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Article

The Manufacture of Lake Pigments from Artificial Colours: Investigating Chemistry and Recipes in the First Book on Synthetic Dyes-Based Lakes

1
Kremer Pigmente, 88317 Aichstetten, Germany
2
Department of Chemistry and Industrial Chemistry, University of Pisa, 56124 Pisa, Italy
3
Department of Earth and Environmental Sciences, University of Milano-Bicocca, 20126 Milan, Italy
4
Consiglio Nazionale delle Ricerche (CNR), Istituto di Chimica dei Composti Organometallici, SS di Pisa, 56124 Pisa, Italy
5
Department of Chemistry, Boston University, Boston, MA 02215, USA
*
Authors to whom correspondence should be addressed.
The author has been retired from Boston University as a Professor Emeritus.
Heritage 2025, 8(7), 245; https://doi.org/10.3390/heritage8070245
Submission received: 30 April 2025 / Revised: 17 June 2025 / Accepted: 18 June 2025 / Published: 24 June 2025
(This article belongs to the Special Issue Dyes in History and Archaeology 43)

Abstract

In 1900, Francis Herbert Jennison’s book The Manufacture of Lake Pigments from Artificial Colours was published in London. In the early 20th century, the technical literature focussing on synthetic dyes mainly dealt with their use for dyeing. Conversely, the literature on lake pigment manufacture is less comprehensive, and Jennison’s publication was the first monograph on this topic. His book comprises descriptions of the dyes, substrates, and various methods for lake making. Practical examples complete the work: sixteen colour plates with original samples of lake pigments showcase the practical effect on colour of the different dyes and preparation methods. Herein, we present an overview of the context of Jennison’s research and delve into a selection of formulations. Green lake pigment plates were sampled and analysed by liquid chromatography coupled with spectroscopic and spectrometric detectors and by X-ray fluorescence spectroscopy to correlate the chemical composition with the recipes reported in the book. Seldom or no longer used and unexplored historical dyes were detected, along with polyphenolic compounds possibly used as precipitating agents in lake pigment formulations. Moreover, the examination of two different editions of the Jennison manuscript (i.e., the English and German books) revealed different chemical profiles corresponding to the same lake pigment formulation. This emphasizes the significance of Jennison’s book, confirming how understanding of early formulations is needed to elucidate the later ones.
Keywords: lake pigments; synthetic dyes; tannins; historical sources; Jennison; LC-DAD-MS/MS lake pigments; synthetic dyes; tannins; historical sources; Jennison; LC-DAD-MS/MS

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MDPI and ACS Style

Eis, E.; Ferretti, A.; Sabatini, F.; Corona, V.; Legnaioli, S.; Laursen, R.; Degano, I. The Manufacture of Lake Pigments from Artificial Colours: Investigating Chemistry and Recipes in the First Book on Synthetic Dyes-Based Lakes. Heritage 2025, 8, 245. https://doi.org/10.3390/heritage8070245

AMA Style

Eis E, Ferretti A, Sabatini F, Corona V, Legnaioli S, Laursen R, Degano I. The Manufacture of Lake Pigments from Artificial Colours: Investigating Chemistry and Recipes in the First Book on Synthetic Dyes-Based Lakes. Heritage. 2025; 8(7):245. https://doi.org/10.3390/heritage8070245

Chicago/Turabian Style

Eis, Eva, Adele Ferretti, Francesca Sabatini, Valentina Corona, Stefano Legnaioli, Richard Laursen, and Ilaria Degano. 2025. "The Manufacture of Lake Pigments from Artificial Colours: Investigating Chemistry and Recipes in the First Book on Synthetic Dyes-Based Lakes" Heritage 8, no. 7: 245. https://doi.org/10.3390/heritage8070245

APA Style

Eis, E., Ferretti, A., Sabatini, F., Corona, V., Legnaioli, S., Laursen, R., & Degano, I. (2025). The Manufacture of Lake Pigments from Artificial Colours: Investigating Chemistry and Recipes in the First Book on Synthetic Dyes-Based Lakes. Heritage, 8(7), 245. https://doi.org/10.3390/heritage8070245

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