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Search Results (1,178)

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22 pages, 2143 KB  
Article
Coarse-Grained Drift Fields and Attractor-Basin Entropy in Kaprekar’s Routine
by Christoph D. Dahl
Entropy 2026, 28(1), 92; https://doi.org/10.3390/e28010092 - 12 Jan 2026
Abstract
Kaprekar’s routine, i.e., sorting the digits of an integer in ascending and descending order and subtracting the two, defines a finite deterministic map on the state space of fixed-length digit strings. While its attractors (such as 495 for D=3 and 6174 [...] Read more.
Kaprekar’s routine, i.e., sorting the digits of an integer in ascending and descending order and subtracting the two, defines a finite deterministic map on the state space of fixed-length digit strings. While its attractors (such as 495 for D=3 and 6174 for D=4) are classical, the global information-theoretic structure of the induced dynamics and its dependence on the digit length D have received little attention. Here an exhaustive analysis is carried out for D{3,4,5,6}. For each D, all states are enumerated and the transition structure is computed numerically; attractors and convergence distances are obtained, and the induced distribution over attractors across iterations is used to construct “entropy funnels”. Despite the combinatorial growth of the state space, average distances remain small and entropy decays rapidly before entering a slow tail. Permutation symmetry is then exploited by grouping states into digit multisets and, in a further reduction, into low-dimensional digit-gap features. On this gap space, a first-order Markov approximation is empirically estimated by counting one-step transitions induced by the exhaustively enumerated deterministic map. From the resulting empirical transition matrix, drift fields and the stationary distribution are computed numerically. These quantities serve as descriptive summaries of the projected dynamics and are not derived in closed form. Full article
(This article belongs to the Section Complexity)
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18 pages, 5591 KB  
Article
Comparative Analysis of Internal Complex Flow and Energy Loss in a Tubular Pump Under Two Rotational Speed Conditions
by Yujing Zhang, Yi Sun, Xu Han, Ran Tao and Ruofu Xiao
Water 2026, 18(2), 188; https://doi.org/10.3390/w18020188 - 10 Jan 2026
Viewed by 54
Abstract
This study focuses on a bulb tubular pump to clarify the flow characteristics and energy loss laws of low-lift tubular pumps under variable speed regulation and addresses deviations from optimal operating conditions in complex scenarios. For two typical rotational speeds, a full-flow passage [...] Read more.
This study focuses on a bulb tubular pump to clarify the flow characteristics and energy loss laws of low-lift tubular pumps under variable speed regulation and addresses deviations from optimal operating conditions in complex scenarios. For two typical rotational speeds, a full-flow passage model was established; the SST k-ω turbulence model was used to solve 3D incompressible viscous flow, energy loss was analyzed via entropy production theory, and simulations were experimentally validated. The results showed the following: pump efficiency exhibited a “first rise then fall” trend, head decreased monotonically with flow rate, and the optimal operating point shifted to lower flow rates at slower speeds. Meanwhile, local entropy production rate effectively characterized loss location and intensity, with aggravated off-design loss concentrated near the hub and rim along the spanwise direction and within 30 mm of the near-wall region. This study clarifies core energy loss mechanisms, providing a quantitative basis for operation optimization and structural improvement to support the safe, economical operation of low-lift pump stations. Full article
(This article belongs to the Section Hydraulics and Hydrodynamics)
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14 pages, 14424 KB  
Article
In-Situ Growth of Carbon Nanotubes on MOF-Derived High-Entropy Alloys with Efficient Electromagnetic Wave Absorption
by Zhongjing Wang, Bin Meng, Xingyu Ping, Qingqing Yang, Kang Wang and Shuo Wang
Materials 2026, 19(2), 239; https://doi.org/10.3390/ma19020239 - 7 Jan 2026
Viewed by 96
Abstract
To obtain an excellent electromagnetic wave (EMW) absorption material, a strategy was proposed in this study with the aid of in-situ growth of carbon nanotubes (CNTs) on the surface of a metal–organic framework (MOF)-derived FeCoNiMnMg high-entropy alloy (HEA). The HEA@CNT composite was successfully [...] Read more.
