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Processes 2019, 7(3), 140;

On the Use of Starch in Emulsion Polymerizations

Department of Chemical and Biological Engineering, Centre for Catalysis Research and Innovation, University of Ottawa, 161 Louis Pasteur Private, Ottawa, ON K1N 6N5, Canada
Department of Chemical Engineering, McMaster University, 1280 Main Street West, Hamilton, ON L8S 4L7, Canada
Department of Chemical Engineering, Queens University, 19 Division Street, Kingston, ON K7L 3N6, Canada
Author to whom correspondence should be addressed.
Received: 17 January 2019 / Revised: 14 February 2019 / Accepted: 28 February 2019 / Published: 6 March 2019
(This article belongs to the Special Issue Renewable Polymers: Processing and Chemical Modifications)
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The substitution of petroleum-based synthetic polymers in latex formulations with sustainable and/or bio-based sources has increasingly been a focus of both academic and industrial research. Emulsion polymerization already provides a more sustainable way to produce polymers for coatings and adhesives, because it is a water-based process. It can be made even more attractive as a green alternative with the addition of starch, a renewable material that has proven to be extremely useful as a filler, stabilizer, property modifier and macromer. This work provides a critical review of attempts to modify and incorporate various types of starch in emulsion polymerizations. This review focusses on the method of initiation, grafting mechanisms, starch feeding strategies and the characterization methods. It provides a needed guide for those looking to modify starch in an emulsion polymerization to achieve a target grafting performance or to incorporate starch in latex formulations for the replacement of synthetic polymers. View Full-Text
Keywords: Starch; graft; polymerization; emulsion; polysaccharide Starch; graft; polymerization; emulsion; polysaccharide

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Cummings, S.; Zhang, Y.; Smeets, N.; Cunningham, M.; Dubé, M.A. On the Use of Starch in Emulsion Polymerizations. Processes 2019, 7, 140.

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