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Authors = Md. Ashraful Hoque

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42 pages, 1598 KB  
Review
Nanoscale Characterization of Nanomaterial-Based Systems: Mechanisms, Experimental Methods, and Challenges in Probing Corrosion, Mechanical, and Tribological Properties
by Md Ashraful Hoque and Chun-Wei Yao
Nanomaterials 2025, 15(23), 1824; https://doi.org/10.3390/nano15231824 - 2 Dec 2025
Cited by 4 | Viewed by 1778
Abstract
Nanomaterial-based systems (NBS) have emerged as transformative elements in advanced surface engineering, offering superior corrosion resistance, mechanical strength, and tribological resilience governed by unique phenomena inherent to the nanoscale. However, bridging the knowledge gap between these enhanced physicochemical properties and the metrological tools [...] Read more.
Nanomaterial-based systems (NBS) have emerged as transformative elements in advanced surface engineering, offering superior corrosion resistance, mechanical strength, and tribological resilience governed by unique phenomena inherent to the nanoscale. However, bridging the knowledge gap between these enhanced physicochemical properties and the metrological tools required to quantify them remains a critical challenge. This review provides a comprehensive examination of the fundamental mechanisms, state-of-the-art experimental techniques, and computational strategies employed to probe NBS behavior. The article first elucidates the core mechanisms driving performance, including passive barrier formation, stimuli-responsive active corrosion inhibition, grain boundary strengthening, and the formation of protective tribo-films by 2D nanomaterial-based systems. Subsequently, the article evaluates the transition from conventional macroscopic testing to high-resolution in situ characterization, highlighting the capabilities of High-Speed Atomic Force Microscopy (HS-AFM), Liquid Cell Transmission Electron Microscopy (LC-TEM), and nanoindentation in visualizing dynamic defect evolution and measuring localized mechanical responses. Furthermore, the indispensable role of computational materials science—specifically Molecular Dynamics (MD) and Machine Learning (ML)—in predictive modeling and elucidating atomic-scale interactions is discussed. Finally, persistent challenges regarding substrate interference, sample heterogeneity, and instrumentation limits are addressed, concluding with a perspective on future research directions focused on standardization, operando testing, and the development of AI-driven “Digital Twins” for accelerated testing and material optimization. Full article
(This article belongs to the Section Nanocomposite Materials)
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10 pages, 2782 KB  
Article
Corrosion Resistance and Nano-Mechanical Properties of a Superhydrophobic Surface
by Chun-Wei Yao, Ian Lian, Jiang Zhou, Paul Bernazzani, Mien Jao and Md Ashraful Hoque
Lubricants 2025, 13(1), 16; https://doi.org/10.3390/lubricants13010016 - 3 Jan 2025
Cited by 2 | Viewed by 2271
Abstract
Nanoindentation has been used to characterize the mechanical and creep properties of various materials. However, research on the viscoelastic and creep properties of superhydrophobic surfaces remains limited. In this study, a superhydrophobic coating was developed and its corrosion resistance was evaluated initially. Electrochemical [...] Read more.
Nanoindentation has been used to characterize the mechanical and creep properties of various materials. However, research on the viscoelastic and creep properties of superhydrophobic surfaces remains limited. In this study, a superhydrophobic coating was developed and its corrosion resistance was evaluated initially. Electrochemical impedance spectroscopy (EIS) results quantitatively confirm the enhanced anti-corrosion performance of the superhydrophobic coating. Subsequently, this study investigates the creep, hardness, strain rate sensitivity, and viscoelastic behavior of the superhydrophobic surface at the nanoscale before and after accelerated corrosion exposure. Our findings reveal that during the creep tests, the logarithmic values of creep strain rate and stress exhibited a good linear relationship. Additionally, the surface retains its key viscoelastic properties (hardness, storage modulus, loss modulus, and tan δ) even after exposure to corrosion. These results highlight the surface’s robustness under corrosive conditions, a crucial factor for applications requiring both mechanical integrity and environmental resilience. Full article
(This article belongs to the Special Issue Mechanical Tribology and Surface Technology)
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24 pages, 4208 KB  
Review
Tribocorrosion Behavior of Micro/Nanoscale Surface Coatings
by Md Ashraful Hoque, Chun-Wei Yao, Mukunda Khanal and Ian Lian
Sensors 2022, 22(24), 9974; https://doi.org/10.3390/s22249974 - 17 Dec 2022
Cited by 22 | Viewed by 6139
Abstract
Wear and corrosion are common issues of material degradation and failure in industrial appliances. Wear is a damaging process that can impact surface contacts and, more specifically, can cause the loss and distortion of material from a surface because of the contacting object’s [...] Read more.