To obtain an excellent electromagnetic wave (EMW) absorption material, a strategy was proposed in this study with the aid of in-situ growth of carbon nanotubes (CNTs) on the surface of a metal–organic framework (MOF)-derived FeCoNiMnMg high-entropy alloy (HEA). The HEA@CNT composite was successfully prepared via a solvothermal method combined with a one-step pyrolysis process. With the pyrolysis temperature increasing from 600 °C to 800 °C, the length of CNTs grew from 200 nm to about 600 nm approximately, while the defect density of CNTs was enhanced. This structural evolution significantly improved the dielectric properties and impedance matching. Consequently, the sample prepared at 800 °C (HEA@CNT-800) exhibited outstanding microwave absorption performances, achieving a minimum reflection loss (RLmin) of −57.52 dB at a matched thickness of 2.3 mm and an effective absorption bandwidth (EAB) of 4.4 GHz at a thinner thickness of 1.9 mm. This work provides a novel perspective for designing high-performance MOF-derived absorption materials. Full article
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29 pages, 3200 KB  
Article
Accurate Prediction of Type 1 Diabetes Using a Novel Hybrid GRU-Transformer Model and Enhanced CGM Features
by Loubna Mazgouti, Nacira Laamiri, Jaouher Ben Ali, Najiba El Amrani El Idrissi, Véronique Di Costanzo, Roomila Naeck and Jean-Mark Ginoux
Algorithms 2026, 19(1), 52; https://doi.org/10.3390/a19010052 - 6 Jan 2026
Viewed by 176
Abstract
Accurate prediction of Blood Glucose (BG) levels is essential for effective diabetes management and the prevention of adverse glycemic events. This study introduces a novel designed hybrid Gated Recurrent Unit-Transformer (GRU-Transformer) model tailored to forecast BG levels at 15, 30, 45, and 60 [...] Read more.
Accurate prediction of Blood Glucose (BG) levels is essential for effective diabetes management and the prevention of adverse glycemic events. This study introduces a novel designed hybrid Gated Recurrent Unit-Transformer (GRU-Transformer) model tailored to forecast BG levels at 15, 30, 45, and 60 min horizons using only Continuous Glucose Monitoring (CGM) data as input. The proposed approach integrates advanced CGM feature extraction step. The extracted features are statistically the mean, the median, the maximum, the entropy, the autocorrelation and the Detrended Fluctuation Analysis (DFA). In addition, in order to define more enhanced and specific features, the custom 3-points monotonicity score, the sinusoidal time encoding, and the workday/weekend binary features are proposed in this work. This approach enables the model to capture physiological dynamics and contextual temporal patterns of Type 1 Diabetes (T1D) with great accuracy. To thoroughly assess the performance of the proposed method, we relied on several well-established metrics, including Root Mean Squared Error (RMSE), Coefficient of Determination (R2), Mean Absolute Error (MAE), Mean Absolute Percentage Error (MAPE), and Root Mean Squared Percentage Error (RMSPE). Experimental results demonstrate that the proposed method achieves superior predictive accuracy for both short-term (15–30 min) and long-term (45–60 min) forecasting. Specifically, the model attained the lowest average RMSE values, with 4.00 mg/dL, 6.65 mg/dL, 7.96 mg/dL, and 8.91 mg/dL and yielding consistently high R2 scores for the respective prediction horizons. This new method distinguishes itself by continuously exceeding current prediction models, reinforcing its potential for real-time CGM and clinical decision support. Its high accuracy and adaptability make it a favorable tool for improving diabetes management and personalized glycemic control. Full article
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75 pages, 1361 KB  
Review
Matrix Quantum Mechanics and Entanglement Entropy: A Review
by Jackson R. Fliss and Alexander Frenkel
Entropy 2026, 28(1), 58; https://doi.org/10.3390/e28010058 - 31 Dec 2025
Viewed by 329
Abstract
We review aspects of entanglement entropy in the quantum mechanics of N×N matrices, i.e., matrix quantum mechanics (MQM), at large N. In doing so, we review standard models of MQM and their relation to string theory, D-brane physics, and emergent [...] Read more.
