Search Results (16)

Traditional β-eucryptite (LiAlSiO₄) is renowned for its unique characteristics of low thermal expansion and high temperature thermal stability, making it an ideal material for precision instruments and aerospace applications. In this study, β-eucryptite was fabricated into an aerogel structure through the sol–gel process and supercritical drying method and using alumina sol as a cost-effective precursor. The synthesized β-eucryptite aerogel demonstrated unique properties including a negative thermal expansion coefficient (−7.85 × 10⁻⁶ K⁻¹), low density (0.60 g/cm³), and high specific surface area (18.1 m²/g). X-ray diffraction (XRD) and transmission electron microscopy (TEM) mutually corroborated the crystalline structure of β-eucryptite, with XRD confirming the phase purity and TEM imaging revealing well-defined crystal lattice characteristics. Combined nitrogen adsorption–desorption analysis and scanning electron microscopy observations supported the hierarchical porous microstructure, with SEM visualizing interconnected nanoporous networks and nitrogen sorption data verifying the porosity. The negative thermal expansion behavior was directly linked to the β-eucryptite crystal structure, as collectively validated by thermal expansion measurements. Additionally, Fourier transform infrared spectroscopy (FTIR) independently confirmed the aluminosilicate framework structure through characteristic vibrational modes. This research shows the innovation in the synthesis of β-eucryptite aerogel, especially its application potential in precision instruments and building materials that need low thermal expansion and high stability, and the use of aluminum sol as an aluminum source has simplified the preparation steps and reduced production costs. Full article

The stability of contemporary ice shelves is under threat due to global warming, and the geological records in the Ross Sea offer such an opportunity to test the linkage between them. However, the absence of calcareous microfossils in the sediments of the Ross Sea results in uncertainties in establishing a precise chronology for studies. Hence, three sediment cores were collected and studied in terms of radiocarbon dating, magnetic susceptibility, and sediment grain size to reconstruct the environmental processes in the Ross Sea since the last glacial period. The main results are as follows: (1) two grain-size components were identified for the studied cores, which can be correlated to ice-shelf and sea-ice transport, respectively; (2) due to old-carbon contamination and an inconsistent carbon reservoir, the radiocarbon dates were generally underestimated, and as an alternative, changes in magnetic susceptibility of the studied cores can be tuned to the ice-core records to establish a reliable age–depth model and; (3) integrating sediment grain-size changes and comparisons with other paleoenvironmental proxies in the Antarctic, a process from a sub-ice sheet in the last glacial period to a sub-ice shelf in the glacial maximum, and, finally, to a glaciomarine state since the last deglacial period was identified in the western Ross Sea. Integrating these findings, the warming processes in the Antarctic were highlighted in the retreat processes of the Ross Ice Shelf in the past. Full article

In this study, we investigate the sensitivity properties of YBa₂Cu₃O_7-δ thin films with a 15° tilting angle in relation to heat flux density. The films were prepared using the laser pulsed deposition (PLD) technique, and their characteristics were evaluated using various techniques, including X-ray diffraction (XRD), transmission electron microscopy (TEM), atomic force microscopy (AFM), and infrared steady-state and laser transient calibration systems. The YBa₂Cu₃O_7-δ films prepared in this study were found to be of good quality, exhibiting a single-phase structure with strict (001) orientation. Both the substrate and film diffraction peaks were sharp and consistent with the step-flow growth mode, indicating high crystalline quality. Ultra-high sensitivity in the range of 0 to 100 kW/m², the maximum sensitivity is 230 μV/(kW/m²), and an uncertainty is only 3%. According to the infrared steady-state heat flux calibration system test, when the single output power of the quartz lamp array is 0.2 kW, 0.3 kW, 0.4 kW and 0.5 kW, the maximum output voltage is 0.19 mV, 0.41 mV, 0.63 mV and 0.94 mV, respectively, indicating that the output voltage of the sensor increases with the increase in heat flux, showing a good linear characteristic, and the fitting linearity is 0.99. Through the test of the laser transient thermal current calibration system, the sensors are found to have excellent response–recovery characteristics at 500 kHz and 1000 kHz fiber laser frequencies, and the maximum voltage output is 8.83 mV and 9.09 mV, respectively. Moreover, the component has excellent repeatability, and the maximum measurement error is only 1.94%. Our findings demonstrate the potential of YBa₂Cu₃O_7-δ thin films for use in heat flux sensing applications. Full article

In order to improve the tool life and micro-hole machining quality, the H-shaped chisel edge micro-drill (HCE-MD) was developed in this paper. The HCE-MD was characterized by the inner edge formed through the chisel edge thinning. In the micro-drilling process, the inner edge can perform positive rake cutting, so the machining area of the workpiece extruded by cutting edge with a negative rake angle is reduced. Based on this, the distribution of rake angle near the chisel edge corner is improved. Then, the HCE-MD was fabricated on the six-axis CNC grinding machine. The grinding process parameters of the micro-drill were optimized based on the orthogonal grinding test and grey relational grade theory. The size and shape accuracy of the micro-drill were controlled by the multi-axis linkage grinding method and the movement-axis micro compensation method. Finally, the 0.25 mm HCE-MD was fabricated with the cutting edge radius of 1.94 μm and the flank surface roughness of 0.25 μm. The drilling performance of HCE-MD was evaluated through comparative drilling experiments. The experimental results show that, compared with common micro drill, the HCE-MD produced lower thrust force and better micro-hole roundness accuracy, and reduced the micro-drill wear on the chisel edge and the flank. Full article