Wear and corrosion are common issues of material degradation and failure in industrial appliances. Wear is a damaging process that can impact surface contacts and, more specifically, can cause the loss and distortion of material from a surface because of the contacting object’s mechanical action via motion. More wear occurs during the process of corrosion, in which oxide particles or debris are released from the contacting material. These types of wear debris and accumulated oxide particles released during corrosion cause a combination of wear-corrosion processes. Bringing together the fields of tribology and corrosion research, tribocorrosion is a field of study which deals with mechanical and electrochemical interactions between bodies in motion. More specifically, it is the study of mechanisms caused by the combined effects of mechanical stress and chemical/electrochemical interactions with the environment. Tribocorrosion testing methods provide new opportunities for studying the electrochemical nature of corrosion combined with mechanical loading to establish a synergistic relationship between corrosion and wear. To improve tribological, mechanical, and anti-corrosion performances, several surface modification techniques are being applied to develop functional coatings with micro/nano features. This review of the literature explores recent and enlightening research into the tribocorrosive properties of micro/nano coatings. It also looks at recent discussions of the most common experimental methods and some newer, promising experimental methods in tribocorrosion to elucidate their applications in the field of micro/nano coatings. Full article
(This article belongs to the Section Nanosensors)
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33 pages, 3966 KB  
Review
Tissue Culture in Ornamentals: Cultivation Factors, Propagation Techniques, and Its Application
by Hasan Mehbub, Ayasha Akter, Mst. Arjina Akter, Mohammad Shamim Hasan Mandal, Md. Ashraful Hoque, Monika Tuleja and Hasan Mehraj
Plants 2022, 11(23), 3208; https://doi.org/10.3390/plants11233208 - 23 Nov 2022
Cited by 71 | Viewed by 29495
Abstract
Ornamentals come in a variety of shapes, sizes, and colors to suit a wide range of climates, landscapes, and gardening needs. Compared to demand, a shortage of plant materials and diversity force the search for solutions for their constant acquisition and improvement to [...] Read more.
Ornamentals come in a variety of shapes, sizes, and colors to suit a wide range of climates, landscapes, and gardening needs. Compared to demand, a shortage of plant materials and diversity force the search for solutions for their constant acquisition and improvement to increase their commercial value, respectively. In vitro cultures are a suitable solution to meet expectations using callus culture, somatic embryogenesis, protoplast culture, and the organogenesis of protocorm-like bodies; many of these techniques are commercially practiced. Factors such as culture media, explants, carbohydrates, plant growth regulators, and light are associated with the success of in vitro propagation. Techniques, especially embryo rescue and somatic hybridization, are widely used to improve ornamentals. The development of synthetic seed allows season-independent seed production and preservation in the long term. Despite the advantages of propagation and the improvement of ornamentals, many barriers still need to be resolved. In contrast to propagation and crop developmental studies, there is also a high scope for molecular studies, especially epigenetic changes caused by plant tissue culture of ornamentals. In this review, we have accumulated and discussed an overall update on cultivation factors, propagation techniques in ornamental plant tissue culture, in vitro plant improvement techniques, and future perspectives. Full article
(This article belongs to the Special Issue New Insight into Research in In Vitro Plants Propagation)
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21 pages, 1338 KB  
Article
Knowledge, Attitude, and Practices on Antimicrobial Use and Antimicrobial Resistance among Commercial Poultry Farmers in Bangladesh
by Mohammad Mahmudul Hassan, Md. Abul Kalam, Md. Abdul Alim, Shahanaj Shano, Md. Raihan Khan Nayem, Md. Rahim Badsha, Md. Abdullah Al Mamun, Ashraful Hoque, Abu Zubayer Tanzin, Chandan Nath, Hamida Khanom, Shahneaz Ali Khan, Md. Mazharul Islam, Md Bashir Uddin and Ariful Islam
Antibiotics 2021, 10(7), 784; https://doi.org/10.3390/antibiotics10070784 - 28 Jun 2021
Cited by 77 | Viewed by 12620
Abstract
Antimicrobial resistance (AMR) has become an emerging health issue globally, posing a threat to zoonotic pathogens and foodborne diseases. In Bangladesh, the poultry sector supplies the majority of the demand for animal-source protein. The irrational and excessive use of antimicrobials (AMU) has been [...] Read more.