We review aspects of entanglement entropy in the quantum mechanics of N×N matrices, i.e., matrix quantum mechanics (MQM), at large N. In doing so, we review standard models of MQM and their relation to string theory, D-brane physics, and emergent non-commutative geometries. We overview, in generality, definitions of subsystems and entanglement entropies in theories with gauge redundancy and discuss the additional structure required for definining subsystems in MQMs possessing a U(N) gauge redundancy. In connecting these subsystems to non-commutative geometry, we review several works on ‘target space entanglement,’ and entanglement in non-commutative field theories, highlighting the conditions in which target space entanglement entropy displays an ‘area law’ at large N. We summarize several example calculations of entanglement entropy in non-commutative geometries and MQMs. We review recent work in connecting the area law entanglement of MQM to the Ryu–Takayanagi formula, highlighting the conditions in which U(N) invariance implies a minimal area formula for the entanglement entropy at large N. Finally, we make comments on open questions and research directions. Full article
(This article belongs to the Special Issue Coarse and Fine-Grained Aspects of Gravitational Entropy)
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67 pages, 7998 KB  
Article
Neural Network Method for Detecting UDP Flood Attacks in Critical Infrastructure Microgrid Protection Systems with Law Enforcement Agencies’ Rapid Response
by Serhii Vladov, Łukasz Ścisło, Anatoliy Sachenko, Jan Krupiński, Victoria Vysotska, Maksym Korniienko, Oleh Uhrovetskyi, Vyacheslav Krykun, Kateryna Levchenko and Alina Sachenko
Energies 2026, 19(1), 209; https://doi.org/10.3390/en19010209 - 30 Dec 2025
Viewed by 276
Abstract
This article develops a hybrid neural network method for detecting UDP flooding in critical infrastructure microgrid protection systems. This method combines sequential statistics (CUSUM) and a multimodal convolutional 1D-CNN architecture with a composite scoring criterion. Input features are generated using packet-aggregated one-minute vectors [...] Read more.
This article develops a hybrid neural network method for detecting UDP flooding in critical infrastructure microgrid protection systems. This method combines sequential statistics (CUSUM) and a multimodal convolutional 1D-CNN architecture with a composite scoring criterion. Input features are generated using packet-aggregated one-minute vectors with metrics for packet count, average size, source entropy, and HHI concentration index, as well as compact sketches of top sources. To ensure forensically relevant incident recording, a greedy artefact selection policy based on the knapsack problem with a limited forensic buffer is implemented. The developed method is theoretically justified using a likelihood ratio criterion and adaptive threshold tuning, which ensures control over the false alarm probability. Experimental validation on traffic datasets demonstrated high efficiency, with an overall accuracy of 98.7%, a sensitivity of 97.4%, an average model inference time of 5.3 ms (2.5 times faster than its LSTM counterpart), a controlled FPR of 0.96%, and a reduction in asymptotic detection latency with an increase in intensity from 35 to 12 s. Moreover, with a storage budget of 10 MB, 28 priority bins were selected (their total size was 7.39 MB), ensuring the approximate preservation of 85% of the most informative packets for subsequent examination. This research contribution involves the creation of a ready-to-deploy, resource-efficient detector with low latency, explainable statistical layers, and a built-in mechanism for generating a standardized evidence package to facilitate rapid law enforcement response. Full article
(This article belongs to the Special Issue Cyber Security in Microgrids and Smart Grids—2nd Edition)
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29 pages, 1605 KB  
Article
Conditional Cosmological Recurrence in Finite Hilbert Spaces and Holographic Bounds Within Causal Patches
by Nikolaos Chronis and Nikolaos Sifakis
Universe 2026, 12(1), 10; https://doi.org/10.3390/universe12010010 - 30 Dec 2025
Viewed by 256
Abstract
A conditional framework of Conditional Cosmological Recurrence (CCR) is introduced, as follows: if a causal patch admits a finite operational Hilbert space dimension D (as motivated by holographic and entropy bounds), then unitary quantum dynamics guarantee almost-periodic evolution, leading to recurrences. The central [...] Read more.
A conditional framework of Conditional Cosmological Recurrence (CCR) is introduced, as follows: if a causal patch admits a finite operational Hilbert space dimension D (as motivated by holographic and entropy bounds), then unitary quantum dynamics guarantee almost-periodic evolution, leading to recurrences. The central contribution is the explicit formulation of a micro-to-macro bridge, as follows: (i) finite regions discretize field modes; (ii) gravitational bounds cap entropy and energy; and (iii) the number of accessible states is finite, yielding CCR. The analysis differentiates global microstate recurrences (with double-exponential timescales in Smax) from operationally relevant coarse-grained returns (exponential in subsystem entropy), with conservative timescale estimates. For predictivity in eternally inflating settings, a causal-diamond measure with xerographic typicality and a single no-Boltzmann-brain constraint is employed, thereby avoiding volume-weighting pathologies. The scope is explicitly conditional: if future quantum gravity demonstrates D= for causal patches, CCR is falsified. Full article
(This article belongs to the Section Cosmology)
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21 pages, 561 KB  
Review
Holographic Naturalness and Pre-Geometric Gravity
by Andrea Addazi, Salvatore Capozziello and Giuseppe Meluccio
Physics 2026, 8(1), 2; https://doi.org/10.3390/physics8010002 - 29 Dec 2025
Viewed by 355
Abstract
The cosmological constant (CC, Λ) problem stands as one of the most profound puzzles in the theory of gravity, representing a remarkable discrepancy of about 120 orders of magnitude between the observed value of dark energy and its natural expectation from quantum [...] Read more.
