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Authors = Danqing Song

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24 pages, 15876 KiB  
Article
Landslide Detection Using the Unsupervised Domain-Adaptive Image Segmentation Method
by Weisong Chen, Zhuo Chen, Danqing Song, Hongjin He, Hao Li and Yuxian Zhu
Land 2024, 13(7), 928; https://doi.org/10.3390/land13070928 - 26 Jun 2024
Cited by 2 | Viewed by 2194
Abstract
After a landslide, swift and precise identification of the affected area is paramount for facilitating urgent rescue operations and damage assessments. This is particularly vital for land use planners and policymakers, enabling them to efficiently address hazard mitigation, the resettlement of those affected [...] Read more.
After a landslide, swift and precise identification of the affected area is paramount for facilitating urgent rescue operations and damage assessments. This is particularly vital for land use planners and policymakers, enabling them to efficiently address hazard mitigation, the resettlement of those affected by the hazards, and to strategize land planning in the impacted regions. Despite the importance, conventional methods of monitoring landslides often fall short due to their restricted scope and the challenges associated with data acquisition. This study proposes a landslide detection method based on unsupervised multisource and target domain adaptive image segmentation (LUDAS) that is capable of achieving robust and generalized landslide mapping across multiple sources and target domains. Specifically, LUDAS consists of two phases. In the first phase, we introduce an unsupervised interdomain translation network to align the styles of multiple source domains to multiple target domains, generating pseudotarget domain data. Our interdomain translation network is capable of style transfer between any two domains. Through careful design of the network structure and loss functions, we ensure effective style transfer while preserving the content structure of the source domain images. In the second phase, the landslide segmentation model is trained in a supervised manner using annotated data from multiple source domains and multiple pseudotarget domains, resulting in a model with strong generalization capabilities that can adapt to multiple source and target domains. Finally, through extensive qualitative and quantitative analysis experiments, our study confirms that the proposed domain-adaptive segmentation model not only achieves exceptional landslide segmentation performance across multiple target domains but also, due to its good generalizability and transferability, has great potential for application in the emergency response to landslide. This capability can provide strong support for post-disaster emergency rescue, disaster assessment, and land planning in areas with scarce data. Full article
(This article belongs to the Section Land Innovations – Data and Machine Learning)
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14 pages, 4131 KiB  
Article
Synthesis, Structure and Properties of Polyester Polyureas via a Non-Isocyanate Route with Good Combined Properties
by Liuchun Zheng, Qiqi Xie, Guangjun Hu, Bing Wang, Danqing Song, Yunchuan Zhang and Yi Liu
Polymers 2024, 16(7), 993; https://doi.org/10.3390/polym16070993 - 4 Apr 2024
Cited by 2 | Viewed by 2441
Abstract
Polyureas have been widely applied in many fields, such as coatings, fibers, foams and dielectric materials. Traditionally, polyureas are prepared from isocyanates, which are highly toxic and harmful to humans and the environment. Synthesis of polyureas via non-isocyanate routes is green, environmentally friendly [...] Read more.
Polyureas have been widely applied in many fields, such as coatings, fibers, foams and dielectric materials. Traditionally, polyureas are prepared from isocyanates, which are highly toxic and harmful to humans and the environment. Synthesis of polyureas via non-isocyanate routes is green, environmentally friendly and sustainable. However, the application of non-isocyanate polyureas is quite restrained due to their brittleness as the result of the lack of a soft segment in their molecular blocks. To address this issue, we have prepared polyester polyureas via an isocyanate-free route and introduced polyester-based soft segments to improve their toughness and endow high impact resistance to the polyureas. In this paper, the soft segments of polyureas were synthesized by the esterification and polycondensation of dodecanedioic acid and 1,4-butanediol. Hard segments of polyureas were synthesized by melt polycondensation of urea and 1,10-diaminodecane without a catalyst or high pressure. A series of polyester polyureas were synthesized by the polycondensation of the soft and hard segments. These synthesized polyester-type polyureas exhibit excellent mechanical and thermal properties. Therefore, they have high potential to substitute traditional polyureas. Full article
(This article belongs to the Special Issue Emerging Smart Applications of Functional Polymeric Materials)
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13 pages, 1454 KiB  
Article
Genetic Diversity and Population Structure of Chinese Longsnout Catfish (Leiocassis longirostris) Using Microsatellite DNA Markers
by Yanling Hou, Huan Ye, Xinhua Song, Jiahui Fan, Junyi Li, Jian Shao, Yizhou Wang, Danqing Lin, Huamei Yue, Rui Ruan and Chuangju Li
Fishes 2024, 9(1), 35; https://doi.org/10.3390/fishes9010035 - 15 Jan 2024
Cited by 2 | Viewed by 2525
Abstract
The Chinese longsnout catfish (Leiocassis longirostris) is an economically important freshwater fish in China; however, its wild resources have declined dramatically in recent decades. Understanding the genetic structure of Chinese longsnout catfish populations is crucial to guide breeding programs and fishy [...] Read more.
