Study of Atmospheric Deposition of Heavy Metals in Europe

A special issue of Atmosphere (ISSN 2073-4433). This special issue belongs to the section "Air Quality and Human Health".

Deadline for manuscript submissions: closed (31 December 2021) | Viewed by 6278

Special Issue Editor


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Guest Editor
Sector of Neutron Activation Analysis and Applied Research, Frank Laboratory of Neutron Physics, Joint Institute for Nuclear Research, 141980 Dubna, Russia
Interests: air pollution with trace elements, radionuclides, and cosmic dust; moss and lichens biomonitoring; nuclear and related analytical techniques for the Life Sciences

Special Issue Information

Dear Colleagues,

Air pollution is now the biggest environmental risk for early death, as it is responsible for more than 6 million premature deaths each year from heart attacks, strokes, diabetes, and respiratory diseases. That represents more deaths than those from AIDS, tuberculosis and malaria combined (http://www.epa.gov/air/). Research suggests that long-term exposure to some pollutants increases the risk of emphysema more than smoking a pack of cigarettes a day. Recent studies show air pollution can affect mental health, worker productivity, and even stock market performance. To develop the best solutions, it is important to better understand this invisible threat. What we typically think of as “air pollution” is actually a mixture of small particles, including the following:

Particulate matter (PM10, PM2.5). The majority of PM in urban areas is formed directly from the burning of fossil fuels by power plants, automobiles, non-road equipment, and industrial facilities. Other sources are dust, diesel emissions, and the formation of secondary particles from gases and vapors. Coarse particulate matter (PM10, particles less than 10 microns in diameter) is known to cause nasal and upper respiratory tract health problems. Fine particulate matter (PM2.5, particles less than 2.5 microns in diameter) penetrates deeper into the lungs and causes heart attacks, strokes, asthma, and bronchitis, as well as premature death from heart ailments, lung disease, and cancer. Studies show that higher PM2.5 exposure can impair brain development in children.

Black carbon (BC). Black carbon is one of the components of particulate matter and comes from burning fuel (especially diesel, wood, and coal). Most air pollution regulations focus on PM2.5, but exposure to black carbon is a serious health threat as well. Populations with higher exposures to black carbon over a long period are at a higher risk for heart attacks and stroke. Black carbon is associated with hypertension, asthma, chronic obstructive pulmonary disease, bronchitis, and a variety of types of cancer.

Nitrogen oxides (NO and NO2). Nitrogen oxide (NO) and nitrogen dioxide (NO2) are produced primarily by the transportation sector. NO is rapidly converted to NO2 in sunlight. NOx (a combination of NO and NO2) is formed in high concentrations around roadways and can result in development and exacerbations of asthma and bronchitis and can lead to a higher risk of heart disease.

Ozone (O3). Ozone high in the atmosphere can protect us from ultraviolet radiation. However, ozine at ground level (where it is part of what is commonly called smog) is a well-established respiratory irritant. Ozone is formed in the atmosphere through reactions of volatile organic compounds and nitrogen oxides, both of which are formed as a result of combustion of fossil fuels. Short-term exposure to ozone can cause chest pain, coughing, and throat irritation, while long term exposure can lead to decreased lung function and cause chronic obstructive pulmonary disease. In addition, ozone exposure can aggravate existing lung diseases.

Sulfur dioxide (SO2). SO2 is emitted into the air by the burning of fossil fuels that contain sulfur. Coal, metal extraction and smelting, ship engines, heavy equipment, and diesel engines burn fuels that contain sulfur. Sulfur dioxide causes eye irritation, worsens asthma, increases susceptibility to respiratory infections, and impacts the cardiovascular system. When SO2 combines with water, it forms sulfuric acid, which is the main component of acid rain, a known contributor to deforestation.

Biomonitoring of atmospheric deposition of toxic heavy metals (Pb, Cd, Hg, etc.), persistent organic pollutants (POPs), polymeric aromatic hydrocarbons (PAHs), radionuclides, cosmic, dust and microplastics.

In the framework of the Convention on Long-Range Transboundary Air Pollution (CLRTAP) biomonitoring with moss is used for mapping atmospheric deposition of trace elements (https://icpvegetation.ceh.ac.uk/). Among air pollutants, heavy metals (trace elements) are of special importance. Heavy metals can be toxic to both humans and wildlife.

The most important emission sectors include

  • Metals industry (Al, As, Cr, Cu, Fe, Zn);
  • Manufacturing industries and construction (As, Cd, Cr, Hg, Ni, Pb);
  • Electricity and heat production (Cd, Hg, Ni);
  • Road transportation (Cu and Sb from brake wear, V, Zn, W from tires and Pb if leaded gasoline is used);
  • Petroleum refining (Ni, V), and
  • Phosphate fertilizers in agricultural areas (Cd).

