Estimation of Water Balance and Nitrate Load in the Upper Basin of Aguascalientes, Mexico, Using SWAT
Abstract
1. Introduction
2. Materials and Methods
2.1. Study Area
2.2. Hydrological Model
2.2.1. Input Data
2.2.2. Model Evaluation
2.3. Statistical Analysis of Empirical Data
2.4. Geospatial Modeling and Nitrate Leaching Risk Assessment
2.4.1. Geocoding and Data Processing
2.4.2. Potential Nitrate Leaching Risk Index IRPN
2.4.3. Multivariate Analysis: MCA and HCPC
2.4.4. Validation and Stability of the Multivariate Structure and IRPN Interpretation
3. Results
3.1. Model Assessment
3.2. Water Balance and Surface Runoff
3.3. Quantification of Intensive Agrochemical Management and Nitrogen Loading Regimes
3.4. Spatial Distribution of Nitrate Loads and Monitoring Network Design
3.5. Temporal Dynamics and Hydrological Response
4. Discussion
4.1. Effect of Forcing Data on Water Balance Simulation
4.2. Sources of Uncertainty and Model Limitations
4.3. Scale-Dependent Hydrological Response
4.4. Agricultural Drivers and the Potential Nitrate Leaching Risk Index
4.5. Social Impact and Policy Implications
4.6. Management Implications
5. Conclusions
Supplementary Materials
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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| Risk Contribution | Management Variable | |
|---|---|---|
| High | 0.345 | Fertilizer Type |
| High | 0.345 | Fertilizer Application Rate |
| Moderate | 0.145 | Irrigation Method |
| Low | 0.075 | Crop Type |
| Low | 0.05 | Fertilizer Application Frequency |
| Negligible | 0.015 | Potassium Source |
| Negligible | 0.015 | Potassium Application Rate |
| Negligible | 0.01 | Potassium Application Frequency |
| Null | 0 | Cultivated Area |
| Statistical Interpretation Criteria | R Package v 4.5.0/ Formula | Objective | Method | Validation Indicator |
|---|---|---|---|---|
| Statistical Interpretation Criteria | FactoMineR (v2.11) | Quantify total variance explained by principal dimensions. | MCA | Explained Inertia |
| Higher inertia indicates better capture of variable associations [37]. | FactoMineR (v2.11) | Identify influential categories for axis construction. | MCA | Variable Contributions |
| High contributions indicate key drivers in axis formation [37]. | FactoMineR (v2.11) | Measure representation quality of variables on axes. | MCA | Squared Cosine (cos2) |
| indicates reliable representation [39]. | Test global dependence between variables. | MCA | Global Chi-squared | |
| justifies MCA application [40]. | FactoMineR (v2.11) | Measure quality of observation projection. | MCA | Individual (cos2) |
| indicates strong representation of individuals [40]. | FactoMineR (v2.11) | Assess robustness to subsampling. | MCA | Cross-validation |
| Correlations > 0.85 suggest robust factor structure [40]. | FactoMineR (v2.11) + cluster | Test clustering reproducibility under resampling. | HCPC | Bootstrap + ARI |
| ARI > 0.6 validates clustering stability [41]. | Cluster | Evaluate cluster compactness and separation. | HCPC | Average Silhouette |
| Period | R2 | NSE | PBIAS (%) | RSR |
|---|---|---|---|---|
| Calibration (2021–2022) | 0.88 | 0.87 | −13.23 | 0.34 |
| Validation (2023–2024) | 0.95 | 0.76 | −58.78 | 0.48 |
| Parameter | Rio Verde Grande Basin | El Niágara Dam |
|---|---|---|
| Peak precipitation (mmd−1) | 6 | 5.8 mm |
| Peak runoff (mmd−1) | 2.4 mm | 2.8 mm |
| Peak evapotranspiration (mmd−1) | 2.7 mm | 2.9 mm |
| Max. Lateral flow (Latq) (mmd−1) | 0.15 | 0 |
| Hydrological response | Moderate | Rapid and intense |
| Fertilizers | Amount (kg ha−1 per Application) | Application (Year) | N Concentration g kg−1 | Total N (kg N ha−1 Year−1 *) |
| Phosphonitrate | 527.8 | 5.83 | 330 | 1015.4 |
| Ammonium phosphate (MAP) | 494.6 | 7.25 | 110 | 398.8 |
| Urea | 278.7 | 2.96 | 460 | 379.5 |
| Herbicides | Amount (kg ha−1 per Application) | Application (Year) | Active Ingredient g L−1 | Total Active Ingredient ** g ha−1 Year−1 |
| Mesotrione | 3.20 | 1.10 | 480 | 8.5 |
| Acetochlor | 2.80 | 1.20 | 900 | 15.12 |
| Insecticides | Amount (kg ha−1 per Application) | Application (Year) | Active Ingredient g L−1 | Total Active Ingredient g ha−1 Year−1 |
| Spinosyns | 6.20 | 3.10 | 240 | 22.32 |
| Chlorantraniliprole | 3.10 | 2.20 | 200 | 7.0 |
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Santiago-Ayala, V.H.; Corrales-Suastegui, A.; Avalos-Cueva, D.; Hernández-Amparan, S.; Monzon, C.O.; Martínez-Calderón, V.M.; Verduzco-Grajeda, L.E. Estimation of Water Balance and Nitrate Load in the Upper Basin of Aguascalientes, Mexico, Using SWAT. Hydrology 2026, 13, 105. https://doi.org/10.3390/hydrology13040105
Santiago-Ayala VH, Corrales-Suastegui A, Avalos-Cueva D, Hernández-Amparan S, Monzon CO, Martínez-Calderón VM, Verduzco-Grajeda LE. Estimation of Water Balance and Nitrate Load in the Upper Basin of Aguascalientes, Mexico, Using SWAT. Hydrology. 2026; 13(4):105. https://doi.org/10.3390/hydrology13040105
Chicago/Turabian StyleSantiago-Ayala, Victor Hugo, Arturo Corrales-Suastegui, David Avalos-Cueva, Saúl Hernández-Amparan, Cesar O. Monzon, Víctor Manuel Martínez-Calderón, and Lidia Elizabeth Verduzco-Grajeda. 2026. "Estimation of Water Balance and Nitrate Load in the Upper Basin of Aguascalientes, Mexico, Using SWAT" Hydrology 13, no. 4: 105. https://doi.org/10.3390/hydrology13040105
APA StyleSantiago-Ayala, V. H., Corrales-Suastegui, A., Avalos-Cueva, D., Hernández-Amparan, S., Monzon, C. O., Martínez-Calderón, V. M., & Verduzco-Grajeda, L. E. (2026). Estimation of Water Balance and Nitrate Load in the Upper Basin of Aguascalientes, Mexico, Using SWAT. Hydrology, 13(4), 105. https://doi.org/10.3390/hydrology13040105