The Chinese longsnout catfish (Leiocassis longirostris) is an economically important freshwater fish in China; however, its wild resources have declined dramatically in recent decades. Understanding the genetic structure of Chinese longsnout catfish populations is crucial to guide breeding programs and fishy restoration. In this study, 15 highly polymorphic microsatellite DNA loci were used to evaluate its genetic diversity and population structure. Chinese longsnout catfish populations show high genetic diversity; they do not show significant genetic differentiation or systematic geographic pattern of variation. From the upper to the lower reaches of the Yangtze River, the genetic diversity of Chinese longsnout catfish populations showed an increasing trend. The Gezhouba and Three Gorges dams, which physically divide the Yangtze River into upstream and mid-downstream sections, did not contribute to the genetic differentiation of Chinese longsnout catfish populations. Hence, the source of broodstock is not critical for within-river breeding programs and stock enhancement to restore the wild population. In addition, possible effects of dams on differentiation among populations are crucial and long-term evaluation is essential. Full article
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21 pages, 5619 KiB  
Article
Proportioning Test on the Similar Materials of the Rock Mass Physical Model Test Considering Seepage and Dynamic Characteristics
by Wanpeng Shi, Jianwei Zhang, Chunlei Xin, Danqing Song, Nan Hu and Bowei Li
J. Mar. Sci. Eng. 2023, 11(9), 1815; https://doi.org/10.3390/jmse11091815 - 18 Sep 2023
Cited by 5 | Viewed by 1589
Abstract
With the development of infrastructure construction, an increasing number of projects are faced with the problem of hydraulic and dynamic coupling. However, traditional physical model materials mainly consider the single factor influence and lack comprehensive research on the hydraulic and dynamic parameters of [...] Read more.
With the development of infrastructure construction, an increasing number of projects are faced with the problem of hydraulic and dynamic coupling. However, traditional physical model materials mainly consider the single factor influence and lack comprehensive research on the hydraulic and dynamic parameters of similar materials. Based on the dimensionless criterion and Buckingham π theorem, the dimension and similarity relation of physical model tests of rock masses under seepage and dynamic coupling are derived. A new type of similar material considering hydraulic and dynamic properties was developed by using quartz sand, barite powder, cement, water glass, rosin, and glycerol as raw materials through a large number of orthogonal tests. Meanwhile, the sensitivity analysis of the physical and mechanical properties of similar materials was carried out and the influence of each component factor on the physical properties was revealed. A material preparation scheme was developed to meet the physical and hydraulic characteristics of different rock and soil physical models. An empirical matching formula considering each parameter is proposed. This work can provide an important reference for physical model tests of similar rock masses. Full article
(This article belongs to the Special Issue Advances in Offshore Geotechnics)
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22 pages, 11995 KiB  
Article
Evaluation of the Damping Layer between the Tunnel Lining and Surrounding Rock via a Shaking Table Test
by Haoyu Wen, Zhiyong Zhou, Xianming Li, Danqing Song, Zhiqian He and Chunlei Xin
Sustainability 2023, 15(17), 13244; https://doi.org/10.3390/su151713244 - 4 Sep 2023
Cited by 5 | Viewed by 1348
Abstract
This paper primarily investigates the protective effect of the damping layer in tunnel lining structures under dynamic loads. A series of shaking table tests was conducted to investigate the seismic response mechanism of tunnel linings and the influence of surrounding rocks using the [...] Read more.