The cosmological constant (CC, Λ) problem stands as one of the most profound puzzles in the theory of gravity, representing a remarkable discrepancy of about 120 orders of magnitude between the observed value of dark energy and its natural expectation from quantum field theory. This paper synthesizes two innovative paradigms—holographic naturalness (HN) and pre-geometric gravity (PGG)—to propose a unified and natural resolution to the problem. The HN framework posits that the stability of the CC is not a matter of radiative corrections but rather of quantum information and entropy. The large entropy SdSMP2/Λ of the de Sitter (dS) vacuum (with MP being the Planck mass) acts as an entropic barrier, exponentially suppressing any quantum transitions that would otherwise destabilize the vacuum. This explains why the universe remains in a state with high entropy and relatively low CC. We then embed this principle within a pre-geometric theory of gravity, where the spacetime geometry and the Einstein–Hilbert action are not fundamental, but emerge dynamically from the spontaneous symmetry breaking of a larger gauge group, SO(1,4)→SO(1,3), driven by a Higgs-like field ϕA. In this mechanism, both MP and Λ are generated from more fundamental parameters. Crucially, we establish a direct correspondence between the vacuum expectation value (VEV) v of the pre-geometric Higgs field and the de Sitter entropy: SdSv (or v3). Thus, the field responsible for generating spacetime itself also encodes its information content. The smallness of Λ is therefore a direct consequence of the largeness of the entropy SdS, which is itself a manifestation of a large Higgs VEV v. The CC is stable for the same reason a large-entropy state is stable: the decay of such state is exponentially suppressed. Our study shows that new semi-classical quantum gravity effects dynamically generate particles we call “hairons”, whose mass is tied to the CC. These particles interact with Standard Model matter and can form a cold condensate. The instability of the dS space, driven by the time evolution of a quantum condensate, points at a dynamical origin for dark energy. This paper provides a comprehensive framework where the emergence of geometry, the hierarchy of scales and the quantum-information structure of spacetime are inextricably linked, thereby providing a novel and compelling path toward solving the CC problem. Full article
(This article belongs to the Special Issue Beyond the Standard Models of Physics and Cosmology: 2nd Edition)
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34 pages, 10361 KB  
Article
Numerical Study of Heat Transfer Intensification in a Chamber with Heat Generating by Irradiated Gold Nanorods: One-Way Multiphysics and Multiscale Approach
by Paweł Ziółkowski, Piotr Radomski, Aimad Koulali, Dominik Kreft, Jacek Barański and Dariusz Mikielewicz
Energies 2026, 19(1), 181; https://doi.org/10.3390/en19010181 - 29 Dec 2025
Viewed by 186
Abstract
This study evaluates energy conversion and heat transfer in a germicidal chamber employing gold nanorods (AuNRs) irradiated with an infrared laser (808 nm, 0.8 W) to generate heat via localized surface plasmon resonance. The investigation focused on the preliminary selection of chamber materials [...] Read more.
