Xerogels: Preparation, Properties and Applications

A special issue of Gels (ISSN 2310-2861). This special issue belongs to the section "Gel Chemistry and Physics".

Deadline for manuscript submissions: 10 September 2026 | Viewed by 1247

Special Issue Editors


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Guest Editor
Department of Inorganic and Organic Chemistry, University of Jaén (UJA), 23071 Jaén, Spain
Interests: sol-gel process; silica xerogels; hybrid materials; adsorption; heterogeneous photocatalysis; water treatment; optical fibre chemical sensors

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Guest Editor
Institute of Carbon Science and Technology from the Spanish Nacional Research Council (INCAR-CSIC), 33011 Oviedo, Spain
Interests: carbon materials; electrolytic reduction; electrocatalysts; oxygen reduction reaction

Special Issue Information

Dear Colleagues,

This Special Issue, entitled “Xerogels: Preparation, Properties and Applications”, is dedicated to recent developments in the synthesis and characterization of xerogels with interesting and enhanced properties for advanced applications.

Polymeric gel materials are traditionally prepared using the sol–gel process, which was discovered by Ebelmen in 1846 via experiments revealing the hydrolysis and condensation of silicon esters upon exposition to moisture. This method constitutes a flexible and versatile synthesis approach that employs mild conditions to obtain micro or nanosized materials whose properties are strongly dependent on the synthesis parameters; these parameters include the ratio of the molecular precursors; the precursor–solvent ratio; the pH of the Sol; the curing solvent and duration; and the way in which the drying step is performed. 

Specifically, xerogels are a type of solid-formed gel that is obtained by slowly drying the cured alcogels at room temperature, which leads to the shrinkage of the polymeric network; this usually produces micro–mesoporous materials with a large surface area and high porosity. In addition, carbon and silicon xerogels are biocompatible, exhibiting thermal and chemical stability and highly customizable properties; they have therefore attracted significant interest with regard to the adsorption of contaminants; the utilization of catalyst supports; the preparation of membranes; biomedical technology; and the development of batteries.

Therefore, in order to provide an overview of recent breakthroughs in the field of xerogels (carbon, silicon, and other metal oxide xerogels), we encourage the submission of original research papers or reviews that address the relationship between the structure of xerogels, their properties and their optimization for specific applications.

Dr. Guillermo Cruz-Quesada
Dr. Natalia Rey-Raap
Guest Editors

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Keywords

  • synthesis of xerogels
  • sol–gel techniques
  • physicochemical characterization
  • synthesis parameters optimization
  • structure–properties relationship
  • xerogel applications
  • water treatment applications
  • heterogeneous catalysis
  • biocompatibility assessment
  • membrane preparation

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Published Papers (1 paper)

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Research

19 pages, 15326 KB  
Article
A Comprehensive Kinetic Study on the Enhanced Thermal Stability of Silica Xerogels with the Addition of Organochlorinated Substituents
by Beatriz Rosales-Reina, Guillermo Cruz-Quesada, Pablo Pujol, Santiago Reinoso, César Elosúa, Gurutze Arzamendi, María Victoria López-Ramón and Julián J. Garrido
Gels 2026, 12(1), 2; https://doi.org/10.3390/gels12010002 - 19 Dec 2025
Viewed by 704
Abstract
Hybrid silica xerogels functionalised with chlorinated organosilanes combine tunable porosity and surface chemistry, rendering them attractive for applications in sensing, membrane technology, and photonics. This study quantitatively investigates the thermal decomposition kinetics of organochlorinated xerogels and correlates with volatile compounds previously identified via [...] Read more.
Hybrid silica xerogels functionalised with chlorinated organosilanes combine tunable porosity and surface chemistry, rendering them attractive for applications in sensing, membrane technology, and photonics. This study quantitatively investigates the thermal decomposition kinetics of organochlorinated xerogels and correlates with volatile compounds previously identified via Thermogravimetric Analysis (TGA) coupled to Fourier-Transform Infrared Spectroscopy (FT–IR) and Gas Chromatography coupled with Mass Spectrometry (GC–MS). The xerogels were synthesised via the sol–gel process using organochlorinated alkoxysilane precursors and yielded highly condensed nanostructures in which the precursor nature strongly influences the morphology and textural properties. In this study, the molar percentage of the organochlorinated compounds was fixed at 10%. Standard N2 adsorption-desorption isotherm at 77 K revealed that increasing the precursor content systematically decreased the specific surface area and pore volume of the materials while promoting the formation of periodic domains, which are observed even at low organosilane molar percentages. Thermal characterisation via TGA/FT–IR/GC–MS revealed at least two main decomposition stages, with thermal stability following the order of 4–chlorophenyl > chloromethyl > 3–chloropropyl > 2–chloroethyl. This study focuses on kinetic and mechanistic insights in the thermal decomposition process through the Flynn–Wall–Ozawa isoconversional method and Criado master plots, using TGA/Differential Scanning Calorimetry (DSC) measurements under nitrogen at multiple heating rates (5, 10, 20, 30, and 40 K min−1), which revealed activation energies ranging from 53 to 290 kJ mol−1. Demonstrating that the chlorinated organosilane precursor directly controls both the textural properties and thermal behaviour of the resulting silica materials, with aromatic groups providing superior thermal stability compared to aliphatic chains. These quantitative kinetic insights provide a predictive framework for designing thermally stable hybrid materials while ensuring safe processing conditions to prevent hazardous volatile release. Full article
(This article belongs to the Special Issue Xerogels: Preparation, Properties and Applications)
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