Antimicrobial resistance (AMR) has become an emerging health issue globally, posing a threat to zoonotic pathogens and foodborne diseases. In Bangladesh, the poultry sector supplies the majority of the demand for animal-source protein. The irrational and excessive use of antimicrobials (AMU) has been observed in the poultry sector. The development of AMR is associated with many factors, including the knowledge and attitudes of poultry farmers. Therefore, AMR reduction requires intervention from all the stockholders, including the farmers who are considered as end users of antimicrobials. This current research conducted a cross-sectional study to assess the knowledge, attitudes, and practices (KAP) of poultry farmers on AMU and AMR in Bangladesh. We determined the KAP of poultry farmers (broiler and layer farmers) of some selected districts of the country using a tested and paper-based questionnaire. The results demonstrated that most of the respondents have insufficient KAP regarding AMU and AMR. The respondents used a variety of antimicrobials primarily in the treatment of various diseases in poultry. One-third of the farmers did not seek antimicrobials from registered vets. Instead, they depended on others or themselves. The factor score analysis further revealed that the farmers’ demographic and socioeconomic variables were significant factors influencing the KAP. An adjusted logistic regression analysis showed that older farmers with 9–12 years of farming experience and graduate-level education, engaging in medium-sized layer farming, were more likely to have correct KAP on AMU and AMR. Further, farmers from the Cox’s Bazar region showed correct knowledge, whereas farmers of the Chattogram region showed a correct attitude towards AMU and AMR. A Spearman’s rank-order correlation revealed a positive association between knowledge–attitudes and knowledge–practices. The findings of the current investigation provide baseline evidence about the KAP of poultry farmers from low-income resources and offer insights into designing interventions and policies for the use of AMU and AMR in Bangladesh. Full article
(This article belongs to the Special Issue Antimicrobial Resistance: From Farm to Fork)
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14 pages, 2343 KB  
Article
Knowledge, Attitude, and Practices on Antimicrobial Use and Antimicrobial Resistance among Poultry Drug and Feed Sellers in Bangladesh
by Md. Abul Kalam, Md. Abdul Alim, Shahanaj Shano, Md. Raihan Khan Nayem, Md. Rahim Badsha, Md. Abdullah Al Mamun, Ashraful Hoque, Abu Zubayer Tanzin, Shahneaz Ali Khan, Ariful Islam, Md. Mazharul Islam and Mohammad Mahmudul Hassan
Vet. Sci. 2021, 8(6), 111; https://doi.org/10.3390/vetsci8060111 - 15 Jun 2021
Cited by 31 | Viewed by 9348
Abstract
Poultry production has boomed in Bangladesh in recent years. The poultry sector has contributed significantly to meet the increased demand for animal source proteins in the country. However, increased use of antimicrobials appeared to be a significant threat to food safety in the [...] Read more.
Poultry production has boomed in Bangladesh in recent years. The poultry sector has contributed significantly to meet the increased demand for animal source proteins in the country. However, increased use of antimicrobials appeared to be a significant threat to food safety in the poultry sector. The poultry drug and feed sellers are at the frontline position involving selecting and delivering the antimicrobials to the poultry farmers. Studies assessing the poultry drug and feed sellers’ knowledge, attitudes, and practices (KAPs) are limited. The current study aimed to assess the community poultry drug and feed sellers’ KAPs of antimicrobial use (AMU) and antimicrobial resistance (AMR) in some selected areas of Bangladesh. We determined the respondents’ (drug and the feed sellers) KAPs of AMU and AMR using a tested and paper-based questionnaire. The study demonstrated that most respondents have insufficient knowledge, less positive attitudes, and inappropriate practices regarding AMU and AMR. The factor score analysis further showed that the type of respondents and their years of experience, level of education, and training on the drug were the significant factors impacting the current knowledge, attitudes, and practices of AMU and AMR. The adjusted logistic regression analysis revealed that the drug sellers who completed their education up to 12th grade and had training on the drug had adequate knowledge of AMU and AMR. The data also showed that the drug sellers belong to the age group 31–35 and 36–40 years and who completed 12th grade had good attitudes on the same. Likewise, the analysis further determined that drug sellers belonging to the age category 18–25 and 26–30 years, and interestingly, the respondents who completed education up to 12th grade, had better practices. Spearman’s rank-order correlation revealed a positive association between each pair of the KAPs scores for the respondents. The correlation was fair between knowledge–attitudes, knowledge–practices, and attitudes–practices. Based on the current study results, we recommend educational interventions and appropriate training for the poultry drug and feed sellers to raise awareness and to upgrade their current knowledge on the appropriate use of antimicrobials. This will ultimately lead to reducing the chances of developing AMR in the poultry sectors of the country. Full article
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10 pages, 19287 KB  
Article
Optical Sideband Injection Locking Using Waveguide Based External Cavity Semiconductor Lasers for Narrow-Line, Tunable Microwave Generation
by Md. Rezaul Hoque Khan and Md. Ashraful Hoque
Photonics 2019, 6(3), 81; https://doi.org/10.3390/photonics6030081 - 20 Jul 2019
Cited by 2 | Viewed by 5443
Abstract
The generation by optical injection locking of spectrally unadulterated microwave signals using waveguide based external cavity semiconductor lasers (WECSL) is demonstrated. A tunable frequency of 2–11 GHz, limited by the modulator’s bandwidth and the photodetector (PD), was created as proof-of-experiment by the injection [...] Read more.
The generation by optical injection locking of spectrally unadulterated microwave signals using waveguide based external cavity semiconductor lasers (WECSL) is demonstrated. A tunable frequency of 2–11 GHz, limited by the modulator’s bandwidth and the photodetector (PD), was created as proof-of-experiment by the injection locking of the two WESCLs. A single sideband (SSB) phase noise of −75 dBc/Hz from the generated carrier at 10 kHz offset and a phase noise variance at an optimum injection ratio region was 0.03 rad2, corresponding to 1.7°, were observed. The main feature of this approach is the consolidation of the upsides of microwave generation at low phase noise with a broad tuning range and the capacity of hybrid photonic integration. In addition, the injection locking characteristics were used to determine the Q factor of the complicated optical cavities with unknown inner losses. Full article
(This article belongs to the Special Issue Semiconductor Laser Dynamics: Fundamentals and Applications)
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