This study evaluates energy conversion and heat transfer in a germicidal chamber employing gold nanorods (AuNRs) irradiated with an infrared laser (808 nm, 0.8 W) to generate heat via localized surface plasmon resonance. The investigation focused on the preliminary selection of chamber materials and the geometry of the bottom surface supporting the AuNRs as the heat source in a photothermoablation application. A one-way multiphysics and multiscale approach was applied, integrating nanoscale heating phenomena with a macroscale fluid and heat flow. The validated 2D numerical model shows satisfactory agreement with experimental data and is suitable for further design analyses. Computational Fluid Dynamics (CFD) simulations were conducted to determine temperature and entropy distributions, mean and maximum temperatures, and Nusselt numbers, allowing the assessment of the energy conversion process under different configurations and AuNR dimensions. The results indicate that a configuration with a gradually descending stepped structure enhances interactions between nanoparticles and the fluid, increasing the internal energy and producing elevated temperatures. Under optimal conditions, a temperature rise of approximately 75 °C was achieved. These findings demonstrate that integrating material selection, surface geometry, and nanoparticle absorbance optimization can significantly improve the efficiency of bacterial inactivation in germicidal chambers. This study provides a framework for future investigations on fully three-dimensional multiscale and multiphysical modeling, as well as a targeted AuNR design to maximize the thermal performance. Full article
(This article belongs to the Special Issue Advances in Heat and Mass Transfer)
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14 pages, 2886 KB  
Article
First-Principle Study of AlCoCrFeNi High-Entropy Alloys
by Andi Huang, Yilong Liu, Jinghao Huang, Jingang Liu and Shiping Yang
Nanomaterials 2026, 16(1), 20; https://doi.org/10.3390/nano16010020 - 23 Dec 2025
Viewed by 352
Abstract
AlCoCrFeNi high-entropy alloys (HEAs) are promising materials due to their exceptional mechanical properties and thermal stability. This study employs first-principles calculations based on density functional theory (DFT) to investigate the phase stability and electronic properties of AlCoCrFeNi HEA. The atomic size difference ( [...] Read more.
AlCoCrFeNi high-entropy alloys (HEAs) are promising materials due to their exceptional mechanical properties and thermal stability. This study employs first-principles calculations based on density functional theory (DFT) to investigate the phase stability and electronic properties of AlCoCrFeNi HEA. The atomic size difference (δ) was determined to be 5.44%, while the mixing enthalpy (ΔHmix) was found to be −14.24 kJ/mol, and the valence electron concentration (VEC) was measured at 7.2, indicating a dual-phase structure consisting of the BCC and B2 phases. The formation energies indicated that the BCC phase exhibits the highest stability under typical conditions. The elastic properties were assessed, revealing Young’s modulus of 250 GPa, a shear modulus of 100 GPa, and a bulk modulus of 169 GPa, which suggest high stiffness. The alloy demonstrated a Poisson’s ratio of 0.25 and a G/B ratio of 0.59, indicating relatively brittle behavior. Microhardness simulations predicted a value of 604 HV0.2, which closely aligns with experimental measurements of 602 HV0.2 at 1300 W laser power, 532 HV0.2 at 1450 W, and 544 HV0.2 at 1600 W. The electronic structure analysis revealed metallic behavior, with the d-orbitals of Co, Fe, and Ni contributing significantly to the electronic states near the Fermi level. These findings offer valuable insights into the phase behavior and mechanical properties of AlCoCrFeNi HEA, which are crucial for the design of high-performance materials suitable for extreme engineering applications. Full article
(This article belongs to the Special Issue Nano-Based Advanced Thermoelectric Design: 2nd Edition)
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25 pages, 3370 KB  
Article
A SimAM-Enhanced Multi-Resolution CNN with BiGRU for EEG Emotion Recognition: 4D-MRSimNet
by Yutao Huang and Jijie Deng
Electronics 2026, 15(1), 39; https://doi.org/10.3390/electronics15010039 - 22 Dec 2025
Viewed by 181
Abstract
This study proposes 4D-MRSimNet, a framework that employs attention mechanisms to focus on distinct dimensions. The approach applies enhancements to key responses in the spatial and spectral domains and provides a characterization of dynamic evolution in temporal domain, which extracts and integrates complementary [...] Read more.
