Polarization Parameters and Scaling Matter—How Processing Environment and Shape Factor Influence Electroactive Nanocomposite Characteristics

Polymeric-ceramic smart nanocomposite piezoelectric and dielectric materials are of interest due to their superior mechanical flexibility and ability to leverage characteristics of constituent materials. A great deal of work has centered on development of processes for manufacturing 0–3 continuity composite piezoelectric materials that vary in scale ranging from bulk, thick and thin film to nanostructured films. Less is known about how material scaling effects the effectiveness of polarization and electromechanical properties. This study elucidates how polarization parameters: contact versus corona, temperature and electrical voltage field influence the piezoelectric and dielectric properties of samples as a function of their shape factor, i.e., bulk versus thick film. Bulk and thick film samples were prepared via sol gel/cast-mold and sol gel/spin coat deposition, for fabrication of bulk and thick films, respectively. It was found that corona polarization was more effective for both bulk and thick film processes and that polarization temperature produced higher normalized changes in samples. Although higher electric field voltages could be achieved with thicker samples, film samples responded the most to coupled increases in temperature and electrical voltage than bulk samples.