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Photochem, Volume 3, Issue 4

December 2023 - 7 articles

Cover Story: Natural generation of vitamin D3 is initiated by UVB exposure of provitamin D3 in the skin where it undergoes ring-opening to form the precursor previtamin D3. The final yield is highly wavelength dependent, however, and the path to vitamin D3 is often sidetracked by formation of tachysterol and other undesired byproducts. The natural amino acid phenylalanine has been shown to possess a dual photoprotective effect on this wavelength-sensitive photochemistry enhancing the concentration and lifetime of previtamin D3 while reducing undesired byproducts. Its ability to both channel and transfer energy from parasitic wavelengths to viable vitamin D3 precursors promotes a more efficient synthesis and paves the way for new strategies of photoprotection in artificial light-harvesting materials. View this paper
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Articles (7)

  • Review
  • Open Access
6 Citations
5,377 Views
35 Pages

12 December 2023

The design of biosourced and/or bioinspired photoinitiators is an active research field as it offers a unique opportunity to develop photoinitiating systems exhibiting better biocompatibility as well as reduced toxicity. In this field, flavonoids can...

  • Article
  • Open Access
1 Citations
2,432 Views
18 Pages

28 November 2023

Provitamin D3 is the biological precursor to naturally formed vitamin D3 in humans, and its conversion is initiated via photoexcitation by near ultraviolet light. Following an initial photolysis, the primary intermediate, known as previtamin D3, is p...

  • Article
  • Open Access
5 Citations
4,255 Views
16 Pages

25 November 2023

Self-cleaning products are commercially available to protect surfaces against soiling and avoid the high consumption of energy and chemical detergents necessary for cleaning. They are based on semiconductor oxides, mostly titanium dioxide (TiO2), whi...

  • Article
  • Open Access
4 Citations
2,644 Views
19 Pages

7 November 2023

In this study, the aqueous photolytic degradation of the neonicotinoid pesticide clothianidin was studied in suspensions and aqueous extracts of hydrochar produced from olive kernels. A slight and nonsignificant decrease in the photodegradation rate...

  • Article
  • Open Access
2 Citations
2,116 Views
15 Pages

24 October 2023

A visible-light-responsive arylazopyrazole-functionalized phenylalanine (4-MeS-AAP-NF) derived ligand was designed and synthesized, and it was found to form metallogels with reversible photo-responsive properties in mixed methanol/water (MeOH/H2O) so...

  • Article
  • Open Access
5 Citations
2,230 Views
19 Pages

Photochemistry of β-γ-Unsaturated Spirolactones

  • Werner Fudickar,
  • Melanie Metz,
  • Tobias Krüger-Braunert,
  • Alexandra Kelling,
  • Eric Sperlich,
  • Pablo Wessig and
  • Torsten Linker

17 October 2023

β-γ-unsaturated spirolactones are easily available by Birch reduction. We describe their photochemistry in the presence of or without carbonyl compounds. The spirolactones show a distinct absorption band at 230 nm, which is not present in...

  • Article
  • Open Access
10 Citations
4,265 Views
18 Pages

Photocatalytic Degradation of Methylene Blue by Magnetic Opal/Fe3O4 Colloidal Crystals under Visible Light Irradiation

  • Abraham Jorge Carmona-Carmona,
  • Enrique Sánchez Mora,
  • Jesús Ivan Peña Flores,
  • César Márquez-Beltrán,
  • María Dolores Castañeda-Antonio,
  • Marlén Alexis González-Reyna,
  • María Concepción Barrera,
  • Khashayar Misaghian,
  • Jesús Eduardo Lugo and
  • Miller Toledo-Solano

8 October 2023

In this study, opal–magnetite photocatalysts based on SiO2 artificial opal crystals infiltrated with different concentrations of Fe3O4 nanoparticles (NPs) were synthesized using a combination of lateral infiltration and co-assembly methods. By...

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Photochem - ISSN 2673-7256