This study proposes 4D-MRSimNet, a framework that employs attention mechanisms to focus on distinct dimensions. The approach applies enhancements to key responses in the spatial and spectral domains and provides a characterization of dynamic evolution in temporal domain, which extracts and integrates complementary emotional features to facilitate final classification. At the feature level, differential entropy (DE) and power spectral density (PSD) are combined within four core frequency bands (θ, α, β, and γ). These bands are recognized as closely related to emotional processing. This integration constructs a complementary feature representation that preserves both energy distribution and entropy variability. These features are organized into a 4D representation that integrates electrode topology, frequency characteristics, and temporal dependencies inherent in EEG signals. At the network level, a multi-resolution convolutional module embedded with SimAM attention extracts spatial and spectral features at different scales and adaptively emphasizes key information. A bidirectional GRU (BiGRU) integrated with temporal attention further emphasizes critical time segments and strengthens the modeling of temporal dependencies. Experiments show that our method achieves an accuracy of 97.68% for valence and 97.61% for arousal on the DEAP dataset and 99.60% for valence and 99.46% for arousal on the DREAMER dataset. The results demonstrate the effectiveness of complementary feature fusion, multidimensional feature representation, and the complementary dual attention enhancement strategy for EEG emotion recognition. Full article
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20 pages, 2800 KB  
Article
A High-Ratio Renewable-Energy Power System Time–Frequency Domain-Cooperative Harmonic Detection Method Based on Enhanced Variational Modal Decomposition and the Prony Algorithm
by Yao Zhong, Guangrun Yang, Jiaqi Qi, Cheng Guo, Dongyan Chen and Qihao Jin
Symmetry 2026, 18(1), 13; https://doi.org/10.3390/sym18010013 - 20 Dec 2025
Viewed by 237
Abstract
Accurate identification of harmonic components is a prerequisite for addressing resonance risks in new energy power stations. Traditional Variational Modal decomposition (VMD) is susceptible to the influence of the modal decomposition order K and the penalty factor α when decomposing harmonic signals. This [...] Read more.
Accurate identification of harmonic components is a prerequisite for addressing resonance risks in new energy power stations. Traditional Variational Modal decomposition (VMD) is susceptible to the influence of the modal decomposition order K and the penalty factor α when decomposing harmonic signals. This paper proposes an adaptive parameter selection method for VMD based on an improved Triangular Topology Aggregation Optimization (TTAO) algorithm. Firstly, the pre-set parameters of variational modal decomposition—modal order K and penalty factor α—exhibit strong coupling. Conventional optimization algorithms cannot effectively coordinate adjustments to both parameters. This paper employs an enhanced TTAO algorithm, whose triangular topology unit structure and dual aggregation mechanism enable simultaneous adjustment of modal order K and penalty factor α, effectively resolving their coupled optimization challenge. Using minimum envelope entropy as the fitness function, the algorithm obtains an optimized parameter combination for VMD to decompose the signal. Subsequently, dominant modal components are selected based on Pearson’s correlation coefficients for reconstruction, with harmonic parameters precisely identified using the Prony algorithm. Simulation results demonstrate that under a 20 dB noise environment, the proposed method achieves a signal-to-noise ratio (SNR) of 25.6952 for steady-state harmonics, with a root mean square error (RMSE) of 0.4889. The mean errors for frequency and amplitude identification are 0.055% and 3.085%, respectively, significantly outperforming methods such as PSO-VMD and EMD. Moreover, the runtime of our model is markedly shorter than that of the PSO-VMD algorithm, effectively resolving the symmetric trade-off between recognition accuracy and runtime inherent in variational modal decomposition. Full article
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30 pages, 6264 KB  
Article
An Efficient Image Encryption Scheme Based on DNA Mutations and Compression Sensing
by Jianhua Qiu, Shenli Zhu, Yu Liu, Xize Luo, Dongxin Liu, Hui Zhou, Congxu Zhu and Zheng Qin
Mathematics 2026, 14(1), 5; https://doi.org/10.3390/math14010005 - 19 Dec 2025
Viewed by 229
Abstract
In communication environments with limited computing resources, securely and efficiently transmitting image data has become a challenging problem. However, most existing image data protection schemes are based on high-dimensional chaotic systems as key generators, which suffer from issues such as high algorithmic complexity [...] Read more.
In communication environments with limited computing resources, securely and efficiently transmitting image data has become a challenging problem. However, most existing image data protection schemes are based on high-dimensional chaotic systems as key generators, which suffer from issues such as high algorithmic complexity and large computational overhead. To address this, this paper presents new designs for a 1D Sine Fractional Chaotic Map (1D-SFCM) as a random sequence generator and provides mathematical proofs related to the boundedness and fixed points of this model. Furthermore, this paper improves the traditional 2D compressive sensing (2DCS) algorithm by using the newly designed 1D-SFCM map to generate a chaotic measurement matrix, which can effectively enhance the quality of image recovery and reconstruction. Moreover, referring to the principle of gene mutation in biogenetics, this paper designs an image encryption algorithm based on DNA base substitution. Finally, the security of the proposed encryption scheme and the quality of image compression and reconstruction are verified through indicators such as key space, information entropy, and Number of Pixel Change Rate (NPCR). Full article
(This article belongs to the Special Issue Chaotic Systems and Their Applications, 2nd Edition)
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20 pages, 3069 KB  
Article
Spatiotemporal Dynamics and Drivers of Shipping Service Industry Agglomeration and Port–City Synergy: Evidence from Jiangsu Province, China
by Tong Zhang, Linan Du, Husong Xing, Jimeng Tang and Cunrui Ma
Sustainability 2025, 17(24), 11366; https://doi.org/10.3390/su172411366 - 18 Dec 2025
Viewed by 294
Abstract
The shipping service industry plays a pivotal role in enhancing port competitiveness and fostering urban economic growth, yet limited studies systematically integrate its spatial temporal dynamics with the processes driving port–city synergy. This study constructs a three-dimensional analytical framework encompassing port operations, urban [...] Read more.
