Development of Microstructured Carbon Coatings by Substrate-Catalytic CVD
Abstract
:1. Introduction
2. Materials and Methods
2.1. Sample Preparation
2.2. Sample Characterization
3. Results
3.1. Surface Morphology
3.1.1. Effect of the Stainless Steel Surface Roughness
3.1.2. Effect of the CVD Process Duration
3.1.3. Effect of the Temperature during CVD
3.2. Electrochemical Characterization
4. Discussion
5. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Band | D | G | D’ | 2D | D+D’ | – | – | |||||
---|---|---|---|---|---|---|---|---|---|---|---|---|
Temp | xc | FWHM | xc | FWHM | xc | FWHM | xc | FWHM | xc | FWHM | ID/IG | ID/ID’ |
500 | 1354.2 | 40.4 | 1582.8 | 32.0 | 1620.3 | 20.0 | 2706.3 | 58.9 | 2944.6 | 70.9 | 1.18 | 5.8 |
600 | 1356.1 | 27.8 | 1581.3 | 16.6 | 1622.9 | 6.7 | 2708.6 | 42.0 | 2968.0 | 34.9 | 0.43 | 4.0 |
700 | 1353.0 | 30.0 | 1580.8 | 17.9 | 1622.0 | 9.3 | 2710.8 | 46.4 | 2948.7 | 60.0 | 0.47 | 4.5 |
CμS | 1335.2 | 158.4 | 1578.8 | 62.0 | 1620.0 | 27.3 | 2708.2 | 227.4 | 2903.0 | 248.6 | 1.46 | 4.8 |
Parameter | SS | CNC-500 °C | CNC-600 °C | CNC-700 °C |
---|---|---|---|---|
C2/µF·cm−2 | 5.9 | 7.8 | 8.2 | 3.9 |
R2/Ω·cm2 | 926 | 1216 | 1314 | 2117 |
Q3/Ω−1·cm−2 sn | 2.7 × 10−5 | 1.1 × 10−4 | 2.5 × 10−5 | 6.3 × 10−6 |
n3 | 0.84 | 0.79 | 0.87 | 0.89 |
R3/Ω·cm2 | 3.61 × 106 | 3.33 × 105 | 1.50 × 106 | 1.18 × 107 |
Parameter | SS | CNC-500 °C | CNC-700 °C |
---|---|---|---|
Ecorr/mV | −115.6 | −104.6 | −11.9 |
Icorr/nA·cm−2 | 40.8 | 361.8 | 4.4 |
βa/mV | 151.0 | 1151.4 | 272.7 |
βc/mV | 39.2 | 79.50 | 83.4 |
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Pierpaoli, M.; Sawczak, M.; Dettlaff, A. Development of Microstructured Carbon Coatings by Substrate-Catalytic CVD. Coatings 2021, 11, 1403. https://doi.org/10.3390/coatings11111403
Pierpaoli M, Sawczak M, Dettlaff A. Development of Microstructured Carbon Coatings by Substrate-Catalytic CVD. Coatings. 2021; 11(11):1403. https://doi.org/10.3390/coatings11111403
Chicago/Turabian StylePierpaoli, Mattia, Mirosław Sawczak, and Anna Dettlaff. 2021. "Development of Microstructured Carbon Coatings by Substrate-Catalytic CVD" Coatings 11, no. 11: 1403. https://doi.org/10.3390/coatings11111403