This paper primarily investigates the protective effect of the damping layer in tunnel lining structures under dynamic loads. A series of shaking table tests was conducted to investigate the seismic response mechanism of tunnel linings and the influence of surrounding rocks using the Wenchuan earthquake (magnitude 8.0) as a reference. The results show that the effect of the damping layer protection measures is accurate using the efficiency evaluation method for the damping layer under seismic excitation. The lower the excitation acceleration is, the better the effect will be. In addition, the damping coefficient is introduced to optimize the efficiency evaluation method for the damping layer. Among the factors influencing the seismic response of lining structures, the type of surrounding rock has a significant impact while the thickness of the damping layer has a relatively lesser influence. In seismic intensity areas of equal magnitude, an increase in the damping layer thickness leads to a more noticeable effect. In the different seismic intensity areas, the difference in the protection effect with the change in thickness is no longer obvious with the increase in seismic intensity. Moreover, the presence of a damping layer alters the intrinsic vibration characteristics of the tunnel lining structure, creating a space for deformation between the lining and the surrounding rock. Full article
(This article belongs to the Section Green Building)
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12 pages, 4859 KiB  
Article
Preparation of Steel Slag Foam Concrete and Fractal Model for Their Thermal Conductivity
by Guosheng Xiang, Danqing Song, Huajian Li, Yinkang Zhou, Hao Wang, Guodong Shen and Zhifeng Zhang
Fractal Fract. 2023, 7(8), 585; https://doi.org/10.3390/fractalfract7080585 - 29 Jul 2023
Cited by 2 | Viewed by 2163
Abstract
The innovation of structural forms and the increase in the energy-saving requirements of buildings have led to higher requirements regarding the application conditions of steel slag foam concrete (SSFC) to ensure that the SSFC has a lower thermal conductivity and sufficient compressive strength, [...] Read more.
The innovation of structural forms and the increase in the energy-saving requirements of buildings have led to higher requirements regarding the application conditions of steel slag foam concrete (SSFC) to ensure that the SSFC has a lower thermal conductivity and sufficient compressive strength, which has become the primary research object. Through a comprehensive consideration of 7 d compressive strength and thermal conductivity, the recommend mix ratio of SSFC was as follows: maximum SS size = 1.18 mm, water–cement ratio = 0.45, replacement rate of SS = 20–30%. Moreover, a theoretical formula was derived to determine thermal conductivity versus porosity based on fractal theory. The measured values of the foam concrete found elsewhere corroborate the fractal relationship regarding thermal conductivity versus porosity. This fractal relationship offers a straightforward and scientifically sound way to forecast the thermal conductivity of SSFC. Full article
(This article belongs to the Special Issue Fractal Mechanics of Engineering Materials)
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21 pages, 2882 KiB  
Article
A General Framework for the Impact of Shield Tunnel Construction on Existing Tunnel in Soil
by Pingrang Wang, Junhao Wu, Danqing Song and Mingfei Zhang
Sustainability 2023, 15(12), 9226; https://doi.org/10.3390/su15129226 - 7 Jun 2023
Cited by 5 | Viewed by 2092
Abstract
During the excavation process of shield tunneling, it is inevitable that the surrounding soil mass is disturbed, which will affect the adjacent structures. This paper proposes a general framework for the impact of shield tunneling construction on existing tunnels. First, the impact partition [...] Read more.
