full article

Experimental results suggest a feasible strategy for tuning the superconducting properties of MgB₂ through the incorporation of an electroluminescent inhomogeneous phase. By introducing GaP electroluminescent inhomogeneous phases into MgB₂, the effects of emission intensity variation on the sample structure, superconducting transition temperature, electrical transport behavior, and magnetic properties were systematically investigated. The results show that, at a fixed GaP addition level, the superconducting transition temperature T_c increases steadily from 38.2 K to 39.6 K with increasing emission intensity of the inhomogeneous phase, corresponding to a maximum enhancement of approximately 1.4 K. Meanwhile, the zero-resistance temperature shifts upward synchronously, indicating that the entire superconducting transition region moves toward higher temperatures. Raman measurements show that the peak position and linewidth of the E_2g phonon mode evolve systematically with emission intensity, while the electron–phonon coupling parameter λ exhibits a trend consistent with that of T_c. In addition, the nanoscale dispersed distribution of the GaP inhomogeneous phase, together with the interface/defect structures it introduces, appears to promote sample densification and enhance flux pinning, resulting in an increase in the critical current density J_c by approximately 69% at 20 K in self-field and an enhancement of the irreversibility field H_irr by about 31.5%. These results suggest that, beyond the effect of static inhomogeneous-phase incorporation, the luminescence-activated state under bias excitation is likely involved in modulating the superconducting response of MgB₂. This work provides a new experimental perspective for synergistically regulating the properties of conventional superconductors through the combined effects of inhomogeneous phases and excited states. Full article

Magnetic superconductor EuRbFe₄As₄ is a quite unique system in which macroscopic superconductivity and magnetic ordering coexist, with interesting interactions between Abrikosov vortices and Eu²⁺ spins that were investigated mostly by static (DC) magnetization measurements. Our aim is to study the dynamic interactions between the two sub-systems using AC susceptibility measurements in a wide range of temperatures and superimposed DC fields. In low DC fields, the magnetic transition at 15 K is clearly visible. We have observed very little difference between the AC susceptibility in different cooling regimes, but large difference for different field orientation. For field perpendicular to the superconducting planes, we have observed an anomalous dependence just below the critical temperature, which is absent in the parallel field orientation. We explained the anomaly by the interplay between the sample dimensions and the temperature dependence of the London penetration depth which may allow the paramagnetic Meissner-like response to be detected in the temperature dependence of the AC susceptibility. We stress that the newly reported phenomenon reflects an AC-susceptibility manifestation of a field-stabilized critical state rather than a thermodynamic phase. In addition, we have observed a paramagnetic AC response in the normal phase, in both field orientations, indicative of interactions between Eu²⁺ spins and flux lines. Full article

The increasing demand for electric power in hybrid electric aircraft platforms prompts the development of multi-megawatt generators featuring high specific power, compactness and intrinsic fault tolerance. Air-core machines constitute a promising solution to overcome the magnetic saturation and mass limitations of conventional iron-core designs. This paper presents a comparative electromagnetic design study of two air-core synchronous generator topologies for aircraft applications, namely a permanent magnet machine with a Halbach array rotor and an electrically excited synchronous machine featuring a high-temperature superconducting field winding. Both the generators are designed for identical output and adopt a double three-phase stator winding to enhance safety and redundancy. The Halbach array machine is used as the reference configuration representative of a technologically mature solution, whereas the superconducting generator targets high magnetic loadings by means of the superconducting excitation, to minimize the active volume. The solutions proposed in this paper are developed in the frame of a national (Italian) research project dedicated to the study of stages of multi-megawatt fault-tolerant aircraft generators. Full article

Since the discovery of iron-based superconductors nearly two decades ago, significant advancements have been made, including the enhancement of the superconducting transition temperature ($T_c$) to above 100 K. However, the underlying pairing mechanism remains an unresolved enigma. In this article, we present experimental developments in iron-based superconductors, focusing on their unique properties and the complexities involved in their behavior. We discuss the recently announced electron–differential phonon coupling model, which aims to provide a framework to calculate the T_c of iron-based superconductors, but raises questions about its applicability to all iron-based superconductors. We selectively analyze several compounds within the major iron-based families to assess their compatibility with the electron–differential phonon coupling model. By comparing experimental data with theoretical predictions, we identify which superconductors align with the model and which do not. Furthermore, our findings reveal several key reasons behind the discrepancies in calculating $T_c$ for those iron-based materials that fall outside the theoretical expectations. Despite this, the pairing mechanism of iron-based superconductors remains an open question. Full article

This editorial consists of a synopsis of the research in the Special Issue on “Superconductors and Magnetic Materials”, specifying the studies and highlighting main results and conclusions. This collection of research (1) demonstrates the possibility of notably decreasing AC losses by replacing the copper encapsulation of rare Earth barium copper oxide tapes with strong magnetic encapsulation; (2) predicts typical gains expected from soft-magnet and superconductor flux concentrators for low magnetic field sensing; (3) reveals that the n-value surfaces of high-Tc tapes can be estimated with a high accuracy using feed-forward deep neural network learning; (4) predicts the detection of a monopole plasma phase in high-Tc iron-based superconductors with a Tc above 70 K; and (5) proposes an analytical model to accurately predict the gap-to-Tc ratio for yttrium hydrides at high pressures. Full article