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Liquids, Volume 5, Issue 3

September 2025 - 7 articles

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Articles (7)

  • Article
  • Open Access
709 Views
17 Pages

Thermodynamic Constraints on the “Hidden” Folding Intermediates

  • Timur A. Mukhametzyanov,
  • Mikhail I. Yagofarov and
  • Christoph Schick

13 September 2025

Experimental data on the folding and unfolding of small globular proteins are often well described assuming a two-state equilibrium process. It means that after careful analysis by a combination of experimental techniques, only folded and unfolded st...

  • Article
  • Open Access
891 Views
16 Pages

Microheterogeneous Polymeric Solvent Systems

  • Thomas J. Malinski,
  • Ying-Hua Fu,
  • Sopida Thavornpradit,
  • Yu Ching Wong,
  • Yunnuen Avila-Martinez,
  • William Dow and
  • David E. Bergbreiter

8 September 2025

This paper shows that low concentrations of either a low-molecular-weight or a recyclable polymeric cosolvent can be used to design recyclable, tunable alkane polymeric solvent systems. We have shown that dyes experience a microheterogeneous environm...

  • Article
  • Open Access
1,519 Views
8 Pages

Entropy-Based Solubility Parameter-Translated Peng–Robinson Equation of State (eSPT-PR EoS)

  • Masaki Ota,
  • Naishu Yang,
  • Hiroyuki Komatsu,
  • Hiroshi Inomata and
  • Richard Lee Smith

25 August 2025

Peng–Robinson equation of state (PR EoS) has good prediction accuracy for phase diagrams of pure substances or mixtures, but liquid density, especially for high polar substances, is known to be ~20% lower value compared with experimental data a...

  • Article
  • Open Access
1,069 Views
21 Pages

Empirical Rules in Thermochemistry: Overlooked Overestimations of the Liquid- and Crystal-Phase Heat Capacities of α,ω-Alkanediols and Their Consequences

  • Riko Siewert,
  • Vladimir V. Emelyanov,
  • Artemiy A. Samarov,
  • Matthis Richter,
  • Karsten Müller and
  • Sergey P. Verevkin

13 August 2025

The utilisation of empirical correlations for the estimation of thermodynamic functions is a valuable approach for reducing experimental effort and for validating existing data. Established correlations and group contribution methods provide reliable...

  • Review
  • Open Access
813 Views
19 Pages

22 July 2025

This article presents a mini-review of the available data on the thermodynamics of the complexation of amino acids and peptides with some nucleic bases in a buffer medium. Data on changes in thermodynamic parameters (binding constants, Gibbs energy,...

  • Communication
  • Open Access
1 Citations
958 Views
9 Pages

11 July 2025

Concentrated suspensions exhibit intriguing behaviors under external forces, including vibration and shear. While previous studies have focused primarily on cornstarch suspensions, this paper reports a novel observation that colloidal silica suspensi...

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Liquids - ISSN 2673-8015