Mosses can be used to trace deposition patterns of radionuclides in the case of radionuclide accidents, such as at the Kyshtym disaster in the South Urals (RF, USSR) in the middle of the 20th century, the 1986 Chernobyl accident (Ukraine, USSR), and the 2011 Fukushina disaster in Japan. The Earth’s surface is showered with thousands of tons of extraterrestrial comic dust particles (micrometeorites) every year. The role of cosmic dust in air pollution should be considered natural pollution, potentially hazardous to living matter. Presently, the most “fashionable” topic in air pollution studies is macroplastics. Mosses as accumulators of deposited microplastic particles serve as a good source for their identification and risk assessment of their impact on human health.

You are very welcome to contribute to this Special Issue on “Air Quality and Human Health”.

Dr. Marina Frontasyeva
Guest Editor

Manuscript Submission Information

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Keywords

  • Air pollution with particulate matter
  • Atmospheric deposition of trace elements
  • Moss and lichens biomonitoring
  • Toxic heavy metals
  • POPs and PAHs
  • Radionuclides
  • Cosmic dust
  • Microplastics
  • Epidemiological data

Published Papers (2 papers)

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Research

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28 pages, 348 KiB  
Article
Comparison of Existing Legal Assessment Values for Heavy Metal Deposition in Western Europe and Calculation of Assessment Values for Luxembourg
by Angela Schlutow and Winfried Schröder
Atmosphere 2021, 12(11), 1455; https://doi.org/10.3390/atmos12111455 - 03 Nov 2021
Viewed by 1521
Abstract
The protection against eco- and human-toxicological impairments caused by atmospheric deposition of heavy metals requires legally defined assessment values. Since such values are missing for Luxembourg, the aim of this investigation was to evaluate different approaches to derive assessment values for the regulation [...] Read more.
The protection against eco- and human-toxicological impairments caused by atmospheric deposition of heavy metals requires legally defined assessment values. Since such values are missing for Luxembourg, the aim of this investigation was to evaluate different approaches to derive assessment values for the regulation of heavy metals that are in accordance with scientific and legal standards. To this end, assessment values for heavy metals were derived from the compilation of respective values implemented in European countries. In addition, (1) precipitation-related assessment values for the protection of soil for Cr, Zn, and Cu and (2) precautionary assessment values (critical loads for Cr, Zn, and Cu, as well as As, Cd, Ni, and Pb) for the protection of human health and ecosystems were calculated. The calculation of the regionally differentiated precipitation-related assessment values resulted in ranges of 17–272 g Cu ha−1 a−1, 167–2672 g Zn ha−1 a−1 and 17–272 g Crtotal ha−1 a−1. The critical loads for drinking water protection vary in the ranges from 1.23 to 2.14 g Cd ha−1 a−1, from 4.05 to 8.63 g Pb ha−1 a−1, from 2.6 to 5.9 g As ha−1 a−1, from 258 to 564 g Cu ha−1 a−1, from 1292 to 2944 g Zn ha−1 a−1, and from 12.9 to 29.9 g Crtotal ha−1 a−1. Ecosystems are significantly more sensitive to Pb, Cu, and Zn inputs than humans. For As and Cr, humans react much more sensitively than ecosystems. For Cd, the critical loads for drinking water, ecosystems, and wheat products are about the same. Full article
(This article belongs to the Special Issue Study of Atmospheric Deposition of Heavy Metals in Europe)

Review

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16 pages, 718 KiB  
Review
Risks for Public Health and Social Infrastructure in Russian Arctic under Climate Change and Permafrost Degradation
by Boris A. Revich, Dmitry O. Eliseev and Dmitry A. Shaposhnikov
Atmosphere 2022, 13(4), 532; https://doi.org/10.3390/atmos13040532 - 28 Mar 2022
Cited by 9 | Viewed by 4018
Abstract
This study analyzes the risks to public health and life quality in the conditions of permafrost degradation caused by the ongoing climate change in the Russian Arctic. There are more than 200 Siberian anthrax cattle burial grounds in the Russian permafrost regions. Permafrost [...] Read more.
This study analyzes the risks to public health and life quality in the conditions of permafrost degradation caused by the ongoing climate change in the Russian Arctic. There are more than 200 Siberian anthrax cattle burial grounds in the Russian permafrost regions. Permafrost degradation poses the risks of thawing of frozen carcasses of the infected animals and propagation of infectious diseases. Permafrost degradation leads to infiltration of toxic waste in the environment. Such waste contains mercury, which migrates into the rivers and forms methylmercury (MeHg) in fish. Other risks associated with permafrost degradation include damage to the existing social infrastructure (housing, health-care facilities, roads, etc.). Various risks to public well-being that emerge because of permafrost degradation were addressed in this study. Relative hazard indices were developed and calculated to characterize the probability of outbreaks of Siberian anthrax in the future. These indices linked the rates of permafrost degradation and the number of Siberian anthrax cattle burials to the potential hazard of re-emergence of Siberian anthrax among local populations in 70 municipal districts under the ongoing warming. The expected damage to public housing, health-care facilities, and motorways was assessed. Accessibility of health care in various regions of the Russian Arctic was analyzed. The economic costs associated with various scenarios of possible destruction of residential buildings, health-care facilities, and roads built on permafrost were estimated. Full article
(This article belongs to the Special Issue Study of Atmospheric Deposition of Heavy Metals in Europe)
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