In recent years, shield tunneling has shown many advantages with the development of underground rail traffic. Geological exploration plays a significant role in tunnel engineering, and detailed geological exploration results can guide the successful construction of a tunnel. This research relies on a super large-diameter shield tunnel construction, using microtremor exploration technology to collect data onsite. Combined with a comparative analysis of the borehole surveying, the reliability of microtremor exploration technology is verified. Moreover, the monitoring result of the impact of large-diameter slurry balanced shield construction on the surrounding environment is analyzed. The results show that microtremor exploration can obtain geological details that traditional detection methods cannot obtain, which can predict the possible local geology mutation in front of the tunnel in advance. The law of surface settlement curve conforms to the Peck formula. This can be divided into five stages: micro deformation, extrusion uplift, reciprocating uplift, detachment settlement, and consolidation settlement. The surface settlement on the eccentric loads side is more prominent. The maximum pressure outside the tunnel segment appears on the lower side of the monitoring section, approximately 0.41 MPa, which will increase with the grouting pressure and become stable in five days. Full article

Carbon aerogel (CA) based materials have multiple advantages, including high porosity, tunable molecular structures, and environmental compatibility. Increasing interest, which has focused on CAs as electrocatalysts for sustainable applications including oxygen reduction reaction (ORR), oxygen evolution reaction (OER), hydrogen evolution reaction (HER), and CO₂ reduction reaction (CO₂RR) has recently been raised. However, a systematic review covering the most recent progress to boost CA-based electrocatalysts for ORR/OER/HER/CO₂RR is now absent. To eliminate the gap, this critical review provides a timely and comprehensive summarization of the applications, synthesis methods, and principles. Furthermore, prospects for emerging synthesis, screening, and construction methods are outlined. Full article

Bio-based polyimide (PI)/halloysite nanotube (HNT) nanocomposites based on 2,5-furandicarboxylic acid were prepared by in situ polymerization. The pristine HNTs were modified by tetraethoxysilane (TEOS) and 4,4′-oxybisbenzenamine (ODA). The bio-based PI/HNT nanocomposite film exhibited lower moisture absorption than pure bio-based polyimide, showing that the water resistance of the bio-based polyimide film was improved. The thermal stability and glass transition temperature (Tg) of PI/HNTs nanocomposites were improved with the addition of modified HNTs. Both the tensile strength and Young’s modulus of bio-based PI/HNTs nanocomposite films were enhanced. A 37.7% increase in tensile strength and a 75.1% increase in Young’s modulus of bio-based PI/HNTs nanocomposite films, with 1 wt% of the modified HNTs, were achieved. The result confirmed that 2,5-furandicarboxylic acid could replace the oil-based material effectively, thus reducing pollution and protecting the environment. Finally, a preparation mechanism to prepare bio-based PI/HNTs nanocomposite is proposed. Full article

Low-cost urea formaldehyde resin (UF)/reactive halloysite nanotubes (HNTs) nanocomposite adhesive was prepared successfully via in situ polymerization. The HNTs were modified to improve its compatibility with polymer. The XRD and FTIR results showed that physical and chemical interaction between the HNTs and polymer resin influenced the structure of UF owing to the functional groups on the HNTs. It is found from SEM images that the modified HNTs could be dispersed uniformly in the resin and the nanocomposite particles were spherical. The performance experiment confirmed that thermal stability of nanocomposite increased largely, formaldehyde emission of UF wood adhesive reduced 62%, and water resistance of UF wood adhesive improved by 84%. Meanwhile, the content of HNTs on the nanocomposites could be up to 60 wt %. The mechanism of the nanocomposites based on the reactive HNTs was proposed. The approach of the preparation could supply an idea to prepare other polymer/clay nanocomposites. Full article

The variability of the winter monsoon is one of the key components of the Asian monsoon, significantly influencing paleoenvironmental evolution in East Asia. However, whether the winter or the summer monsoon is the dominated factor controlling sedimentary dynamics of the muddy areas of the continental shelves of the East China Sea is debated, due to lack of consistency between various winter monsoon proxies in previous studies. In this work, the sediments of the upper part of core ECS-DZ1 with several marine surface samples were studied in terms of sediment grain size and radiocarbon dating, and changes in sedimentary dynamics of the northern muddy area of the ECS over the past 5000 years were documented. The main findings are as follows: (1) regional sedimentary dynamics were low and did not significantly change since the middle Holocene; (2) coarse particles are the dominated component in the sediments; (3) a proxy can be derived to indicate changes in winter monsoon. Based on this reconstructed winter monsoon record, we found that this record was generally negatively correlated to the stalagmite-based summer monsoon variability over the past 3500 years, but positively correlated before that. Moreover, this record can be well correlated to changes in the Kuroshio Current and the Bond ice-rafting debris events in the North Atlantic on millennial timescales, inferring large-scale and common atmospheric dynamics across the Asian continent over the past 5000 years. Therefore, we concluded that the winter monsoon is the predominant factor controlling sedimentary dynamics in the northern part of the ECS and proposed that the contribution of coarse particles may be one of potential indices to identify the role of the winter and the summer monsoons in sedimentary evolution. Full article