During the excavation process of shield tunneling, it is inevitable that the surrounding soil mass is disturbed, which will affect the adjacent structures. This paper proposes a general framework for the impact of shield tunneling construction on existing tunnels. First, the impact partition of shield tunneling construction regarding adjacent tunnels and buildings is established by a three-dimensional numerical analysis method. Then, the displacement of adjacent tunnels and buildings is predicted using fuzzy gray theory. Finally, based on the results of a numerical simulation and experiment, the risk classification standard of adjacent buildings is established. This framework has certain reference significance and value for the deformation prediction and safety evaluation of adjacent buildings. Full article
(This article belongs to the Special Issue Sustainability in Geology and Civil Engineering)
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23 pages, 5898 KiB  
Article
Mechanistic Insights into the Role of OPN in Mediating Brain Damage via Triggering Lysosomal Damage in Microglia/Macrophage
by Chengcheng Gai, Yijing Zhao, Danqing Xin, Tingting Li, Yahong Cheng, Zige Jiang, Yan Song, Dexiang Liu and Zhen Wang
Cells 2023, 12(6), 854; https://doi.org/10.3390/cells12060854 - 9 Mar 2023
Cited by 2 | Viewed by 2721
Abstract
We previously found that osteopontin (OPN) played a role in hypoxia–ischemia (HI) brain damage. However, its underlying mechanism is still unknown. Bioinformatics analysis revealed that the OPN protein was linked to the lysosomal cathepsin B (CTSB) and galectin-3 (GAL-3) proteins after HI exposure. [...] Read more.
We previously found that osteopontin (OPN) played a role in hypoxia–ischemia (HI) brain damage. However, its underlying mechanism is still unknown. Bioinformatics analysis revealed that the OPN protein was linked to the lysosomal cathepsin B (CTSB) and galectin-3 (GAL-3) proteins after HI exposure. In the present study, we tested the hypothesis that OPN was able to play a critical role in the lysosomal damage of microglia/macrophages following HI insult in neonatal mice. The results showed that OPN expression was enhanced, especially in microglia/macrophages, and colocalized with lysosomal-associated membrane protein 1 (LAMP1) and GAL-3; this was accompanied by increased LAMP1 and GAL-3 expression, CTSB leakage, as well as impairment of autophagic flux in the early stage of the HI process. In addition, the knockdown of OPN expression markedly restored lysosomal function with significant improvements in the autophagic flux after HI insult. Interestingly, cleavage of OPN was observed in the ipsilateral cortex following HI. The wild-type OPN and C-terminal OPN (Leu152-Asn294), rather than N-terminal OPN (Met1-Gly151), interacted with GAL-3 to induce lysosomal damage. Furthermore, the secreted OPN stimulated lysosomal damage by binding to CD44 in microglia in vitro. Collectively, this study demonstrated that upregulated OPN in microglia/macrophages and its cleavage product was able to interact with GAL-3, and secreted OPN combined with CD44, leading to lysosomal damage and exacerbating autophagosome accumulation after HI exposure. Full article
(This article belongs to the Section Cells of the Nervous System)
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12 pages, 5189 KiB  
Article
The Role of Fluid Overpressure on the Fracture Slip Mechanism Based on Laboratory Tests That Stimulating Reservoir-Induced Seismicity
by Yujie Zhu, Chen Xu, Danqing Song, Xiaoli Liu and Enzhi Wang
Appl. Sci. 2023, 13(6), 3382; https://doi.org/10.3390/app13063382 - 7 Mar 2023
Viewed by 1755
Abstract
A critically stressed fracture will slide in response to the increase in fluid pressure inside the fracture while impounding, which will trigger induced seismicity. The mechanism of fluid overpressure is regarded as a significant factor in the reaction of the fracture slip after [...] Read more.