The shipping service industry plays a pivotal role in enhancing port competitiveness and fostering urban economic growth, yet limited studies systematically integrate its spatial temporal dynamics with the processes driving port–city synergy. This study constructs a three-dimensional analytical framework encompassing port operations, urban economic development, and shipping service industry agglomeration. Using data from 13 port cities in Jiangsu Province (2015–2023), we apply the entropy weight method, coupling coordination degree model, relative development model, and panel Tobit regression to evaluate interaction intensity, coordination patterns, and influencing factors. Results reveal a clear spatial gradient in coupling coordination, higher in southern Jiangsu and lower in the north, driven by disparities in economic foundations, port capacities, and service industry structures. In most cities, port operations and urban economies lag behind shipping service industry agglomeration, reflecting the predominance of low- and mid-end services. Port construction level, cargo and container throughput, economic development, openness, fixed asset investment, and population density significantly promote coordination, whereas R&D capacity shows no significant effect. The findings advance understanding of port–city service interlinkages and provide targeted policy recommendations for differentiated regional development, infrastructure enhancement, and upgrading toward high-end shipping services, with implications for maritime regions worldwide. Full article
(This article belongs to the Special Issue Advanced Studies in Sustainable Urban Planning and Urban Development)
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18 pages, 3879 KB  
Article
Exploring Dacarbazine Complexation with a Cellobiose-Based Carrier: A Multimethod Theoretical, NMR, and Thermochemical Study
by Marta Hoelm, Zdzisław Kinart and Stanisław Porwański
Molecules 2025, 30(24), 4819; https://doi.org/10.3390/molecules30244819 - 18 Dec 2025
Viewed by 293
Abstract
Dacarbazine (DTIC) is a clinically important anticancer drug whose photosensitivity poses challenges for its stability and interactions with supramolecular hosts. Here, we investigate its complexation with the host 1,10-N,N′-bis-(β-D-ureidocellobiosyl)-4,7,13,16-tetraoxa-1,10-diazacyclooctadecane (TN), a hybrid urea–carbohydrate–diazacrown system, using combined experimental and computational approaches. While [...] Read more.
Dacarbazine (DTIC) is a clinically important anticancer drug whose photosensitivity poses challenges for its stability and interactions with supramolecular hosts. Here, we investigate its complexation with the host 1,10-N,N′-bis-(β-D-ureidocellobiosyl)-4,7,13,16-tetraoxa-1,10-diazacyclooctadecane (TN), a hybrid urea–carbohydrate–diazacrown system, using combined experimental and computational approaches. While TN has been studied as a host molecule, its specific interactions with DTIC and the associated thermodynamic characteristics had not been characterized. Computational results (obtained at the density functional theory level (DFT)) indicate that TN primarily forms non-inclusion complexes, with DTIC engaging in hydrogen bonding with sugar units, urea bridges, and diazacrown ether moieties. Experimental 1H NMR studies in D2O confirmed these interaction patterns, showing notable chemical shifts for sugar protons. Conductometric measurements between 293 and 313 K allowed for the determination of formation constants and thermodynamic parameters. The results demonstrate that TN:DTIC complexation is spontaneous, exothermic, and enthalpy-driven, accompanied by decreased system entropy. Comparison with previous studies on cyclodextrin complexes shows that TN forms strong associations with DTIC, owing to its abundant donor–acceptor groups, which facilitate extensive hydrogen-bonding networks. These findings provide new insights into DTIC stabilization and highlight TN’s potential as a multifunctional platform for drug delivery. Full article
(This article belongs to the Special Issue Alternative Routes for the Delivery of Drug Molecules)
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