In this work, thermo-optic (TO) lateral shift apodized sampled waveguide grating for 1550 nm wavelength is designed and fabricated by the metal-printing technique based on fluorinated epoxy-terminated polycarbonates (FBPA-PC EP) and fluorinated epoxy resin (FSU-8) materials. The optical characteristics and thermal stability of the FBPA-PC EP and FSU-8 materials are analyzed. To realize periodic wide-spectrum filtering and suppress the side-lobes of grating, a lateral shift apodized sampled waveguide grating is proposed. The 3 dB bandwidth and wavelength spacing can reach 4.8 nm and 9.7 nm. The side-lobe suppression ratio of proposed device can reach 22.6 dB, which is much better than traditional Bragg grating (6.1 dB). Driving electrical powers of 42.4 mW and 87.2 mW can produce blueshifts of 1.8 nm and 3.5 nm in the measured reflection spectrum, respectively. This device realizes the aim of multiple functions, including periodic filtering, wide-spectrum filtering, and high side-lobe suppression. The device is applicable of realizing signal processing and wavelength division multiplexing (WDM )systems. Full article

In this paper, we present and analyze a compact inner-wall grating slot microring resonator (IG-SMRR) with the footprint of less than 13 μm × 13 μm on the silicon-on-insulator (SOI) platform for label-free sensing, which comprises a slot microring resonator (SMRR) and inner-wall grating (IG). Its detection range is significantly enhanced without the limitation of the free spectral region (FSR) owing to the combination of SMRR and IG. The IG-SMRR has an ultra-large quasi-FSR of 84.5 nm as the detection range, and enlarged factor is up to over 3 compared with the conventional SMRR. The concentration sensitivities of sodium chloride solutions and D-glucose solutions are 996.91 pm/% and 968.05 pm/%, respectively, and the corresponding refractive index (RI) sensitivities are 559.5 nm/RIU (refractive index unit) and 558.3 nm/RIU, respectively. The investigation on the combination of SMRR and IG is a valuable exploration of label-free sensing application for ultra-large detection range and ultra-high sensitivity in future. Full article

Surface plasmon resonances of a Au ring-strip nanosystem with tunable multipolar Fano resonances have been investigated based on the finite-difference time-domain (FDTD) method. Abundant plasmon properties of a Au ring-strip nanosystem can be obtained on the basis of the unique electronic properties of different geometry parameters. In our research models, these multipolar Fano resonances are induced and can be tuned independently by changing the geometry parameters of the Au ring-strip nanosystem. Complex electric field distributions excited by the Au ring-strip nanosystem provide possibility to form dark plasmonic modes. Multipolar Fano resonances display strong light extinction in the Au ring-strip nanosystem, which can offer a new approach for an optical tunable filter, optical switching, and advanced biosensing. Full article

In this paper, we come up with a wavelength tunable absorber which is made up of periodically elliptical graphene arrays in the far-infrared and terahertz regions. Through simulation, we find that we can increase the length of long axis of the ellipse, raise the incidence angles of TM- and TE-polarization (TM- and TE-polarization indicate the direction of the incident electric field along the direction of the x and the y axis, respectively.) within certain limits, and increase the chemical potential of graphene, so as to enhance the absorption of light in the elliptical graphene arrays. We also compare the absorption spectra of the original structure and the complementary structure, and find that the absorption of the original structure is higher than that of the complementary structure. In the end, we study the changes in the absorption rate of the double layer structure of the elliptical array with the increase in the thickness of SiO₂. The elliptical array structure can be applied to tunable spectral detectors, filters and sensors at far-infrared and terahertz wavelengths. Full article

This work was inspired by previous experiments which managed to establish an optimal template-dealloying route to prepare ultralow density metal foams. In this study, we propose a new analytical–numerical model of hollow-structured metal foams with structural hierarchy to predict its stiffness and strength. The two-level model comprises a main backbone and a secondary nanoporous structure. The main backbone is composed of hollow sphere-packing architecture, while the secondary one is constructed of a bicontinuous nanoporous network proposed to describe the nanoscale interactions in the shell. Firstly, two nanoporous models with different geometries are generated by Voronoi tessellation, then the scaling laws of the mechanical properties are determined as a function of relative density by finite volume simulation. Furthermore, the scaling laws are applied to identify the uniaxial compression behavior of metal foams. It is shown that the thickness and relative density highly influence the Young’s modulus and yield strength, and vacancy defect determines the foams being self-supported. The present study provides not only new insights into the mechanical behaviors of both nanoporous metals and metal foams, but also a practical guide for their fabrication and application. Full article