A critically stressed fracture will slide in response to the increase in fluid pressure inside the fracture while impounding, which will trigger induced seismicity. The mechanism of fluid overpressure is regarded as a significant factor in the reaction of the fracture slip after water diffusing. This study uses a shearing test with a cylinder of granite, with 100 mm height and 50 mm diameter, under the condition of hydraulic-mechanic (HM) coupling to figure out how fluid overpressure alters the mechanical behavior of the critically stressed fracture. The cyclic water pressurization simulates periodical impounding in the water reservoir. Results show that several slip events happen when water pressure continues to rise higher than the stable state. The change of roughness also indicates the deterioration of the fracture surface while sliding. According to the results, we conclude that the difference between inlet pressure and outlet pressure leads to an overpressure of the fracture, promoting a series of slips and induced seismicity. Hydraulic energy is introduced to explain the relationship between the input and output energy, which is also strong evidence to illustrate that fluid overpressure is a crucial mechanism in reservoir-induced seismicity. Full article
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24 pages, 8787 KiB  
Article
Numerical Investigation of a Local Precise Reinforcement Method for Dynamic Stability of Rock Slope under Earthquakes Using Continuum–Discontinuum Element Method
by Danqing Song, Wanpeng Shi, Chengwen Wang, Lihu Dong, Xin He, Enge Wu, Jianjun Zhao and Runhu Lu
Sustainability 2023, 15(3), 2490; https://doi.org/10.3390/su15032490 - 30 Jan 2023
Cited by 8 | Viewed by 2106
Abstract
The slope reinforcement scheme has an important influence on the prevention and control of landslides. A reasonable reinforcement scheme can improve the reliability, economy and efficiency of landslide resistance. It is urgent to establish a local precise reinforcement method for landslides on the [...] Read more.
The slope reinforcement scheme has an important influence on the prevention and control of landslides. A reasonable reinforcement scheme can improve the reliability, economy and efficiency of landslide resistance. It is urgent to establish a local precise reinforcement method for landslides on the basis of clear process and the instability modes of landslides. Taking a high-steep anti-dip rock slope as an example, six numerical models are established by using the continuum–discontinuum element method (CDEM) to carry out seismic damage and dynamic analysis of slopes. By comparing the seismic response and damage characteristics of being unstrengthened, local precise reinforcement and overall reinforcement models, the applicability of the proposed local precise reinforcement method for the slopes is discussed. The results show that the determination of the dynamic amplifying effect and seismic damage characteristics of slopes is the primary prerequisite of the local precise reinforcement method. The dynamic amplification effect of the slope toe, crest and shallow slope surface are much larger, that is, they are the potential reinforcement areas. The local precision reinforcement times should be controlled within a certain number of times, and the slope after the first three times of the local reinforcement effect is the best. However, more than three times after the reinforcement effect it becomes worse. Moreover, the dynamic amplification effect, the equivalent crack ratio and the mechanical energy of the slope after three times of local precision reinforcement are similar to the overall reinforcement effect, which indicates that local precision reinforcement has good feasibility. This work can provide references for landslide disasters prevention and control. Full article
(This article belongs to the Special Issue Sustainability in Geology and Civil Engineering)
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22 pages, 16372 KiB  
Article
Investigation on the Seismic Wave Propagation Characteristics Excited by Explosion Source in High-Steep Rock Slope Site Using Discrete Element Method
by Danqing Song, Xuerui Quan, Mengxin Liu, Chun Liu, Weihua Liu, Xiaoyu Wang and Dechao Han
Sustainability 2022, 14(24), 17028; https://doi.org/10.3390/su142417028 - 19 Dec 2022
Cited by 6 | Viewed by 3375
Abstract
The influence of seismic waves induced by explosion sources on the dynamic response characteristics of rock slope sites is one of the most important problems affecting engineering construction. To investigate the wave propagation characteristics and attenuation law of seismic waves induced by explosive [...] Read more.
The influence of seismic waves induced by explosion sources on the dynamic response characteristics of rock slope sites is one of the most important problems affecting engineering construction. To investigate the wave propagation characteristics and attenuation law of seismic waves induced by explosive sources in rock sites from the perspective of time and frequency domains, the high-performance matrix discrete element method (MatDEM) is used to carry out numerical simulation tests on a granite rock medium site. The discrete element model of the high-steep rock slope is established by MatDEM, and the dynamic analysis of the rock medium site is conducted by loading blasting vibration load to generate seismic waves. The results show that the seismic waves in the rock site present characteristics of arc propagation attenuation. The maximum attenuation rate of the dynamic response is the fastest within 0.3 s and 25 m from the explosion source. The slope region can weaken the dynamic response of seismic waves generated by the explosion source. In particular, the high-frequency band (>20 Hz) has an obvious filtering effect. The dynamic response of the P-wave induced by the explosive source is greater than that of the S-wave in the bedrock and surface region. The dynamic amplification effect of the P-wave is greater than that of the S-wave in the slope region. The seismic waves in the slope region show an attenuation effect along the slope surface and have a typical elevation amplification effect inside the slope. Full article
(This article belongs to the Special Issue Sustainability in Geology and Civil Engineering)
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21 pages, 9269 KiB  
Article
Application of Long-Range Cross-Hole Acoustic Wave Detection Technology in Geotechnical Engineering Detection: Case Studies of Tunnel-Surrounding Rock, Foundation and Subgrade
by Lihu Dong, Jundong Chen, Danqing Song, Chengwen Wang, Xiaoli Liu, Mengxin Liu and Enzhi Wang
Sustainability 2022, 14(24), 16947; https://doi.org/10.3390/su142416947 - 17 Dec 2022
Cited by 6 | Viewed by 2434
Abstract
The adverse geological conditions of soil cave, karst cave and goaf in deep foundation directly affect the safety and economy of geotechnical engineering construction. It is a difficult problem in geotechnical engineering detection to detect the distribution of bad geological conditions efficiently and [...] Read more.
The adverse geological conditions of soil cave, karst cave and goaf in deep foundation directly affect the safety and economy of geotechnical engineering construction. It is a difficult problem in geotechnical engineering detection to detect the distribution of bad geological conditions efficiently and accurately. Aiming at the problems of short penetrating distance and low resolution of cross-hole acoustic wave detection in rock-soil mass, based on the characteristics of acoustic wave propagation in rock and soil layers and comprehensively utilizing the spark source and data acquisition device, a long-distance cross-hole acoustic wave detection technology is proposed. According to the indoor concrete model test and field tests of geotechnical engineering, the applicability of the long-distance cross-hole acoustic wave detection technology in the detection of geotechnical structure and adverse geological phenomena under complex geological conditions is verified. The results show that acoustic wave CT imaging can accurately detect the cavities in the indoor concrete model test. In addition, the field tests of the grouting effect of tunnel-surrounding rock, high-rise building foundation and subgrade further verify the rapidity, accuracy and intuitiveness of the long-distance cross-hole acoustic wave detection technology. This work provides a reference for eliminating the potential safety problems caused by adverse geological conditions and similar geotechnical engineering investigation. Full article
(This article belongs to the Special Issue Sustainability in Geology and Civil Engineering)
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13 pages, 6506 KiB  
Article
Spacing Optimization of the TBM Disc Cutter Rock Fragmentation, Based on the Energy Entropy Method
by Chen Xu, Yujie Zhu, Danqing Song, Xiaoli Liu, Wanli Guo and Enzhi Wang
Sustainability 2022, 14(20), 13226; https://doi.org/10.3390/su142013226 - 14 Oct 2022
Cited by 5 | Viewed by 2266
Abstract
We used the hyperbolic Drucker–Prager and damage-failure models to simulate a three-dimensional rock fragmentation with a tunnel boring machine (TBM) disc cutter through ABAQUS. The energy entropy method was proposed to identify the optimal disc cutter spacing. In order to verify the results [...] Read more.
We used the hyperbolic Drucker–Prager and damage-failure models to simulate a three-dimensional rock fragmentation with a tunnel boring machine (TBM) disc cutter through ABAQUS. The energy entropy method was proposed to identify the optimal disc cutter spacing. In order to verify the results of the numerical simulation, previous linear cutting machine (LCM) test data were referred to. The results of the numerical simulation were verified by comparing the mean rolling force and the specific energy against the corresponding values from the LCM tests. The proposed energy entropy method showed a good agreement with the LCM test results, thus proving its usefulness in analyzing rock fragmentation for various disc cutter spacings. The comparison between energy entropy and the specific energy showed that both methods provide similar conclusions with regard to optimal spacing. The results of this research showed that energy entropy can predict the performance of TBM disc cutters and could help improve their design. Full article
(This article belongs to the Special Issue Sustainability in Geology and Civil Engineering)
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20 pages, 8090 KiB  
Article
Comparison of DEM Models with Different Elemental Dimensions for TBM Disc Cutter Rock Fragmentation
by Chen Xu, Yujie Zhu, Danqing Song, Xiaogang Guo, Xiaoli Liu, Enzhi Wang and Runhu Lu
Sustainability 2022, 14(19), 12909; https://doi.org/10.3390/su141912909 - 10 Oct 2022
Cited by 4 | Viewed by 2516
Abstract
Disc cutters are the dominant tool used in the excavation of hard rock formations in any underground construction application, such as when tunneling using tunnel-boring machines (TBM), as well as in shaft- and raise boring operations. Optimization of the cutting geometry of a [...] Read more.
Disc cutters are the dominant tool used in the excavation of hard rock formations in any underground construction application, such as when tunneling using tunnel-boring machines (TBM), as well as in shaft- and raise boring operations. Optimization of the cutting geometry of a given disc cutter for application in a rock formation often involves full-scale cutting tests, which is a difficult and costly proposition. An alternative to full-scale testing is the numerical simulation of TBM disc cutters for optimization under different settings. Recent efforts in the field of numerical simulations of rock cutting have shown the relative success of discrete element models, such as particle flow code (PFC), to simulate two- and three-dimensional rock fragmentation. This study is focused on a sensitivity analysis of PFC simulation of rock-cutting relative to the size of the elements. The calculated cutting forces were compared with the recorded forces under various conditions during full-scale tests using a linear cutting machine (LCM) on Colorado red granite (CRG). The estimated cutting coefficient and specific energy in the LCM tests and simulations showed good correlations, which validates the numerical simulation results. Two- and three-dimensional models showed that two-dimensional numerical models can offer a qualitative assessment of crack development, whereas three-dimensional models could be used to estimate the specific energy when cutting. The results can help in predicting the cutting forces in different rocks and ultimately improving disc-cutter geometry and cutter-head design. Full article
(This article belongs to the Special Issue Sustainability in Geology and Civil Engineering)
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17 pages, 6776 KiB  
Article
A Non-Isocyanate Route to Poly(Ether Urethane): Synthesis and Effect of Chemical Structures of Hard Segment
by Ziyun Shen, Liuchun Zheng, Danqing Song, Yi Liu, Chuncheng Li, Jiajian Liu, Yaonan Xiao, Shaohua Wu, Tianbo Zhou, Bo Zhang, Xuedong Lv and Qiyong Mei
Polymers 2022, 14(10), 2039; https://doi.org/10.3390/polym14102039 - 16 May 2022
Cited by 10 | Viewed by 3510
Abstract
A series of non-isocyanate poly(ether urethane) (PEU) were prepared by an environmentally friendly route based on dimethyl carbonate, diols and a polyether. The effect of the chemical structure of polyurethane hard segments on the properties of this kind of PEU was systematically investigated [...] Read more.
A series of non-isocyanate poly(ether urethane) (PEU) were prepared by an environmentally friendly route based on dimethyl carbonate, diols and a polyether. The effect of the chemical structure of polyurethane hard segments on the properties of this kind of PEU was systematically investigated in this work. Polyurethane hard segments with different structures were first prepared from hexamethylene di-carbamate (BHC) and different diols (butanediol, hexanediol, octanediol and decanediol). Subsequently, a series of non-isocyanate PEU were obtained by polycondensation of the polyurethane hard segments with the polyether soft segments (PTMG2000). The PEU were characterized by GPC, FT-IR, 1H NMR, DSC, WAXD, SAXS, AFM and tensile testing. The results show that the urea groups generated by the side reaction affect the degree of crystallization of hard segments by influencing the hydrogen bonding of the hard segments molecular chains. The degree of hard segment crystallization, in turn, affects the thermal and mechanical properties of the polymer. The urea group content is related to the carbon chain length of the diol used for the synthesis of hard segments. When butanediol is applied to synthesize hard segment, the hard segment of the resulting PEU is unable to crystallize. Therefore, the tensile strength and modulus of elasticity of butanediol-based PEU is lowest among three, though it possesses the highest urea group content. When longer octanediol or decanediol is applied to synthesize the hard segment, the hard segments in the resulting polyether-based polyurethane are crystallizable and the resulting PEU possesses higher tensile strength. Full article
(This article belongs to the Section Polymer Chemistry)
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